CN104496180A - Tawny crystal bead blank and preparation method thereof - Google Patents
Tawny crystal bead blank and preparation method thereof Download PDFInfo
- Publication number
- CN104496180A CN104496180A CN201510003788.6A CN201510003788A CN104496180A CN 104496180 A CN104496180 A CN 104496180A CN 201510003788 A CN201510003788 A CN 201510003788A CN 104496180 A CN104496180 A CN 104496180A
- Authority
- CN
- China
- Prior art keywords
- parts
- citrite
- pearl embryo
- salt
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Cosmetics (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
The invention discloses a tawny crystal bead blank and a preparation method thereof. The tawny crystal bead blank is composed of the following components in parts by weight: 95-165 parts of quartz sand, 10-18 parts of zinc oxide, 28-52 parts of sodium carbonate, 15-31 parts of potassium carbonate, 6-16 parts of boric acid, 3-5 parts of calcium carbonate, 0.8-3.2 parts of aluminum hydroxide, 1-2 parts of salt, 2-5 parts of antimony trioxide, 0.1-2 parts of potassium nitrate, 0.01-0.18 part of sodium selenite, 0.001-0.003 part of ferrous sulfide and 0.1-0.9 part of neodymium oxide. In the tawny crystal bead blank preparation process, no abundant rare-earth cerium compound is adopted for coloring the immobilized selenium and compounds thereof in the secondary reshaping. The tawny crystal bead blank is free of any leady raw material, and has the advantages of favorable glossiness, bright color, high regularity, no color difference, no grains, high yield, no lead or pollution and favorable production benefit.
Description
Technical field
The present invention relates to a kind of citrite pearl embryo and preparation method thereof.
Background technology
Citrite pearl embryo is used to the work in-process preparing citrite product, existing citrite pearl embryo technique adopts crucible manufacture, there is aberration, color is uneven, have decorative pattern, unstable product quality, production efficiency is low, be not suitable for continuous production in enormous quantities, and cause environmental pollution by coal burning.And the rare-earth oxidation erbium of the consumption costliness had in existing technical recipe, but some selenium powders are painted unstable, the lead compound containing contaminate environment had.
Summary of the invention
It is good that technical problem to be solved by this invention is to provide a kind of color reproduction, and solid colour no color differnece, without decorative pattern, constant product quality, production efficiency is high, and can be applicable to the production operation of continuous tank furnace, production cost is low, free of contamination citrite pearl embryo.
For solving the problem, the present invention is achieved through the following technical solutions: a kind of citrite pearl embryo, and this citrite pearl embryo is made up of following weight composition: quartz sand 95-165 part, zinc oxide 10-18 part, soda ash 28-52 part, salt of wormwood 15-31 part, boric acid 6-16 part, calcium carbonate 3-5 part, aluminium hydroxide 0.8-3.2 part, salt 1-2 part, antimonous oxide 2-5 part, saltpetre 0.1-2 part, Sodium Selenite 0.01-0.18 part, Iron sulfuret 0.001-0.003 part and Neodymium trioxide 0.1-0.9 part.
Another technical problem to be solved by this invention is to provide a kind of preparation method of citrite pearl embryo,
The present invention is achieved through the following technical solutions: the preparation process of described citrite pearl embryo is as follows:
1) extract quartz sand 95-165 part, zinc oxide 10-18 part, soda ash 28-52 part, salt of wormwood 15-31 part, boric acid 6-16 part, calcium carbonate 3-5 part, aluminium hydroxide 0.8-3.2 part, salt 1-2 part, antimonous oxide 2-5 part, saltpetre 0.1-2 part, Sodium Selenite 0.01-0.18 part, Iron sulfuret 0.001-0.003 part and Neodymium trioxide 0.1-0.9 part by weight ratio to mix;
2) the citrite pearl embryo raw material mixed is carried out granulation by tablets press;
3) granular citrite pearl embryo raw material will be made put into glass quartz tank furnace and found, and when founding, keep weak oxide atmosphere and liquid level of solution to stablize;
4) crystal solution is molded into citrite pearl embryo after the homogenizing cooling of material road;
5) shaping pearl embryo is put into fire and throw stove polishing, integer, uniform coloring, shaping pearl embryo is allowed at the uniform velocity to enter stainless steel pipes, pipe temperature controls at 800 DEG C-900 DEG C, rotating speed 180 revolutions per seconds, in pipeline 5 minutes, pipeline was out just through integer, solid colour, no color differnece, citrite pearl embryo without decorative pattern.
Further, described in the preparation process 3 of citrite pearl embryo, when founding, temperature controls at 1320 DEG C-1380 DEG C.
Further, described in the preparation process 4 of citrite pearl embryo, cooling temperature controls at 800 DEG C-1000 DEG C.
