CN104585245B - One kind compounding molluscicide - Google Patents
One kind compounding molluscicide Download PDFInfo
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- CN104585245B CN104585245B CN201510025184.1A CN201510025184A CN104585245B CN 104585245 B CN104585245 B CN 104585245B CN 201510025184 A CN201510025184 A CN 201510025184A CN 104585245 B CN104585245 B CN 104585245B
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- molluscicide
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Abstract
The present invention relates to one kind to compound molluscicide.The compounding molluscicide is to be compounded using emamectin-benzoate and tea seed cake powder as the two-spot that active ingredient is carried out, and the mass ratio of the active ingredient emamectin-benzoate and tea seed cake powder is 1:10‑10:1.Present invention compounding molluscicide has significant prevention effect to Pomacea canaliculata.
Description
Technical field
The invention belongs to pesticides application technical field, be related to a kind of compounding molluscicide, it is specifically a kind of by effectively into
The molluscicide for dividing emamectin-benzoate and tea seed cake powder to be compounded.
Background technology
Being presently used for the pesticide control of rice field Pomacea canaliculata, mainly to have 50% niclosamide wettable powder, 70,%00 spiral shell to kill wettable
Property pulvis, 6% close naturally kill spiral shell thing up to the chemical agent such as granule and 90% copper sulfate crystal and pulverized limestone and Magnesium Borate Ore Powder etc.
Matter.Toxicity of the spiral shell medicine to aquatiles such as mammal and fish is killed in order to reduce chemistry, the molluscicidal effect of spiral shell medicament is killed in increase
And security, what is extracted from plant is studied killing spiral shell active ingredient, and it is Phytolacca acinosa successively to kill including property of spiral shell power by it
Section, Mimosaceae, polygonaceae, Verenaceae, Caesalpiniaceae, Euphorbiaceae.The plant of these sections or its extract, which kill spiral shell thing and can be used as, to be changed
Molluscacide synergist is learned, it is increased molluscicidal effect in the case where reducing the dosage of molluscacide, eliminates or reduces and kill spiral shell
Pollution of the medicine to environment and the murder by poisoning to poultry, animals and plants.But the non-popularization and application of plant molluscicide, subject matter are effective
Composition content in plant is not high, and usage amount is too big, expense is too high.Next to that influence factor is more, performance is unstable.
Chemistry or plant molluscacide is used in combination to strengthen the relevant report of the research for spiral shell effect of going out, primarily directed to chlorine nitre
Willow amine is compounded or mixture.Existing formula has niclosamidum and bromine second phthalein amine compound, and there is solution to kill spiral shell ovum effect；It is pungent
Sulphur phosphorus and niclosamidum compounding, have the effect for improving snail killing function and reducing toxicity.Learn, yet there are no from existing data check
Insecticide to routine compounds with the plant for having bioactivity and is applied to the preventing and treating of Pomacea canaliculata.
Existing molluscicide is still mainly based on traditional chemical molluscicide, external patent report methylamino Avermectin
Plain benzoate is as the pesticide control that can prevent and treat harmful aquatic organisms；The country, which yet there are no conventional insecticide and apply, to be prevented and treated
On Pomacea canaliculata.Although reporting many biological species for having ovicidal trait, relevant biological species molluscicide is not converted to just
Formula production.
The content of the invention
The main object of the present invention is to provide a kind of has synergistic effect, the compounding small to environmental disruption to kill to Pomacea canaliculata
Spiral shell agent, solved it is long-term using single chemical molluscicide cause formulation rate is big, cost accounting is high, polluted water, preventing and treating imitate
The problem of fruit is poor, preventing and treating is not thorough, Pomacea canaliculata gradually increases the resistance to the action of a drug of medicament, difficulty of prevention and cure increase.
The technical scheme is that：
One kind compounding molluscicide, it is characterised in that described to kill active ingredient emamectin benzoate benzene first in spiral shell composition
The mass ratio of hydrochlorate and tea seed cake powder is 1:10-10:1.
