CN104530855A - Water-based rust conversion and prevention paint - Google Patents

Water-based rust conversion and prevention paint Download PDF

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Publication number
CN104530855A
CN104530855A CN201410667256.8A CN201410667256A CN104530855A CN 104530855 A CN104530855 A CN 104530855A CN 201410667256 A CN201410667256 A CN 201410667256A CN 104530855 A CN104530855 A CN 104530855A
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China
Prior art keywords
water
parts
raw material
stirred
add
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Pending
Application number
CN201410667256.8A
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Chinese (zh)
Inventor
周长
李寿国
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Maanshan City Jin Han Coating Manufacturing Co Ltd
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Maanshan City Jin Han Coating Manufacturing Co Ltd
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Priority to CN201410667256.8A priority Critical patent/CN104530855A/en
Publication of CN104530855A publication Critical patent/CN104530855A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20Diluents or solvents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a water-based rust conversion and prevention paint. The water-based rust conversion and prevention paint is composed of following raw materials, by weight, 0.3 to 1 part of isophorone oxide, 10 to 13 parts of alkyd resin, 1 to 2 parts of tea saponin, 1 to 2 parts of 2-mercaptobenzimidazol, 0.3 to 0.5 part of steel slag powder, 0.7 to 1 part of chilli powder, 0.8 to 2 parts of polyhexamethylene guanidine, 3 to 4 parts of barium metaborate, 4 to 6 parts of bauxite, 0.7 to 1 part of polyacrylamide, 1 to 2 parts of monopotassium phosphate, 4 to 5 parts of iso-octyl methacrylate, 100 to 110 parts of waterborne acrylic emulsion, 0.5 to 1 part of sodium hexametaphosphate, 2 to 3 parts of an auxiliary agent, 0.1 to 0.2 part of simethicone, and 6 to 10 parts of deionized water. The water-based rust conversion and prevention paint possesses excellent corrosion resistance; when the water-based rust conversion and prevention paint is used, direct spraying or painting can be performed without surface processing; rust resistance is excellent; and water is taken as the solvent, so that the water-based rust conversion and prevention paint is capable of avoiding environment pollution caused by solvent based coatings.