The beneficial effect of citrite pearl embryo of the present invention is: the compound not adopting a large amount of ceriums time prepared by described citrite pearl embryo, fixes the painted of methyl seleninic acid in secondary integer; Do not adopt leaded raw material, have glossiness good, bright-colored, neat, no color differnece, without decorative pattern, output is high, unleaded pollution-free, the advantage that productivity effect is good.
Embodiment
Following examples for illustration of the present invention, but are not used for limiting the scope of the invention.
Embodiment 1
A kind of citrite pearl embryo of the present invention, this citrite pearl embryo is made up of following weight composition: quartz sand 150 parts, 13 parts, zinc oxide, soda ash 30 parts, 18 parts, salt of wormwood, boric acid 15 parts, 3.8 parts, calcium carbonate, 1.2 parts, aluminium hydroxide, salt 1.8 parts, antimonous oxide 2.2 parts, 0.5 part, saltpetre, Sodium Selenite 0.015 part, Iron sulfuret 0.0011 part and Neodymium trioxide 0.16 part.
The preparation process of described citrite pearl embryo is as follows:
1) extract quartz sand 150 parts, 13 parts, zinc oxide, soda ash 30 parts, 18 parts, salt of wormwood, boric acid 15 parts, 3.8 parts, calcium carbonate, 1.2 parts, aluminium hydroxide, salt 1.8 parts, antimonous oxide 2.2 parts, 0.5 part, saltpetre, Sodium Selenite 0.015 part, Iron sulfuret 0.0011 part and Neodymium trioxide 0.16 part by weight ratio to mix;
2) the citrite pearl embryo raw material mixed is carried out granulation by tablets press;
3) will make granular citrite pearl embryo raw material to put into glass quartz tank furnace and found, keep weak oxide atmosphere and liquid level of solution to stablize when founding, glass melting temperature controls at 1320 DEG C-1380 DEG C;
4) crystal solution is molded into citrite pearl embryo after the homogenizing cooling of material road, cooling temperature controls at 800 DEG C-1000 DEG C;
5) shaping pearl embryo is put into fire and throw stove polishing, integer, uniform coloring, shaping pearl embryo is allowed at the uniform velocity to enter stainless steel pipes, pipe temperature controls at 800 DEG C-900 DEG C, rotating speed 180 revolutions per seconds, in pipeline 5 minutes, pipeline was out just through integer, solid colour, no color differnece, citrite pearl embryo without decorative pattern.
Embodiment 2
Its difference from Example 1 is, this citrite pearl embryo is made up of following weight composition: quartz sand 165 parts, 18 parts, zinc oxide, soda ash 52 parts, 31 parts, salt of wormwood, boric acid 16 parts, 5 parts, calcium carbonate, 3.2 parts, aluminium hydroxide, salt 2 parts, antimonous oxide 5 parts, 2 parts, saltpetre, Sodium Selenite 0.18 part, Iron sulfuret 0.003 part and Neodymium trioxide 0.9 part.
Embodiment 3
Its difference from Example 1 is, this citrite pearl embryo is made up of following weight composition: quartz sand 95 parts, 10 parts, zinc oxide, soda ash 28 parts, 15 parts, salt of wormwood, boric acid 6 parts, 3 parts, calcium carbonate, 0.8 part, aluminium hydroxide, salt 1 part, antimonous oxide 2 parts, 0.1 part, saltpetre, Sodium Selenite 0.01 part, Iron sulfuret 0.001 part and Neodymium trioxide 0.1 part.
Embodiment 4
Its difference from Example 1 is, this citrite pearl embryo is made up of following weight composition: quartz sand 155 parts, 17 parts, zinc oxide, soda ash 49 parts, 29 parts, salt of wormwood, boric acid 15 parts, 4.7 parts, calcium carbonate, 3 parts, aluminium hydroxide, salt 1.8 parts, antimonous oxide 4.4 parts, 1.8 parts, saltpetre, Sodium Selenite 0.16 part, Iron sulfuret 0.0025 part and Neodymium trioxide 0.7 part.
Embodiment 5
Its difference from Example 1 is, this citrite pearl embryo is made up of following weight composition: quartz sand 100 parts, 11 parts, zinc oxide, soda ash 30 parts, 17 parts, salt of wormwood, boric acid 8 parts, 3.3 parts, calcium carbonate, 1 part, aluminium hydroxide, salt 1.2 parts, antimonous oxide 2.4 parts, 0.4 part, saltpetre, Sodium Selenite 0.03 part, Iron sulfuret 0.0013 part and Neodymium trioxide 0.3 part.
Embodiment 6
Its difference from Example 1 is, this citrite pearl embryo is made up of following weight composition: quartz sand 130 parts, 14 parts, zinc oxide, soda ash 41 parts, 22 parts, salt of wormwood, boric acid 12 parts, 4.1 parts, calcium carbonate, 1.6 parts, aluminium hydroxide, salt 1.6 parts, antimonous oxide 3.7 parts, 1.1 parts, saltpetre, Sodium Selenite 0.09 part, Iron sulfuret 0.0021 part and Neodymium trioxide 0.5 part.
