CN106465733A - A kind of Semen Cuscutae administers agent - Google Patents

A kind of Semen Cuscutae administers agent Download PDF

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Publication number
CN106465733A
CN106465733A CN201610828389.8A CN201610828389A CN106465733A CN 106465733 A CN106465733 A CN 106465733A CN 201610828389 A CN201610828389 A CN 201610828389A CN 106465733 A CN106465733 A CN 106465733A
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parts
agent
semen cuscutae
administer
compositions
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CN201610828389.8A
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郑浩
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Chengdu Cedisen Biological Technology Co Ltd
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Chengdu Cedisen Biological Technology Co Ltd
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Priority to CN201610828389.8A priority Critical patent/CN106465733A/en
Publication of CN106465733A publication Critical patent/CN106465733A/en
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N63/00—Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates
    • A01N63/10—Animals; Substances produced thereby or obtained therefrom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/26—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests in coated particulate form
    • A01N25/28—Microcapsules or nanocapsules
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02—Amines; Quaternary ammonium compounds
    • A01N33/12—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/28—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
    • A01N47/44—Guanidine; Derivatives thereof

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  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Dentistry (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Environmental Sciences (AREA)
  • Biotechnology (AREA)
  • Microbiology (AREA)
  • Virology (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a kind of Semen Cuscutae administers agent, belong to pesticide field.A kind of Semen Cuscutae of the present invention administers agent, by 37 ~ 45 parts of acylhydrazone schiff base compounds of mass parts, 22 ~ 40 parts of prestox divinyl triiodide ammoniums, 14 ~ 20 parts of chitinases, 12 ~ 23 parts of solvents, 8 ~ 17 parts of slow releasing agents and 5 ~ 10 parts of buffer agent compositions.A kind of Semen Cuscutae of the present invention is administered agent and is had for Semen Cuscutae parasitic character, disturb the perception of its Herba Lobeliae Chinensiss lactone receptor, promote Semen Cuscutae natural apoptosis, thus reach preventing and treating purpose, reduce pressure and the destructive power that broad-spectrum herbicide brings to environment, reduce the workload manually rooted out, improve the feature of Semen Cuscutae governance efficiency.

