CN104582512A - Fragrance-carrying cigarette constituent member and cigarette containing same - Google Patents
Fragrance-carrying cigarette constituent member and cigarette containing same Download PDFInfo
- Publication number
- CN104582512A CN104582512A CN201380045426.2A CN201380045426A CN104582512A CN 104582512 A CN104582512 A CN 104582512A CN 201380045426 A CN201380045426 A CN 201380045426A CN 104582512 A CN104582512 A CN 104582512A
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- China
- Prior art keywords
- cigarette
- menthol
- tobacco
- spices
- formation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B3/00—Preparing tobacco in the factory
- A24B3/12—Steaming, curing, or flavouring tobacco
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/281—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed
- A24B15/282—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed by indirect addition of the chemical substances, e.g. in the wrapper, in the case
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
- A24B15/302—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances by natural substances obtained from animals or plants
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/002—Cigars; Cigarettes with additives, e.g. for flavouring
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/02—Cigars; Cigarettes with special covers
Abstract
A fragrance-carrying cigarette constituent member characterized in being obtained by: applying a fragrance composition in a sol state to the surface of a cigarette constituent member, the fragrance composition containing a fragrance, water, and a polysaccharide selected from the group consisting carrageenan, gellan gum, and a combination of gellan gum and tamarind gum; then cooling the cigarette constituent member to which the fragrance-carrying composition has been applied to 0 to 40 DEG C to gel the fragrance composition; and thereafter heating and drying the cigarette constituent member to which the fragrance composition has been applied.
Description
Technical field
The present invention relates to a kind of support spices cigarette member of formation and containing its cigarette.
Background technology
Menthols etc. have volatile fragrance component when being added in pipe tobacco with solution state, exist long-time hide put time fragrance component loss, the fragrance response problem that do not continue.In order to solve this problem, existing various report up to now.
As the example configuring fragrance component in combustion section and pipe tobacco or its coil paper coated, existing report in patent document 1 ~ 3.
Patent document 1 discloses the method coated by the spices raw material adding fragrance component in the tridimensional network of dextran molecule on the coil paper of coated tobacco fill material.The cigarette of patent document 1 fragrance component is added the tridimensional network of dextran molecule inner and fixing, keep, therefore, fragrance protectiveness is good.But because fragrance component is present in dextran molecule with less amount (less than 20 % by weight), therefore, when needing the fragrance component of more addition for menthol etc., the cooperation quantitative change of spices raw material in cigarette is many.
Patent document 2 discloses and liquid perfume and carragheen colloidal sol to be mixed and drip in solion (solution containing potassium ion) and prepare granulated gel, it is dry in atmosphere, prepare " stabilisation aromatic substance stable to 180 DEG C " thus.But, the method for patent document 2 owing to making granulated gel dry in atmosphere, therefore, in order to prepare a large amount of raw material needs longer time and larger equipment.
Patent document 3 discloses and makes the slurry drying containing the fragrance components such as menthol and polysaccharide and make the reconstituted tobacco that fragrance component contains with the state coated by the gel of polysaccharide, is added on after its chopping in pipe tobacco.Patent document 3 containing spices reconstituted tobacco due to fragrance component coated by the gel of polysaccharide, therefore, be not easily vaporized, there is higher spices containing ratio.
Prior art document
Patent document
Patent document 1: Japanese Unexamined Patent Publication 9-28366 publication
Patent document 2: Japanese Kohyo 11-509566 publication
Patent document 3: International Publication No. 2009/142159 pamphlet
Summary of the invention
Invent problem to be solved
The present inventor etc. are based on patent document 3, when the chopping thing of the reconstituted tobacco containing spices with higher spices containing ratio is matched with cigarette as tobacco fill material with less amount (such as the mixing ratio of 2 % by weight), notice that the distribution of spices in tobacco rod sometimes can produce inequality.In order to improve this aspect, the object of the invention is to, provide a kind of cigarette member of formation supporting spices, it has higher perfume stable, and spices can be engaged in cigarette equably when being assembled in cigarette.
For solving the technical scheme of problem
The discoveries such as the present inventor, when the slurry containing specific polysaccharide and spices being applied to the cigarette member of formation such as tobacco fill material or tobacco coil paper, higher perfume stable can be obtained, and spices can be engaged in cigarette equably, and the inequality of menthol use level between cigarette can be suppressed, so that complete the present invention.
Namely, according to a first aspect of the invention, a kind of cigarette member of formation supporting spices can be provided, it obtains as follows: the flavor compositions of the collosol state of polysaccharide, spices and water in the surface applications of cigarette member of formation contains the combination being selected from carragheen, gellan gum and gellan gum and tamarind gum, and the cigarette member of formation applying flavor compositions is cooled to 0 ~ 40 DEG C, make flavor compositions gelation, then, the described cigarette member of formation heat drying applying flavor compositions is made.
According to preferred embodiment, the mode that described heat drying remains on 70 ~ 100 DEG C with the surface temperature of described flavor compositions is carried out.
According to concrete embodiment, described cigarette member of formation is tobacco fill material or tobacco coil paper.According to embodiment more specifically, described tobacco fill material is pipe tobacco or reconstituted tobacco.
According to a second aspect of the invention, can provide a kind of containing the cigarette supporting the cigarette member of formation of spices of the present invention.
The effect of invention
The cigarette member of formation supporting spices of the present invention has higher Tibetan and puts fragrance protectiveness, and when being assembled in cigarette, there is the advantage that spices can be engaged in equably in cigarette in (more accurately for being assembled with the position of the cigarette member of formation supporting spices).That is, when using the cigarette member of formation supporting spices of the present invention to manufacture cigarette, the spices skewness in tobacco rod can be suppressed.Therefore, use the cigarette supporting the cigarette member of formation manufacture of spices of the present invention to continue during whole smoking and stably to transmit spices, thus, can identical perfume (or spice) be provided to inhale taste to smoker during whole smoking.
In addition, the cigarette member of formation supporting spices of the present invention, owing to coordinating spices equably in cigarette, therefore, when using it to manufacture multiple cigarette, also has the advantage of the flavour content inequality suppressed between cigarette.
Accompanying drawing explanation
Fig. 1 is the chart that in the pipe tobacco of the composition shown in surface applications containing menthol, fragrance protectiveness is put in the Tibetan of menthol.
Fig. 2 is the chart that fragrance protectiveness is put in the Tibetan of menthol in the cigarette of the pipe tobacco shown containing the composition in surface applications containing menthol.
Fig. 3 is the chart that in the reconstituted tobacco of the composition shown in surface applications containing menthol, fragrance protectiveness is put in the Tibetan of menthol.
Fig. 4 is the chart that fragrance protectiveness is put in the Tibetan of menthol in the cigarette of the reconstituted tobacco shown containing the composition in surface applications containing menthol.
Fig. 5 is the chart that in the tobacco coil paper of the composition shown in surface applications containing menthol, fragrance protectiveness is put in the Tibetan of menthol.
Fig. 6 is the chart that fragrance protectiveness is put in the Tibetan of menthol in the cigarette of the tobacco coil paper shown containing the composition in surface applications containing menthol.
Fig. 7 A shows viscosity along with the temperature that carragheen contains liquid to decline the chart changed.
Fig. 7 B shows viscosity along with the temperature that carragheen contains liquid to rise the chart changed.
Fig. 8 A shows viscosity along with the temperature that gellan gum contains liquid to decline the chart changed.
Fig. 8 B shows viscosity along with the temperature that gellan gum contains liquid to rise the chart changed.
Fig. 9 A shows viscosity along with the fluid temperature containing gellan gum and tamarind gum to decline the chart changed.
Fig. 9 B shows viscosity along with the fluid temperature containing gellan gum and tamarind gum to rise the chart changed.
Detailed description of the invention
Below, the present invention will be described, but the following description is to describe in detail for the purpose of the present invention, does not limit the present invention.
The cigarette member of formation supporting spices of the present invention obtains as follows: the flavor compositions of the collosol state of polysaccharide, spices and water in the surface applications of cigarette member of formation contains the combination being selected from carragheen, gellan gum and gellan gum and tamarind gum, and the cigarette member of formation applying flavor compositions is cooled to 0 ~ 40 DEG C, make flavor compositions gelation, then, the described cigarette member of formation heat drying applying flavor compositions is made.
