CN104499221A - 用于废旧衣物制备的涤纶纤维除静电装置 - Google Patents
用于废旧衣物制备的涤纶纤维除静电装置 Download PDFInfo
- Publication number
- CN104499221A CN104499221A CN201410662957.2A CN201410662957A CN104499221A CN 104499221 A CN104499221 A CN 104499221A CN 201410662957 A CN201410662957 A CN 201410662957A CN 104499221 A CN104499221 A CN 104499221A
- Authority
- CN
- China
- Prior art keywords
- parts
- polyster fibre
- polyester fibers
- cavity volume
- cationic antistatic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 52
- 239000002699 waste material Substances 0.000 title claims abstract description 18
- 230000005611 electricity Effects 0.000 title abstract description 7
- 230000003068 static effect Effects 0.000 title abstract description 5
- 229920000728 polyester Polymers 0.000 title abstract 8
- 125000002091 cationic group Chemical group 0.000 claims abstract description 26
- 239000002216 antistatic agent Substances 0.000 claims abstract description 20
- 230000000694 effects Effects 0.000 claims abstract description 7
- 239000005518 polymer electrolyte Substances 0.000 claims description 16
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 9
- 239000000654 additive Substances 0.000 claims description 9
- 230000000996 additive effect Effects 0.000 claims description 9
- -1 polyethylene Polymers 0.000 claims description 9
- 229910021389 graphene Inorganic materials 0.000 claims description 7
- JLPULHDHAOZNQI-ZTIMHPMXSA-N 1-hexadecanoyl-2-(9Z,12Z-octadecadienoyl)-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCC\C=C/C\C=C/CCCCC JLPULHDHAOZNQI-ZTIMHPMXSA-N 0.000 claims description 6
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 6
- 235000002918 Fraxinus excelsior Nutrition 0.000 claims description 6
- 239000004698 Polyethylene Substances 0.000 claims description 6
- 229920002472 Starch Polymers 0.000 claims description 6
- 235000021355 Stearic acid Nutrition 0.000 claims description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 6
- 239000005864 Sulphur Substances 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- 239000003963 antioxidant agent Substances 0.000 claims description 6
- 230000003078 antioxidant effect Effects 0.000 claims description 6
- 239000002956 ash Substances 0.000 claims description 6
- 239000004359 castor oil Substances 0.000 claims description 6
- 235000019438 castor oil Nutrition 0.000 claims description 6