Preferably, the mass ratio of emamectin-benzoate and tea seed cake powder is in the compounding molluscicide：2：
8。
Preferably, the quality of the compounding molluscicide active ingredient emamectin-benzoate and tea seed cake powder accounts for
The 1-80% of spiral shell composition gross mass is killed, remaining is the auxiliary element for allowing to use in agricultural chemicals.
Preferably, allow the auxiliary element that uses in the agricultural chemicals by solvent, cosolvent, emulsifying agent, wetting agent, scattered
One or more of compositions in agent, thickener, antifreezing agent, carrier and disintegrant.
Preferably, the solvent is esters or sulfone class, the cosolvent is ketone or higher alcohol, the emulsifying agent, profit
Humectant, dispersant are nonionic surfactant or anion surfactant, the thickener be xanthans, Arabic gum,
Magnesiumaluminumsilicate and polyvinyl alcohol, the antifreezing agent are polyalcohol, and the carrier is white carbon, kaolin or diatomite, described to collapse
Solution agent is ammonium sulfate, sodium chloride or ammonium sulfate.
Preferably, the esters are sec-butyl acetate and ethyl acetate；Sulfone class is dimethyl sulfoxide (DMSO)；The ketone is ring
Hexanone and N- pyrrolidones；Higher alcohol is n-butanol；The nonionic surfactant is castor oil polyoxyethylene ether, nonyl phenol
APEO, styryl phenyl polyoxyethylene poly-oxygen propylene aether, aliphatic alcohol polyethenoxy polyoxypropylene graft copolymer, three
Styryl phenyl APEO and calcium dodecyl benzene sulfonate castor oil polyoxyethylene ether；Anion surfactant is ten
Dialkyl benzene sulfonic acids calcium, sodium lignin sulfonate lauryl sodium sulfate, thermally coupled distillation columns and fatty alcohol polyoxy
Ethene ether phosphate ammonium salt；The polyalcohol is ethylene glycol, glycerine and propane diols.
Preferably, the compounding molluscicide is prepared into aqueous emulsion, microemulsion, suspending agent, wettable powder or moisture and dissipated
Granula.
In addition, the purposes the invention also discloses above-mentioned compounding molluscicide in Pomacea canaliculata is prevented and treated.
Compared with prior art, the beneficial effects of the invention are as follows：
1st, compounding molluscicide of the invention has obvious synergistic effect.Illustrate, by this formula compounding, to carry out Pomacea canaliculata
During preventing and treating, compared with using single pesticide control, can reach and reduce dosage, reduce cost accounting.
2nd, one of active ingredient of the invention tea seed cake powder is remaining slag after the oil expression of Wild camellia seed oil fruit, is that a kind of processing is secondary
Product, environment is not polluted, and easy a large amount of acquisitions, abundance, and solve tea seed cake powder and add as a kind of
The problem of work byproduct.
Embodiment
The present invention is described in detail its advantage with specific examples below.
First, indoor virulence test determines
1st, determination of activity is carried out to Pomacea canaliculata using the different modes of action and different types of medicament, test method is using leaching
Spiral shell method is carried out；Virulence of 14 kinds of medicaments to Pomacea canaliculata is determined altogether, is filtered out to Pomacea canaliculata activity height and to ecological environment
Two kinds of friendly medicaments, by LC50Size, having filtered out chemical agent has tea seed cake powder and emamectin-benzoate,
Two kinds of medicament LC50Respectively 0.4611mg/L and 0.7355mg/L, virulence regression equation be respectively y=7.1746+6.4676x and y=
It is 5.1836+1.3762x high to the bioactivity of Pomacea canaliculata.
2nd, tea seed cake powder and emamectin-benzoate are interacted into determination method with the use of tea seed cake powder respectively to be matched
Screening, filters out the compounded combination high to Pomacea canaliculata bioactivity；The LC of each single dose is obtained in indoor bioassay method50It is worth and is
Basis, 9 concentration gradients and blank control are set（It is shown in Table 1）.
Test data is analyzed with DPS statistical analysis softwares, calculates the LC50 of each medicament, to evaluate each medicament
Insecticidal activity.And the co-toxicity coefficient of mixture is calculated according to the abundant methods of Sun Yun（CTC values）.