As the spices used in the present invention, as long as the spices used in smoking article does not just limit, arbitrary spices can be used.As main spices, can enumerate: menthol, leaf tobacco extract, natural plant spices (such as Chinese cassia tree, Salvia japonica, medicinal herbs, yellow chamomile, Pueraria lobota grass, sweet tea, clove tree, lavender, cardamom, cloves, nutmeg, bergamot, fish pelargonium, honey essence, attar of rose, lemon, oranges and tangerines, cassia bark, fennel seeds, jasmine, ginger, coriander, vanilla extract, spearmint, peppermint, cassia bark (cassia), coffee, celery, card lamb's-quarters, santal, cocoa, Yilan, fennel, anise, Radix Glycyrrhizae, carob seed (St John'.s Bread), Prunus salicina Lindl. Extract, peach extract etc.), carbohydrate (such as glucose, fructose, isomerized sugar, caramel etc.), cocoa class (powder, extract etc.), ester class (such as isoamyl acetate, linalyl acetate, propionic acid agalloch eaglewood ester, butyric acid agalloch eaglewood ester etc.), ketone (such as menthones, ionone, damascenone, ethyl maltol etc.), alcohols (such as geraniol, linalool, anethole, eugenol etc.), aldehydes (such as vanillic aldehyde, benzaldehyde, anisaldehyde etc.), lactone (such as gamma-undecalactone, nonyl lactone etc.), animality spices (such as Moschus, ambergris, civet, castoreum etc.), hydro carbons (such as citrene, firpene etc.).Easily form the spices of dispersity preferably by adding emulsifying agent in a solvent, such as, can use hydrophobic perfume or oil soluble flavors etc.These spices can be used alone, also can be used in combination.
Below, to use menthol, as the situation of spices, the present invention is described.
1. the composition containing menthol
In one embodiment, the cigarette member of formation supporting spices of the present invention is obtained by the composition (composition hereinafter referred to as containing menthol) applied on cigarette member of formation containing the polysaccharide be selected from the combination of carragheen, gellan gum and gellan gum and tamarind gum and menthol.Preferably the cigarette member of formation supporting spices of the present invention passes through to obtain at the above-mentioned flavor compositions of the surface applications of cigarette member of formation.
The composition containing menthol used in the present invention is the slurry form under heating-up temperature (such as 60 ~ 90 DEG C) with mobility as the state before drying.
The coordinating example of the composition (slurry) containing menthol, as relative to water 10L, can be set to the polysaccharide of 200 ~ 500g, the menthol of 1000 ~ 2500g, the emulsifier solution 80 ~ 200ml of 2 ~ 10 % by weight.The moisture of the composition (slurry) containing menthol is generally 70 ~ 95 % by weight, is preferably 80 ~ 90 % by weight.Ratio (weight ratio) containing polysaccharide and menthol in the composition of menthol can be set to 1:1 ~ 1:10.
In the present invention, polysaccharide can the gelation when being cooled by its aqueous solution, has and is fixed and coated character by the micella of the spices such as menthol.As the polysaccharide with this character, the polysaccharide in the combination being selected from carragheen, gellan gum and gellan gum and tamarind gum can be used.In addition, in the present invention, when using carragheen as polysaccharide, other polysaccharides such as the gellan gum of the amount more less than carragheen or tamarind gum can also be contained in containing the composition of menthol.Equally, when using gellan gum as polysaccharide, also can contain other polysaccharide such as carragheen than gellan gum less amount in containing the composition of menthol.
In the present invention, menthol can use l-menthol.
In the present invention, emulsifying agent can use the emulsifying agent of natural origin, such as lecithin, specifically can use Sun Lecithin A-1 (Taiyo Kagaku Co., Ltd.).
In the present invention, the slurry of the composition containing menthol is prepared by the method comprising following operation: (i) is by polysaccharide and water mixing, heating and prepare the operation of the aqueous solution of polysaccharide; (ii) in this aqueous solution, menthol and emulsifying agent is added and operation that is mixing, emulsification.
Operation (i) specifically by while be marginally added in water by polysaccharide and stir at every turn, makes it dissolve to carry out.Be 60 ~ 90 DEG C in this heating-up temperature, be preferably 75 ~ 85 DEG C.Operation (ii) has 10 due to the slurry of the composition containing menthol under above-mentioned heating-up temperature, about 000mPas following (collosol state), the viscosity that do not hinder emulsification, therefore, by using homogenizer and utilizing known emulsifying technology to carry out.
2. the application of composition in cigarette member of formation containing menthol
In the present invention, the above-mentioned composition containing menthol is applied to the surface that cigarette member of formation is preferably applied to cigarette member of formation.
Specifically, in the present invention, cigarette member of formation is be configured at the member of formation not with the mouth of smoker or the position of oral contact when being assembled in cigarette, in other words, cigarette member of formation is the member of formation being configured at the position of being distributed together with mainstream smoke by the spices such as menthol by burning during smoking when being assembled in cigarette.
More specifically, cigarette member of formation is tobacco fill material or tobacco coil paper.More specifically, tobacco fill material is pipe tobacco or reconstituted tobacco.
As long as the composition (slurry) containing menthol can be applied to cigarette member of formation and just be not particularly limited by method equably that the composition containing menthol is applied to cigarette member of formation, composition (slurry) containing menthol can be added or coats the surface of cigarette member of formation, also the composition (slurry) containing menthol can be sparged the surface of cigarette member of formation, also cigarette member of formation can be immersed in the composition (slurry) containing menthol.
When the slurry (about 60 ~ 90 DEG C, collosol state) of the composition containing menthol is applied to pipe tobacco, can adopt, by shifting pump, the composition (slurry) containing menthol is directly added on pipe tobacco surface, or be sprayed at the method on pipe tobacco by nozzle fog machine.Or, with regard to being applied to by the composition (slurry) containing menthol with regard to pipe tobacco, pipe tobacco also can be made to impregnated in the slurry of the composition containing menthol.
When the slurry (about 60 ~ 90 DEG C, collosol state) of menthol composition is applied to reconstituted tobacco, the method for surperficial the extruding of reconstituted tobacco being added by slit dispenser or the method be coated with film coated device etc. can be adopted.Or, according to the method identical with when being applied to pipe tobacco, spraying or impregnating method also can be adopted.
When the slurry (about 60 ~ 90 DEG C, collosol state) of menthol composition is applied to tobacco coil paper, as mentioned above, can adopt and extruded by slit dispenser and the method for adding or the method be coated with film coated device etc.Or, according to the method identical with when being applied to pipe tobacco, spraying or impregnating method also can be adopted.
When pipe tobacco, the application quantity of the slurry of the composition containing menthol, relative to pipe tobacco 100 weight portion, can be set to 5 ~ 40 weight portions, can preferably be set to 15 ~ 25 weight portions.When reconstituted tobacco, the application quantity of the slurry of the composition containing menthol, relative to reconstituted tobacco 100 weight portion, can be set to 50 ~ 400 weight portions, can preferably be set to 100 ~ 200 weight portions.When tobacco coil paper, the application quantity of the slurry of the composition containing menthol, relative to tobacco coil paper 100 weight portion, can be set to 10 ~ 70 weight portions, can preferably be set to 30 ~ 50 weight portions.
The cigarette member of formation applying the slurry of the composition containing menthol preferably makes the abundant gelation of the slurry of the composition containing menthol (less than 40 DEG C) before the drying, and be usually temporarily cooled to emulsion can not be made to freeze and destroy temperature (more than 0 DEG C), namely 0 ~ 40 DEG C, be preferably 0 ~ 30 DEG C, be more preferably 15 ~ 25 DEG C.At this, the slurry of composition containing menthol before cooling has 60 ~ 90 DEG C, the preferred temperature of 75 ~ 85 DEG C, is in collosol state.This pre-cooled cold wind (such as 10 DEG C) that can produce by means of only air-supply or some cooler (such as Suiden SS-25DD-1) in the cigarette member of formation of slurry applying the composition containing menthol blows 2 ~ 3 minutes to carry out.Or precooling is undertaken by making the cigarette member of formation of the slurry of the composition applied containing menthol contact 1 ~ 2 minute with the pipe of the cold-producing medium (such as 10 DEG C) produced by cold warm water generator (cooler, such as (strain) Spiste PCU-1600R) also.Or precooling is positioned over room temperature to carry out by the cigarette member of formation of the slurry by the composition applied containing menthol also.