Embodiment 7
Its difference from Example 1 is, this citrite pearl embryo is made up of following weight composition: quartz sand 125 parts, 13 parts, zinc oxide, soda ash 36 parts, 24 parts, salt of wormwood, boric acid 12 parts, 3.9 parts, calcium carbonate, 2.2 parts, aluminium hydroxide, salt 1 part, antimonous oxide 5 parts, 1.1 parts, saltpetre, Sodium Selenite 0.11 part, Iron sulfuret 0.0022 part and Neodymium trioxide 0.7 part.
Embodiment 8
Its difference from Example 1 is, this citrite pearl embryo is made up of following weight composition: quartz sand 115 parts, 14 parts, zinc oxide, soda ash 42 parts, 19 parts, salt of wormwood, boric acid 9 parts, 4.4 parts, calcium carbonate, 2.8 parts, aluminium hydroxide, salt 1.7 parts, antimonous oxide 3.6 parts, 1.4 parts, saltpetre, Sodium Selenite 0.14 part, Iron sulfuret 0.0014 part and Neodymium trioxide 0.2 part.
The present invention is not limited to above-mentioned preferred forms, anyone other any or akin products identical with the present invention drawn under enlightenment of the present invention, all drops within protection scope of the present invention.
Claims (4)
1. a citrite pearl embryo, is characterized in that: this citrite pearl embryo is made up of following weight composition: quartz sand 95-165 part, zinc oxide 10-18 part, soda ash 28-52 part, salt of wormwood 15-31 part, boric acid 6-16 part, calcium carbonate 3-5 part, aluminium hydroxide 0.8-3.2 part, salt 1-2 part, antimonous oxide 2-5 part, saltpetre 0.1-2 part, Sodium Selenite 0.01-0.18 part, Iron sulfuret 0.001-0.003 part and Neodymium trioxide 0.1-0.9 part.
2. prepare a preparation method for citrite pearl embryo according to claim 1, it is characterized in that: the method comprises the following steps:
1) extract quartz sand 95-165 part, zinc oxide 10-18 part, soda ash 28-52 part, salt of wormwood 15-31 part, boric acid 6-16 part, calcium carbonate 3-5 part, aluminium hydroxide 0.8-3.2 part, salt 1-2 part, antimonous oxide 2-5 part, saltpetre 0.1-2 part, Sodium Selenite 0.01-0.18 part, Iron sulfuret 0.001-0.003 part and Neodymium trioxide 0.1-0.9 part by weight ratio to mix;
2) the citrite pearl embryo raw material mixed is carried out granulation by tablets press;
3) granular citrite pearl embryo raw material will be made put into glass quartz tank furnace and found, and when founding, keep weak oxide atmosphere and liquid level of solution to stablize;
4) crystal solution is molded into citrite pearl embryo after the homogenizing cooling of material road;
5) shaping pearl embryo is put into fire and throw stove polishing, integer, uniform coloring, shaping pearl embryo is allowed at the uniform velocity to enter stainless steel pipes, pipe temperature controls at 800 DEG C-900 DEG C, rotating speed 180 revolutions per seconds, in pipeline 5 minutes, pipeline was out just through integer, solid colour, no color differnece, citrite pearl embryo without decorative pattern.
3. citrite pearl embryo preparation method according to claim 2, is characterized in that: described in the preparation process 3 of citrite pearl embryo, when founding, temperature controls at 1320 DEG C-1380 DEG C.