Description

A kind of Semen Cuscutae administers agent
Technical field
The present invention relates to a kind of herbicide, particularly a kind of Semen Cuscutae improvement agent.
Background technology
Semen Cuscutae is kind of an annual parasitism draft, and parasitic scope is wider, can parasitize pulse family, Solanaceae, Rosaceae, Fructus Sapindi Mukouossi The woody and herbaceous plant of many sections such as section, its root is degenerated, and blade deteriorates to flakey, and stem is yellow filament, very thin, meat Matter, is around in the stem of parasitic plant, is connected with the fibrovascular system of haustorium and host, not only absorbs nutrient and the water of host Point, also result in the mechanical sexual disorders of host's conducting tissue, the thread physical ability that it is wound around on host constantly extends, and spreads.Due to not having There is herbicide effective for Semen Cuscutae, existing Semen Cuscutae prevention and controls are manually to root out to combine chemical control, manually root out Not only workload is larger, and cures the symptoms, not the disease it is difficult to accomplish thoroughly to eradicate, and chemical control generally adopts broad-spectrum herbicide, right The inhibitory action of Semen Cuscutae is limited, also has lethal effect to other straw or like vegetables simultaneously, and regulation effect is not good.
Content of the invention
The goal of the invention of the present invention is：For above-mentioned problem, provide one kind to be directed to Semen Cuscutae parasitic character, do Disturbing the perception of its Herba Lobeliae Chinensiss lactone receptor, promote Semen Cuscutae natural apoptosis, thus reach preventing and treating purpose, reducing broad-spectrum herbicide pair Pressure and destructive power that environment brings, reduce the workload manually rooted out, and the Semen Cuscutae improving Semen Cuscutae governance efficiency administers agent.
The technical solution used in the present invention is as follows：
A kind of Semen Cuscutae of the present invention administers agent, by 37～45 parts of acylhydrazone schiff base compounds of mass parts, 22～40 part of eight first Base divinyl triiodide ammonium, 14～20 parts of chitinases, 12～23 parts of solvents, 8～17 parts of slow releasing agents and 5～10 parts of buffer agent groups Become, described acylhydrazone schiff base compounds structural formula is,.
Foot gold lactone has stimulation parasitic plant seed and sprouts, promotes AMF mycelia to produce branch, directly or Indirectly suppression plant sprouting of lateral bud and with all multiactions such as host plant symbiosis, plant, in growth course, can discharge Herba Lobeliae Chinensiss To in soil, Semen Cuscutae passes through to perceive Herba Lobeliae Chinensiss lactone this hormone of lactone, promotes its germination, is attached to host's root and sucks battalion Support.Due to employing technique scheme, can interfere with the receptor that Semen Cuscutae perceives to Herba Lobeliae Chinensiss lactone, thus suppressing Semen Cuscutae Growth, promotes its natural apoptosis, reaches the purpose of preventing and treating；Without broad-spectrum herbicide composition, little to other plant growth effect, right The pressure that environment and ecology are brought is less.
A kind of Semen Cuscutae of the present invention administers agent, by 42 parts of acylhydrazone schiff base compounds of mass parts, 30 parts of prestox diethyls Alkene triiodide ammonium, 16 parts of chitinases, 18 parts of solvents, 17 parts of slow releasing agents and 9 parts of buffer agent compositions, described acylhydrazone Schiff's base chemical combination Thing structural formula is,.
Due to employing technique scheme, aforementioned proportion is optimum, and after spraying 10d, apoptosis rate is 64.7%, growth Suppression ratio is 80.3%.
A kind of Semen Cuscutae of the present invention administers agent, and described chitinase is with sodium alginate, 2- methyl -6- nitrobenzene sulfonamide Make microcapsule with VE for wall material.
Due to employing technique scheme, prepared microcapsule good forming effect, in uniform-spherical, surface of microcapsule shape Become the gel of three-dimensional network shape, form one layer of fine and close protecting film, increased the intensity of microcapsule, the life of chitinase can be made Thing activity is maintained, long-time in administering agent in the presence of still keep good biological activity.
A kind of Semen Cuscutae of the present invention administers agent, and described microcapsule is wet microcapsule, the matter of described chitinase and wall material Amount ratio is 1：3.5, by 14 parts of sodium alginates of mass parts, 7 parts of 2- methyl -6- nitrobenzene sulfonamides and 3 parts of VE form described wall material.
Due to employing technique scheme, aforementioned proportion is optimum, and the average diameter of microcapsule granule is 41.4 μm, Wall material can be slowly by slow disintegrate in slow releasing agent, and a length of 7.2d of complete disintegrate mean time extends the biological of chitinase and lives Property keep duration.