The aqueous solution of the polysaccharide used described in the present invention has temporarily cooling and gelation, even if temperature rises afterwards, also solation is not easy, the character (with reference to embodiment described later) that gelation state can be kept such at the temperature changing gel into.If it is pre-cooled to utilize this character to carry out before the slurry drying making the composition containing menthol, even if then the pre-cooled rear undried composition containing menthol temperature when drying rises, also not easily make wherein contained polysaccharide solation, be especially not easily vaporized with the menthol that this polysaccharide is coated.As mentioned above, in the present invention, due to pre-cooled, the composition containing menthol can be exposed in drying process afterwards in the environment of heat, the drying of short time can be realized thus.
The heat drying applying the cigarette member of formation of the composition containing menthol is undertaken by the arbitrary heat drying mode such as heated-air drying, infrared dehydration.
The drying of the composition containing menthol applied in cigarette member of formation can remain less than 100 DEG C with specimen temperature in total drying process, the mode that preferably remains 70 ~ 100 DEG C carries out.In order to keep the specimen temperature of less than 100 DEG C, the baking temperature of 100 DEG C ~ 130 DEG C preferably can be adopted.In order to keep the specimen temperature of 70 ~ 100 DEG C, the baking temperature of 100 DEG C ~ 130 DEG C preferably can be adopted.At this, " specimen temperature " refers to the surface temperature of the composition containing menthol in drying process, and " baking temperature " refers to the temperature in drying machine, and when heated-air drying, the temperature in drying machine is identical with hot blast temperature.
Preferred drying comprise with the baking temperature of more than 100 DEG C (preferably 100 DEG C ~ 130 DEG C) and via total drying time more than 1/4 time chien shih it is dry, can be that there is the state of moisture lower than 10% to carry out being dried to the cigarette member of formation supporting spices total drying time of less than 20 minutes.Drying preferably under the baking temperature of more than 100 DEG C initial dry time carry out, then, make its drying with the temperature identical with initial baking temperature or the temperature lower than initial baking temperature (be preferably more than 70 DEG C and lower than 100 DEG C).
Baking temperature makes specimen temperature be always less than 100 DEG C in total drying process, and in addition, whole drying process can be certain temperature, also can change between drying process.When changing baking temperature, preferably dry by the initial stage drying of high temperature drying temperature of more than 100 DEG C and carrying out with the later stage drying of the low temperature drying temperature lower than 100 DEG C afterwards.In this manual, " initial stage is dry " refers to the initial drying of the drying process of the high temperature of use more than 100 DEG C, and " later stage is dry " refers to the drying of use lower than the then initial stage drying of the low temperature of 100 DEG C.As mentioned above, if the later stage drying under initial stage under high temperature dry and low temperature is carried out in combination, then the specimen temperature too high temperature that can not become, in total drying process, specimen temperature is always less than 100 DEG C, and has the advantage that can shorten drying time.
Preferably drying is undertaken by following method further:
With the baking temperature of more than 100 DEG C and via total drying time more than 1/4 initial stage of time dry, afterwards
With lower than 100 DEG C baking temperature and via total drying time more than 1/4 later stage of time dry,
To carry out total drying time of less than 20 minutes until make to support spices cigarette member of formation be regulation moisture (specifically, what in pipe tobacco, apply the composition containing menthol supports in the cigarette member of formation of spices, make moisture less than about 12 % by weight, apply in reconstituted tobacco or tobacco coil paper and support in the cigarette member of formation of spices containing menthol composition, moisture is below about 10 % by weight).
As mentioned above, the initial stage drying under high temperature and the later stage drying under low temperature is carried out by combination, the cigarette member of formation supporting spices of the present invention can have extra high menthol content after manufacturing, and menthol content also can be kept to be extra high value in Tibetan postpone.
When utilizing heated-air drying to carry out drying, the initial stage is dry such as can carry out 4 ~ 6 minutes under the hot blast temperature of less than 130 DEG C more than 100 DEG C, and later stage drying such as can carry out 4 ~ 6 minutes lower than under the hot blast temperature of 100 DEG C more than 70 DEG C.The air quantity of hot blast such as can be set to 3 ~ 20m/ second.Total drying time is less than 20 minutes, is preferably 10 ~ 18 minutes.
The condition (temperature, time and air quantity) that initial stage is dry and the later stage is dry such as can be suitable for setting in above-mentioned scope.
Baking temperature between initial stage dry period can be constant, also can change and makes them more than 100 DEG C and reduce successively between less than 130 DEG C.In addition, the baking temperature of later stage drying room also can be constant, also can change and makes them more than 70 DEG C and reduce successively between 100 DEG C.Such as, the drying machine used in embodiment described later has 3 hothouses, sample is transported with conveyer belt with the order of Room the 1st → Room the 2nd → Room the 3rd, therefore, Room 1st and Room the 2nd can be used for initial stage drying (more than 100 DEG C) with identical or different temperature, Room 3rd is used for later stage drying (lower than 100 DEG C), also Room the 1st can be used for initial stage drying (more than 100 DEG C), Room the 2nd and Room the 3rd are used for later stage drying (lower than 100 DEG C) with identical or different temperature.
The dry moisture preferably proceeding to the cigarette member of formation making to support spices be the moisture of regulation (specifically, in pipe tobacco, apply supporting in the cigarette member of formation of spices of the composition containing menthol is less than about 12 % by weight, and applying containing supporting in the cigarette member of formation of spices of menthol composition in reconstituted tobacco or tobacco coil paper is less than about 10 % by weight).The value that the assay method recorded records is referred in by aftermentioned embodiment in this moisture.
3. cigarette
According to the present invention, can provide a kind of containing the cigarette supporting the cigarette member of formation of spices of the present invention.Cigarette of the present invention, except the member of formation of common cigarette being replaced with the cigarette member of formation supporting spices of the present invention, has the formation identical with common cigarette.In a particular embodiment, cigarette packets of the present invention containing apply flavor compositions of the present invention pipe tobacco, apply the reconstituted tobacco of flavor compositions of the present invention or apply the tobacco coil paper of flavor compositions of the present invention.Cigarette of the present invention also can be combined containing member of formation of the present invention.Such as, can combine containing applying the pipe tobacco of flavor compositions of the present invention and applying the reconstituted tobacco of flavor compositions of the present invention, also can combine containing applying the pipe tobacco of flavor compositions of the present invention and applying the tobacco coil paper of flavor compositions of the present invention.
If tobacco fill material contained in 1 cigarette is set to 100 % by weight, then the pipe tobacco applying flavor compositions of the present invention can coordinate in the mode of account for total tobacco fill material 20 ~ 100 % by weight.If tobacco fill material contained in 1 cigarette is set to 100 % by weight, then the reconstituted tobacco applying flavor compositions of the present invention can coordinate in the mode of account for total tobacco fill material 10 ~ 40 % by weight.
Embodiment
Below, by embodiment, the present invention will be described.
The preparation of the composition (slurry) 1 ~ 3 [1] containing menthol
The composition (using carragheen as polysaccharide) of the composition (slurry) 1 containing menthol
Water 10L
Carragheen (CS-530/ tri-Rong Yuan FFI) 500g
Lecithin (Sun Lecithin A-1/ sun chemistry (strain)) 200mL (5% aqueous solution)
Menthol (Takasago spices Industry Co) 2500g
The composition (using gellan gum as polysaccharide) of the composition (slurry) 2 containing menthol
Water 10L
Gellan gum (kelcogel/ tri-Rong Yuan FFI) 300g
Lecithin (Sun Lecithin A-1/ sun chemistry (strain)) 120mL (5% aqueous solution)
Menthol (Takasago spices Industry Co) 1500g
The composition (using gellan gum and tamarind gum as polysaccharide) of the composition (slurry) 3 containing menthol
Water 10L
Gellan gum (kelcogel/ tri-Rong Yuan FFI) 150g
Tamarind gum (Bistop D-2032/ tri-Rong Yuan FFI) 150g
Lecithin (Sun Lecithin A-1/ sun chemistry (strain)) 120mL (5% aqueous solution)
Menthol (Takasago spices Industry Co) 1500g
The composition (slurry) 1 ~ 3 containing menthol of the above-mentioned composition of following preparation.
