CN106555339A - A kind of high temperature resistant not preparation of sticky cloth and application process - Google Patents

A kind of high temperature resistant not preparation of sticky cloth and application process Download PDF

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Publication number
CN106555339A
CN106555339A CN201610981818.5A CN201610981818A CN106555339A CN 106555339 A CN106555339 A CN 106555339A CN 201610981818 A CN201610981818 A CN 201610981818A CN 106555339 A CN106555339 A CN 106555339A
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CN
China
Prior art keywords
high temperature
temperature resistant
sticky cloth
carbon fiber
application process
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Pending
Application number
CN201610981818.5A
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Chinese (zh)
Inventor
杨建校
刘君基
曾自力
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Yangzhou Dongrun New Mstar Technology Ltd
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Yangzhou Dongrun New Mstar Technology Ltd
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Priority to CN201610981818.5A priority Critical patent/CN106555339A/en
Publication of CN106555339A publication Critical patent/CN106555339A/en
Pending legal-status Critical Current

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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • D06N3/0022Glass fibres
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/41Phenol-aldehyde or phenol-ketone resins
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0011Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using non-woven fabrics
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/007Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
    • D06N3/0077Embossing; Pressing of the surface; Tumbling and crumbling; Cracking; Cooling; Heating, e.g. mirror finish
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0088Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/047Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with fluoropolymers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/40Fibres of carbon
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/06Properties of the materials having thermal properties

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

A kind of high temperature resistant not preparation of sticky cloth and application process, belong to new material technology field, sticky cloth glass fabric coating polytetrafluoroethylene (PTFE) is not processed the high temperature resistant, applied during carbon fiber felt is produced, using the high temperature resistant and sticky cloth does not make workpiece not glue with bolster in multi-daylight press solidification process, is easy to the demoulding.Sticky cloth heat-resisting quantity is not strong for high temperature resistant of the present invention, and ageing resistance is high;Surface is smooth, not easy-adhesion any material;The corrosion of resistance to strong acid and highly basic;Insulation, fire protection flame retarding.It is applied in carbon fiber felt producing process, easily, product surface is smooth, smooth for the demoulding;Binder free permeates and mold sticking;The a large amount of paper scraps caused by brown paper are used in overcoming solidification process in the past, to the potential safety hazard that burner hearth is caused;Overcome the past to be sticked on upper and lower mould with the binding agent seepage caused by brown paper place mat, and after solidifying every time, clear up the spent plenty of time;It is reusable, not only reduces cost but also save resources.