Description

A kind of water-based anti-rust paint for rusty surfaces
Technical field
The main technical field of coatings of the present invention, particularly relates to a kind of water-based anti-rust paint for rusty surfaces.
Background technology
At present, major part coating is solvent based coating, in solvent based coating containing have an appointment 50% organic solvent, a large amount of VOC gas can be discharged after these paint spay-coatings, not only healthy to end user of serious harm, also can pollute air, damage ecotope, and existing rust-inhibiting paint cost is high, and performance is single, as or only high temperature resistant or only corrosion-resistant or only there is flame retardant resistance, significantly limit the Application Areas of rust proof paint thus.
Summary of the invention
The object of the invention is just to provide a kind of water-based anti-rust paint for rusty surfaces.
The present invention is achieved by the following technical solutions:
A kind of water-based anti-rust paint for rusty surfaces, is made up of the raw material of following weight parts:
Oxidation isophorone 0.3-1, Synolac 10-13, tea saponin 1-2,2-thiol group benzimidazolyl 1-2, steel-making slag powder 0.3-0.5, red chilly powder 0.7-1, polyhexamethylene guanidine 0.8-2, barium metaborate 3-4, bauxitic clay 4-6, polyacrylamide 0.7-1, potassium primary phosphate 1-2, Isooctyl methacrylate 4-5, aqueous acrylic emulsion 100-110, Sodium hexametaphosphate 99 0.5-1, auxiliary agent 2-3, dimethyl silicone oil 0.1-0.2, deionized water 6-10;
Described auxiliary agent is made up of the raw material of following weight parts:
Chlorinated polyether resin 20-30, calcium aluminate powder 4-6, zinc borate 2-3, propandiol butyl ether 5-8, Trimethoprim lactate 1-2, tetradecanoic acid soda soap 5-7, Natvosol 1-2, deionized water 6-10;
Natvosol is joined in deionized water, after stirring, add Trimethoprim lactate, calcium aluminate powder, be stirred to water and do; Mixed with tetradecanoic acid soda soap by propandiol butyl ether, be uniformly mixed 3-5 minute, add chlorinated polyether resin, be stirred to normal temperature at 40-50 DEG C, add each raw material of residue, 200-300 rev/min is stirred 10-20 minute, obtains described auxiliary agent.
A preparation method for water-based anti-rust paint for rusty surfaces, comprises the following steps:
By Synolac, aqueous acrylic emulsion, tea saponin, 2-thiol group benzimidazolyl, Sodium hexametaphosphate 99, dimethyl silicone oil mixing, 300-400 rev/min of dispersed with stirring 10-20 minute, obtains slurries;
Bauxitic clay, steel-making slag powder, red chilly powder, potassium primary phosphate are mixed to join in deionized water, are uniformly mixed 2-3 minute at 50-60 DEG C, add polyacrylamide, be stirred to normal temperature;
By each raw material mixing after above-mentioned process, add each raw material of residue, pour at 0 DEG C in stirred pot, slowly stir and be warming up to room temperature, stir 2-3 hour, obtain described water-based anti-rust paint for rusty surfaces.
Advantage of the present invention is:
Rust-inhibiting paint of the present invention has excellent erosion resistance, and in use, without the need to carrying out surface treatment, directly carrying out spraying or brushing, favorable rust preventing effect, take water as solvent, overcomes the pollution of solvent based coating to environment.
Embodiment
Embodiment 1
A kind of water-based anti-rust paint for rusty surfaces, it is made up of the raw material of following weight parts:
Oxidation isophorone 0.3, Synolac 13, tea saponin 1,2-thiol group benzimidazolyl 1, steel-making slag powder 0.5, red chilly powder 0.7, polyhexamethylene guanidine 0.8, barium metaborate 3, bauxitic clay 4, polyacrylamide 0.7, potassium primary phosphate 1, Isooctyl methacrylate 5, aqueous acrylic emulsion 110, Sodium hexametaphosphate 99 0.5, auxiliary agent 2, dimethyl silicone oil 0.2, deionized water 10;
Described auxiliary agent is made up of the raw material of following weight parts:
Chlorinated polyether resin 30, calcium aluminate powder 6, zinc borate 2, propandiol butyl ether 8, Trimethoprim lactate 2, tetradecanoic acid soda soap 7, Natvosol 1, deionized water 10;
Natvosol is joined in deionized water, after stirring, add Trimethoprim lactate, calcium aluminate powder, be stirred to water and do; Mixed with tetradecanoic acid soda soap by propandiol butyl ether, be uniformly mixed 5 minutes, add chlorinated polyether resin, be stirred to normal temperature at 50 DEG C, add each raw material of residue, 00 rev/min is stirred 20 minutes, obtains described auxiliary agent.
A preparation method for water-based anti-rust paint for rusty surfaces, comprises the following steps:
By Synolac, aqueous acrylic emulsion, tea saponin, 2-thiol group benzimidazolyl, Sodium hexametaphosphate 99, dimethyl silicone oil mixing, 400 revs/min of dispersed with stirring 20 minutes, obtain slurries;
Bauxitic clay, steel-making slag powder, red chilly powder, potassium primary phosphate are mixed to join in deionized water, are uniformly mixed 3 minutes at 60 DEG C, add polyacrylamide, be stirred to normal temperature;
By each raw material mixing after above-mentioned process, add each raw material of residue, pour at 0 DEG C in stirred pot, slowly stir and be warming up to room temperature, stir 2 hours, obtain described water-based anti-rust paint for rusty surfaces.
Performance test:
Paint film uniform hue, smooth;
Salt water resistance (3% sodium-chlor, 24h): not bubble, do not come off, without blushing;
Abrasion resistance: 5000 times are not show-through.

Claims (2)