Water (10L) is remained on 80 DEG C, while with agitator (PRIMIX T.K.AUTO MIXER Model40/ is provided with solution stirring rotator/2000rpm) stir make polysaccharide (when containing menthol composition 1 for carragheen (500g), when containing menthol composition 2 be gellan gum (300g), when containing menthol composition 3 for gellan gum (150g) and tamarind gum (150g)) dissolve (required time about 20 minutes) on a small quantity in the mode that can not lump at every turn, add menthol (when containing menthol composition 1 be 2500g, when containing menthol composition 2 and 3 be 1500g).
Change homogenizer (PRIMIX T.K.AUTO MIXER Model 40/ is provided with rotor-stator head/4000rpm) into by agitator and carry out emulsification in 10 minutes, and then add lecithin (when containing menthol composition 1 be 200mL (5% aqueous solution), when containing menthol composition 2 and 3 be 120mL (5% aqueous solution)) continuation emulsification 10 minutes, obtain the composition (slurry) containing menthol.
The composition (slurry) 1 ~ 3 containing menthol obtained is used in following experiment.
[2] preparation of the cigarette member of formation of spices is supported
[2-1] supports the preparation of the pipe tobacco of spices
Composition (slurry) (20 weight portion) (about 60 DEG C, collosol state) containing menthol is applied in an uniform manner to the pipe tobacco (100 weight portion) of Mild Seven Super Lights product (Japan tobacco Inc).At this, utilize shifting pump (Hyoao Equipment Co., Ltd. Heishin Monopump 2NVL06F) that the composition (slurry) containing menthol is made an addition to pipe tobacco.
Be added with the pipe tobacco of the composition (slurry) containing menthol by 10 DEG C of cold wind (cold wind generation equipment; Suiden SS-25DD-1) make the temperature of the pipe tobacco of the composition that with the addition of containing menthol temporarily be cooled to less than 20 DEG C (product temperature Measuring Devices; Optechs Co., Ltd. system, PT-7LD).
Then, make the pipe tobacco of cooling by conveyer belt transfer type air drier (hot blast temperature condition; 110 DEG C, 2.5 minutes → 100 DEG C, 5 minutes → 80 DEG C, 2.5 minutes) moisture that is dried to the pipe tobacco of the composition that with the addition of containing menthol is about 12 % by weight (with reference to " mensuration of moisture " described later), the pipe tobacco of caking untied and prepares " pipe tobacco supporting spices of the present invention ".The pipe tobacco of the composition 1 applied containing menthol is called " pipe tobacco 1 supporting spices of the present invention ", the pipe tobacco of the composition 2 applied containing menthol is called " pipe tobacco 2 supporting spices of the present invention ", the pipe tobacco of the composition 3 applied containing menthol is called " pipe tobacco 3 supporting spices of the present invention ".The moisture supporting the pipe tobacco 1 ~ 3 of spices of the present invention is 12 % by weight ~ 13 % by weight.
By contrast, the control sample of pipe tobacco as pipe tobacco of menthol will be added by usual way in pipe tobacco.That is, by coming tobacco perfuming to the ethanolic solution of pipe tobacco spray perfume (menthol).Perfuming is carried out to pipe tobacco, makes the menthol amount of per unit weight pipe tobacco be 1.0 % by weight.
[2-2] supports the preparation of the reconstituted tobacco of spices
The composition (slurry) (about 60 DEG C, collosol state) containing menthol is applied in mode as far as possible equably in the reconstituted tobacco prepared by papermaking process (reconstituted tobacco raw material).That is, utilize film coated device that the composition (slurry) containing menthol is cast in (0.2mm is thick) on reconstituted tobacco, the slurry of the composition of coating containing menthol on reconstituted tobacco.At this, the composition containing menthol is with relative to reconstituted tobacco (100 weight portion), and the composition (slurry) containing menthol is that the mode of 150 weight portions is coated with.
The reconstituted tobacco being coated with the composition (slurry) containing menthol passes through the cold wind of 10 DEG C (cold wind generation equipment; Suiden SS-25DD-1) make the temperature of the pipe tobacco of the composition containing menthol coating reconstituted tobacco temporarily be cooled to less than 20 DEG C (product temperature Measuring Devices; Optechs Co., Ltd. system, PT-7LD).
Then, make by conveyer belt transfer type air drier (hot blast temperature condition; 110 DEG C, 2.5 minutes → 100 DEG C, 5 minutes → 80 DEG C, 2.5 minutes) moisture that is dried to the reconstituted tobacco of the composition be coated with containing menthol is about 10 % by weight (with reference to " mensuration of moisture " described later), preparation " reconstituted tobacco supporting spices of the present invention ".The reconstituted tobacco of the composition 1 applied containing menthol is called " reconstituted tobacco 1 supporting spices of the present invention ", the reconstituted tobacco of the composition 2 applied containing menthol is called " reconstituted tobacco 2 supporting spices of the present invention ", the reconstituted tobacco of the composition 3 applied containing menthol is called " reconstituted tobacco 3 supporting spices of the present invention ".The moisture supporting the reconstituted tobacco 1 ~ 3 of spices of the present invention is 9 % by weight ~ 10 % by weight.
By contrast, the usual perfuming gimmick to pipe tobacco is applied to reconstituted tobacco and it can be used as the control sample of reconstituted tobacco.That is, by coming reconstituted tobacco perfuming to the ethanolic solution of reconstituted tobacco spray perfume (menthol).Reconstituted tobacco is with per unit weight reconstituted tobacco, and menthol amount is the mode perfuming of 5.0 % by weight.
[2-3] supports the preparation of the tobacco coil paper of spices
At tobacco coil paper (weight per unit area 40g/m
2, thickness 35 μm) in apply the composition (slurry) (about 60 DEG C, collosol state) containing menthol in mode as far as possible equably.That is, utilize film coated device on tobacco coil paper, be coated with the composition (slurry) containing menthol.At this, the composition containing menthol is with relative to tobacco coil paper (100 weight portion), and the composition (slurry) containing menthol is that the mode of 40 weight portions is coated with.
The tobacco coil paper being coated with the composition (slurry) containing menthol passes through the cold wind of 10 DEG C (cold wind generation equipment; Suiden SS-25DD-1) make the temperature of the pipe tobacco of the composition containing menthol coating tobacco coil paper temporarily be cooled to less than 20 DEG C (product temperature Measuring Devices; Optechs Co., Ltd. system, PT-7LD).
Then, make by conveyer belt transfer type air drier (hot blast temperature condition; 110 DEG C, 2.5 minutes → 100 DEG C, 5 minutes → 80 DEG C, 2.5 minutes) moisture that is dried to the tobacco coil paper of the composition be coated with containing menthol is about 10 % by weight (with reference to " mensuration of moisture " described later), preparation " tobacco coil paper of the present invention ".
The tobacco coil paper of the composition 1 applied containing menthol is called " the tobacco coil paper 1 supporting spices of the present invention ", the tobacco coil paper of the composition 2 applied containing menthol is called " the tobacco coil paper 2 supporting spices of the present invention ", the tobacco coil paper of the composition 3 applied containing menthol is called " the tobacco coil paper 3 supporting spices of the present invention ".The moisture supporting the tobacco coil paper 1 ~ 3 of spices of the present invention is 6 % by weight ~ 7 % by weight.
By contrast, the usual perfuming gimmick to pipe tobacco is applied to tobacco coil paper and it can be used as the control sample of reconstituted tobacco.That is, by coming tobacco coil paper perfuming to the ethanolic solution of tobacco coil paper spray perfume (menthol).Tobacco coil paper is with per unit weight tobacco coil paper, and menthol amount is the mode perfuming of 1.0 % by weight.
[3] mensuration of moisture
In order to grasp the dry condition of the slurry of the composition containing menthol being applied to cigarette member of formation, measure moisture according to following method.
The preparation of [3-1] determination of moisture solution
Weigh the cigarette member of formation 0.1g supporting spices of preparation, methyl alcohol (special grade chemical or the equal above methyl alcohol of 10mL is added in the closed container (being stored in drier) adding 50mL capacity, in order to the impact of the moisture absorption in deaeration, new product not to be exposed in air and to use distributor dispensing), vibrate 40 minutes (200 times per minute of linear reciprocation vibration (reciprocating) amplitude 3cm) with vibrating machine (AS ONE SHAKER SRR-2).After placing an evening, again carry out vibration (equal conditions: 200rpm) in 40 minutes, the supernatant (not being exposed to air as far as possible) after leaving standstill is loaded in bottle, as determination of moisture solution.
[3-2] GC-TCD determination of moisture
The determination of moisture solution obtained is placed in following GC-TCD and is undertaken quantitatively by calibration curve method.