Survey toxicity index（ATI）=（Standard agent LC50/ reagent agents LC50）×100.
Theoretical toxicity index（TTI）A percentage composition+B medicament toxicity index in=A medicament toxicity index × mixture × mixed
B percentage composition in agent.
Co-toxicity coefficient（CTC）=[mixture surveys toxicity index（ATI）/ mixture theoretical toxicity index（TTI）] ×100.
The criteria for classifying is acted on according to NY/T1154.13-2008 insecticide combinations：Co-toxicity coefficient（CTC）>=120 show as increasing
Effect acts on；Co-toxicity coefficient（CTC）≤ 80 show as antagonism；80<Co-toxicity coefficient（CTC）<120 show as summation action.
The indoor joint toxicity measuring of the emamectin benzoate of table 1 and tea seed cake powder to Pomacea canaliculata
Note：Emamectin benzoate is the abbreviation of emamectin-benzoate.
Toxicity Determination result shows：The mass ratio of emamectin benzoate and tea seed cake powder is 10 in said composition:1-1:10 scopes
Interior, co-toxicity coefficient is all higher than 120, i.e. said composition shows as synergistic effect to Pomacea canaliculata bioactivity；Especially emamectin benzoate and
Tea seed cake powder is mass ratio 2:When 8, co-toxicity coefficient 262.91, synergistic effect becomes apparent from.
2nd, agricultural chemicals prepares embodiment
Embodiment 1：1% emamectin benzoate tea seed cake powder aqueous emulsion
Emamectin benzoate（Active ingredient） 0.1%
Tea seed cake powder（Active ingredient） 0.9%
Tristyrylphenyl APEO（Emulsifying agent） 1%
Castor oil polyoxyethylene ether（Emulsifying agent） 3%
Aliphatic alcohol polyethenoxy polyoxypropylene graft copolymer（Dispersant） 1.5%
Styryl phenyl polyoxyethylene poly-oxygen propylene aether（Wetting agent） 2%
Sec-butyl acetate（Solvent） 13%
Glycerine（Antifreezing agent） 3%
Water（Solvent）Complement to 100%
Embodiment 2：10% emamectin benzoate tea seed cake powder aqueous emulsion
Emamectin benzoate（Active ingredient） 1%
Tea seed cake powder（Active ingredient） 9%
Calcium dodecyl benzene sulfonate castor oil polyoxyethylene ether（Emulsifying agent） 1%
NPE（Wetting agent） 1%
Castor oil polyoxyethylene ether（Emulsifying agent） 1%
Thermally coupled distillation columns（Emulsifying agent） 2%
Cyclohexanone（Cosolvent） 11%
Sec-butyl acetate（Solvent） 20%
Glycerine（Antifreezing agent） 2%
Water（Solvent）Complement to 100%
Embodiment 3：15% emamectin benzoate tea seed cake powder aqueous emulsion
Emamectin benzoate（Active ingredient） 3.0%
Tea seed cake powder（Active ingredient） 12%
Tristyrylphenyl APEO（Emulsifying agent） 1%
NPE（Wetting agent） 1%
Aliphatic alcohol polyethenoxy polyoxypropylene graft copolymer（Dispersant） 1%
Styryl phenyl polyoxyethylene poly-oxygen propylene aether（Emulsifying agent） 2%
Cyclohexanone（Cosolvent） 6%
Sec-butyl acetate（Solvent） 18%
Glycerine（Antifreezing agent） 2.0%
Water（Solvent）Complement to 100%
The preparation method of aqueous emulsion is described in 3 embodiments of the above：By active ingredient emamectin benzoate and tea seed cake powder solvent,
After cosolvent fully dissolves, input emulsifying agent, dispersant, wetting agent form oil phase after being sufficiently stirred；Antifreezing agent is added to the water
Dissolving, form aqueous phase；Aqueous phase is slowly added in oil phase, sheared using high-speed shearing machine, you can obtains aqueous emulsion.