A kind of Semen Cuscutae of the present invention administers agent, described solvent by mass parts 30 water, 16 parts of glycol dimethyl ethers, 8 part third Ketone and 18 parts of hydrxyethyl ether compositions.
Due to employing technique scheme, dissolving is relatively completely it is ensured that administer the permeability in soil of agent.
A kind of Semen Cuscutae of the present invention administers agent, described slow releasing agent by 8 parts of dispersing agent MFs of mass parts, 8 The multiple phenol polyethenoxy ether of part Diphenethyl, 15 parts of glycerol and 12 parts of ethylene glycol compositions.
Due to employing technique scheme, slow releasing agent will be administered active ingredient in agent and fully wrap up, and form atomization oil smoke Agent, thus expanding the spray area administering agent, it is to avoid at one, spraying agent is excessive, brings pressure to other plants and environment, Between the oiliness droplet being formed and target, affinity is strong, has the longer lasting period；Medication economy, easy to use, produce effects fast, use When this preparation is quantitatively delivered to, by fog machine, the moment mixing in fuming pipe with high-temperature high-speed airflow, be injected into big immediately Volatilize rapidly and formed the microdroplet of a diameter of a few micrometers in gas, suspension can be diffused for a long time in an atmosphere, can be voluntarily to crop clump Middle diffusion, infiltration, are uniformly deposited in the different azimuth at each position of target, deposition effect is good, prevent and treat efficiency high, Neng Gou great Area is prevented and treated.
A kind of Semen Cuscutae of the present invention administers agent, and described buffer agent is made up of barbital sodium and hydrochloric acid.
A kind of Semen Cuscutae of the present invention administers agent, and the pH value administering agent is maintained 6.3～6.8 scopes by described buffer agent Interior.
Due to employing technique scheme, administer using effect in this pH value range for the agent good.
In sum, due to employing technique scheme, the invention has the beneficial effects as follows：
1st, it is directed to Semen Cuscutae parasitic character, disturbs the perception of its Herba Lobeliae Chinensiss lactone receptor, promote Semen Cuscutae natural apoptosis, from And reach and prevent and treat purpose, reduce pressure and the destructive power that broad-spectrum herbicide brings to environment, reduce the workload manually rooted out, carry High Semen Cuscutae governance efficiency.
2nd, form atomization fume agent, thus expanding the spray area administering agent, it is to avoid at one, spraying agent is excessive, to other Plant and environment bring pressure, between the oiliness droplet of formation and target, affinity is strong, has the longer lasting period；Medication warp Ji, easy to use, produce effects fast.
3rd, surface of microcapsule forms the gel of three-dimensional network shape, forms one layer of fine and close protecting film, increased microcapsule Intensity, can make the biological activity of chitinase be maintained, long-time in administering agent in the presence of still keep good biology Activity；After spraying 10d, apoptosis rate is 64.7%, and growth inhibition ratio is 80.3%.
Brief description
Fig. 1 is that in prestox divinyl triiodide ammonium, quaternary ammonium root cation is wrapped up schematic diagram by high poly- iodide ion；
Fig. 2 is U-shaped in prestox divinyl triiodide ammoniumAnd Z-typeForm discrete supramolecular structure schematic diagram.
Specific embodiment
The present invention is described in detail below.
In order that the purpose of invention, technical scheme and advantage become more apparent, with reference to embodiments, the present invention is entered Row further describes.It should be appreciated that specific embodiment described herein, only in order to explain the present invention, is not used to limit Determine the present invention.
1st, acylhydrazone schiff base compoundsSynthetic route is as follows：
Weigh parachlorobenzoic-acid 1.57g, with the methanol 30mL (ratio 1 of the amount of material：1) dissolve, transfer to the single port of 50mL In flask, it is slow added into 7mL concentrated sulphuric acid, mix homogeneously.Constant temperature back flow reaction 5h.It is cooled to room temperature, pour into equipped with going on a small quantity In the beaker of ionized water, that is, white extraction is had to separate out, dehydrated alcohol is recrystallized to give parachlorobenzoic-acid methyl ester.
Weigh parachlorobenzoic-acid methyl ester 0.5g, with ethanol dissolving, mix with appropriate hydrazine hydrate that (amount of material compares 1：1), permanent Warm back flow reaction 5h.It is cooled to room temperature, sucking filtration.Dehydrated alcohol recrystallization, obtains white plates crystal, p-chloro benzoyl hydrazine.