GC-TCD:Hewlett Packard Inc. 6890 gas chromatograph
Post: HP Polapack Q (packed column)
Carrier gas: He constant current mode 20.0mL/min
Injection amount: 1.0 μ L
Inlet: EPC cleans packed column inlet heater: 230 DEG C
Inlet gas: He total flow: 21.1mL/min
Insulating box: 160 DEG C of (keeping 4.5min) → (60 DEG C/min) → 220 DEG C (keeping 4.0min)
Detector: TCD detector reference gas (He) flow: 20mL/min
Make-up gas (He) 3.0mL/min
Signal rate: 5Hz
Calibration curve solution concentration: 0,1,3,5,10,20 [mg-H
2o/10mL] 6 points.
[4] mensuration of menthol content
" supporting the menthol content of the cigarette member of formation of spices " and " menthol content in mainstream smoke " is measured according to following method.
Measure the menthol content supporting the cigarette member of formation of spices of preparation, put the cooperation uniformity of fragrance protectiveness and spices with the Tibetan examining or check spices.In addition, measure the menthol content in mainstream smoke, put fragrance protectiveness with the Tibetan examining or check spices.
[4-1] is for measuring the preparation of the solution of the menthol content of cigarette member of formation
Weigh the cigarette member of formation 0.1g supporting spices of preparation, add the methyl alcohol (special grade chemical or equal more than) of 10mL in the closed container (helix tube) adding 50mL capacity, vibrate 40 minutes (linear reciprocation vibrate (reciprocating) amplitude 3cm 200 times per minute) with vibrating machine (AS ONE SHAKER SRR-2).After placing an evening, again carry out vibration (equal conditions: 200rpm) in 40 minutes, supernatant after dilution ratio dilution (in this case × 10 methanol dilution) measured to be suitable for GC leaves standstill, measures solution as the menthol measured for GC-FID.
[4-2] is for measuring the preparation of the solution of the menthol content in mainstream smoke
Following preparation Cambridge filter extraction solution, measures solution as menthol.Namely, add the methyl alcohol (special grade chemical or equal more than) of 10mL in the closed container (helix tube) Cambridge filter sample being added 50mL capacity, vibrate 40 minutes (linear reciprocation vibrate (reciprocating) amplitude 3cm 200 times per minute) with vibrating machine (AS ONE SHAKER SRR-2).Supernatant after leaving standstill is loaded bottle, measures solution as the menthol measured for GC-FID.
[4-3] GC-FID menthol content measures
The menthol obtained is measured solution be placed in following GC-TCD and undertaken quantitatively by calibration curve method.
GC-FID; Agilent Inc. 6890N gas chromatograph
Post: DB-WAX 30m x 530 μm of x 1 μm (Max 220 DEG C)
Carrier gas: He constant voltage mode 5.5psi (speed; 50cm/sec)
Injection amount: 1.0 μ L
Inlet: Spritless pattern 250 DEG C of 5.5psi
Insulating box: 80 DEG C → (10 DEG C/min) → 170 DEG C (keeping 6.0min)
Detector: fid detector 250 DEG C of (H
2: 40mL/min air: 450mL/min)
Signal rate: 20Hz
Calibration curve solution concentration: 0,0.01,0.05,0.1,0.3,0.5,0.7,1.0 [mg-menthol/mL] 8 points.
[5] accelerated test
The cigarette member of formation supporting spices of preparation is put into 50 DEG C of thermostats (Yamato science Co., Ltd. DX600), hides and put 1 week, 2 weeks or 1 month (30 days).As above measure the menthol content in each moment, hide based on its Assessment of Changes and put fragrance protectiveness.
[6] making of cigarette and smoking experiment
The cigarette member of formation supporting spices of the present invention is used to manufacture cigarette as follows.
According to Mild Seven Super Lights (Japan tobacco Inc), the cigarette member of formation supporting spices of preparation is used to make cigarette respectively.
Specifically, use the pipe tobacco of Mild Seven Super Lights product to prepare the pipe tobacco supporting spices of the present invention as raw material containing the cigarette supporting the pipe tobacco of spices of the present invention, use the various material product (coil paper or filter tip etc.) of Mild Seven Super Lights manufacture wherein and make.
Coordinate in the pipe tobacco (85 weight portion) manufactured at Mild Seven Super Lights containing the cigarette supporting the pipe tobacco of spices of the present invention of the present invention support spices reconstituted tobacco (15 weight portion) and make the loading of regulation, use the various material product (coil paper or filter tip etc.) of Mild Seven Super Lights product wherein and make.
Make by the tobacco coil paper of Mild Seven Super Lights product is replaced with the tobacco coil paper supporting spices of the present invention containing the cigarette supporting the tobacco coil paper of spices of the present invention.Cigarette carries out adjustment as far as possible makes tar value constant.
Smoking conditions: carry out smoking experiment by the standard smoking conditions (smoking 2 seconds (58 seconds standby) in 1 minute, by smoking capacity 35mL, the long 35mm of stub (tipping paper+3mm)) of defined in ISO.
In mainstream smoke, Cambridge filter traps composition as above carries out extracting and measures by menthol content.
[7] result (pipe tobacco)
Use above-mentioned experiment gimmick, for pipe tobacco, obtain following result.
Fragrance protectiveness (employing the evaluation of pipe tobacco) is put in the Tibetan of [7-1] menthol
Fragrance protectiveness is put in the Tibetan of the menthol using " pipe tobacco 1 ~ 3 supporting spices of the present invention " and " control sample of pipe tobacco " as above prepared to evaluate in pipe tobacco.The results are shown in Fig. 1.
Pipe tobacco is placed under specified time limit (0 day, 7 days, 14 days, 30 days) acceleration environment.In addition, the mensuration of the menthol content in pipe tobacco measures as described above by GC-FID carries out.In FIG, the result supporting the pipe tobacco 1 of spices of the present invention is expressed as " carragheen ", the result supporting the pipe tobacco 2 of spices of the present invention is expressed as " gellan gum ", the result supporting the pipe tobacco 3 of spices of the present invention is expressed as " gellan gum+tamarind gum ", and the result of control sample is expressed as " control group ".Menthol content (% by weight) through type: { weight (mg) of measured value (the mg)/pipe tobacco of menthol content } × 100 are tried to achieve.
The menthol content of control sample puts start time (0 day) in Tibetan be about 0.7 % by weight.This control sample is placed in 50 DEG C of thermostats, results verification along with the time through and tendency that menthol content significantly reduces.
By contrast, the menthol content of (0 day) display 1.2 ~ 1.5 % by weight put start time by the pipe tobacco 1 ~ 3 supporting spices of the present invention in Tibetan, confirming under the acceleration environment of 50 DEG C, hide postpone has good fragrance protectiveness at least 1 month.
Fragrance protectiveness (employing the evaluation of cigarette) is put in the Tibetan of [7-2] menthol
Fragrance protectiveness is put in the Tibetan of the menthol using the cigarette containing " pipe tobacco 1 ~ 3 supporting spices of the present invention " and the contrast cigarette containing " control sample of pipe tobacco " to evaluate in cigarette.The results are shown in Fig. 2.
Pipe tobacco is placed as mentioned above under specified time limit (0 day, 7 days, 14 days, 30 days) acceleration environment, and making employs the cigarette of this pipe tobacco and carries out smoking experiment.The mensuration of the menthol amount in mainstream smoke measures as described above by GC-FID carries out.
In fig. 2, be expressed as " carragheen " containing the result supporting the cigarette of the pipe tobacco 1 of spices of the present invention, be expressed as " gellan gum " containing the result supporting the cigarette of the pipe tobacco 2 of spices of the present invention, be expressed as " gellan gum+tamarind gum " containing the result supporting the cigarette of the pipe tobacco 3 of spices of the present invention, the result of the cigarette containing control sample is expressed as " control group ".In fig. 2, in mainstream smoke, menthol amount [mg/cig] represents the measured value (mg) of the menthol amount of every 1 cigarette.
The cigarette of the pipe tobacco containing control sample when use hide that to put number of days be the pipe tobacco of 0 day, show menthol amount in higher mainstream smoke, but when to use Tibetan to put number of days be the pipe tobacco of 7 days, menthol amount significantly reduces.
By contrast, though containing the cigarette supporting the pipe tobacco 1 ~ 3 of spices of the present invention be used in hide the pipe tobacco put under the acceleration environment of 50 DEG C when, also confirm within least 1 month, there is good fragrance protectiveness.
