A kind of herbicide preventing and kill off Semen Cuscutae
Technical field
The present invention relates to a kind of herbicide, be specifically related to a kind of herbicide preventing and kill off Semen Cuscutae.
Background technology
Semen Cuscutae is the pernicious parasitic seed plant of Convolvulaceae semen cuscatue spp, main parasitic dicotyledon, has that generation region is wide, spread rapidly, harm is serious, be difficult to features such as preventing and kill off.After Semen Cuscutae germination is unearthed, once running into host, its root is the most withered, it is adsorbed on plant with the climing winding of stem, blade is degenerated, and loses photosynthesis, obtains self required moisture and nutrition in pin main body, grow rapid and in great numbers, often result in host plant malnutrition, grow suppressed, show as yellowing leaf, branch wilting, rate of blossoming and bearing fruit reduction etc., time serious, plant is the most dead, causes huge economic loss.
Preventing and kill off Semen Cuscutae typically to carry out three periods, one is seed stage, and two is Seedling Stage, and three is the rattan phase.
At seed stage, i.e. before Semen Cuscutae germination, spray bud pre-treatment herbicide prometryn, Acetochlor etc., primary source of infection can be substantially reduced, but owing to Semen Cuscutae seed amount is big, survival time is long, can survive for many years in soil, and distribution and germinating time are difficult to grasp, covering plus plant, medicinal liquid is difficult to spray thoughtfully, it is impossible to form the medicine film layer closing ground, so being difficult to play the bud pre-treatment herbicide inhibitory action to Semen Cuscutae seed.
At Seedling Stage, after i.e. Semen Cuscutae seed is unearthed, seedling can independent growths about 10 days, covering due to plant, often being difficult to be found, medicinal liquid is the most difficult to be sprayed onto on very thin Semen Cuscutae seedling, adds that the drug effect of herbicide typically the most gradually to manifest, so spraying medicine at Seedling Stage, it is difficult to determine whether herbicide has effect.
In the rattan phase, after i.e. Semen Cuscutae is wrapped in plant, consume moisture and the nutrition of host, needed for meeting the growth of self, its rattan is flourishing and trophophase was up to 4 ~ 5 months, it is easy to identifies, now prevents and kill off, can accomplish with a definite target in view, with seeing with removing, so the rattan phase is the best period preventing and kill off Semen Cuscutae.
At the trophophase of Semen Cuscutae rattan, prevent and kill off frequently with two kinds of methods:
Manually pull out method.Owing to Semen Cuscutae is closely coupled with host plant by haustorium, manually pulls out and waste time and energy, be difficult to thoroughly remove, and the residual segment of Semen Cuscutae is when condition is suitable, again can continued growth, form new stem climing, then secondary parasite, so that repeatedly pull out.
Stem and leaf processes the anti-division of herbicide.Spray stem and leaf and process herbicide, easy and simple to handle, instant effect, but alternative herbicide kind is rare.The Shandong often mentioned in document protects No. one, has started the beginning of Chinese microbe herbicide, and it, to people and animals' nonhazardous, easily grows, and is a kind of effective biological weed killer, but owing to this product storage life is short, and do not carry out commercial production;Use " glyphosate " prevents and treats Semen Cuscutae to have document to report, but this medicine is steriland herbicide, does not has selectivity being both between the host of dicotyledon and Semen Cuscutae, and while Semen Cuscutae is prevented and kill off, host plant also can produce obvious poisoning;" butralin " has inhibitory action to the rattan of Semen Cuscutae separately to have document to report, but in practice, it has been found that preventive effect is unsatisfactory, the only tender point to Semen Cuscutae has slight inhibitory action, and concentration increases, and host will be produced poisoning.
Chinese patent CN103098798A discloses a kind of herbicide for Soybean Field, it uses bud pre-treatment Determination of Herbicide Acetochlor that Semen Cuscutae seed is played inhibitory action, Semen Cuscutae seedling is worked by fomesafen, stem and leaf processes herbicide haloxyfop-r-methyl and Quizalotop-ethyl is high selectivity herbicide, described haloxyfop-r-methyl and Quizalotop-ethyl have chosen and well known to a person skilled in the art conventional amount used condition, only monocotyledonous stem and leaf there is is inhibitory action, dicotyledon Semen Cuscutae is prevented and kill off almost without effect.
Summary of the invention
In order to solve the problems referred to above that prior art exists, the present invention provides a kind of herbicide prevented and kill off it at the trophophase of Semen Cuscutae rattan.
