CN104497769A - Tree spraying agent for offshore dredger fill - Google Patents
Tree spraying agent for offshore dredger fill Download PDFInfo
- Publication number
- CN104497769A CN104497769A CN201410768502.9A CN201410768502A CN104497769A CN 104497769 A CN104497769 A CN 104497769A CN 201410768502 A CN201410768502 A CN 201410768502A CN 104497769 A CN104497769 A CN 104497769A
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- Prior art keywords
- spraying agent
- agent according
- spraying
- mixture
- sterilant
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
Abstract
The invention provides a tree spraying agent for offshore dredger fill, which comprises 10-25% of calcium carbonate, 10-20% of lithopone, 5-10% of titanium white, 10-20% of cationic mixed emulsion, 0.1-1% of emulsifier, 0.5-1.5% of dispersing agent, 2-5% of bactericide and/or pesticide, 0.5-5% of pearl essence, 0.5-5% of reflective powder and the balance of water. On the premise of ensuring the effects of preventing pests and plant diseases, preventing sunburn and frost damage and the like in the original whitening agent, the spraying agent can adapt to garden trees in offshore dredger fill and other alkaline regions, and has the effect of beautifying.
Description
Technical field
The invention belong to ornamental trees and shrubs protection field, be specifically related to a kind of trees being applicable to hydraulic reclamation soil, strand survive the winter protection and spraying agent attractive in appearance.
Background technology
White-out agent or spraying agent are mainly used in the trunk whitewashing of ornamental plantation trees, shade tree and fruit tree, and vital role is prevention and elimination of disease and pests, and prevention day burns and frostbite.The tree whitening agent composition that different areas preparation is conventional and ratio are slightly distinguished, but basal component is roughly the same, generally forms by the mixed preparing such as unslaked lime, sulphur or lime sulfur mixture, salt, animal oil, water, is mostly alkalescence.In the barged-in fill area, strand that saline and alkaline is higher, afforestation is inherently more difficult, and gardening expense is high, and the life-time service of common white-out agent must add the salinization of heavy soil, produces adverse influence to the growth of ornamental trees and shrubs.
Mostly North China's ornamental trees and shrubs in winter are bare a slice, lack life, are difficult to play the effect of beautifying the environment.Although certain aesthetic is played in the use of common white-out agent, relative color is more single, and landscaping effect is not obvious.
Summary of the invention
The invention is a kind of in the original prevention and elimination of disease and pests of guarantee, and prevention is burnt and while the effect such as frostbite, can be adapted to the spraying agent that the varieties in saline-alkali areas ornamental trees and shrubs such as strand barged-in fill use, also have colorful landscaping effect attractive in appearance day.
The spraying agent of the invention comprises following component: calcium carbonate 10-25%, zinc sulfide white 10-20%, titanium dioxide 5-10%, positively charged ion mixed emulsion 10-20%, emulsifying agent 0.1-1%, dispersion agent 0.5-1.5%, sterilant and/or sterilant 2-5%, pearlescence 0.5-5%, reflective powder 0.5-5%, water surplus; Per-cent in described component is per-cent in mass.
Wherein, described zinc sulfide white is the mixture of zinc sulphide and barium sulfate, accounts for the 25-35% of zinc sulfide white total mass, be generally 28-30% in total zinc amount of zinc sulphide; Described positively charged ion mixed emulsion is the mixture of cationic polyacrylate emulsion and cationic styrene-acrylic emulsion, and the two quality optimization is for than being 1: (1.5-3), is more preferably 1: 2; Described emulsifying agent can adopt lauryl ammonium chloride, cetyl trimethylammonium bromide or its mixture; Described dispersion agent can adopt sodium methylene bis-naphthalene sulfonate, hydrolytic polymaleic anhydride HPMA or its mixture; Described sterilant and/or sterilant according to local disease and pest feature, can select different kinds and dosage, can be selected from one or more following mixture: ethylicin, quintozene, prochloraz; Described pearlescence is the main component of toning, can adopt the pearlescence of shades of colour effect, conventional blue, green, white three kinds.
Described calcium carbonate, titanium dioxide, zinc sulfide white are preferably 400-1000 order, as primary white filler, play covering, anti-frostbite, anti-day burn etc. effect.The wherein barium sulfate composition that contains of zinc sulfide white, weather resistance is slightly poor, resistance to chalking is poor, low price, therefore can use by Some substitute titanium dioxide, play the effect regulating spraying agent sticking power and weather resistance, appropriate zinc sulfide white had both ensured difficult drop-off in the winter time, rain drop erosion easily can come off again after temperature in the beginning of spring rises; Described positively charged ion mixed emulsion, emulsifying agent, dispersion agent can make powder form uniform and stable emulsion, are applicable to long preservation, transport, and evenly can be attached to surface of trees by spraying; Described pearlescence, reflective powder not only play toning effect, filler can also be coordinated to strengthen effect of burning anti-day by refraction action.
