CN104496178B - A kind of rose crystal bead blank and preparation method thereof - Google Patents
A kind of rose crystal bead blank and preparation method thereof Download PDFInfo
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- CN104496178B CN104496178B CN201510003622.4A CN201510003622A CN104496178B CN 104496178 B CN104496178 B CN 104496178B CN 201510003622 A CN201510003622 A CN 201510003622A CN 104496178 B CN104496178 B CN 104496178B
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C12/00—Powdered glass; Bead compositions
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/02—Compositions for glass with special properties for coloured glass
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
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- Geochemistry & Mineralogy (AREA)
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- Organic Chemistry (AREA)
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Abstract
The invention discloses a kind of rose crystal bead blank and preparation method thereof, this rose crystal bead blank is made up of following weight composition: quartz sand 90-160 part, zinc oxide 8-16 part, soda ash 28-50 part, salt of wormwood 17-29 part, saltpetre 13-26 part, boric acid 8-15 part, calcium carbonate 3-5 part, aluminium hydroxide 1-3 part, salt 1-2 part, gold trichloride 0.01-0.03 part, antimonous oxide 1.5-3.5 part and cerium oxide 1-5 part.Time prepared by rose crystal bead blank of the present invention with zinc oxide as the painted protecting glue of gold, adjust redox condition with cerium oxide, the painted rose-colored technique of gold adopted to existing lead glass; Do not adopt leaded raw material, have glossiness good, bright-colored, neat, no color differnece, without decorative pattern, output is high, and tint permanence is good, unleaded pollution-free, the advantage that productivity effect is good.
Description
Technical field
The present invention relates to a kind of rose crystal bead blank and preparation method thereof.
Background technology
Rose crystal bead blank is used to the work in-process preparing rose crystal product, existing rose crystal bead blank technique adopts crucible manufacture, there is aberration, color is uneven, have decorative pattern, unstable product quality, production efficiency is low, be not suitable for continuous production in enormous quantities, and cause environmental pollution by coal burning.And using Lead pollution environment in existing technical recipe, use poisonous white arsenic in starting material, the painted instability of secondary color technique, reproducibility is poor.
Summary of the invention
It is good that technical problem to be solved by this invention is to provide a kind of color reproduction, and solid colour no color differnece, without decorative pattern, constant product quality, production efficiency is high, can be applicable to the production operation of continuous tank furnace, unleaded free of contamination rose crystal bead blank.
For solving the problem, the present invention is achieved through the following technical solutions: a kind of rose crystal bead blank, and this rose crystal bead blank is made up of following weight composition: quartz sand 90-160 part, zinc oxide 8-16 part, soda ash 28-50 part, salt of wormwood 17-29 part, saltpetre 13-26 part, boric acid 8-15 part, calcium carbonate 3-5 part, aluminium hydroxide 1-3 part, salt 1-2 part, gold trichloride 0.01-0.03 part, antimonous oxide 1.5-3.5 part and cerium oxide 1-5 part.
Another technical problem to be solved by this invention is to provide a kind of preparation method of rose crystal bead blank,
The present invention is achieved through the following technical solutions: the preparation process of described rose crystal bead blank is as follows:
1) extract quartz sand 90-160 part, zinc oxide 8-16 part, soda ash 28-50 part, salt of wormwood 17-29 part, saltpetre 13-26 part, boric acid 8-15 part, calcium carbonate 3-5 part, aluminium hydroxide 1-3 part, salt 1-2 part, gold trichloride 0.01-0.03 part, antimonous oxide 1.5-3.5 part and cerium oxide 1-5 part by weight ratio to mix;
2) the rose crystal bead blank raw material mixed is carried out granulation by tablets press;
3) granular rose crystal bead blank raw material will be made put into glass quartz tank furnace and found, and when founding, keep strong oxidizing atmosphere and liquid level of solution to stablize;
4) crystal solution is molded into rose crystal bead blank after the homogenizing cooling of material road;
5) shaping pearl embryo is put into fire and throw stove polishing, integer, uniform coloring, shaping pearl embryo is allowed at the uniform velocity to enter stainless steel pipes, pipe temperature controls at 800 DEG C-900 DEG C, rotating speed 180 revolutions per seconds, in pipeline 5 minutes, pipeline was out just through integer, solid colour, no color differnece, rose crystal bead blank without decorative pattern.