Weigh 0.2g to chlorobenzene benzoyl hydrazine agent appropriate Biformyl (amount of material compares 1：2), it is situated between with dehydrated alcohol for reaction Matter, back flow reaction 5h.Standing cooling, sucking filtration obtains crude product, dehydrated alcohol recrystallization, obtains target product, cream-white crystals.1H NMR(DMSO-d6)δ：10.85～10.87 (s, 2H), 7.54～7.59 (m, 4H), 7.91～7.96 (m, 6H)；1H NMR (DMSO-d6)δ：137.6,130.9,130.1,128.4,161.2,147.9.
2nd, prestox divinyl triiodide ammoniumSynthetic route as follows：
Add pentamethyl-diethylenetriamine 2.1mL and DMF30mL in reaction bulb, stirring is lower to add iodomethane 5.6mL, in Room temperature reaction 24h.Sucking filtration, filter cake is washed with a small amount of acetonitrile, and vacuum drying obtains white solid A.
Sequentially add methanol 25mL and 0.3gA in reaction bulb, stirring makes it dissolve, is warming up to backflow, is slowly added dropwise I2 Methanol (25mL) solution of 1.2g, reacts 2h after completion of dropping.Standing cooling, Chu's black acicular crystal perhaps, sucking filtration, filter cake vacuum It is dried to obtain black acicular crystal, obtain rhombus bulk black crystals with sewage recrystallizing methanol, be target product.
In target product, quaternary ammonium cation is wrapped up by the height of surrounding poly- iodine anion completely, whereinAnd its it is adjacentComposition is U-shapedAnd I2With adjacent twoComposition Z-typeTwo U-shapedWith a Z-typeAlternately arranged Constitute 3 discrete supermolecule iodine chain elementary cell.With adjacent discrete iodine chain elementary cell pattern of rows and columns and U-shapedOpening The difference in direction, makesDiscrete supermolecule iodine chain element piles up the three dimensional structure for high poly- iodide ion.
Quaternary ammonium root cation is as shown in Figure 1 with the relative position of high poly- iodide ion.N1 is in an approximate rectangular plane The Dian Huan center of (Layer 2), 19 are in the plane (Layer 1) directly over this iodine ring, The rugosity iodine ring of I10A ... I7A ... I12A ... I10B ... I1lB formation that N2 and N3 atom is respectively by I11A ... surrounds, meanwhile, By two groups (IlD-I2D-I3D and I1E-I2E-I3E) about iodine ring, I10C and I11C is closed N3, make whole quaternary ammonium root sun from Son is surrounded by high poly- iodide ion completely.In target product, there is the poly- iodine unit (as shown in Figure 2) of three kinds of different height, respectively Be two kinds one-dimensional asymmetricChain (IlA-I2A-I3A and I7A-I6A-I10A) and one are in 89.715 (22) ° of V-type(I4A-I5A-I12A-I9A-I8A), its bond distance and bond angle are shown in Table 1.
The main bond distance of table 1 prestox divinyl triiodide ammonium and bond angle
a1-x ,-y ,-z；b- x, 1-y, 1-z
3rd, chitinase is inoculated in 10mL fluid medium according to 0.1% amount, 37 DEG C of constant temperature culture 12h, activates 2 After～3 times, then it is inoculated in 250mL fluid medium by 0.1% amount, 37 DEG C of constant temperature culture 15h, 4500r/min is centrifuged 15min harvests enzyme liquid, 0.9% brine, and 4500r/min is centrifuged 15min, then washes twice results enzyme liquid.
Sodium alginate soln is mixed homogeneously with 2- methyl -6- nitrobenzene sulfonamide and VE according to mass ratio, to mixed liquor In be continuously passed through sterile nitrogen, according still further to mass ratio add enzyme liquid mixing, with 2mL syringe, mixed liquor is instilled after stirring 3%CaCl2In solution, after solidification 30min with 0.9% brine 3 times, prepared microcapsule.
4th, acylhydrazone schiff base compounds are weighed according to mass ratio, prestox divinyl triiodide ammonium and make the several of microcapsule Fourth matter enzyme, quality parts ratio is as shown in table 2, by solvent according to mass parts 30 water, 16 parts of glycol dimethyl ethers, 8 parts of acetone and 18 Part hydrxyethyl ether shake up miscible after, be continuously passed through sterile nitrogen in solution, by acylhydrazone schiff base compounds, prestox divinyl Triiodide ammonium and chitinase are slowly added to solution, are stirred overnight at a temperature of 4 DEG C, and standing is recovered to room temperature, uses bar ratio The pH value that appropriate sodium-hydrochloride buffer adjusts improvement reason agent is 6.3～6.8；By 8 parts of dispersing agent MFs of mass parts, 8 The multiple phenol polyethenoxy ether of part Diphenethyl, 15 parts of glycerol and 12 parts of ethylene glycol are configured to slow releasing agent, and mixed liquor is added to slow Release agent, make slow release fume agent.
5th, administer agent biological activity test, each group is administered agent and sprays Semen Cuscutae according to 75g/ha metering is lower, test after 10d , to the apoptosis rate of Semen Cuscutae biological action and suppression ratio, the apoptosis rate of blank control group is 99.4%, and suppression ratio is for it 0%.
Agent each constituent mass when biological activity administered by table 2
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all essences in the present invention Any modification, equivalent and improvement made within god and principle etc., should be included within the scope of the present invention.

