CN109233584A - It is a kind of it is novel can thermal jet Environment-friendlywater-soluble water-soluble antirust paint and preparation method thereof - Google Patents

It is a kind of it is novel can thermal jet Environment-friendlywater-soluble water-soluble antirust paint and preparation method thereof Download PDF

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Publication number
CN109233584A
CN109233584A CN201811028473.7A CN201811028473A CN109233584A CN 109233584 A CN109233584 A CN 109233584A CN 201811028473 A CN201811028473 A CN 201811028473A CN 109233584 A CN109233584 A CN 109233584A
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Prior art keywords
soluble
water
friendlywater
novel
agent
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CN201811028473.7A
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Inventor
张洋
霍东升
李启贵
何汉江
胡华院
徐亦为
王彩霞
王鹏飞
何晓芸
吕喜康
石苗
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Xi'an Ruilian New Material Co Ltd
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Xi'an Ruilian New Material Co Ltd
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Priority to CN201811028473.7A priority Critical patent/CN109233584A/en
Publication of CN109233584A publication Critical patent/CN109233584A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/08Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02Homopolymers or copolymers of hydrocarbons
    • C09D125/04Homopolymers or copolymers of styrene
    • C09D125/08Copolymers of styrene
    • C09D125/14Copolymers of styrene with unsaturated esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/66Additives characterised by particle size
    • C09D7/68Particle size between 100-1000 nm
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/66Additives characterised by particle size
    • C09D7/69Particle size larger than 1000 nm
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2265Oxides; Hydroxides of metals of iron
    • C08K2003/2272Ferric oxide (Fe2O3)
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives

Abstract

The invention discloses it is a kind of it is novel can thermal jet Environment-friendlywater-soluble water-soluble antirust paint and preparation method thereof, including following parts by weight of component: filler 15~25, pigment 5~8, preservative 0.05~0.25, corrosion inhibiter 0.5~1.5, aqueous alkide resin 15~25, styrene-acrylic resin 15~20, film forming agent 0.5~2.0, PH regulator 0.5~2.0, thickener 0.2~0.5, dispersing agent 0.2~0.5, levelling agent 0.2~0.5, defoaming agent 0.2~0.5, bottom wetting agent 0.2~0.5, water 30~40.By the present invention in that selected specific auxiliary agent type with the resin of two-component, water paint is enable to spray on heating material, and have film thickness thin, the features such as adhesive force is strong, and paint film setting rate is fast.