Further, described in the preparation process 3 of rose crystal bead blank, when founding, temperature controls at 1380 DEG C-1450 DEG C.
Further, described in the preparation process 4 of rose crystal bead blank, cooling temperature controls at 800 DEG C-1000 DEG C.
The beneficial effect of rose crystal bead blank of the present invention is: time prepared by described rose crystal bead blank with zinc oxide as the painted protecting glue of gold, adjust redox condition with cerium oxide, the painted rose-colored technique of gold adopted to existing lead glass; Do not adopt leaded raw material, have glossiness good, bright-colored, neat, no color differnece, without decorative pattern, output is high, and tint permanence is good, unleaded pollution-free, the advantage that productivity effect is good.
Embodiment
Following examples for illustration of the present invention, but are not used for limiting the scope of the invention.
Embodiment 1
A kind of rose crystal bead blank of the present invention, this rose crystal bead blank is made up of following weight composition: quartz sand 150 parts, 10 parts, zinc oxide, soda ash 39 parts, 28 parts, salt of wormwood, 20 parts, saltpetre, boric acid 13 parts, 4 parts, calcium carbonate, 2 parts, aluminium hydroxide, salt 1.5 parts, gold trichloride 0.01 part, antimonous oxide 2.3 parts and cerium oxide 1.8 parts.
The preparation process of described rose crystal bead blank is as follows:
1) extract quartz sand 150 parts, 10 parts, zinc oxide, soda ash 39 parts, 28 parts, salt of wormwood, 20 parts, saltpetre, boric acid 13 parts, 4 parts, calcium carbonate, 2 parts, aluminium hydroxide, salt 1.5 parts, gold trichloride 0.01 part, antimonous oxide 2.3 parts and cerium oxide 1.8 parts by weight ratio to mix;
2) the rose crystal bead blank raw material mixed is carried out granulation by tablets press;
3) will make granular rose crystal bead blank raw material to put into glass quartz tank furnace and found, keep strong oxidizing atmosphere and liquid level of solution to stablize when founding, glass melting temperature controls at 1380 DEG C-1450 DEG C;
4) crystal solution is molded into rose crystal bead blank after the homogenizing cooling of material road, cooling temperature controls at 800 DEG C-1000 DEG C;
5) shaping pearl embryo is put into fire and throw stove polishing, integer, uniform coloring, shaping pearl embryo is allowed at the uniform velocity to enter stainless steel pipes, pipe temperature controls at 800 DEG C-900 DEG C, rotating speed 180 revolutions per seconds, in pipeline 5 minutes, pipeline was out just through integer, solid colour, no color differnece, rose crystal bead blank without decorative pattern.
Embodiment 2
Its difference from Example 1 is, this rose crystal bead blank is made up of following weight composition: quartz sand 160 parts, 16 parts, zinc oxide, soda ash 50 parts, 29 parts, salt of wormwood, 26 parts, saltpetre, boric acid 15 parts, 5 parts, calcium carbonate, 3 parts, aluminium hydroxide, salt 2 parts, gold trichloride 0.03 part, antimonous oxide 3.5 parts and cerium oxide 5 parts.
Embodiment 3
Its difference from Example 1 is, this rose crystal bead blank is made up of following weight composition: quartz sand 90 parts, 8 parts, zinc oxide, soda ash 28 parts, 17 parts, salt of wormwood, 13 parts, saltpetre, boric acid 8 parts, 3 parts, calcium carbonate, 1 part, aluminium hydroxide, salt 1 part, gold trichloride 0.01 part, antimonous oxide 1.5 parts and cerium oxide 1 part.
Embodiment 4
Its difference from Example 1 is, this rose crystal bead blank is made up of following weight composition: quartz sand 130 parts, 11 parts, zinc oxide, soda ash 40 parts, 21 parts, salt of wormwood, 19 parts, saltpetre, boric acid 13 parts, 3.5 parts, calcium carbonate, 2.7 parts, aluminium hydroxide, salt 1.6 parts, gold trichloride 0.018 part, antimonous oxide 1.9 parts and cerium oxide 2.8 parts.