The cooperation uniformity of [7-3] menthol
Be which kind of degree to the inequality of the spices use level that 10 cigarettes containing the pipe tobacco supporting spices of the present invention are examined or check between each cigarette.In addition, be divided into 3 equal portions by containing the cigarette sticks supporting the pipe tobacco of spices of the present invention, which kind of degree is the inequality of the spices use level between examination each several part be.Result is shown in table 1 with " inequality between cigarette " and " inequality in cigarette " respectively.The mean value that inequality (CV%) in cigarette obtains for measuring 10 cigarettes.
About control group, the ratio with 2 % by weight coordinates the chopping thing (International Publication 2009/142159) of the reconstituted tobacco containing menthol to replace the pipe tobacco supporting spices of the present invention in pipe tobacco, makes tar value consistent and makes sample cigarette.In the mainstream smoke of this sample cigarette, menthol amount is roughly the same with employing the cigarette supporting the pipe tobacco of spices of the present invention, and one is equivalent to 0.4mg.
[table 1]
When by the reconstituted tobacco chopping one-tenth containing menthol and the equal shape of pipe tobacco and when being engaged in pipe tobacco, the inequality (CV%) between cigarette is 34%, in cigarette, be not 54%.The reconstituted tobacco fit rate that this inequality results from containing menthol is low, if the reconstituted tobacco fit rate containing menthol is more than 10 % by weight, uneven (CV%) is reduced to about 10%.On the other hand, when using the pipe tobacco supporting spices of the present invention to prepare cigarette, the inequality between cigarette and the inequality in cigarette are compared with control group, and its value all significantly reduces.
From these results, compared with the cigarette coordinated using the chopping thing of the reconstituted tobacco containing menthol as tobacco fill material, the inequality of the menthol use level between cigarette can be suppressed containing the cigarette supporting the pipe tobacco of spices of the present invention, and in cigarette sticks, menthol can be coordinated equably.Thus, the perfume (or spice) of every root cigarette can be suppressed to inhale the change of the change of taste or the perfume (or spice) suction taste during cigarette smoking containing the cigarette supporting the pipe tobacco of spices of the present invention.In addition, in the present invention, owing to applying flavor compositions in normally used cigarette member of formation, therefore, existing equipment can be utilized easily to carry out cigarette manufacture.
[8] result (reconstituted tobacco)
Use above-mentioned experiment gimmick, following result is obtained for reconstituted tobacco.
Fragrance protectiveness (employing the evaluation of reconstituted tobacco) is put in the Tibetan of [8-1] menthol
Fragrance protectiveness is put in the Tibetan of the menthol using " reconstituted tobacco 1 ~ 3 supporting spices of the present invention " and " control sample of reconstituted tobacco " as above prepared to evaluate in reconstituted tobacco.The results are shown in Fig. 3.
Reconstituted tobacco is placed under specified time limit (0 day, 7 days, 14 days, 30 days) acceleration environment.In addition, the mensuration of the menthol content in reconstituted tobacco measures as described above by GC-FID carries out.In figure 3, the result supporting the reconstituted tobacco 1 of spices of the present invention is expressed as " carragheen ", the result supporting the reconstituted tobacco 2 of spices of the present invention is expressed as " gellan gum ", the result supporting the reconstituted tobacco 3 of spices of the present invention is expressed as " gellan gum+tamarind gum ", and the result of control sample is expressed as " control group ".Menthol content (% by weight) through type: { weight (mg) of measured value (the mg)/reconstituted tobacco of menthol content } × 100 are tried to achieve.
The menthol content of control sample puts start time (0 day) in Tibetan be about 3 % by weight.This control sample is placed in 50 DEG C of thermostats, results verification along with the time through and menthol content significantly reduces, after one week, almost becoming zero.
By contrast, the reconstituted tobacco 1 ~ 3 supporting spices of the present invention puts start time the menthol content of (0 day) display 5 ~ 7 about % by weight in Tibetan, under the acceleration environment of 50 DEG C, hide postpone menthol content also more, confirms good fragrance protectiveness.
Fragrance protectiveness (employing the evaluation of cigarette) is put in the Tibetan of [8-2] menthol
Fragrance protectiveness is put in the Tibetan of the menthol using the cigarette containing " reconstituted tobacco 1 ~ 3 supporting spices of the present invention " and the contrast cigarette containing " control sample of reconstituted tobacco " to evaluate in cigarette.The results are shown in Fig. 4.
Reconstituted tobacco is placed as mentioned above under specified time limit (0 day, 7 days, 14 days, 30 days) acceleration environment, makes the cigarette employing this reconstituted tobacco.The mensuration of the menthol amount in mainstream smoke measures as described above by GC-FID carries out.
In the diagram, be expressed as " carragheen " containing the result supporting the cigarette of the reconstituted tobacco 1 of spices of the present invention, be expressed as " gellan gum " containing the result supporting the cigarette of the reconstituted tobacco 2 of spices of the present invention, be expressed as " gellan gum+tamarind gum " containing the result supporting the cigarette of the reconstituted tobacco 3 of spices of the present invention, the result of the cigarette containing control sample is expressed as " control group ".In the diagram, in mainstream smoke, menthol amount [mg/cig] represents the measured value (mg) of the menthol amount of every 1 cigarette.
The cigarette of the reconstituted tobacco containing control sample when use hide that to put number of days be the reconstituted tobacco of 0 day, display with containing menthol amount in the equal mainstream smoke of the cigarette supporting the reconstituted tobacco of spices of the present invention, but when use hide that to put number of days be the reconstituted tobacco of 7 days, menthol amount almost becomes zero.
By contrast, though containing the cigarette sample supporting the reconstituted tobacco 1 ~ 3 of spices of the present invention be used in hide the reconstituted tobacco put under the acceleration environment of 50 DEG C when, in mainstream smoke, menthol amount is also more, confirms good fragrance protectiveness.
The cooperation uniformity of [8-3] menthol
Which kind of degree is the inequality examining or check the use level of the spices between each cigarette containing the cigarette supporting the reconstituted tobacco of spices of the present invention to 10 be.In addition, be divided into 3 equal portions by containing the cigarette sticks supporting the reconstituted tobacco of spices of the present invention, which kind of degree is the inequality of the use level of the spices between examination each several part be.Result is shown in table 2 with " inequality between cigarette " and " inequality in cigarette " respectively.The mean value that inequality (CV%) in cigarette obtains for measuring 10 cigarettes.
About control group, with above-mentioned support in the item of the pipe tobacco of spices describe identical, ratio with 2 % by weight coordinates the chopping thing (International Publication 2009/142159) of the reconstituted tobacco containing menthol to replace the pipe tobacco supporting spices of the present invention in pipe tobacco, makes tar value consistent and makes sample cigarette.
[table 2]
When by shape equal with pipe tobacco for the reconstituted tobacco chopping one-tenth containing menthol and when coordinating (2 % by weight) in pipe tobacco, the inequality (CV%) between cigarette is 34%, in cigarette, be not 54%.On the other hand, when using the reconstituted tobacco supporting spices of the present invention to prepare cigarette (use level is (based on gross weight) 15 % by weight), inequality between cigarette and the inequality in cigarette are compared with control group, and its value all significantly reduces.
From these results, compared with the cigarette coordinated using the chopping thing of the reconstituted tobacco containing menthol as tobacco fill material, the inequality of the menthol use level between cigarette can be suppressed containing the cigarette supporting the reconstituted tobacco of spices of the present invention, and in cigarette sticks, menthol can be coordinated equably.Thus, every root cigarette perfume can be suppressed to inhale the change of the change of taste or the perfume (or spice) suction taste during cigarette smoking containing the cigarette supporting the reconstituted tobacco of spices of the present invention.
[9] result (tobacco coil paper)
Use above-mentioned experiment gimmick, for tobacco coil paper, obtain following result.
Fragrance protectiveness (employing the evaluation of tobacco coil paper) is put in the Tibetan of [9-1] menthol
Fragrance protectiveness is put in the Tibetan of the menthol using " the tobacco coil paper 1 ~ 3 supporting spices of the present invention " and " control sample of tobacco coil paper " as above prepared to evaluate in tobacco coil paper.The results are shown in Fig. 5.
