CN104532504A - Preparation method of polytetrafluoroethylene glass fiber breathable varnished cloth - Google Patents

Preparation method of polytetrafluoroethylene glass fiber breathable varnished cloth Download PDF

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Publication number
CN104532504A
CN104532504A CN201410823621.XA CN201410823621A CN104532504A CN 104532504 A CN104532504 A CN 104532504A CN 201410823621 A CN201410823621 A CN 201410823621A CN 104532504 A CN104532504 A CN 104532504A
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cloth
glass fiber
glass
polytetrafluoroethylene
sintering
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CN201410823621.XA
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赵文杰
赵晖
侯金国
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JIANGSU TAIFULONG TECHNOLOGY Co Ltd
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JIANGSU TAIFULONG TECHNOLOGY Co Ltd
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Priority to CN201410823621.XA priority Critical patent/CN104532504A/en
Publication of CN104532504A publication Critical patent/CN104532504A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N1/00Linoleum, e.g. linoxyn, polymerised or oxidised resin
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • D06N3/0022Glass fibres
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0088Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin
    • D06N3/0093Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin by applying resin powders; by sintering
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/047Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with fluoropolymers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00Macromolecular materials of the coating layers
    • D06N2203/04Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N2203/044Fluoropolymers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/12Permeability or impermeability properties
    • D06N2209/121Permeability to gases, adsorption
    • D06N2209/123Breathable

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Reinforced Plastic Materials (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention relates to a preparation method of polytetrafluoroethylene glass fiber breathable varnished cloth. The preparation method comprises the following steps: (1) pre-treating glass cloth; (2) impregnating the glass cloth; (3) drying; (4) roasting; (5) sintering; and (6) cooling to obtain the polytetrafluoroethylene glass fiber breathable varnished cloth. The preparation process provided by the invention has the beneficial effects that by uniformly coating and impregnating alkali-free glass cloth by polytetrafluoroethylene emulsion, the glass fiber cloth is primarily moulded by impregnating, drying, roasting and sintering, so that the preparation process is simplified and the energy consumption is reduced; the polytetrafluoroethylene glass fiber breathable varnished cloth produced is free of bubbles on the surface, uniform in glue content, good in air permeability and low in production cost, has the high-temperature-resisting and high-strength performances of a glass fiber fabric, and also has a series of excellent performances such as insulation and anti-adherence of polytetrafluoroethylene. The polytetrafluoroethylene glass fiber breathable varnished cloth widely applied to all fields is a macromolecular composite material which is high in performance and diversified in function.