Description

It is a kind of it is novel can thermal jet Environment-friendlywater-soluble water-soluble antirust paint and preparation method thereof
Technical field
The present invention relates to a kind of aqueous environment protection coating, especially a kind of water solubility that can be sprayed on heating material is anti- Rust paint.
Background technique
As the mankind are to the pay attention to day by day of environment and health, water paint has obtained more and more extensive application.Tradition The pollution that the volatile organic substance (VOC) that solvent based coating is discharged in the production and use process generates becomes row at present City primary pollution source after automobile.In order to make coating reach the requirement of environmental protection, scientific worker is placed on research emphasis In the research and development for replacing traditional solvent based coating.These substituted type coating include: high solid coating, water paint, powder Coating and radiation curable coating etc..These coating can reduce the discharge of VOC, the generation for reducing harmful waste, reduce worker couple The contact of toxic releaser.Wherein, water paint has convenient sources, is easy to purification, is low cost, low-viscosity, nontoxic, stingless The features such as swashing, is non-ignitable, becomes current research hotspot.
At present the main coating mode of coating be cold spraying, in use, film thickness is thicker, film forming speed compared with Slowly, spray efficiency is lower.The equipment sprayed on a kind of existing high temperature (120 DEG C) pipe fitting, spray efficiency is high, high yield rate, spraying Film thickness is controllable and saves coating.But blistering, corrosion resistant are all easy to happen in most of water paint use processes on the market The problems such as corrosion is poor, and film-formation result is undesirable.
Summary of the invention
The object of the present invention is to provide it is a kind of it is novel can thermal jet Environment-friendlywater-soluble water-soluble antirust paint and preparation method thereof, by making With the resin of two-component, specific auxiliary agent type is selected, water paint is enable to spray on heating material, and there is film thickness The features such as thin, adhesive force is strong, and paint film setting rate is fast.
It is a kind of it is novel can thermal jet Environment-friendlywater-soluble water-soluble antirust paint, it is characterized in that being made of following parts by weight of component, filler 15 ~25, pigment 5~8, preservative 0.05~0.25, corrosion inhibiter 0.5~1.5, aqueous alkide resin 15~25, styrene-acrylic resin 15~ 20, film forming agent 0.5~2.0, PH regulator 0.5~2.0, thickener 0.2~0.5, dispersing agent 0.2~0.5, levelling agent 0.2~ 0.5, defoaming agent 0.2~0.5, bottom wetting agent 0.2~0.5, water 30~40.
The filler is any two kinds of combinations of calcium carbonate, talcum powder or kaolin, silica.
Preferably, the calcium carbonate, kaolin partial size are 600nm~20um.
Preferably, the talcum powder, silica partial size are 600 mesh~2000 mesh.
The pigment is any one in iron oxide red and zinc oxide.
The preservative is benzoic acid.
The corrosion inhibiter is six phosphate of aluminium dihydrogen tripolyphosphate and cyclohexanol;Preferably six phosphate of cyclohexanol.
The aqueous alkide resin is esterified by dry vegetable oil, polyalcohol, polyacid, then is made through acrylic acid modified copolymerization ?.
The styrene-acrylic resin is the styrene-acrylic resin of epoxy resin modification.
It is described it is novel can thermal jet Environment-friendlywater-soluble water-soluble antirust paint preparation method, which is characterized in that the step are as follows:
1) each component of precise;
2) after mixing by filler, pigment, preservative, corrosion inhibiter, water, 25 DEG C~35 DEG C grinding 1h of temperature control, are prepared into The slurry of uniform particle diameter;
3) aqueous alkide resin, dispersing agent, levelling agent, bottom wetting agent are pre-mixed, mixed liquor is made;
4) mixed liquor prepared by step 3) is added under 1500rpm/min stirring condition in the slurry of step 3) preparation, It finishes, stirs 1h with this condition, 25 DEG C~35 DEG C of temperature control;It is slowly added to styrene-acrylic resin under 500rpm/min stirring, is added After defoaming agent defoaming, film forming agent, PH regulator and thickener is added, speed regulation to 1000~1500rpm/min stirring 10min can obtain It is novel can thermal jet Environment-friendlywater-soluble water-soluble antirust paint.
By the present invention in that being selected specific auxiliary agent type with the resin of two-component, being enable water paint in heating material Upper spraying, and have film thickness thin, the features such as adhesive force is strong, and paint film setting rate is fast.
Specific embodiment
The principles and features of the present invention are described below, and the given examples are served only to explain the present invention, is not intended to limit Determine the scope of the present invention.
Embodiment 1
It is a kind of it is novel can thermal jet Environment-friendlywater-soluble water-soluble antirust paint, be made of following parts by weight of component: filler 10um kaolin 10,1200 mesh silica 7 of filler, pigment zinc oxide 6, preservative benzoic acid 0.10, corrosion inhibiter aluminium dihydrogen tripolyphosphate 1.0, Aqueous alkide resin 20, styrene-acrylic resin 20, film forming agent 1.0, PH regulator 0.5, thickener 0.5, dispersing agent 0.2, levelling agent 0.2, defoaming agent 0.3, bottom wetting agent 0.5, water 30.
Each component can be bought on the market.
It is easy to operate to present embodiments provide a kind of use, can be sprayed on heating material, and have film thickness thin, it is attached Put forth effort strong, the fast aqueous antirust paint of paint film setting rate.
1) each component of precise;