- 230000008014 freezing Effects 0.000 claims description 6
- 238000007710 freezing Methods 0.000 claims description 6
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- NHOIBRJOQAYBJT-IMGVWCFESA-N nimbin Chemical compound C=1([C@@H]2C[C@H]3O[C@H]4[C@](C3=C2C)(C)[C@@H]([C@]2(C(=O)C=C[C@](C)([C@@H]2[C@H]4OC(C)=O)C(=O)OC)C)CC(=O)OC)C=COC=1 NHOIBRJOQAYBJT-IMGVWCFESA-N 0.000 claims description 6
- ZQIYJHBQRBBBRZ-UHFFFAOYSA-N nimbin Natural products COC(=O)CC1C2C(C(OC(=O)C)C3OC4CC(C(=C4C13C)C)c5cocc5)C(C)(C=CC2=O)C(=O)OC ZQIYJHBQRBBBRZ-UHFFFAOYSA-N 0.000 claims description 6
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 6
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 6
- 229920000573 polyethylene Polymers 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 6
- 229940083466 soybean lecithin Drugs 0.000 claims description 6
- 239000008107 starch Substances 0.000 claims description 6
- 235000019698 starch Nutrition 0.000 claims description 6
- 239000008117 stearic acid Substances 0.000 claims description 6
- 238000000227 grinding Methods 0.000 claims description 5
- 230000004048 modification Effects 0.000 claims description 5
- 238000012986 modification Methods 0.000 claims description 5
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 claims description 4
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims description 3
- MHZGKXUYDGKKIU-UHFFFAOYSA-N Decylamine Chemical group CCCCCCCCCCN MHZGKXUYDGKKIU-UHFFFAOYSA-N 0.000 claims description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 3
- 235000019482 Palm oil Nutrition 0.000 claims description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 3
- 229930013930 alkaloid Natural products 0.000 claims description 3
- 150000003797 alkaloid derivatives Chemical class 0.000 claims description 3
- 235000019270 ammonium chloride Nutrition 0.000 claims description 3
- 238000000498 ball milling Methods 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 229940008099 dimethicone Drugs 0.000 claims description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 239000004205 dimethyl polysiloxane Chemical group 0.000 claims description 3
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 3
- 238000001802 infusion Methods 0.000 claims description 3
- 229960003511 macrogol Drugs 0.000 claims description 3
- 239000002540 palm oil Substances 0.000 claims description 3