The present invention adopts the following technical scheme that
A kind of herbicide preventing and kill off Semen Cuscutae, it includes effective constituents A agent and B agent and auxiliary agent, use with following proportioning: described A agent is the one in the haloxyfop-r-methyl that mass concentration is 95% of 20 ~ 100 parts by volume or the Quizalotop-ethyl of 2.5 ~ 12 weight portions, B agent is the one in the coumarin of 450 ~ 600 weight portions or the P-coumaric acid of 500 ~ 650 weight portions, auxiliary agent be mass concentration be modified poly-trisiloxanes 150 ~ 200 parts by volume of ethyoxyl of 100%;Described weight portion is all in terms of former medicine.
Further, described A agent, B agent and auxiliary agent use with following proportioning: described A agent is the one in the haloxyfop-r-methyl that mass concentration is 95% of 30 ~ 80 parts by volume or the Quizalotop-ethyl of 4 ~ 10 weight portions, B agent is the one in the coumarin of 500 ~ 600 weight portions or the P-coumaric acid of 550 ~ 650 weight portions, auxiliary agent be mass concentration be modified poly-trisiloxanes 170 ~ 200 parts by volume of ethyoxyl of 100%;Described weight portion is all in terms of former medicine.
Further, described A agent, B agent and auxiliary agent use with following proportioning: described A agent is the one in the haloxyfop-r-methyl that mass concentration is 95% of 50 ~ 60 parts by volume or the Quizalotop-ethyl of 6 ~ 8 weight portions, B agent is the one in the coumarin of 550 ~ 600 weight portions or the P-coumaric acid of 600 ~ 650 weight portions, auxiliary agent be mass concentration be modified poly-trisiloxanes 180 ~ 200 parts by volume of ethyoxyl of 100%;Described weight portion is all in terms of former medicine.
Preferably, described A agent, B agent and auxiliary agent use by following proportioning: in terms of former medicine, described A agent is the Quizalotop-ethyl of 12 weight portions, and described B agent is P-coumaric acid 600 weight portion, described auxiliary agent be mass concentration be modified poly-trisiloxanes 200 parts by volume of ethyoxyl of 100%.
Technique effect acquired by the present invention is:
The present invention uses three kinds of reagent to compound and forms, one during wherein A agent is haloxyfop-r-methyl or Quizalotop-ethyl, its consumption have employed to be different from and well known to a person skilled in the art conventional amount used, is found surprisingly that it has played effect on preventing and treating dicotyledon Semen Cuscutae;B agent uses coumarin or P-coumaric acid, and as having the material of natural activity of weeding, its inhibited report that has no of rattan to Semen Cuscutae, inventor has been found by experiment that it is inhibited to the rattan of Semen Cuscutae;Compounding by A agent and B agent, more enhances the present invention inhibitory action to Semen Cuscutae rattan;Invention also uses the modified poly-trisiloxanes of ethyoxyl so that A, B agent exhibition on Semen Cuscutae rattan surface is puted forth effort and Adhesion enhancement, thus improves the drug effect of A, B agent, reduces its amount of application.The present invention has good preventive effect to Semen Cuscutae, and fatality rate is up to 95%, and A agent uses essence quinoline and spirit, the most also can have good inhibiting effect to the inflorescence of Semen Cuscutae, and to most dicotyledonous host plant safety, itself low toxicity, to people, animal, the safety of water source.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described in detail.Scope is not limited to embodiment, and those skilled in the art make any change in the range of claim limits and fall within the scope of protection of the invention.
Medicine used and reagent are as follows, and wherein, described concentration is mass percentage concentration:
Dehydrated alcohol, is purchased from Tianjin Guang Cheng chemical reagent company limited, and concentration is more than 99%.
Haloxyfop-r-methyl, chemical entitled 2-[4-(5-trifluoromethyl-3-chloro-pyridine-2-epoxide) phenoxy group] methyl propionate, it is purchased from Shandong Binnong Technology Co., Ltd., concentration is 95%.
Quizalotop-ethyl, chemistry entitled (R)-2-[4-(6-chloroquinoxalin-2-yloxy) phenoxy group] ethyl propionate, it is purchased from Shandong Chen Yu Chemical Co., Ltd., concentration is 95%.
Coumarin, chemistry entitled 1,2-benzopyrone, it is purchased from Chengdu Ke Long chemical reagent factory, concentration is 99%.
P-coumaric acid, chemical entitled 3-(4-hydroxy phenyl)-2 acrylic acid, it is purchased from Shanghai Jin Sui Science and Technology Ltd., concentration is 98%.
The modified poly-trisiloxanes of ethyoxyl, is purchased from Europe, Yantai bass biochemistry corporation,Ltd., and concentration is 100%.