The making processes of the spraying agent described in the invention, both can component be disposable mixes by all required at normal temperatures, obtained the spraying agent that can directly use; Also first the 15-25% of calcium carbonate, zinc sulfide white, titanium dioxide, positively charged ion mixed emulsion, emulsifying agent, dispersion agent, sterilant and/or sterilant, pearlescence, reflective powder and total water requirements can be mixed at normal temperatures, obtain the concentrated solution of the invention spraying agent; Before using, in concentrated solution, add the remaining water yield stir, can carry out spraying or whitewashing.
The value that the viscosity of the spraying agent of the invention is preferably under coating-4 viscosity meter is 20-30 second.Before using, small viscosity adjustment can also be carried out to the concentrated solution after the disposable spraying agent for preparing or dilution, be conducive to spraying operation on the one hand.Be conducive to even fast filming on the other hand, and with trunk surface, there is suitable adhesion strength after film forming.
The advantage that the invention has and positively effect are: (1) the present invention can adopt the equipment of spraying to spray, and formed armor coated uniformly, saving spray paint usage quantity also reduces labor cost; (2) the present invention can form the reflective protective layer of light color antibacterial, pest-resistant uniformly in tree surface, effectively can hide tree surface, prevention day burns, frostbite and insect pest; (3) after emulsion formulations of the present invention spraying and trees sticking power moderate, both difficult drop-off had in the winter time been ensured, only need spray or brush and once can reach requirement, can come off through rain drop erosion after rising in temperature in the beginning of spring again, therefore saving of labor, save time, cost saving again; (4) the present invention's not only environmental protection completely, harmless to trees, pollution-free to surrounding enviroment; And in acid, life-time service effectively can avoid salting of soil, can not only be used for the trees of general soil plantation, be specially adapted to the trees that the saltingss such as strand barged-in fill are planted; (5) the present invention not only has multiple color to select, and greatly improves the effect that it is beautified the environment; And can effective reflection ray, play road boundary mark will warning function, greatly improve driving at night security; Pearlescence and reflecting beads can also play the action effect burnt auxiliary anti-day; (6) raw material of the present invention is general industry raw material, with low cost, is applicable to scale operation and use.
Embodiment
Below by specific embodiment, the invention is further described.
Embodiment 1 prepares the white spraying agent of 100kg
By 500 order calcium carbonate 10kg, zinc sulfide white 10kg, titanium dioxide 5kg, and the mixture 15kg that the mixture of cationic polyacrylate emulsion and cationic styrene-acrylic emulsion is mixed with mass ratio 1: 2, cetyl trimethylammonium bromide 1kg, prochloraz 2kg, sodium methylene bis-naphthalene sulfonate 1kg, white pearlescent powder 1kg, reflective powder 1kg, water 20kg, under normal temperature, Homogeneous phase mixing is mixed with concentrated solution, deposits to facilitate and transports.Add 34kg water again during use, the value under the acquisition coating-4 viscosity meter that stirs is the spraying agent of 20 seconds.Adopt and spray the tree body limb surface of equipment even application in saline land greening gardens, Binhai New Area in Tianjin.The beginning of spring in the coming year temperature rise after spraying agent self falling under rain drop erosion, trees do not occur insect pest, frostbite, day burn etc. infringement, grow fine, percentage of germination is high.
Embodiment 2 prepares the reflective spraying agent of blueness of 100kg
Mixture 18kg, ethylicin 4kg that the mixture of 800 order calcium carbonate 15kg, zinc sulfide white 10kg, titanium dioxide 5kg, cationic polyacrylate emulsion and cationic styrene-acrylic emulsion is mixed with mass ratio 1: 3, lauryl ammonium chloride 1kg, sodium methylene bis-naphthalene sulfonate 1kg, blue pearlescence 5kg, white reflection powder 3kg, other are water, Homogeneous phase mixing under normal temperature, the value obtained under coating-4 viscosity meter is the spraying agent of 25 seconds.Adopt and spray the tree body limb surface of equipment even application in saline land greening gardens, Binhai New Area in Tianjin.The beginning of spring in the coming year temperature rise after spraying agent self falling under rain drop erosion, trees do not occur insect pest, frostbite, day burn etc. infringement, grow fine, percentage of germination is high.
The above; be only the invention preferably embodiment; but the protection domain of the invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the invention discloses; be equal to according to the technical scheme of the invention and inventive concept thereof and replace or change, within the protection domain that all should be encompassed in the invention.