- 229920000435 poly(dimethylsiloxane) Chemical group 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 229920005573 silicon-containing polymer Polymers 0.000 claims description 3
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 230000008901 benefit Effects 0.000 abstract description 2
- 239000004753 textile Substances 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000008929 regeneration Effects 0.000 description 3
- 238000011069 regeneration method Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 229920004933 Terylene® Polymers 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- 230000001413 cellular effect Effects 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000004332 deodorization Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 229910003460 diamond Inorganic materials 0.000 description 2
- 239000010432 diamond Substances 0.000 description 2
- 238000006073 displacement reaction Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 229920006253 high performance fiber Polymers 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000003471 mutagenic agent Substances 0.000 description 1
- 231100000707 mutagenic chemical Toxicity 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/02—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fibres, slivers or rovings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F226/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
- C08F226/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a single or double bond to nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/13—Ammonium halides or halides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/05—Cellulose or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/11—Starch or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
- D06M15/3562—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Artificial Filaments (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
一种用于废旧衣物制备的涤纶纤维除静电装置，包括一能够采用蒸汽进行加热的箱体，该箱体内具有一容腔，所述容腔上部设有能够将该容腔盖合的盖体，盖合后使容腔呈密闭状态，在所述容腔内放入有高分子型阳离子抗静电剂，所述箱体两端分别设有导辊，用于传导涤纶纤维，使涤纶纤维能够顺利从箱体内穿过，在所述容腔内间隔设有横梁，在所述横梁上间隔设有定位杆，用于形成对涤纶纤维的定位，使涤纶纤维均匀分布在高分子型阳离子抗静电剂中，利用蒸汽对箱体内的高分子型阳离子抗静电剂进行加热，加温至260-270℃，使高分子型阳离子抗静电剂能够融入到涤纶纤维中，从而使涤纶纤维具有抗静电功效。
Description
技术领域
本发明涉及资源再利用技术领域，具体涉及一种用于废旧衣物制备的涤纶纤维除静电装置。
背景技术