2) after mixing by filler, pigment, preservative, corrosion inhibiter, water, 25 DEG C~35 DEG C grinding 1h of temperature control, are prepared into The slurry of uniform particle diameter;
3) aqueous alkide resin, dispersing agent, levelling agent, bottom wetting agent are pre-mixed, mixed liquor is made;
4) mixed liquor prepared by step 3) is added to the mixing slurry of step 2) preparation under 1500rpm/min stirring condition Body finishes, and stirs 1h with this condition, and 25 DEG C~35 DEG C of temperature control;Styrene-acrylic resin is slowly added under 500rpm/min stirring, then plus After entering defoaming agent defoaming, film forming agent, PH regulator and thickener is added, speed regulation to 1000~1500rpm/min stirring 10min can Obtain it is novel can thermal jet Environment-friendlywater-soluble water-soluble antirust paint.
Gained grey water paint sprays, film thickness 20um, not blistering, good film-forming property, hardness on heat pipes (120 DEG C) HB, adhesive force 100/100, salt-fog resistant test (5%NaCl, 35 DEG C) are greater than for 24 hours, and water resistance (40 DEG C of thermostatted water impregnations) is greater than 48h。
Embodiment 2
It is a kind of it is novel can thermal jet Environment-friendlywater-soluble water-soluble antirust paint, be made of following parts by weight of component: filler 10um calcium carbonate 10,1200 mesh talcum powder 7 of filler, pigment zinc oxide 6, preservative benzoic acid 0.10, corrosion inhibiter aluminium dihydrogen tripolyphosphate 1.0, water Property alkyd resin 20, styrene-acrylic resin 20, film forming agent 1.0, PH regulator 0.5, thickener 0.5, dispersing agent 0.2, levelling agent 0.2, Defoaming agent 0.3, bottom wetting agent 0.5, water 30.
Preparation process is same as Example 1, gained grey water paint, sprays on heat pipes (120 DEG C), film thickness 20um, not blistering, good film-forming property, hardness HB, adhesive force 100/100, salt-fog resistant test (5%NaCl, 35 DEG C) is greater than for 24 hours, resistance to Aqueous (40 DEG C of thermostatted water impregnations) is greater than 48h.
Embodiment 3
It is a kind of it is novel can thermal jet Environment-friendlywater-soluble water-soluble antirust paint, be made of following parts by weight of component: are as follows: filler 600nm carbon Sour calcium 10,800 mesh talcum powder 7 of filler, pigment zinc oxide 6, preservative benzoic acid 0.10, corrosion inhibiter aluminium dihydrogen tripolyphosphate 1.0, Aqueous alkide resin 20, styrene-acrylic resin 20, film forming agent 1.0, PH regulator 0.5, thickener 0.5, dispersing agent 0.2, levelling agent 0.2, defoaming agent 0.3, bottom wetting agent 0.5, water 30.
Preparation process is same as Example 1, gained grey water paint, sprays on heat pipes (120 DEG C), film thickness 20um, not blistering, good film-forming property, hardness HB, adhesive force 100/100, salt-fog resistant test (5%NaCl, 35 DEG C) is greater than for 24 hours, resistance to Aqueous (40 DEG C of thermostatted water impregnations) is greater than 48h.
Embodiment 4
It is a kind of it is novel can thermal jet Environment-friendlywater-soluble water-soluble antirust paint, be made of following parts by weight of component: filler 600nm calcium carbonate 10,800 mesh talcum powder 7 of filler, pigment zinc oxide 6, preservative benzoic acid 0.10, six phosphate 1.0 of corrosion inhibiter cyclohexanol, aqueous Alkyd resin 20, film forming agent 1.0, PH regulator 0.5, thickener 0.5, dispersing agent 0.2, levelling agent 0.2, disappears at styrene-acrylic resin 20 Infusion 0.3, bottom wetting agent 0.5, water 30.
Preparation process is same as Example 1, gained grey water paint, sprays on heat pipes (120 DEG C), film thickness 20um, not blistering, good film-forming property, hardness HB, adhesive force 100/100, salt-fog resistant test (5%NaCl, 35 DEG C) is greater than 48h, resistance to Aqueous (40 DEG C of thermostatted water impregnations) is greater than 48h.
Embodiment 5
It is a kind of it is novel can thermal jet Environment-friendlywater-soluble water-soluble antirust paint, be made of following parts by weight of component: filler 600nm calcium carbonate 18,800 mesh talcum powder 6 of filler, pigment zinc oxide 7, preservative benzoic acid 0.2, six phosphate 1.0 of corrosion inhibiter cyclohexanol, aqueous Alkyd resin 18.6, styrene-acrylic resin 16.7, film forming agent 1.0, PH regulator 0.5, thickener 0.4, dispersing agent 0.3, levelling agent 0.3, defoaming agent 0.3, bottom wetting agent 0.5, water 35.2.
Preparation process is same as Example 1, gained grey water paint, sprays on heat pipes (120 DEG C), film thickness 20um, not blistering, good film-forming property, hardness HB, adhesive force 100/100, salt-fog resistant test (5%NaCl, 35 DEG C) is greater than 72h, resistance to Aqueous (40 DEG C of thermostatted water impregnations) is greater than 96h.
Embodiment 6
It is a kind of it is novel can thermal jet Environment-friendlywater-soluble water-soluble antirust paint, be made of following parts by weight of component: filler 600nm calcium carbonate 18,800 mesh talcum powder 6 of filler, pigment iron oxide red 7, preservative benzoic acid 0.2, six phosphate 1.0 of corrosion inhibiter cyclohexanol, water Property alkyd resin 18.6, styrene-acrylic resin 16.7, film forming agent 1.0, PH regulator 0.5, thickener 0.4, dispersing agent 0.3, levelling agent 0.3, defoaming agent 0.3, bottom wetting agent 0.5, water 35.2.
Preparation process is same as Example 1, gained red water paint, sprays on heat pipes (120 DEG C), film thickness 20um, not blistering, good film-forming property, hardness HB, adhesive force 100/100, salt-fog resistant test (5%NaCl, 35 DEG C) is greater than 72h, resistance to Aqueous (40 DEG C of thermostatted water impregnations) is greater than 96h.
The foregoing is merely preferable embodiments of the invention, are not intended to limit the invention, all in essence of the invention Within mind and principle, any modification made, equivalent replacement, improvement etc. be should all be included in the protection scope of the present invention.