The quality of each formula medicine described in embodiment is its former medicine quality, and the drug quality i.e. buied by producer is multiplied by the quality of the pure medicine that the concentration of this medicine obtains.
The computational methods of fatality rate are:
Fatality rate (%)=(comparison Semen Cuscutae survival rattan number processes Semen Cuscutae survival rattan number) ÷ comparison Semen Cuscutae survival rattan number × 100
Wherein, processing Semen Cuscutae survival rattan number is the Semen Cuscutae rattan number using the present invention to survive after spraying;Comparison Semen Cuscutae survival rattan number is the Semen Cuscutae rattan number using clear water to survive after spraying.
Embodiment 1
In terms of former medicine, take Quizalotop-ethyl 12mg and P-coumaric acid 600mg, complement to 1 liter with water again with after a small amount of anhydrous alcohol solution, shake up standby, add the modified poly-trisiloxanes 200mL of ethyoxyl before sprinkling, be sprayed on after mix homogeneously on the Cuscuta Japonica rattan colonizing in Euonymus japonicus.Result shows, Cuscuta Japonica fatality rate is 95%, and Semen Cuscutae inflorescence is suppressed, and the growth of host Euonymus japonicus is normal.
Embodiment 2
In terms of former medicine, take haloxyfop-r-methyl 30mL and coumarin 500mg, complement to 1 liter with water again with after anhydrous alcohol solution, shake up standby, add the modified poly-trisiloxanes 150mL of ethyoxyl before sprinkling, be sprayed on after mix homogeneously on the Cuscuta Japonica rattan colonizing in Euonymus japonicus.Result shows, the Cuscuta Japonica tender rattan segmentation of children is withered, and fatality rate is 65%, and inflorescence growth is normal, and the growth of host Euonymus japonicus is normal.
Embodiment 3 ~ 12
The compound method of embodiment 3 ~ 12 is same as in Example 1, and the preparation prepared sprays on the Cuscuta Japonica rattan colonizing in Euonymus japonicus, and its formula and preventive effect are as shown in table 1 below:
Table 1
EXPERIMENTAL EXAMPLE 1
In terms of former medicine, take haloxyfop-r-methyl 20mL, complement to 1 liter with water again with after a small amount of anhydrous alcohol solution, shake up standby, add the modified poly-trisiloxanes 200mL of ethyoxyl before sprinkling, be sprayed on after mix homogeneously on the Cuscuta Japonica rattan colonizing in Euonymus japonicus.Result shows, Cuscuta Japonica fatality rate is 15%, and the only segmentation of Semen Cuscutae rattan is withered.
EXPERIMENTAL EXAMPLE 2 ~ 6
The compound method of EXPERIMENTAL EXAMPLE 2 ~ 6 is identical with EXPERIMENTAL EXAMPLE 1, and the preparation prepared sprays on the Cuscuta Japonica rattan colonizing in Euonymus japonicus, and its formula and preventive effect are as shown in table 2 below:
Table 2
Can be seen that from EXPERIMENTAL EXAMPLE 1 ~ 6, only use in the haloxyfop-r-methyl in A agent or Quizalotop-ethyl a kind of time, haloxyfop-r-methyl or Quizalotop-ethyl are in the concentration range it described, inhibited to the rattan of Semen Cuscutae, but acting on more weak, the youngest tender part is suppressed substantially, to thicker rattan DeGrain, and along with the raising of concentration, the effect of Quizalotop-ethyl is obviously improved than the inhibitory action of haloxyfop-r-methyl.
EXPERIMENTAL EXAMPLE 7 ~ 12
The compound method of EXPERIMENTAL EXAMPLE 7 ~ 12 is identical with EXPERIMENTAL EXAMPLE 1, and the preparation prepared sprays on the Cuscuta Japonica rattan colonizing in Euonymus japonicus, and its formula and preventive effect are as shown in table 3 below:
Table 3
From EXPERIMENTAL EXAMPLE 7 ~ 12 it can be seen that only use in the coumarin B agent or P-coumaric acid a kind of time, in its described respective concentration range, the rattan of Semen Cuscutae is had inhibitory action, but effect is not fine.
In conjunction with the embodiments 1 ~ 12 and EXPERIMENTAL EXAMPLE 1 ~ 12, it can be seen that the present invention, by A agent and B agent being compounded, significantly enhances the inhibitory action to Semen Cuscutae rattan.
According to the above embodiments, the present invention is described in detail.It should be noted that, above embodiment is just to illustrating invention.On the premise of without departing from spirit and substance of the present invention, those skilled in the art can be designed that multiple alternative and the improvement project of the present invention, within it all should be understood protection scope of the present invention again.