Embodiment 4：5% emamectin benzoate tea seed cake powder microemulsion
Emamectin benzoate（Active ingredient） 1%
Tea seed cake powder（Active ingredient） 4%
Tristyrylphenyl APEO（Emulsifying agent） 7%
Styryl phenyl polyoxyethylene polystyrene ether（Emulsifying agent） 8%
Calcium dodecyl benzene sulfonate（Emulsifying agent） 5%
Dimethyl sulfoxide (DMSO)（Cosolvent） 5%
Sec-butyl acetate（Solvent） 6%
N- pyrrolidones（Cosolvent） 12%
Ethylene glycol（Antifreezing agent） 3%
Water（Solvent）Complement to 100%
Embodiment 5：8% emamectin benzoate tea seed cake powder microemulsion
Emamectin benzoate（Active ingredient） 0.8%
Tea seed cake powder（Active ingredient） 7.2%
Styryl phenyl polyoxyethylene polystyrene ether 5%
Tristyrylphenyl APEO 6%
Calcium dodecyl benzene sulfonate 6%
Cyclohexanone（Cosolvent） 10%
N-butanol（Cosolvent） 5%
Sec-butyl acetate（Solvent） 5%
Water（Solvent）Complement to 100%
Embodiment 6：16% emamectin benzoate tea seed cake powder microemulsion
Emamectin benzoate（Active ingredient） 2%
Tea seed cake powder（Active ingredient） 14%
Tristyrylphenyl APEO（Emulsifying agent） 7%
NPE（Emulsifying agent） 3%
Calcium dodecyl benzene sulfonate（Emulsifying agent） 7%
Ethyl acetate（Solvent） 12%
N-butanol（Cosolvent） 5%
Sec-butyl acetate（Solvent） 5%
Water（Solvent）Complement to 100%
The preparation method of microemulsion is described in 3 embodiments of the above：By active component emamectin benzoate and tea seed cake powder solvent,
After cosolvent fully dissolves, emulsifying agent is put into, oil phase is formed after being sufficiently stirred；Antifreezing agent is added to the water to obtain aqueous phase；By water
Mutually it is slowly added in oil phase, is sheared using high-speed shearing machine, you can obtains transparent microemulsion.
Embodiment 7：20% emamectin benzoate tea seed cake powder suspending agent
Emamectin benzoate（Active ingredient） 15%
Tea seed cake powder（Active ingredient） 5.0%
Aliphatic alcohol polyoxyvinethene phosphate ammonium salt（Dispersant） 4%
NPE（Wetting agent） 1%
Aluminium-magnesium silicate（Thickener） 1%
Xanthans（Thickener） 0.5%
Ethylene glycol（Antifreezing agent） 2.5%
Water（Solvent）Complement to 100%
Embodiment 8：30% emamectin benzoate tea seed cake powder suspending agent
Emamectin benzoate（Active ingredient） 10%
Tea seed cake powder（Active ingredient） 20%
Aliphatic alcohol polyethenoxy polyoxypropylene graft copolymer（Dispersant） 1%
Thermally coupled distillation columns（Wetting agent） 1%
Castor oil polyoxyethylene ether（Dispersant） 2%
Polyvinyl alcohol（Thickener） 2.5%
Arabic gum（Thickener） 0.5%
Ethylene glycol（Antifreezing agent） 3%
Water（Solvent）Complement to 100%
Embodiment 9：50% emamectin benzoate tea seed cake powder suspending agent
Emamectin benzoate（Active ingredient） 5.0%
Tea seed cake powder（Active ingredient） 45%
Aliphatic alcohol polyethenoxy polyoxypropylene graft copolymer（Dispersant） 1%
Thermally coupled distillation columns（Wetting agent） 1%
Aluminium-magnesium silicate（Thickener） 1%
Ethylene glycol（Antifreezing agent） 1%
Water（Solvent）Complement to 100%
The preparation method of suspending agent is described in 3 embodiments of the above：Active component emamectin benzoate and tea seed cake powder are used into gas
After flowing pulverizer crushing, put into stirred tank, while put into dispersant, wetting agent, antifreezing agent and water, after being sufficiently stirred, by thing
Material is pumped into sand mill and is fully ground, and after the completion of grinding, is pumped into high-speed shearing machine, after adding thickener, carries out at a high speed
Shearing, suspending agent is made after the completion of shearing.