资源的匮乏和被污染，这是当今全球共同面临的问题。而纺织工业与人们的生活密切相关，当今世界纺织工业也面临着两大问题：一是随着世界经济和科技的发展，纺织品的应用领域逐渐扩大，但其使用周期反而缩短，加之世界人口的飞速增长，纺织品的消耗量极具增加，导致纺织品原料出现紧缺，价格大幅度上扬。二是大量使用过的旧衣服大都被当作垃圾掩埋或焚烧，这既造成了资源浪费，又污染了环境。一件服装的完成包含了一个复杂的产业链和大量的能源消耗，在能源和资源越来越紧张的今天，废旧衣物的回收利用必将成为大家关注的焦点。
废旧衣物回收是一个不断壮大的产业领域。从经济的角度考虑，目前主要的纺织纤维价格上扬也促使厂家认真考虑如何提高利润。加强废旧衣物废料的回收利用，变废为宝，不仅对弥补纺织原料的不足具有重要意义，而且也是一项成本低、效益高、资源再利用、节能环保的项目。目前，大多数针对废旧衣物回收都采用物理回收法，即进行初步机械加工，开松或熔融等方法，再作为玩具或枕芯等填充物或工业用途织物。此法投资少，技术简单，但其获得的再生纤维品质差，企业利润低，极大地限制了废旧衣物的回收价值和再生经济价值。
如中国专利(CN103924325A)公开了一种混合材质的废旧衣物再生成为可纺纤维生产工艺技术，主要技术特征是：整个生产线设有非织物固体异物去除工序和设有均匀分布沉降的工序及采用多次钢针滚梳理工序，同时采用物理过滤的除尘技术，采用渐进式的风动技术，从而形成了一种全新的可将各种混合材质的废旧衣物再生成可纺纤维的无污染的自动化生产线，为解决大量废旧衣物的无害化处理提供了一种有效的方法。但其制成的可纺纤维在性能上并没有多大改善，利用率较低。
由于涤纶属于电介质，体积电阻率和表面电阻率都比较大，容易在表面聚集电荷。在涤纶纺丝过程中，纤维与纤维之间、纤维与金属之间因磨擦易产生静电，降低纤维集束性、平滑性及分纤性，对纤维后加工相关工序造成不良影响。
发明内容
本发明所要解决的技术问题在于提供一种方法简单，环境、经济效益好的用于废旧衣物制备的涤纶纤维除静电装置。
本发明所要解决的技术问题采用以下技术方案来实现：
一种用于废旧衣物制备的涤纶纤维除静电装置，包括一能够采用蒸汽进行加热的箱体，该箱体内具有一容腔，所述容腔上部设有能够将该容腔盖合的盖体，盖合后使容腔呈密闭状态，在所述容腔内放入有高分子型阳离子抗静电剂，所述箱体两端分别设有导辊，用于传导涤纶纤维，使涤纶纤维能够顺利从箱体内穿过，在所述容腔内间隔设有横梁，在所述横梁上间隔设有定位杆，用于形成对涤纶纤维的定位，使涤纶纤维均匀分布在高分子型阳离子抗静电剂中，利用蒸汽对箱体内的高分子型阳离子抗静电剂进行加热，加温至260-270℃，使高分子型阳离子抗静电剂能够融入到涤纶纤维中，从而使涤纶纤维具有抗静电功效。
上述高分子型阳离子抗静电剂是由以下重量份数的组分构成：二甲基二烯丙基氯化铵20份、丙烯酸羟乙酯15份、苯乙烯单体20份、聚二甲基硅氧烷二季胺盐10份、二甲基硅油50份、氯化铵5份、石墨烯微片10份、聚乙烯二醇10份、茶叶生物碱5份、十八醇0.5份、棕榈油2份、改性助剂5份、烟草纤维素5份；与涤纶纤维相容性好，抗静电性能持久，耐水洗性能优良；
上述改性助剂是由以下重量份数的组分构成：蓖麻油60份、氧化聚乙烯5份、硬脂酸2份、秸秆灰烬5份、抗氧剂2份、叔丁酚醛硫化树脂2份、大豆卵磷脂2份、印楝素2份、硫磺0.5份、阳离子淀粉5份、氯铂酸0.5份、烟草纤维素1.5份；
上述改性助剂的制备步骤如下：
1)将蓖麻油放入坩埚中加温至沸腾状态，在搅拌状态下氧化聚乙烯、硬脂酸、秸秆灰烬、抗氧剂、叔丁酚醛硫化树脂、大豆卵磷脂、印楝素、硫磺、阳离子淀粉、氯铂酸及烟草纤维素熬煮30-40分钟，呈粘稠状，然后冷却至块状；
2)将步骤1)中的块状物料送入研磨机中，在转速为150转/分的条件下，连续球磨4小时，过80目筛制得粉料；
3)取出步骤2)中研磨后的粉料，在零下3℃的环境下冷冻30分钟，进行改性处理，冷冻完成后真空包装即可。
上述石墨烯微片是以立体的蜂窝方式长晶生成(如同金刚石矿类)，而每一个碳原子的四个价电子都形成共价键被束缚住了，不能形成定向移动的电子流，于是就不能导电，生成后石墨碳晶体利用湿式纳米研磨方式，以单一方向研磨，产生厚度为纳米化，面积为微米化的石墨烯微片。
本申请可根据下游产业的需要生产抗起线/抗静电/导电/防臭/防水/防辐射等功能的高性能纤维。
本发明的有益效果是：本发明通过合成二甲基二烯丙基氯化铵为有效组分的高分子型阳离子抗静电剂，对涤纶纤维进行抗静电化改性，调节纤维的摩擦性能，防止或消除静电积累，赋予纤维平滑、集束、抗静电、柔软等性能，使长丝顺利通过纺丝、拉伸、加弹、纺织及织造等工序。
附图说明
图1为本发明箱体结构示意图。
具体实施方式
为了使本发明实现的技术手段、创作特征、达成目的与功效易于明白了解，下面结合具体图示，进一步阐述本发明。
实施例1
如图1所示，一种用于废旧衣物制备的涤纶纤维除静电装置，包括一能够采用蒸汽进行加热的箱体1，该箱体1内具有一容腔2，所述容腔2上部设有能够将该容腔盖合的盖体3，盖合后使容腔2呈密闭状态，在所述容腔2内放入有高分子型阳离子抗静电剂，所述箱体1两端分别设有导辊4，用于传导涤纶纤维，使涤纶纤维能够顺利从箱体1内穿过，在所述容腔2内间隔设有横梁5，在所述横梁5上间隔设有定位杆6，用于形成对涤纶纤维的定位，使涤纶纤维均匀分布在高分子型阳离子抗静电剂中，利用蒸汽对箱体1内的高分子型阳离子抗静电剂进行加热，加温至260-270℃，使高分子型阳离子抗静电剂能够融入到涤纶纤维中，从而使涤纶纤维具有抗静电功效。
上述高分子型阳离子抗静电剂是由以下重量份数的组分构成：二甲基二烯丙基氯化铵20份、丙烯酸羟乙酯15份、苯乙烯单体20份、聚二甲基硅氧烷二季胺盐10份、二甲基硅油50份、氯化铵5份、石墨烯微片10份、聚乙烯二醇10份、茶叶生物碱5份、十八醇0.5份、棕榈油2份、改性助剂5份、烟草纤维素5份；与涤纶纤维相容性好，抗静电性能持久，耐水洗性能优良；