1. a water-based anti-rust paint for rusty surfaces, is characterized in that what it was made up of the raw material of following weight parts:
Oxidation isophorone 0.3-1, Synolac 10-13, tea saponin 1-2,2-thiol group benzimidazolyl 1-2, steel-making slag powder 0.3-0.5, red chilly powder 0.7-1, polyhexamethylene guanidine 0.8-2, barium metaborate 3-4, bauxitic clay 4-6, polyacrylamide 0.7-1, potassium primary phosphate 1-2, Isooctyl methacrylate 4-5, aqueous acrylic emulsion 100-110, Sodium hexametaphosphate 99 0.5-1, auxiliary agent 2-3, dimethyl silicone oil 0.1-0.2, deionized water 6-10;
Described auxiliary agent is made up of the raw material of following weight parts:
Chlorinated polyether resin 20-30, calcium aluminate powder 4-6, zinc borate 2-3, propandiol butyl ether 5-8, Trimethoprim lactate 1-2, tetradecanoic acid soda soap 5-7, Natvosol 1-2, deionized water 6-10;
Natvosol is joined in deionized water, after stirring, add Trimethoprim lactate, calcium aluminate powder, be stirred to water and do; Mixed with tetradecanoic acid soda soap by propandiol butyl ether, be uniformly mixed 3-5 minute, add chlorinated polyether resin, be stirred to normal temperature at 40-50 DEG C, add each raw material of residue, 200-300 rev/min is stirred 10-20 minute, obtains described auxiliary agent.
2. a preparation method for water-based anti-rust paint for rusty surfaces as claimed in claim 1, is characterized in that comprising the following steps:
By Synolac, aqueous acrylic emulsion, tea saponin, 2-thiol group benzimidazolyl, Sodium hexametaphosphate 99, dimethyl silicone oil mixing, 300-400 rev/min of dispersed with stirring 10-20 minute, obtains slurries;
Bauxitic clay, steel-making slag powder, red chilly powder, potassium primary phosphate are mixed to join in deionized water, are uniformly mixed 2-3 minute at 50-60 DEG C, add polyacrylamide, be stirred to normal temperature;
By each raw material mixing after above-mentioned process, add each raw material of residue, pour at 0 DEG C in stirred pot, slowly stir and be warming up to room temperature, stir 2-3 hour, obtain described water-based anti-rust paint for rusty surfaces.
CN201410667256.8A 2014-11-20 2014-11-20 Water-based rust conversion and prevention paint Pending CN104530855A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410667256.8A CN104530855A (en) 2014-11-20 2014-11-20 Water-based rust conversion and prevention paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410667256.8A CN104530855A (en) 2014-11-20 2014-11-20 Water-based rust conversion and prevention paint

Publications (1)

Publication Number Publication Date
CN104530855A true CN104530855A (en) 2015-04-22

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105462385A (en) * 2015-11-27 2016-04-06 湖南省英越船舶配套工程有限责任公司 Environment-friendly boot topping paint for yacht and preparation method of boot topping paint
CN106590180A (en) * 2016-12-13 2017-04-26 苏州科胜仓储物流设备有限公司 Anti-rust specimen holder
CN115160867A (en) * 2022-04-20 2022-10-11 江苏华夏制漆科技有限公司 Water-based on-rust paint and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101240137A (en) * 2008-02-20 2008-08-13 江阴市天邦涂料化工有限公司 Special-purpose protection dope for petroleum pipe/drill pipe and its preparation method and construction method
WO2012153382A1 (en) * 2011-05-09 2012-11-15 日本ペイントマリン株式会社 Anti-corrosive coating composition and method for forming coating film
CN103409017A (en) * 2013-07-18 2013-11-27 吴江骏达电梯部件有限公司 Aqueous antirust paint with rust
CN103436120A (en) * 2013-08-07 2013-12-11 山东奔腾漆业有限公司 Water-based alkyd resin and modified acrylic emulsion metal paint and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101240137A (en) * 2008-02-20 2008-08-13 江阴市天邦涂料化工有限公司 Special-purpose protection dope for petroleum pipe/drill pipe and its preparation method and construction method
WO2012153382A1 (en) * 2011-05-09 2012-11-15 日本ペイントマリン株式会社 Anti-corrosive coating composition and method for forming coating film
CN103409017A (en) * 2013-07-18 2013-11-27 吴江骏达电梯部件有限公司 Aqueous antirust paint with rust
CN103436120A (en) * 2013-08-07 2013-12-11 山东奔腾漆业有限公司 Water-based alkyd resin and modified acrylic emulsion metal paint and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105462385A (en) * 2015-11-27 2016-04-06 湖南省英越船舶配套工程有限责任公司 Environment-friendly boot topping paint for yacht and preparation method of boot topping paint
CN106590180A (en) * 2016-12-13 2017-04-26 苏州科胜仓储物流设备有限公司 Anti-rust specimen holder
CN115160867A (en) * 2022-04-20 2022-10-11 江苏华夏制漆科技有限公司 Water-based on-rust paint and preparation method thereof

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Application publication date: 20150422

RJ01 Rejection of invention patent application after publication