Description

A kind of polytetrafluoroethylglass glass fiber is breathed freely the preparation technology of varnished cloth
Technical field
The invention belongs to technical field of polymer composite materials, be specifically related to a kind of polytetrafluoroethylglass glass fiber and breathe freely the preparation technology of varnished cloth.
Background technology
Glass fabric does not have that intensity is high, dimensionally stable, high temperature resistant, good corrosion resistance and filter efficiency advantages of higher, but glass fibre also has obvious shortcoming, i.e. crisp, the not folding of property, wear-resisting, easily weares and teares, fractures, affect service life.
Polytetrafluoroethylmicroporous microporous membrane adopts biaxial tension technology to produce, there is unique microcellular structure, Air permenbility is large, resistance is low, high particulate trap rate, temperature tolerance are good, anti-strong acid, alkali, organic solvent and oxidant, the features such as ageing-resistant and sticky, noninflammability and nontoxic, biocompatibility, use after the application technology of current microporous teflon membran mainly carries out compound with fabric or supatex fabric, its complex process, cost is high.
To improving the performances such as the folding of glass fabric, wear-resisting and hydrophobicity after coated glass fiber polytetrafluoroethylene (PTFE), increase the service life most important.Glass fabric is after dipping ptfe emulsion; through super-dry, cure, the operation such as sintering; maceration extract is dried and makes it in fiber surface film forming; reach protection fiber; make it from chemical attack; and improve outside the properties such as its folding, wear-resisting and hydrophobicity, also must possess superior permeability.
The breathable cloth complex process that in prior art, (1) polytetrafluoroethylmicroporous microporous membrane and glass fabric compound obtain, production cost are high, unstable properties; (2) method of the direct coated glass fiber cloth of ptfe emulsion, because emulsion formulations is unreasonable, easily produce bubble, gel content is higher, and permeability is poor, is difficult to the technical requirement reaching regulation.
Summary of the invention
For solving the problems of the technologies described above, as follows for the technical scheme of the employing of invention:
Prepare polytetrafluoroethylglass glass fiber to breathe freely the technique of varnished cloth, comprise the following steps:
(1) preliminary treatment of glass cloth: the wax of 2.5% must be added owing to preventing when ORGANDY is woven into glass cloth fractureing as lubricant, first should eliminate before impregnation, otherwise not easily be infiltrated by PTFE emulsion, and spread can be uneven.Pretreated method dries with the speed of 10 ~ 15 m/min to burn under the high temperature of 450 DEG C, sintering zone, both can remove wax, and also can remove glass hair in small, broken bits;
(2) impregnated glass colth: pretreated for step (1) ORGANDY is immersed four dipping tanks containing polytetrafluoroethylene (PTFE), the polytetrafluoroethylene content of dipping tank respectively: 30%, 30%, 40%, 40%, soak time is 2-6m/min;
(3) dry, the glass cloth soaked in step (2) is carried out drying, and baking temperature is 80-90 DEG C, removing moisture, makes grey cloth micro-dry;
(4) cure, cured by dried glass cloth in step (3), stoving temperature is 280-290 DEG C, and the surfactant in removing ptfe emulsion and moisture, through repeatedly flooding the grey cloth obtaining larger coating;
(5) sinter, baked grey cloth in step (4) is sintered through sintering zone, sintering temperature is 380-400 DEG C, sintering velocity is identical with impregnating speed, behind sintering zone, polytetrafluoroethylene (PTFE) components fuse, interface disappears and welding is surperficial at glass fiber yarn, become the Compound Fabric having good bonding power with ORGANDY, the surfactant in maceration extract all decomposes at a sintering temperature and does not remain in goods;
(6) cool, sintered part can be taken out in high temperature furnace after terminating and cool, improve Wear Resistance.
Preferably, in step (2), preferred dip time is 2.5m/min.
Preferably, in step (3), preferred baking temperature is 85 DEG C.
Preferably, in step (4), preferred stoving temperature is 285 DEG C.
Preferably, in step (5), preferred sintering temperature is 388 DEG C.
Beneficial effect of the present invention: by being applied equably by ptfe emulsion, being immersed on alkali-free glass cloth, makes glass fabric through ptfe emulsion dipping, drying, bakes and banks up with earth, sinters one-shot forming, simplify preparation technology, saved energy consumption.Breathe freely varnished cloth surface bubble-free, gel content of the polytetrafluoroethylglass glass fiber produced is even, permeability is good, production cost is low, it had both had high temperature resistant, the high-intensity performance of glass fabric, there is again the excellent insulation of polytetrafluoroethylene (PTFE), a series of performance such as antiseized, be widely used in high temperature resistant, ventilative, antiseized, vacuumize, eliminate the field such as negative pressure and the demoulding, be a kind of high-performance, multiduty polymer composite.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is set forth further:
Prepare polytetrafluoroethylglass glass fiber to breathe freely the technique of varnished cloth, comprise the following steps:
(1) preliminary treatment of glass cloth: the wax of 2.5% must be added owing to preventing when ORGANDY is woven into glass cloth fractureing as lubricant, first should eliminate before impregnation, otherwise not easily be infiltrated by PTFE emulsion, and spread can be uneven.Pretreated method dries with the speed of 10 ~ 15 m/min to burn under the high temperature of 450 DEG C, sintering zone, both can remove wax, and also can remove glass hair in small, broken bits;
(2) impregnated glass colth: pretreated for step (1) ORGANDY is immersed four dipping tanks containing polytetrafluoroethylene (PTFE), the polytetrafluoroethylene content of dipping tank respectively: 30%, 30%, 40%, 40%, soak time is 2-6m/min;