上述改性助剂是由以下重量份数的组分构成：蓖麻油60份、氧化聚乙烯5份、硬脂酸2份、秸秆灰烬5份、抗氧剂2份、叔丁酚醛硫化树脂2份、大豆卵磷脂2份、印楝素2份、硫磺0.5份、阳离子淀粉5份、氯铂酸0.5份、烟草纤维素1.5份；
上述改性助剂的制备步骤如下：
1)将蓖麻油放入坩埚中加温至沸腾状态，在搅拌状态下氧化聚乙烯、硬脂酸、秸秆灰烬、抗氧剂、叔丁酚醛硫化树脂、大豆卵磷脂、印楝素、硫磺、阳离子淀粉、氯铂酸及烟草纤维素熬煮30-40分钟，呈粘稠状，然后冷却至块状；
2)将步骤1)中的块状物料送入研磨机中，在转速为150转/分的条件下，连续球磨4小时，过80目筛制得粉料；
3)取出步骤2)中研磨后的粉料，在零下3℃的环境下冷冻30分钟，进行改性处理，冷冻完成后真空包装即可。
上述石墨烯微片是以立体的蜂窝方式长晶生成(如同金刚石矿类)，而每一个碳原子的四个价电子都形成共价键被束缚住了，不能形成定向移动的电子流，于是就不能导电，生成后石墨碳晶体利用湿式纳米研磨方式，以单一方向研磨，产生厚度为纳米化，面积为微米化的石墨烯微片。
本申请可根据下游产业的需要生产抗起线/抗静电/导电/防臭/防水/防辐射等功能的高性能纤维。
以上显示和描述了本发明的基本原理和主要特征和本发明的优点。本行业的技术人员应该了解，本发明不受上述实施例的限制，上述实施例和说明书中描述的只是说明本发明的原理，在不脱离本发明精神和范围的前提下，本发明还会有各种变化和改进，这些变化和改进都落入要求保护的本发明范围内。本发明要求保护范围由所附的权利要求书及其等效物界定。
Claims (1)
1.一种用于废旧衣物制备的涤纶纤维除静电装置，其特征在于：包括一能够采用蒸汽进行加热的箱体，该箱体内具有一容腔，所述容腔上部设有能够将该容腔盖合的盖体，盖合后使容腔呈密闭状态，在所述容腔内放入有高分子型阳离子抗静电剂，所述箱体两端分别设有导辊，用于传导涤纶纤维，使涤纶纤维能够顺利从箱体内穿过，在所述容腔内间隔设有横梁，在所述横梁上间隔设有定位杆，用于形成对涤纶纤维的定位，使涤纶纤维均匀分布在高分子型阳离子抗静电剂中，利用蒸汽对箱体内的高分子型阳离子抗静电剂进行加热，加温至260-270℃，使高分子型阳离子抗静电剂能够融入到涤纶纤维中，从而使涤纶纤维具有抗静电功效；
上述高分子型阳离子抗静电剂是由以下重量份数的组分构成：二甲基二烯丙基氯化铵20份、丙烯酸羟乙酯15份、苯乙烯单体20份、聚二甲基硅氧烷二季胺盐10份、二甲基硅油50份、氯化铵5份、石墨烯微片10份、聚乙烯二醇10份、茶叶生物碱5份、十八醇0.5份、棕榈油2份、改性助剂5份、烟草纤维素5份；
上述改性助剂是由以下重量份数的组分构成：蓖麻油60份、氧化聚乙烯5份、硬脂酸2份、秸秆灰烬5份、抗氧剂2份、叔丁酚醛硫化树脂2份、大豆卵磷脂2份、印楝素2份、硫磺0.5份、阳离子淀粉5份、氯铂酸0.5份、烟草纤维素1.5份；
上述改性助剂的制备步骤如下：
1)将蓖麻油放入坩埚中加温至沸腾状态，在搅拌状态下氧化聚乙烯、硬脂酸、秸秆灰烬、抗氧剂、叔丁酚醛硫化树脂、大豆卵磷脂、印楝素、硫磺、阳离子淀粉、氯铂酸及烟草纤维素熬煮30-40分钟，呈粘稠状，然后冷却至块状；
2)将步骤1)中的块状物料送入研磨机中，在转速为150转/分的条件下，连续球磨4小时，过80目筛制得粉料；
3)取出步骤2)中研磨后的粉料，在零下3℃的环境下冷冻30分钟，进行改性处理，冷冻完成后真空包装即可。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410662957.2A CN104499221A (zh) | 2014-11-19 | 2014-11-19 | 用于废旧衣物制备的涤纶纤维除静电装置 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410662957.2A CN104499221A (zh) | 2014-11-19 | 2014-11-19 | 用于废旧衣物制备的涤纶纤维除静电装置 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104499221A true CN104499221A (zh) | 2015-04-08 |
Family
ID=52940668
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410662957.2A Pending CN104499221A (zh) | 2014-11-19 | 2014-11-19 | 用于废旧衣物制备的涤纶纤维除静电装置 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104499221A (zh) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101824715A (zh) * | 2010-01-22 | 2010-09-08 | 中国人民解放军总后勤部军需装备研究所 | 一种纤维束漂洗柔软方法及装置 |
| CN201896247U (zh) * | 2010-12-11 | 2011-07-13 | 巨石集团有限公司 | 一种外涂抗静电剂系统 |
| CN103145348A (zh) * | 2011-12-07 | 2013-06-12 | 重庆国际复合材料有限公司 | 一种玻璃纤维外涂抗静电剂的方法、系统及专用部件 |