Claims (8)
1. one kind is applicable to the trees spraying agent in hydraulic reclamation soil, strand, comprise following component: calcium carbonate 10-25%, zinc sulfide white 10-20%, titanium dioxide 5-10%, positively charged ion mixed emulsion 10-20%, emulsifying agent 0.1-1%, dispersion agent 0.5-1.5%, sterilant and/or sterilant 2-5%, pearlescence 0.5-5%, reflective powder 0.5-5%, water surplus; Per-cent in described component is per-cent in mass.
2. spraying agent according to claim 1, is characterized in that: described positively charged ion mixed emulsion is the mixture of cationic polyacrylate emulsion and cationic styrene-acrylic emulsion.
3. spraying agent according to claim 2, is characterized in that: the mass ratio of described positively charged ion mixed emulsion cationic polyacrylate dispersion and cationic styrene-acrylic emulsion is 1: (1.5-3).
4. spraying agent according to claim 1, is characterized in that: described emulsifying agent is lauryl ammonium chloride, cetyl trimethylammonium bromide or its mixture.
5. spraying agent according to claim 1, is characterized in that: described dispersion agent is sodium methylene bis-naphthalene sulfonate, hydrolytic polymaleic anhydride HPMA or its mixture.
6. spraying agent according to claim 1, is characterized in that: described sterilant and/or sterilant are selected from one or more following mixture: ethylicin, quintozene, prochloraz.
7. spraying agent according to claim 1, is characterized in that: described calcium carbonate, titanium dioxide, zinc sulfide white are preferably 400-1000 order.
8. spraying agent according to claim 1, is characterized in that: the value of described spraying agent under coating-4 viscosity meter is 20
-30 seconds.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410768502.9A CN104497769A (en) | 2014-12-11 | 2014-12-11 | Tree spraying agent for offshore dredger fill |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410768502.9A CN104497769A (en) | 2014-12-11 | 2014-12-11 | Tree spraying agent for offshore dredger fill |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104497769A true CN104497769A (en) | 2015-04-08 |
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ID=52939230
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410768502.9A Pending CN104497769A (en) | 2014-12-11 | 2014-12-11 | Tree spraying agent for offshore dredger fill |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104497769A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105815309A (en) * | 2016-04-19 | 2016-08-03 | 东北林业大学 | Neutral environment-friendly whitewashing agent and preparation method thereof |
| CN106258647A (en) * | 2016-08-05 | 2017-01-04 | 广东龙湖科技股份有限公司 | A kind of method utilizing cement mortar that trees are protected |
| CN106577061A (en) * | 2016-12-05 | 2017-04-26 | 益阳金宙建材科技有限公司 | Grinded mortar used for protection of plant external layer |
| CN107815184A (en) * | 2017-09-29 | 2018-03-20 | 江苏闽江矿业有限公司 | A kind of preparation method of mining industry equipment spray liniment |
| CN107828286A (en) * | 2017-09-15 | 2018-03-23 | 江苏闽江矿业有限公司 | A kind of mining industry equipment spray liniment |
| CN110024805A (en) * | 2019-05-08 | 2019-07-19 | 青岛农业大学 | A kind of forest limb sterilization smears and its preparation method and application |
| CN111925685A (en) * | 2020-07-30 | 2020-11-13 | 陕西谱润生物科技有限公司 | Plant sun-screening agent and preparation method and application thereof |
| CN112898847A (en) * | 2021-03-19 | 2021-06-04 | 河北三棵树涂料有限公司 | Special insect-proof and pest-proof paint for whitening forest trees |
-
2014
- 2014-12-11 CN CN201410768502.9A patent/CN104497769A/en active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105815309A (en) * | 2016-04-19 | 2016-08-03 | 东北林业大学 | Neutral environment-friendly whitewashing agent and preparation method thereof |
| CN106258647A (en) * | 2016-08-05 | 2017-01-04 | 广东龙湖科技股份有限公司 | A kind of method utilizing cement mortar that trees are protected |
| CN106577061A (en) * | 2016-12-05 | 2017-04-26 | 益阳金宙建材科技有限公司 | Grinded mortar used for protection of plant external layer |
| CN107828286A (en) * | 2017-09-15 | 2018-03-23 | 江苏闽江矿业有限公司 | A kind of mining industry equipment spray liniment |
| CN107815184A (en) * | 2017-09-29 | 2018-03-20 | 江苏闽江矿业有限公司 | A kind of preparation method of mining industry equipment spray liniment |
| CN110024805A (en) * | 2019-05-08 | 2019-07-19 | 青岛农业大学 | A kind of forest limb sterilization smears and its preparation method and application |
| CN111925685A (en) * | 2020-07-30 | 2020-11-13 | 陕西谱润生物科技有限公司 | Plant sun-screening agent and preparation method and application thereof |
| CN112898847A (en) * | 2021-03-19 | 2021-06-04 | 河北三棵树涂料有限公司 | Special insect-proof and pest-proof paint for whitening forest trees |
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Application publication date: 20150408 |