Claims (9)

1. it is a kind of it is novel can thermal jet Environment-friendlywater-soluble water-soluble antirust paint, it is characterized in that being made of following parts by weight of component: filler 15~ 25, pigment 5~8, preservative 0.05~0.25, corrosion inhibiter 0.5~1.5, aqueous alkide resin 15~25, styrene-acrylic resin 15~ 20, film forming agent 0.5~2.0, PH regulator 0.5~2.0, thickener 0.2~0.5, dispersing agent 0.2~0.5, levelling agent 0.2~ 0.5, defoaming agent 0.2~0.5, bottom wetting agent 0.2~0.5, water 30~40.
2. it is according to claim 1 it is novel can thermal jet Environment-friendlywater-soluble water-soluble antirust paint, which is characterized in that the filler be carbon Any two kinds of combinations of sour calcium, talcum powder, kaolin, silica.
3. it is according to claim 2 it is novel can thermal jet Environment-friendlywater-soluble water-soluble antirust paint, which is characterized in that the calcium carbonate, Kaolin partial size is 600nm~20um;The talcum powder, silica partial size are 600 mesh~2000 mesh.
4. it is according to claim 1 it is novel can thermal jet Environment-friendlywater-soluble water-soluble antirust paint, which is characterized in that the pigment be oxygen Change any one in iron oxide red and zinc oxide.
5. it is according to claim 1 it is novel can thermal jet Environment-friendlywater-soluble water-soluble antirust paint, which is characterized in that the preservative is Benzoic acid.
6. it is according to claim 1 it is novel can thermal jet Environment-friendlywater-soluble water-soluble antirust paint, which is characterized in that the corrosion inhibiter is Six phosphate of aluminium dihydrogen tripolyphosphate and cyclohexanol, preferably six phosphate of cyclohexanol.
7. it is according to claim 1 it is novel can thermal jet Environment-friendlywater-soluble water-soluble antirust paint, which is characterized in that the water alcohol acid Resin is esterified by dry vegetable oil, polyalcohol, polyacid, then is made through acrylic acid modified copolymerization.
8. it is according to claim 1 it is novel can thermal jet Environment-friendlywater-soluble water-soluble antirust paint, which is characterized in that the styrene-acrylic resin For the styrene-acrylic resin of epoxy resin modification.
9. it is according to claim 1 it is novel can thermal jet Environment-friendlywater-soluble water-soluble antirust paint, which is characterized in that the antirust paint The preparation method comprises the following steps:
1) each component of precise;
2) after mixing by filler, pigment, preservative, corrosion inhibiter, water, 25 DEG C~35 DEG C grinding 1h of temperature control, are prepared into partial size Uniform slurry;
3) aqueous alkide resin, dispersing agent, levelling agent, bottom wetting agent are pre-mixed, mixed liquor is made;
4) mixed liquor prepared by step 3) is added in the slurry of step 2) preparation under 1500rpm/min stirring condition, is finished, Stir 1h with this condition, 25 DEG C~35 DEG C of temperature control;It is slowly added to styrene-acrylic resin under 500rpm/min stirring, adds defoaming agent After defoaming, film forming agent, PH regulator and thickener is added, speed regulation to 1000~1500rpm/min stirring 10min can be obtained newly Type can thermal jet Environment-friendlywater-soluble water-soluble antirust paint.
CN201811028473.7A 2018-09-05 2018-09-05 It is a kind of it is novel can thermal jet Environment-friendlywater-soluble water-soluble antirust paint and preparation method thereof Withdrawn CN109233584A (en)

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CN201811028473.7A CN109233584A (en) 2018-09-05 2018-09-05 It is a kind of it is novel can thermal jet Environment-friendlywater-soluble water-soluble antirust paint and preparation method thereof

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CN201811028473.7A CN109233584A (en) 2018-09-05 2018-09-05 It is a kind of it is novel can thermal jet Environment-friendlywater-soluble water-soluble antirust paint and preparation method thereof

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110961332A (en) * 2019-12-11 2020-04-07 上海横艺会展服务有限公司 Metal surface antirust treatment process

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106883739A (en) * 2017-02-16 2017-06-23 河北晨阳工贸集团有限公司 One kind lives people's container environmentally friendly sealing wax and preparation method thereof
CN107163703A (en) * 2017-07-04 2017-09-15 合肥择浚电气设备有限公司 It is a kind of to be used for the antirust paint of machinery

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106883739A (en) * 2017-02-16 2017-06-23 河北晨阳工贸集团有限公司 One kind lives people's container environmentally friendly sealing wax and preparation method thereof
CN107163703A (en) * 2017-07-04 2017-09-15 合肥择浚电气设备有限公司 It is a kind of to be used for the antirust paint of machinery

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110961332A (en) * 2019-12-11 2020-04-07 上海横艺会展服务有限公司 Metal surface antirust treatment process

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Application publication date: 20190118