| CN103361922A (zh) * | 2013-07-31 | 2013-10-23 | 山东南山纺织服饰有限公司 | 一种有色羊毛拉伸细化和永久定形的方法 |
| CN103669000A (zh) * | 2013-11-22 | 2014-03-26 | 南通市通州区川姜镇盛世王朝家用纺织品设计工作室 | 抗静电衣物柔顺剂及其制备方法 |
| CN203546401U (zh) * | 2013-09-29 | 2014-04-16 | 吴江市科时达纺织有限公司 | 一种纱线染色机 |
| CN103738791A (zh) * | 2014-01-02 | 2014-04-23 | 芜湖华烨工业用布有限公司 | 一种纺织工业布用的过线定位机构 |
-
2014
- 2014-11-19 CN CN201410662957.2A patent/CN104499221A/zh active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101824715A (zh) * | 2010-01-22 | 2010-09-08 | 中国人民解放军总后勤部军需装备研究所 | 一种纤维束漂洗柔软方法及装置 |
| CN201896247U (zh) * | 2010-12-11 | 2011-07-13 | 巨石集团有限公司 | 一种外涂抗静电剂系统 |
| CN103145348A (zh) * | 2011-12-07 | 2013-06-12 | 重庆国际复合材料有限公司 | 一种玻璃纤维外涂抗静电剂的方法、系统及专用部件 |
| CN103361922A (zh) * | 2013-07-31 | 2013-10-23 | 山东南山纺织服饰有限公司 | 一种有色羊毛拉伸细化和永久定形的方法 |
| CN203546401U (zh) * | 2013-09-29 | 2014-04-16 | 吴江市科时达纺织有限公司 | 一种纱线染色机 |
| CN103669000A (zh) * | 2013-11-22 | 2014-03-26 | 南通市通州区川姜镇盛世王朝家用纺织品设计工作室 | 抗静电衣物柔顺剂及其制备方法 |
| CN103738791A (zh) * | 2014-01-02 | 2014-04-23 | 芜湖华烨工业用布有限公司 | 一种纺织工业布用的过线定位机构 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103966844B (zh) | 一种石墨烯导电复合纤维的制备方法 | |
| CN104606955A (zh) | 一种聚四氟乙烯/聚丙烯复合针刺过滤毡的制备方法 | |
| CN104452310A (zh) | 基于废旧衣物制备高性能涤纶纤维新工艺 | |
| CN107768622A (zh) | 一种氮掺杂碳纳米纤维/二硫化钼复合材料及其制备方法和应用 | |
| CN106637921A (zh) | 一种聚丙烯腈/硫化铜光热纳米纤维布及其制备和应用 | |
| CN106003934A (zh) | 一种抗静电纳米纤维非织造材料及制备方法 | |
| CN102943315A (zh) | 一种聚乳酸导电纤维及其制备方法 | |
| CN104477875A (zh) | 利用废纸或纤维织物转化为石墨烯-碳纤维复合材料的方法 | |
| CN111100603A (zh) | 基于静电纺的高导热相变储能材料及其制备方法 | |
| CN103435839A (zh) | 一种绿色回收废弃衣物转化再生物的方法 | |
| CN113209726B (zh) | 一种用于褶皱滤袋的硬挺滤料的制备方法 | |
| CN104499221A (zh) | 用于废旧衣物制备的涤纶纤维除静电装置 | |
| CN105624916B (zh) | 一种绗缝成型的碳纤维隔热材料的制作工艺 | |
| CN205343963U (zh) | 一种防静电面料 | |
| CN205419217U (zh) | 一种布料收集架 | |
| CN105714399B (zh) | 一种浅色碘化亚铜/聚丙烯腈复合导电纤维的制备方法 | |
| CN112030554A (zh) | 一种防辐射透气抗菌面料 | |
| CN202846992U (zh) | 一种挺括型针织摇粒绒复合面料 | |
| CN204325732U (zh) | 利用废旧衣服生产涤纶纤维专用高效除静电装置 | |
| CN109534323A (zh) | 一种用于改性涤纶长丝纤维的石墨烯的制备方法 | |
| CN205802630U (zh) | 一种多层式防潮纺织辊架 | |
| CN104544599A (zh) | 一种绿色环保服装的设计方法 | |
| CN105140476B (zh) | 一种具有多级分层结构的二硫化钼纳米复合纤维的制备方法 | |
| CN111139643A (zh) | 一种滤料开松用预处理整理剂及其应用 | |
| CN112111858A (zh) | 一种节能型微纳米熔喷生产设备及其工作原理 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150408 |
|
| RJ01 | Rejection of invention patent application after publication |