(3) dry, the glass cloth soaked in step (2) is carried out drying, and baking temperature is 80-90 DEG C, removing moisture, makes grey cloth micro-dry;
(4) cure, cured by dried glass cloth in step (3), stoving temperature is 280-290 DEG C, and the surfactant in removing ptfe emulsion and moisture, through repeatedly flooding the grey cloth obtaining larger coating;
(5) sinter, baked grey cloth in step (4) is sintered through sintering zone, sintering temperature is 380-400 DEG C, sintering velocity is identical with impregnating speed, behind sintering zone, polytetrafluoroethylene (PTFE) components fuse, interface disappears and welding is surperficial at glass fiber yarn, become the Compound Fabric having good bonding power with ORGANDY, the surfactant in maceration extract all decomposes at a sintering temperature and does not remain in goods;
(6) cool, sintered part can be taken out in high temperature furnace after terminating and cool, improve Wear Resistance.
embodiment 1
Prepare polytetrafluoroethylglass glass fiber to breathe freely the technique of varnished cloth, comprise the following steps:
(1) preliminary treatment of glass cloth: the wax of 2.5% must be added owing to preventing when ORGANDY is woven into glass cloth fractureing as lubricant, first should eliminate before impregnation, otherwise not easily be infiltrated by PTFE emulsion, and spread can be uneven.Pretreated method dries with the speed of 10 m/min to burn under the high temperature of 450 DEG C, sintering zone, both can remove wax, and also can remove glass hair in small, broken bits;
(2) impregnated glass colth: pretreated for step (1) ORGANDY is immersed four dipping tanks containing polytetrafluoroethylene (PTFE), the polytetrafluoroethylene content of dipping tank respectively: 30%, 30%, 40%, 40%, soak time is 2m/min;
(3) dry, the glass cloth soaked in step (2) is carried out drying, and baking temperature is 80-90 DEG C, removing moisture, makes grey cloth micro-dry;
(4) cure, cured by dried glass cloth in step (3), stoving temperature is 280 DEG C, and the surfactant in removing ptfe emulsion and moisture, through repeatedly flooding the grey cloth obtaining larger coating;
(5) sinter, baked grey cloth in step (4) is sintered through sintering zone, sintering temperature is 380 DEG C, sintering velocity is identical with impregnating speed, behind sintering zone, polytetrafluoroethylene (PTFE) components fuse, interface disappears and welding is surperficial at glass fiber yarn, become the Compound Fabric having good bonding power with ORGANDY, the surfactant in maceration extract all decomposes at a sintering temperature and does not remain in goods;
(6) cool, sintered part can be taken out in high temperature furnace after terminating and cool, improve Wear Resistance.
embodiment 2
Prepare polytetrafluoroethylglass glass fiber to breathe freely the technique of varnished cloth, comprise the following steps:
(1) preliminary treatment of glass cloth: the wax of 2.5% must be added owing to preventing when ORGANDY is woven into glass cloth fractureing as lubricant, first should eliminate before impregnation, otherwise not easily be infiltrated by PTFE emulsion, and spread can be uneven.Pretreated method dries with the speed of 12 m/min to burn under the high temperature of 450 DEG C, sintering zone, both can remove wax, and also can remove glass hair in small, broken bits;
(2) impregnated glass colth: pretreated for step (1) ORGANDY is immersed four dipping tanks containing polytetrafluoroethylene (PTFE), the polytetrafluoroethylene content of dipping tank respectively: 30%, 30%, 40%, 40%, soak time is 2.5m/min;
(3) dry, the glass cloth soaked in step (2) is carried out drying, and baking temperature is 85 DEG C, removing moisture, makes grey cloth micro-dry;
(4) cure, cured by dried glass cloth in step (3), stoving temperature is 285 DEG C, and the surfactant in removing ptfe emulsion and moisture, through repeatedly flooding the grey cloth obtaining larger coating;
(5) sinter, baked grey cloth in step (4) is sintered through sintering zone, sintering temperature is 88 DEG C, sintering velocity is identical with impregnating speed, behind sintering zone, polytetrafluoroethylene (PTFE) components fuse, interface disappears and welding is surperficial at glass fiber yarn, become the Compound Fabric having good bonding power with ORGANDY, the surfactant in maceration extract all decomposes at a sintering temperature and does not remain in goods;
(6) cool, sintered part can be taken out in high temperature furnace after terminating and cool, improve Wear Resistance.
embodiment 3
Prepare polytetrafluoroethylglass glass fiber to breathe freely the technique of varnished cloth, comprise the following steps:
(1) preliminary treatment of glass cloth: the wax of 2.5% must be added owing to preventing when ORGANDY is woven into glass cloth fractureing as lubricant, first should eliminate before impregnation, otherwise not easily be infiltrated by PTFE emulsion, and spread can be uneven.Pretreated method dries with the speed of 15 m/min to burn under the high temperature of 450 DEG C, sintering zone, both can remove wax, and also can remove glass hair in small, broken bits;
(2) impregnated glass colth: pretreated for step (1) ORGANDY is immersed four dipping tanks containing polytetrafluoroethylene (PTFE), the polytetrafluoroethylene content of dipping tank respectively: 30%, 30%, 40%, 40%, soak time is 6m/min;
(3) dry, the glass cloth soaked in step (2) is carried out drying, and baking temperature is 90 DEG C, removing moisture, makes grey cloth micro-dry;
(4) cure, cured by dried glass cloth in step (3), stoving temperature is 290 DEG C, and the surfactant in removing ptfe emulsion and moisture, through repeatedly flooding the grey cloth obtaining larger coating;
(5) sinter, baked grey cloth in step (4) is sintered through sintering zone, sintering temperature is 400 DEG C, sintering velocity is identical with impregnating speed, behind sintering zone, polytetrafluoroethylene (PTFE) components fuse, interface disappears and welding is surperficial at glass fiber yarn, become the Compound Fabric having good bonding power with ORGANDY, the surfactant in maceration extract all decomposes at a sintering temperature and does not remain in goods;
(6) cool, sintered part can be taken out in high temperature furnace after terminating and cool, improve Wear Resistance.