Embodiment 10：50% emamectin benzoate tea seed cake powder wettable powder
Emamectin benzoate（Active ingredient） 25%
Tea seed cake powder（Active ingredient） 25%
Sodium lignin sulfonate（Dispersant） 8%
Lauryl sodium sulfate（Wetting agent） 2%
White carbon（Carrier） 8%
Kaolin（Carrier）Complement to 100%
Embodiment 11：60% emamectin benzoate tea seed cake powder wettable powder
Emamectin benzoate（Active ingredient） 10%
Tea seed cake powder（Active ingredient） 50%
Sodium lignin sulfonate（Dispersant） 8%
Lauryl sodium sulfate（Wetting agent） 2%
White carbon（Carrier） 5%
Diatomite（Carrier）Complement to 100%
Embodiment 12：80% emamectin benzoate tea seed cake powder wettable powder
Emamectin benzoate（Active ingredient） 20%
Tea seed cake powder（Active ingredient） 60%
Sodium lignin sulfonate（Dispersant） 9%
Lauryl sodium sulfate（Wetting agent） 2%
White carbon（Carrier）Complement to 100%
The preparation method of wettable powder is described in 3 embodiments of the above：By formula rate, by active ingredient and preparation
Auxiliary element is well mixed, and is crushed through airslide disintegrating mill, remixes uniformly, that is, wettable powder is made.
5th, moisture dissipates the preparation of granular agent
Embodiment 13：25% emamectin benzoate tea seed cake powder water dispersible granules
Emamectin benzoate（Active ingredient） 5%
Tea seed cake powder（Active ingredient） 20%
Sodium lignin sulfonate（Dispersant） 3.2%
Lauryl sodium sulfate（Wetting agent） 6.3%
Ammonium sulfate（Disintegrant） 15%
Kaolin（Carrier）Complement to 100%
Embodiment 14：50% emamectin benzoate tea seed cake powder water dispersible granules
Emamectin benzoate（Active ingredient） 10%
Tea seed cake powder（Active ingredient） 40%
Sodium lignin sulfonate（Dispersant） 3.0%
Lauryl sodium sulfate（Wetting agent） 5.0%
Ammonium sulfate（Disintegrant） 14%
Kaolin（Carrier）Complement to 100%
Embodiment 15：70% emamectin benzoate tea seed cake powder water dispersible granules
Emamectin benzoate（Active ingredient） 10%
Tea seed cake powder（Active ingredient） 60%
Sodium lignin sulfonate（Dispersant） 4.2%
Lauryl sodium sulfate（Wetting agent） 5.5%
Sodium chloride（Disintegrant） 10%
Diatomite（Carrier）Complement to 100%
The preparation method of water dispersible granules is described in 3 embodiments of the above：By formula rate, by active ingredient and preparation
After auxiliary element is well mixed, crushes through airslide disintegrating mill, be well mixed again, then, add a certain amount of water and mix this
Thing is mediated, extruder grain, is sieved through drying, that is, is obtained water dispersible granules.
The description of the foregoing specific illustrative embodiment to the present invention is to illustrate and the purpose of illustration.These descriptions
It is not wishing to limit the invention to disclosed precise forms, and it will be apparent that according to above-mentioned teaching, can be much changed
And change.The purpose of selecting and describing the exemplary embodiment is that explain that the certain principles of the present invention and its reality should
With so that those skilled in the art can realize and utilize the present invention a variety of exemplaries and
Various chooses and changes.The scope of the present invention is intended to be limited by claims and its equivalents.
Claims (7)
1. one kind compounding molluscicide, it is characterised in that：Active ingredient emamectin benzoate benzoic acid in the compounding molluscicide
The mass ratio of salt and tea seed cake powder is 2:8.
2. molluscicide is compounded according to claim 1, it is characterised in that：The compounding molluscicide active ingredient methylamino AVM hereinafter
The quality of rhzomorph benzoate and tea seed cake powder accounts for the 1-80% for killing spiral shell composition gross mass, and remaining is auxiliary to allow to use in agricultural chemicals
Co-ingredients.