Description

A kind of high temperature resistant not preparation of sticky cloth and application process
Technical field
The invention belongs to new material technology field, more particularly to a kind of high temperature resistant not preparation of sticky cloth and application process.
Background technology
During the hard felt of Carbon fiber thermal insulation is produced, hot-press solidifying is an important process, and past during this Paste with upper/lower die toward the workpiece for occurring producing, often isolated using brown paper in conventional solidification process, but Jing often goes out Existing phenolic resin infiltration or isolation not exclusively cause sticking to mould, and after the demoulding, resin solidification is remained on upper and lower mould, is difficult to clean up, and ox Mulberry paper is sticked to when carrying out high-temperature process on workpiece, brings very big injury, cleaning thoroughly not to cause lower batch to be produced again to burner hearth Product surface produces indenture or a large amount of cuts, so that product becomes unqualified, it is therefore proposed that a kind of new material had both been resistant to 250 DEG C high Temperature is easy to the demoulding to be a research direction again.
The content of the invention
For the problems referred to above, it is an object of the invention to provide a kind of preparation method of high temperature resistant not sticky cloth, the present invention's is another One purpose is to provide this kind of high temperature resistant not application process of the sticky cloth during the hard felt of Carbon fiber thermal insulation is produced.
For achieving the above object, the present invention takes technical scheme below:A kind of preparation method of high temperature resistant not sticky cloth, which is special Levy and be, comprise the following steps:
The first step:Braided glass fibre shapes:Glass fibre Jing shreddings, unclog and readjust, into net, laying acupuncture shaping;
Second step:Dipping and coating Teflon resin:Compiled with glass fibre is coated on Teflon resin suspension impregnation On fabric;
3rd step:Drying:Glass fabric after dipping or coating is dried after drying in resistance-type baking oven.
Used in the second step is 20%-30% Teflon resin suspension.
In 3rd step, drying temperature is 60 DEG C, and drying time is 40-80min.
The high temperature resistant not sticky cloth thickness be 0.08-0.9mm, density be 165-1650g/m.
A kind of application process of high temperature resistant not sticky cloth, the application process are, during carbon fiber felt is produced, to utilize The high temperature resistant and not sticky cloth make workpiece not glue with bolster in multi-daylight press solidification process, are easy to the demoulding, concrete to wrap Include following steps:
The first step:Carbon fiber felt is through infiltration, extruding, dry for standby;
Second step:With high temperature resistant, sticky cloth is not laid on lower mould sheet metal;
3rd step:Carbon fiber felt laying and layers cementing operation are carried out on the high temperature resistant that finishes of laying not sticky cloth;
4th step:After bonding reaches design thickness, then sticky cloth is not covered in uppermost carbon fiber felt laying with high temperature resistant On, deliver to;
5th step:Solidification is finished and is cooled to room temperature, and into some strength, sticky cloth is not carried out simply clearly workpiece to take out high temperature resistant Reason.
In the first step, impregnating agent is 10% phenolic resin and 90% industrial alcohol according to 2.5:1 ratio is mixed, Infiltrating time is 10min, and drying temperature is 60 DEG C, and drying time is 30-60min.
In the second step, sticky cloth does not tile 1 layer high temperature resistant.
In 4th step, sticky cloth does not cover 1 layer to high temperature resistant.
Sticky cloth heat-resisting quantity is strong for high temperature resistant of the present invention, can 300 DEG C of high temperature resistant, ageing resistance is high, can continuously repeatedly Use;Surface is smooth, not easy-adhesion any material, it is easy to remove various attachments;The corrosion of resistance to strong acid and highly basic;Insulate, prevent Fire is fire-retardant.By the high temperature resistant, sticky cloth is not applied in carbon fiber felt producing process, and easily, product surface is smooth, smooth for the demoulding; Binder free permeates and mold sticking;In carbonisation, a large amount of paper caused by brown paper in overcoming solidification process in the past, are used Bits, to the potential safety hazard that burner hearth is caused;The past was overcome to be sticked on upper and lower mould with the binding agent seepage caused by brown paper place mat, The spent plenty of time is cleared up after solidifying every time;Improve start number of times and effect;It is reusable, save substantial amounts of ox-hide Paper, not only reduces cost but also save resources.
Specific embodiment
Embodiment 1
The preparation method of a kind of high temperature resistant not sticky cloth, it is characterised in that comprise the following steps:
The first step:Braided glass fibre shapes:Glass fibre Jing shreddings, unclog and readjust, into net, laying acupuncture shaping;
Second step:Dipping and coating Teflon resin:With 20% Teflon resin suspension impregnation be coated on glass fibers On dimension braid;
3rd step:Drying:Glass fabric after dipping or coating is dried after drying in resistance-type baking oven, drying temperature Spend for 60 DEG C, drying time is 40min.
High temperature resistant after the preparation not sticky cloth thickness be 0.08mm, density is 165g/m.The high temperature resistant not sticky cloth chi Very little stable, intensity is high, extends sum and is less than 5%;Temperature tolerance is good, 70-260 DEG C of continuous operating temperature;Table machine coefficient of friction is little, Good insulating;Resistance to bond is good, it is easy to which cleaning is attached to the various oil stains on surface, stain or other attachments;Good corrosion resistance, no Burning, it is ageing-resistant.
Embodiment 2
The application process of high temperature resistant not sticky cloth in a kind of embodiment 1, the application process is to produce the mistake of carbon fiber felt Cheng Zhong, using the high temperature resistant and sticky cloth does not make workpiece not glue with bolster in multi-daylight press solidification process, is easy to take off Mould, specifically includes following steps:
The first step:10% phenolic resin and 90% industrial alcohol are according to 2.5:1 proportions impregnating agent, carbon fiber felt is with matching somebody with somebody The impregnating agent infiltration 10min of system, extruding, 60 DEG C of drying 30-60min, it is standby;
Second step:With 1 layer of high temperature resistant, sticky cloth is not laid on lower mould sheet metal;
3rd step:Carbon fiber felt laying and layers cementing operation are carried out on the high temperature resistant that finishes of laying not sticky cloth;
4th step:After bonding reaches design thickness, then sticky cloth is not covered in uppermost carbon fiber felt paving with 1 layer of high temperature resistant On layer, deliver to;
5th step:Solidification is finished and is cooled to room temperature, and into some strength, sticky cloth is not carried out simply clearly workpiece to take out high temperature resistant Reason.
Embodiment 3
A kind of each step of preparation method of the not sticky cloth of the high temperature resistant described in the present embodiment is in the same manner as in Example 1, different Technical parameter be:Second step 25% Teflon resin suspension impregnation and coating;3rd step drying time is 60min;System The thickness of the not sticky cloth of the high temperature resistant after standby is 0.49mm, and density is 905g/m.
Embodiment 4
A kind of each step of preparation method of the not sticky cloth of the high temperature resistant described in the present embodiment is in the same manner as in Example 1, different Technical parameter be:Second step 30% Teflon resin suspension impregnation and coating;3rd step drying time is 80min;System The thickness of the not sticky cloth of the high temperature resistant after standby is 0.9mm, and density is 1650g/m.
The general principle and principal character of the present invention are had been shown and described above, those skilled in the art should be recognized that this Invention is not restricted to the described embodiments, the above embodiments and specification description merely illustrate the principles of the invention, not On the premise of departing from spirit and scope of the invention, the present invention has various changes and modifications, and these changes and improvements both fall within this In the claimed scope of invention, the claimed scope of the invention is by appending claims and equivalent thereof.