4. citrite pearl embryo preparation method according to claim 2, is characterized in that: described in the preparation process 4 of citrite pearl embryo, cooling temperature controls at 800 DEG C-1000 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510003788.6A CN104496180B (en) | 2015-01-06 | 2015-01-06 | A kind of citrite pearl embryo and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510003788.6A CN104496180B (en) | 2015-01-06 | 2015-01-06 | A kind of citrite pearl embryo and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104496180A true CN104496180A (en) | 2015-04-08 |
| CN104496180B CN104496180B (en) | 2016-03-23 |
Family
ID=52937660
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510003788.6A Active CN104496180B (en) | 2015-01-06 | 2015-01-06 | A kind of citrite pearl embryo and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104496180B (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5656559A (en) * | 1994-06-23 | 1997-08-12 | Saint-Gobain Vitrage | Clear glass composition intended for the production of panes |
| CN1640836A (en) * | 2004-01-17 | 2005-07-20 | 德州振华装饰玻璃有限公司 | Colour glass pink colouring pigment and its preparing process |
| CN102503126A (en) * | 2011-10-08 | 2012-06-20 | 浙江伟兴水晶有限公司 | Preparation method for smoky yellow crystal bead blanks |
| CN102838277A (en) * | 2012-09-17 | 2012-12-26 | 江苏锦程集团科技有限公司 | Production process of honey peach CZ diamond |
| CN102837251A (en) * | 2012-09-17 | 2012-12-26 | 江苏锦程集团科技有限公司 | Diamond bead blank fire polishing furnace |
| CN103508671A (en) * | 2012-06-26 | 2014-01-15 | 广东华兴玻璃有限公司 | Brown glass and preparation method thereof |
-
2015
- 2015-01-06 CN CN201510003788.6A patent/CN104496180B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5656559A (en) * | 1994-06-23 | 1997-08-12 | Saint-Gobain Vitrage | Clear glass composition intended for the production of panes |
| CN1640836A (en) * | 2004-01-17 | 2005-07-20 | 德州振华装饰玻璃有限公司 | Colour glass pink colouring pigment and its preparing process |
| CN102503126A (en) * | 2011-10-08 | 2012-06-20 | 浙江伟兴水晶有限公司 | Preparation method for smoky yellow crystal bead blanks |
| CN103508671A (en) * | 2012-06-26 | 2014-01-15 | 广东华兴玻璃有限公司 | Brown glass and preparation method thereof |
| CN102838277A (en) * | 2012-09-17 | 2012-12-26 | 江苏锦程集团科技有限公司 | Production process of honey peach CZ diamond |
| CN102837251A (en) * | 2012-09-17 | 2012-12-26 | 江苏锦程集团科技有限公司 | Diamond bead blank fire polishing furnace |
Non-Patent Citations (3)
| Title |
|---|
| 林元: ""介绍几种加速玻璃熔化的助熔剂"", 《建筑材料工业》 * |
| 王承遇等主编: "《玻璃性质与工艺手册》", 30 June 2013, 化学工艺出版社 * |
| 赵彦钊 等: "《玻璃工艺学》", 30 September 2006, 化学工业出版社 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104496180B (en) | 2016-03-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102211874B (en) | Microcrystalline glass and preparation method thereof | |
| CN1099359A (en) | Formula and process of preparing devitroceram using flyash | |
| CN104556698B (en) | A kind of cigarette yellow crystal pearl embryo and preparation method thereof | |
| CN102515532B (en) | Preparation method of light-peach-colored crystal bead blanks | |
| CN103922594B (en) | A kind of large red color crystal bead blank and preparation method thereof | |
| CN104478214B (en) | A kind of pale pink look crystal bead blank and preparation method thereof | |
| CN101717182A (en) | Low-hydroxide radical gray quartz tube and method for producing same | |
| CN107879631B (en) | Ingredient quenching and tempering material suitable for blast furnace slag microcrystalline glass and quenching and tempering method thereof | |
| CN110922058A (en) | Preparation method for sintering microcrystalline glass plate by using multi-tube distribution | |
| CN104496178B (en) | A kind of rose crystal bead blank and preparation method thereof | |
| CN102503127A (en) | Preparation method for light blue crystal bead blanks | |
| CN104496179B (en) | A kind of transparent black crystal ball blank and preparation method thereof | |
| CN104556696B (en) | A kind of rosy quartz pearl embryo and preparation method thereof | |
| CN104556699B (en) | A kind of red-purple crystal bead blank and preparation method thereof | |
| CN104496180B (en) | A kind of citrite pearl embryo and preparation method thereof | |
| CN103936282B (en) | A kind of shallow large red color crystal bead blank and preparation method thereof | |
| CN102674694B (en) | Preparation method for modena crystal bead blank | |
| CN104556697B (en) | A kind of golden yellow crystal bead blank and preparation method thereof | |
| CN103922593B (en) | A kind of deep-red coloration crystal bead blank and preparation method thereof | |
| CN103922592B (en) | A kind of orange color crystal bead blank and preparation method thereof | |
| CN102320747B (en) | Preparation method of shallow crystal and yellow crystal bead blank | |
| CN102515531B (en) | Preparation method of dark green crystal bead blanks | |
| CN106365446A (en) | Light-blue colored crystal bead blank and preparation method thereof | |
| CN102372432B (en) | Preparation method of dark blue crystal ball blank | |
| CN103170494B (en) | The preparation method of steel wire and the application in chemical industry and pharmacy in automobile waste and used rubber tyre |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20220208 Address after: 321000 No. 668, Xuecheng East Road, Hanxiang Industrial Park, Tangya Town, Jindong District, Jinhua City, Zhejiang Province Patentee after: Zhejiang xinweixing crystal Co.,Ltd. Address before: 321000 Jindong comprehensive development park, Jinhua City, Zhejiang Province Patentee before: ZHEJIANG WEIXING CRYSTAL Co.,Ltd. |