Claims (5)

1. prepare polytetrafluoroethylglass glass fiber to breathe freely the technique of varnished cloth, it is characterized in that, comprise the following steps:
(1) preliminary treatment of glass cloth: the wax of 2.5% must be added owing to preventing when ORGANDY is woven into glass cloth fractureing as lubricant, should first eliminate before impregnation, otherwise not easily infiltrated by PTFE emulsion, and spread can be uneven, pretreated method dries with the speed of 10 ~ 15 m/min to burn under the high temperature of 450 DEG C, sintering zone, both can remove wax, also can remove glass hair in small, broken bits;
(2) impregnated glass colth: pretreated for step (1) ORGANDY is immersed four dipping tanks containing polytetrafluoroethylene (PTFE), the polytetrafluoroethylene content of dipping tank respectively: 30%, 30%, 40%, 40%, soak time is 2-6m/min;
(3) dry, the glass cloth soaked in step (2) is carried out drying, and baking temperature is 80-90 DEG C, removing moisture, makes grey cloth micro-dry;
(4) cure, cured by dried glass cloth in step (3), stoving temperature is 280-290 DEG C, and the surfactant in removing ptfe emulsion and moisture, through repeatedly flooding the grey cloth obtaining larger coating;
(5) sinter, baked grey cloth in step (4) is sintered through sintering zone, sintering temperature is 380-400 DEG C, sintering velocity is identical with impregnating speed, behind sintering zone, polytetrafluoroethylene (PTFE) components fuse, interface disappears and welding is surperficial at glass fiber yarn, become the Compound Fabric having good bonding power with ORGANDY, the surfactant in maceration extract all decomposes at a sintering temperature and does not remain in goods;
(6) cool, sintered part can be taken out in high temperature furnace after terminating and cool, improve Wear Resistance.
2. polytetrafluoroethylglass glass fiber of preparing according to claim 3 is breathed freely the technique of varnished cloth, it is characterized in that: in step (2), preferred dip time is 2.5m/min.
3. polytetrafluoroethylglass glass fiber of preparing according to claim 3 is breathed freely the technique of varnished cloth, it is characterized in that: in step (3), preferred baking temperature is 85 DEG C.
4. polytetrafluoroethylglass glass fiber of preparing according to claim 3 is breathed freely the technique of varnished cloth, it is characterized in that: in step (4), preferred stoving temperature is 285 DEG C.
5. polytetrafluoroethylglass glass fiber of preparing according to claim 3 is breathed freely the technique of varnished cloth, it is characterized in that: in step (5), preferred sintering temperature is 388 DEG C.
CN201410823621.XA 2014-12-26 2014-12-26 Preparation method of polytetrafluoroethylene glass fiber breathable varnished cloth Pending CN104532504A (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105128350A (en) * 2015-09-01 2015-12-09 广东德美精细化工股份有限公司 Method for preparing polytetrafluoroethylene building membrane
CN106274007A (en) * 2016-07-30 2017-01-04 龙宇电子(梅州)有限公司 For multilayer printed wiring board and the preparation method of the cushion pad of copper-clad plate process for pressing
CN106370454A (en) * 2016-08-18 2017-02-01 江苏泰氟隆科技有限公司 Sampling scraping sheet for explosive detecting instrument and manufacturing process thereof
CN106555339A (en) * 2016-11-08 2017-04-05 扬州东润新材料科技有限公司 A kind of high temperature resistant not preparation of sticky cloth and application process
WO2018032795A1 (en) * 2016-08-18 2018-02-22 江苏泰氟隆科技有限公司 Laminated cloth for 4g or 5g network circuit board substrate and manufacturing process of same
CN108929526A (en) * 2017-05-25 2018-12-04 合肥杰事杰新材料股份有限公司 A kind of low smell, PET composition of high abrasion and preparation method thereof
CN113103694A (en) * 2020-01-13 2021-07-13 北京服装学院 Preparation method of novel imitation leather environment-friendly fabric
CN113718532A (en) * 2021-09-16 2021-11-30 江苏奥凯新材料科技有限公司 Corrosion-resistant and heat-resistant bump-free high-temperature anti-sticking cloth and manufacturing process thereof
CN114908570A (en) * 2022-04-29 2022-08-16 安徽汉烯科技有限公司 Base film for graphene oxide coating and preparation method thereof
WO2024130754A1 (en) * 2022-12-24 2024-06-27 杜肯新材料(武汉)集团股份有限公司 Flexible fireproof air conduit