Claims (8)

1. a kind of Semen Cuscutae administer agent it is characterised in that：By 37 ~ 45 parts of acylhydrazone schiff base compounds of mass parts, 22 ~ 40 part of eight first Base divinyl triiodide ammonium, 14 ~ 20 parts of chitinases, 12 ~ 23 parts of solvents, 8 ~ 17 parts of slow releasing agents and 5 ~ 10 parts of buffer agent compositions, Described acylhydrazone schiff base compounds structural formula is.
2. as claimed in claim 1 a kind of Semen Cuscutae administer agent it is characterised in that：By 42 parts of acylhydrazone Schiff's base chemical combination of mass parts Thing, 30 parts of prestox divinyl triiodide ammoniums, 16 parts of chitinases, 18 parts of solvents, 17 parts of slow releasing agents and 9 parts of buffer agent compositions, Described acylhydrazone schiff base compounds structural formula is.
3. as claimed in claim 1 or 2 a kind of Semen Cuscutae administer agent it is characterised in that：Described chitinase with sodium alginate, 2- methyl -6- nitrobenzene sulfonamide and VE make microcapsule for wall material.
4. as claimed in claim 3 a kind of Semen Cuscutae administer agent it is characterised in that：Described microcapsule is wet microcapsule, described Chitinase is 1 with the mass ratio of wall material：3.5, described wall material is by 14 parts of sodium alginates of mass parts, 7 parts of 2- methyl -6- Nitrobenzol Sulfonamide and 3 parts of VE compositions.
5. as claimed in claim 4 a kind of Semen Cuscutae administer agent it is characterised in that：Described solvent by mass parts 30 water, 16 parts Glycol dimethyl ether, 8 parts of acetone and 18 parts of hydrxyethyl ether compositions.
6. a kind of Semen Cuscutae as described in claim 4 or 5 administer agent it is characterised in that：Described slow releasing agent is by 8 parts of Asias of mass parts The double methyl naphthalene sulfonic acid sodium of methyl, 8 parts of Diphenethyl phenol polyethenoxy ethers again, 15 parts of glycerol and 12 parts of ethylene glycol compositions.
7. as claimed in claim 6 a kind of Semen Cuscutae administer agent it is characterised in that：Described buffer agent is by barbital sodium and hydrochloric acid Composition.
8. as claimed in claim 7 a kind of Semen Cuscutae administer agent it is characterised in that：Described buffer agent will administer the pH value dimension of agent Hold in the range of 6.3 ~ 6.8.
CN201610828389.8A 2016-09-18 2016-09-18 A kind of Semen Cuscutae administers agent Pending CN106465733A (en)

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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104542609A (en) * 2015-01-05 2015-04-29 乔建国 Herbicide for preventing and removing semen cuscutae

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104542609A (en) * 2015-01-05 2015-04-29 乔建国 Herbicide for preventing and removing semen cuscutae

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
M. LEVER: ""BIS-AROYLHYDRAZONES OF α-DIKETONES AS REAGENTS FOR COLORIMETRIC AND FLUORIMETRIC DETERMINATIONS OF CALCIUM, CADMIUM AND OTHER CATIONS"", 《ANALYTICA CHIMICA ACTA》 *
于新等: "《天然食品添加剂》", 31 March 2014, 中国轻工业出版社 *
王渊等: ""八甲基二乙烯三碘化铵高聚碘的合成及其晶体结构"", 《合成化学》 *

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Application publication date: 20170301