Tobacco coil paper is placed under specified time limit (0 day, 7 days, 14 days, 30 days) acceleration environment.In addition, the mensuration of the menthol content in tobacco coil paper measures as described above by GC-FID carries out.In Figure 5, the result supporting the tobacco coil paper 1 of spices of the present invention is expressed as " carragheen ", the result supporting the tobacco coil paper 2 of spices of the present invention is expressed as " gellan gum ", the result supporting the tobacco coil paper 3 of spices of the present invention is expressed as " gellan gum+tamarind gum ", and the result of control sample is expressed as " control group ".Menthol content (% by weight) through type: { weight (mg) of measured value (the mg)/reconstituted tobacco of menthol content } × 100 are tried to achieve.
The menthol content of control sample puts start time (0 day) in Tibetan be about 0.7 % by weight.This control sample is placed in 50 DEG C of thermostats, results verification along with the time through and menthol content significantly reduces, after one week, almost becoming zero.
By contrast, the tobacco coil paper 1 ~ 3 supporting spices of the present invention puts start time the menthol content of (0 day) display 4 ~ 1.7 about % by weight in Tibetan, under the acceleration environment of 50 DEG C, hide postpone menthol content also more, confirm good fragrance protectiveness.
Fragrance protectiveness (employing the evaluation of cigarette) is put in the Tibetan of [9-2] menthol
Fragrance protectiveness is put in the Tibetan of the menthol using the cigarette containing " the tobacco coil paper 1 ~ 3 supporting spices of the present invention " and the contrast cigarette containing " control sample of tobacco coil paper " to evaluate in cigarette.The results are shown in Fig. 6.
Tobacco coil paper is placed as mentioned above under specified time limit (0 day, 7 days, 14 days, 30 days) acceleration environment, and uses this tobacco coil paper to make sample cigarette as mentioned above.The mensuration of the menthol amount in mainstream smoke measures as described above by GC-FID carries out.
In figure 6, be expressed as " carragheen " containing the result supporting the cigarette of the tobacco coil paper 1 of spices of the present invention, be expressed as " gellan gum " containing the result supporting the cigarette of the tobacco coil paper 2 of spices of the present invention, be expressed as " gellan gum+tamarind gum " containing the result supporting the cigarette of the tobacco coil paper 3 of spices of the present invention, the result of the cigarette containing control sample is expressed as " control group ".In figure 6, in mainstream smoke, menthol amount [mg/cig] represents the measured value (mg) of the menthol amount of every 1 cigarette.
The cigarette of the tobacco coil paper containing control sample when use hide that to put number of days be the tobacco coil paper of 0 day, display with containing menthol amount in the equal mainstream smoke of the cigarette supporting the tobacco coil paper of spices of the present invention, but when use hide that to put number of days be the tobacco coil paper of 7 days, menthol amount almost becomes zero.
By contrast, even if when hiding the tobacco coil paper put under being used in the acceleration environment of 50 DEG C containing the cigarette supporting the tobacco coil paper 1 ~ 3 of spices of the present invention, in mainstream smoke, menthol amount is also more, confirms good fragrance protectiveness.
The cooperation uniformity of [9-3] menthol
Which kind of degree is the inequality examining or check the use level of the spices between each cigarette containing the cigarette supporting the tobacco coil paper of spices of the present invention to 10 be.In addition, be divided into 3 equal portions by containing the cigarette sticks supporting the tobacco coil paper of spices of the present invention, which kind of degree is the inequality of the use level of the spices between examination each several part be.Result is shown in table 3 with " inequality between cigarette " and " inequality in cigarette " respectively.The mean value that inequality (CV%) in cigarette obtains for measuring 10 cigarettes.
About control group, with above-mentioned support in the item of the pipe tobacco of spices describe identical, ratio with 2 % by weight coordinates the chopping thing (International Publication 2009/142159) of the reconstituted tobacco containing menthol to replace the pipe tobacco supporting spices of the present invention in pipe tobacco, makes tar value consistent and makes sample cigarette.
[table 3]
When by shape equal with pipe tobacco for the reconstituted tobacco chopping one-tenth containing menthol and when coordinating (2 % by weight) in pipe tobacco, the inequality (CV%) between cigarette is 34%, in cigarette, be not 54%.On the other hand, when using the tobacco coil paper supporting spices of the present invention to prepare cigarette, the inequality between cigarette and the inequality in cigarette are compared with control group, and its value all significantly reduces.
From these results, compared with the cigarette coordinated using the chopping thing of the reconstituted tobacco containing menthol as tobacco fill material, the inequality of the menthol use level between cigarette can be suppressed containing the cigarette supporting the tobacco coil paper of spices of the present invention, and in cigarette, menthol can be coordinated equably.Thus, the perfume (or spice) of every root cigarette can be suppressed to inhale the change of the change of taste or the perfume (or spice) suction taste during cigarette smoking containing the cigarette supporting the tobacco coil paper of spices of the present invention.
[10] polysaccharide contains the temperature-responsive sol-gel transition characteristic of liquid
In this experiment, the polysaccharide examining or check following (1) ~ (3) contains the temperature-responsive sol-gel transition characteristic of liquid (slurry).
[10-1] polysaccharide contains the preparation of liquid
(1) carragheen contains liquid
Water 0.1L
Kappa-carrageenan (Karaginin CS-530/ tri-Rong Yuan FFI) 5g
(2) gellan gum contains liquid
Water 0.1L
Gellan gum (kelcogel/ tri-Rong Yuan FFI) 5g
Contain liquid about carragheen and gellan gum contains liquid, prepare as follows.
Water (0.1L) is remained 70 DEG C, while stir with (strain) E-Tech Japan high-performance agitator DMM, while make polysaccharide (5g) dissolve on a small quantity with the method that can not lump at every turn, prepare polysaccharide and contain liquid (slurry).
(3) liquid containing gellan gum and tamarind gum
Water 10L
Gellan gum (kelcogel/ tri-Rong Yuan FFI) 250g
Tamarind gum (Bistop D-2032/ tri-Rong Yuan FFI) 250g
The 5% lecithin aqueous solution (Sun Lecithin A-1/ sun chemistry (strain)) 200mL
Menthol (Takasago spices Industry Co) 2500g
Prepare as follows about the liquid containing gellan gum and tamarind gum.
While water (heating and thermal insulation is 80 DEG C) 10L (100 weight portion) is stirred with agitator (PRIMIX T.K.AUTO MIXER Model 40/ is provided with solution stirring rotator/2000rpm), while the mixing ratio (weight ratio) making the gellan gum of polysaccharide and tamarind gum become above-mentioned, and make the total amount 500g of two kinds of polysaccharide (5 weight portion) dissolve (required time about 20 minutes) on a small quantity in the mode that can not lump at every turn.Add the l-menthol of 2500g (25 weight portion) at such a temperature.Change homogenizer (PRIMIX T.K.AUTO MIXER Model 40/ is provided with rotor-stator head/4000rpm) into by mixer and carry out emulsification in 10 minutes, add the 5% lecithin aqueous solution of 200mL (2 weight portion) further and stir.Menthol is dispersed in the mixing polysaccharide class aqueous solution of gellan gum and tamarind gum.
[10-2] result
Polysaccharide is contained liquid (70 DEG C) cooling, be cooled to through about 900 seconds 25 DEG C (0.05 DEG C/sec).Then, 70 DEG C were warming up to through about 900 seconds.How the viscosity (mobility) containing liquid by flow graph (Thermo-Haake Inc., RheoStress 1) mensuration polysaccharide changes because of such variations in temperature.
Result carragheen being contained liquid is shown in Fig. 7 A and 7B, and result gellan gum being contained liquid is shown in Fig. 8 A and 8B, and the result of the liquid containing gellan gum and tamarind gum is shown in Fig. 9 A and 9B.
Carragheen contains liquid as shown in Figure 7 A, if be cooled to 25 DEG C, then viscosity is lower near sol-gel transition temperature namely about 50 DEG C, but viscosity rises (gelation) rapidly at the temperature lower than transition temperature.If by this hydrogel warms, then as shown in Figure 7 B, even if be heated beyond transition temperature, be also not easy to return to colloidal sol, can gel state be kept.
Carragheen contains liquid as shown in Figure 8 A, if be cooled to 25 DEG C, then viscosity is lower to 50 DEG C (mobility is high), but viscosity rises (gel phenomenon) rapidly below 40 DEG C.If by this hydrogel warms, then as shown in Figure 8 B, even if exceed the temperature (40 DEG C) of gelation, be also not easy to return to colloidal sol, gel state can be retained to very high temperature.