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CN101869789A (en) * 2009-04-27 2010-10-27 上海科格思过滤材料有限公司 Polyfluortetraethylene coating film filter material
CN102700196A (en) * 2012-06-25 2012-10-03 上海市塑料研究所 Preparation method of polytetrafluoroethylene glass fiber wear-resistance plate
JP2013049945A (en) * 2010-04-05 2013-03-14 Nitto Boseki Co Ltd Silica particulate-holding glass fiber fabric and fiber-reinforced resin-molded body

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CN101869789A (en) * 2009-04-27 2010-10-27 上海科格思过滤材料有限公司 Polyfluortetraethylene coating film filter material
JP2013049945A (en) * 2010-04-05 2013-03-14 Nitto Boseki Co Ltd Silica particulate-holding glass fiber fabric and fiber-reinforced resin-molded body
CN102700196A (en) * 2012-06-25 2012-10-03 上海市塑料研究所 Preparation method of polytetrafluoroethylene glass fiber wear-resistance plate

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105128350A (en) * 2015-09-01 2015-12-09 广东德美精细化工股份有限公司 Method for preparing polytetrafluoroethylene building membrane
CN106274007B (en) * 2016-07-30 2018-12-25 龙宇电子(梅州)有限公司 Preparation method for multilayer printed wiring board and the cushion of copper-clad plate process for pressing
CN106274007A (en) * 2016-07-30 2017-01-04 龙宇电子(梅州)有限公司 For multilayer printed wiring board and the preparation method of the cushion pad of copper-clad plate process for pressing
CN106370454A (en) * 2016-08-18 2017-02-01 江苏泰氟隆科技有限公司 Sampling scraping sheet for explosive detecting instrument and manufacturing process thereof
WO2018032795A1 (en) * 2016-08-18 2018-02-22 江苏泰氟隆科技有限公司 Laminated cloth for 4g or 5g network circuit board substrate and manufacturing process of same
CN106555339A (en) * 2016-11-08 2017-04-05 扬州东润新材料科技有限公司 A kind of high temperature resistant not preparation of sticky cloth and application process
CN108929526A (en) * 2017-05-25 2018-12-04 合肥杰事杰新材料股份有限公司 A kind of low smell, PET composition of high abrasion and preparation method thereof
CN108929526B (en) * 2017-05-25 2022-06-28 合肥杰事杰新材料股份有限公司 Low-odor and high-wear-resistance PET (polyethylene terephthalate) composition and preparation method thereof
CN113103694A (en) * 2020-01-13 2021-07-13 北京服装学院 Preparation method of novel imitation leather environment-friendly fabric
CN113718532A (en) * 2021-09-16 2021-11-30 江苏奥凯新材料科技有限公司 Corrosion-resistant and heat-resistant bump-free high-temperature anti-sticking cloth and manufacturing process thereof
CN114908570A (en) * 2022-04-29 2022-08-16 安徽汉烯科技有限公司 Base film for graphene oxide coating and preparation method thereof
CN114908570B (en) * 2022-04-29 2023-11-17 安徽汉烯科技有限公司 Base film for graphene oxide coating and preparation method thereof
WO2024130754A1 (en) * 2022-12-24 2024-06-27 杜肯新材料(武汉)集团股份有限公司 Flexible fireproof air conduit

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