3. molluscicide is compounded according to claim 2, it is characterised in that：The auxiliary element for allowing to use in the agricultural chemicals is by molten
One or more of compositions in agent, cosolvent, emulsifying agent, wetting agent, dispersant, thickener, antifreezing agent, carrier and disintegrant.
4. molluscicide is compounded according to claim 3, it is characterised in that：The solvent is esters or sulfone class, the cosolvent
For ketone or higher alcohol, the emulsifying agent, wetting agent, dispersant are nonionic surfactant or anion surfactant,
The thickener is xanthans, Arabic gum, Magnesiumaluminumsilicate and polyvinyl alcohol, and the antifreezing agent is polyalcohol, and the carrier is
White carbon, kaolin or diatomite, the disintegrant are ammonium sulfate or sodium chloride.
5. molluscicide is compounded according to claim 4, it is characterised in that：The esters are sec-butyl acetate and ethyl acetate；
Sulfone class is dimethyl sulfoxide (DMSO)；The ketone is cyclohexanone and N- pyrrolidones；Higher alcohol is n-butanol；The non-ionic surface is lived
Property agent be castor oil polyoxyethylene ether, NPE, styryl phenyl polyoxyethylene poly-oxygen propylene aether, fatty alcohol
Polyoxyethylene polyoxypropylene graft copolymer, tristyrylphenyl APEO and calcium dodecyl benzene sulfonate castor oil gather
Oxygen vinethene；Anion surfactant is calcium dodecyl benzene sulfonate, sodium lignin sulfonate lauryl sodium sulfate, nonyl phenol
Polyoxyethylene ether phosphate and aliphatic alcohol polyoxyvinethene phosphate ammonium salt；The polyalcohol is ethylene glycol, glycerine and the third two
Alcohol.
6. molluscicide is compounded according to claim 2, it is characterised in that：The compounding molluscicide can be prepared into wettable powder
Or water dispersible granules.
7. purposes of the molluscicide in Pomacea canaliculata is prevented and treated is compounded according to claim 2.
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| CN201510025184.1A CN104585245B (en) | 2015-01-19 | 2015-01-19 | One kind compounding molluscicide |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104920372A (en) * | 2015-05-08 | 2015-09-23 | 天峨县平昌生态农业有限公司 | Acaricidal composition comprising pyriminostrobin and chlorofluorocarbon cyantraniliprole |
| CN105638690B (en) * | 2016-03-09 | 2017-10-24 | 安徽省农业科学院植物保护与农产品质量安全研究所 | A kind of composition pesticide containing emamectin benzoate and niclosamide ethanolamine salt |
| CN108719295A (en) * | 2018-05-19 | 2018-11-02 | 安徽省农业科学院植物保护与农产品质量安全研究所 | A kind of molluscicide composition containing Tea Saponin |
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| CN1669422A (en) * | 2005-03-14 | 2005-09-21 | 武汉绿世纪生物工程有限责任公司 | Methylamino avermectin benzoate water dispersant granule and preparation method thereof |
| WO2008032331A1 (en) * | 2006-09-12 | 2008-03-20 | Himalaya Global Holdings Ltd. | Herbal composition for the prevention of wrinkles and skin disorders, methods of preparing the same and uses thereof |
| CN102775241A (en) * | 2011-05-09 | 2012-11-14 | 深圳诺普信农化股份有限公司 | Granular pesticide fertilizer, and preparation method and application thereof |
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| CN1669422A (en) * | 2005-03-14 | 2005-09-21 | 武汉绿世纪生物工程有限责任公司 | Methylamino avermectin benzoate water dispersant granule and preparation method thereof |
| WO2008032331A1 (en) * | 2006-09-12 | 2008-03-20 | Himalaya Global Holdings Ltd. | Herbal composition for the prevention of wrinkles and skin disorders, methods of preparing the same and uses thereof |
| CN102775241A (en) * | 2011-05-09 | 2012-11-14 | 深圳诺普信农化股份有限公司 | Granular pesticide fertilizer, and preparation method and application thereof |
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