As shown in Figure 9 A, if be cooled to 25 DEG C, then viscosity is lower to 40 DEG C, but viscosity rises (gel phenomenon) rapidly below 35 DEG C for liquid containing gellan gum and tamarind gum.If by this hydrogel warms, then as shown in Figure 9 B, even if exceed the temperature (35 DEG C) of gelation, be also not easy to return to colloidal sol, gel state can be retained to very high temperature.
From these results, if the slurry containing above-mentioned polysaccharide temporarily cools and gelation, even if then make temperature rise afterwards also not easily return to colloidal sol, gel state can be kept.If it is pre-cooled that the present invention utilizes the character of this polysaccharide to carry out before making raw material slurry drying, even if the temperature when drying of the raw material slurry after then pre-cooled rises, also not easily make wherein contained polysaccharide solation, be not easily vaporized with the menthol that this polysaccharide is coated.
Claims (7)
1. support a cigarette member of formation for spices, it obtains as follows:
The flavor compositions of the collosol state of polysaccharide, spices and water is contained in the surface applications of cigarette member of formation, then, the cigarette member of formation applying flavor compositions is cooled to 0 ~ 40 DEG C, make flavor compositions gelation, then, make the described cigarette member of formation heat drying applying flavor compositions, wherein, described polysaccharide is selected from the combination of gellan gum and tamarind gum, carragheen and gellan gum.
2. the cigarette member of formation supporting spices according to claim 1, wherein, the mode that described heat drying remains on 70 ~ 100 DEG C with the surface temperature of described flavor compositions is carried out.
3. the cigarette member of formation supporting spices according to claim 1 and 2, wherein, described cigarette member of formation is tobacco coil paper.
4. the cigarette member of formation supporting spices according to claim 1 and 2, wherein, described cigarette member of formation is tobacco fill material.
5. the cigarette member of formation supporting spices according to claim 4, wherein, described cigarette packing material is pipe tobacco.
6. the cigarette member of formation supporting spices according to claim 4, wherein, described cigarette packing material is reconstituted tobacco.
7. a cigarette, it comprises the cigarette member of formation supporting spices according to any one of claim 1 ~ 6.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910561087.2A CN110279140B (en) | 2012-08-31 | 2013-08-26 | Cigarette component carrying flavor and cigarette comprising same |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2012192248 | 2012-08-31 | ||
| JP2012-192248 | 2012-08-31 | ||
| PCT/JP2013/072774 WO2014034619A1 (en) | 2012-08-31 | 2013-08-26 | Fragrance-carrying cigarette constituent member and cigarette containing same |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910561087.2A Division CN110279140B (en) | 2012-08-31 | 2013-08-26 | Cigarette component carrying flavor and cigarette comprising same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104582512A true CN104582512A (en) | 2015-04-29 |
Family
ID=50183431
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201380045426.2A Pending CN104582512A (en) | 2012-08-31 | 2013-08-26 | Fragrance-carrying cigarette constituent member and cigarette containing same |
| CN201910561087.2A Active CN110279140B (en) | 2012-08-31 | 2013-08-26 | Cigarette component carrying flavor and cigarette comprising same |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910561087.2A Active CN110279140B (en) | 2012-08-31 | 2013-08-26 | Cigarette component carrying flavor and cigarette comprising same |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP2891409B1 (en) |
| JP (1) | JP5934799B2 (en) |
| CN (2) | CN104582512A (en) |
| RU (1) | RU2587075C1 (en) |
| TW (1) | TW201420025A (en) |
| WO (1) | WO2014034619A1 (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105876852B (en) * | 2016-06-13 | 2017-04-12 | 四川三联卷烟材料有限公司 | Production method of thermal-induced fragrance-holding filter rod |
| CN110693064B (en) * | 2019-11-20 | 2022-01-14 | 湖北中烟工业有限责任公司 | Treatment liquid and treatment method for burley tobacco |
| CN111500366B (en) * | 2020-05-07 | 2023-06-09 | 云南中烟工业有限责任公司 | Preparation method and system of aroma-carrying gel |
| WO2022138260A1 (en) | 2020-12-24 | 2022-06-30 | 日本たばこ産業株式会社 | Tobacco composition, tobacco-containing segment, non-combustion heating-type flavor inhaler, and non-combustion heating-type flavor inhalation system |
| WO2022138263A1 (en) | 2020-12-24 | 2022-06-30 | 日本たばこ産業株式会社 | Method for manufacturing tobacco rod part for non-combustion heating-type flavor inhalation article |
| CN113455699A (en) * | 2021-07-12 | 2021-10-01 | 河南中烟工业有限责任公司 | Heating cigarette with uniform fragrance release amount by mouth |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0928366A (en) * | 1995-07-24 | 1997-02-04 | Japan Tobacco Inc | Cigarette |
| CN1193893A (en) * | 1995-07-07 | 1998-09-23 | 英美烟草公司 | Stabilisation of flavourants |
| JP2007023065A (en) * | 2005-07-12 | 2007-02-01 | Sanei Gen Ffi Inc | Essential oil-containing composition |
| EP2279677A1 (en) * | 2008-05-19 | 2011-02-02 | Japan Tobacco, Inc. | Material containing flavoring agent for cigarette, method for production thereof, and cigarette |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6174567A (en) * | 1984-09-19 | 1986-04-16 | 日本たばこ産業株式会社 | Flavor and smoking taste modifier for tobacco |
| GB9605117D0 (en) * | 1996-03-07 | 1996-05-08 | British American Tobacco Co | Smokable filler material for smoking articles |
| CN1082356C (en) * | 1999-04-07 | 2002-04-10 | 颐中烟草(集团)有限公司 | Method for preparing imitation tobacco sheet by adding wood pulp fiber into tobacco powder |
| EP1252831A3 (en) * | 2001-04-26 | 2004-01-21 | Givaudan SA | Particles for tobacco products |
| ZA200604406B (en) * | 2003-11-07 | 2008-12-31 | Us Smokeless Tobacco Co | Tobacco compositions |
| US8646463B2 (en) * | 2005-08-15 | 2014-02-11 | Philip Morris Usa Inc. | Gravure-printed, banded cigarette paper |
| CN103501642B (en) * | 2011-03-02 | 2018-07-24 | 日本烟草产业株式会社 | Sheet material containing fragrance and its manufacturing method and smoking article comprising the sheet material |
-
2013
- 2013-08-26 EP EP13833905.6A patent/EP2891409B1/en active Active
- 2013-08-26 JP JP2014533001A patent/JP5934799B2/en active Active
- 2013-08-26 CN CN201380045426.2A patent/CN104582512A/en active Pending
- 2013-08-26 CN CN201910561087.2A patent/CN110279140B/en active Active
- 2013-08-26 RU RU2015111175/12A patent/RU2587075C1/en active
- 2013-08-26 WO PCT/JP2013/072774 patent/WO2014034619A1/en unknown
- 2013-08-29 TW TW102131005A patent/TW201420025A/en unknown
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1193893A (en) * | 1995-07-07 | 1998-09-23 | 英美烟草公司 | Stabilisation of flavourants |
| JPH11509566A (en) * | 1995-07-07 | 1999-08-24 | ブリティッシュ−アメリカン・タバコ・カンパニー・リミテッド | Air freshener stabilization |
| JPH0928366A (en) * | 1995-07-24 | 1997-02-04 | Japan Tobacco Inc | Cigarette |
| JP2007023065A (en) * | 2005-07-12 | 2007-02-01 | Sanei Gen Ffi Inc | Essential oil-containing composition |
| EP2279677A1 (en) * | 2008-05-19 | 2011-02-02 | Japan Tobacco, Inc. | Material containing flavoring agent for cigarette, method for production thereof, and cigarette |
Also Published As
| Publication number | Publication date |
|---|---|
| RU2587075C1 (en) | 2016-06-10 |
| WO2014034619A1 (en) | 2014-03-06 |
| TW201420025A (en) | 2014-06-01 |
| JP5934799B2 (en) | 2016-06-15 |
| JPWO2014034619A1 (en) | 2016-08-08 |
| EP2891409A1 (en) | 2015-07-08 |
| EP2891409B1 (en) | 2019-06-12 |
| CN110279140A (en) | 2019-09-27 |
| CN110279140B (en) | 2022-11-29 |
| EP2891409A4 (en) | 2016-04-13 |
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