Claims (9)

1. the preparation method of a kind of high temperature resistant not sticky cloth, it is characterised in that comprise the following steps:
The first step:Braided glass fibre shapes:Glass fibre Jing shreddings, unclog and readjust, into net, laying acupuncture shaping;
Second step:Dipping and coating Teflon resin:With Teflon resin suspension impregnation be coated on fiberglass braided thing On;
3rd step:Drying:Glass fabric after dipping or coating is dried after drying in resistance-type baking oven.
2. a kind of preparation method of high temperature resistant according to claim 1 not sticky cloth, it is characterised in that institute in the second step With for 20%-30% Teflon resin suspension.
3. the preparation method of a kind of high temperature resistant according to claim 1 not sticky cloth, it is characterised in that dry in the 3rd step Dry temperature is 60 DEG C, and drying time is 40-80min.
4. the preparation method according to a kind of arbitrary described high temperature resistant of claims 1 to 3 not sticky cloth, it is characterised in that described resistance to High temperature not sticky cloth thickness be 0.08-0.9mm, density be 165-1650g/m.
5. a kind of application process according to the arbitrary described high temperature resistant of claims 1 to 3 not sticky cloth, it is characterised in that it is described should It is that, during carbon fiber felt is produced, using the high temperature resistant and sticky cloth is not made in multi-daylight press solidification process with method Workpiece is not glued with bolster, is easy to the demoulding.
6. the application process of a kind of high temperature resistant according to claim 5 not sticky cloth, it is characterised in that specifically include following step Suddenly:
The first step:Carbon fiber felt is through infiltration, extruding, dry for standby;
Second step:With high temperature resistant, sticky cloth is not laid on lower mould sheet metal;
3rd step:Carbon fiber felt laying and layers cementing operation are carried out on the high temperature resistant that finishes of laying not sticky cloth;
4th step:After bonding reaches design thickness, then with high temperature resistant, sticky cloth is not covered in uppermost carbon fiber felt laying, is sent Curing process is carried out to multi-daylight press;
5th step:Solidification is finished and is cooled to room temperature, and into some strength, sticky cloth is not carried out simply workpiece to take out high temperature resistant:Cleaning.
7. the application process of a kind of high temperature resistant according to claim 6 not sticky cloth, it is characterised in that soak in the first step Stain agent is 10% phenolic resin and 95% industrial alcohol according to 2.5:1 ratio is mixed, and infiltrating time is 10min, drying temperature Spend for 60 DEG C, drying time is 30-60min.
8. the application process of a kind of high temperature resistant according to claim 4 not sticky cloth, it is characterised in that resistance in the second step Sticky cloth does not tile 1 layer high temperature.
9. the application process of a kind of high temperature resistant according to claim 4 not sticky cloth, it is characterised in that resistance in the 4th step Sticky cloth does not cover 1 layer to high temperature.
CN201610981818.5A 2016-11-08 2016-11-08 A kind of high temperature resistant not preparation of sticky cloth and application process Pending CN106555339A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610981818.5A CN106555339A (en) 2016-11-08 2016-11-08 A kind of high temperature resistant not preparation of sticky cloth and application process

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Application Number Priority Date Filing Date Title
CN201610981818.5A CN106555339A (en) 2016-11-08 2016-11-08 A kind of high temperature resistant not preparation of sticky cloth and application process

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Publication Number Publication Date
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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5221500A (en) * 1975-08-12 1977-02-18 Toray Industries Fire resistant sheet
CN1135952A (en) * 1995-05-15 1996-11-20 郭晓明 Teflon fabrics and its application
CN103088638A (en) * 2012-12-04 2013-05-08 靖江市星杰电力设备制造有限公司 New processing technology of Teflon high-temperature cloth
CN104249496A (en) * 2013-06-26 2014-12-31 上海杰事杰新材料(集团)股份有限公司 Fireproof heat insulation composite lightweight sheet material and preparation method thereof
CN104532504A (en) * 2014-12-26 2015-04-22 江苏泰氟隆科技有限公司 Preparation method of polytetrafluoroethylene glass fiber breathable varnished cloth
CN106012534A (en) * 2016-06-21 2016-10-12 江苏曜彰体育用品有限公司 Processing method of high-temperature-resistant fabric

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5221500A (en) * 1975-08-12 1977-02-18 Toray Industries Fire resistant sheet
CN1135952A (en) * 1995-05-15 1996-11-20 郭晓明 Teflon fabrics and its application
CN103088638A (en) * 2012-12-04 2013-05-08 靖江市星杰电力设备制造有限公司 New processing technology of Teflon high-temperature cloth
CN104249496A (en) * 2013-06-26 2014-12-31 上海杰事杰新材料(集团)股份有限公司 Fireproof heat insulation composite lightweight sheet material and preparation method thereof
CN104532504A (en) * 2014-12-26 2015-04-22 江苏泰氟隆科技有限公司 Preparation method of polytetrafluoroethylene glass fiber breathable varnished cloth
CN106012534A (en) * 2016-06-21 2016-10-12 江苏曜彰体育用品有限公司 Processing method of high-temperature-resistant fabric

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