Embodiment 5
Its difference from Example 1 is, this rose crystal bead blank is made up of following weight composition: quartz sand 105 parts, 14 parts, zinc oxide, soda ash 43 parts, 19 parts, salt of wormwood, 22 parts, saltpetre, boric acid 9 parts, 3.7 parts, calcium carbonate, 1.4 parts, aluminium hydroxide, salt 1.3 parts, gold trichloride 0.022 part, antimonous oxide 2.3 parts and cerium oxide 4.1 parts.
Embodiment 6
Its difference from Example 1 is, this rose crystal bead blank is made up of following weight composition: quartz sand 135 parts, 9 parts, zinc oxide, soda ash 31 parts, 26 parts, salt of wormwood, 15 parts, saltpetre, boric acid 9 parts, 3.6 parts, calcium carbonate, 2.3 parts, aluminium hydroxide, salt 1 part, gold trichloride 0.025 part, antimonous oxide 2 parts and cerium oxide 3.2 parts.
Embodiment 7
Its difference from Example 1 is, this rose crystal bead blank is made up of following weight composition: quartz sand 110 parts, 11 parts, zinc oxide, soda ash 37 parts, 21 parts, salt of wormwood, 17 parts, saltpetre, boric acid 11 parts, 4 parts, calcium carbonate, 1.9 parts, aluminium hydroxide, salt 1.3 parts, gold trichloride 0.018 part, antimonous oxide 1.9 parts and cerium oxide 2.6 parts.
Embodiment 8
Its difference from Example 1 is, this rose crystal bead blank is made up of following weight composition: quartz sand 155 parts, 14 parts, zinc oxide, soda ash 43 parts, 27 parts, salt of wormwood, 24 parts, saltpetre, boric acid 13 parts, 4.4 parts, calcium carbonate, 2.4 parts, aluminium hydroxide, salt 1.7 parts, gold trichloride 0.025 part, antimonous oxide 3.2 parts and cerium oxide 4.6 parts.
The present invention is not limited to above-mentioned preferred forms, anyone other any or akin products identical with the present invention drawn under enlightenment of the present invention, all drops within protection scope of the present invention.
Claims (1)
1. a rose crystal bead blank, it is characterized in that: this rose crystal bead blank is made up of following weight composition: quartz sand 150 parts, 10 parts, zinc oxide, soda ash 39 parts, 28 parts, salt of wormwood, 20 parts, saltpetre, boric acid 13 parts, 4 parts, calcium carbonate, 2 parts, aluminium hydroxide, salt 1.5 parts, gold trichloride 0.01 part, antimonous oxide 2.3 parts and cerium oxide 1.8 parts, the preparation process of described rose crystal bead blank is as follows:
1) extract quartz sand 150 parts, 10 parts, zinc oxide, soda ash 39 parts, 28 parts, salt of wormwood, 20 parts, saltpetre, boric acid 13 parts, 4 parts, calcium carbonate, 2 parts, aluminium hydroxide, salt 1.5 parts, gold trichloride 0.01 part, antimonous oxide 2.3 parts and cerium oxide 1.8 parts by weight ratio to mix;
2) the rose crystal bead blank raw material mixed is carried out granulation by tablets press;
3) will make granular rose crystal bead blank raw material to put into glass quartz tank furnace and found, keep strong oxidizing atmosphere and liquid level of solution to stablize when founding, glass melting temperature controls at 1380 DEG C-1450 DEG C;
4) crystal solution is molded into rose crystal bead blank after the homogenizing cooling of material road, cooling temperature controls at 800 DEG C-1000 DEG C;
5) shaping pearl embryo is put into fire and throw stove polishing, integer, uniform coloring, shaping pearl embryo is allowed at the uniform velocity to enter stainless steel pipes, pipe temperature controls at 800 DEG C-900 DEG C, rotating speed 180 revolutions per seconds, in pipeline 5 minutes, pipeline was out just through integer, solid colour, no color differnece, rose crystal bead blank without decorative pattern.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510003622.4A CN104496178B (en) | 2015-01-06 | 2015-01-06 | A kind of rose crystal bead blank and preparation method thereof |
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| CN201510003622.4A CN104496178B (en) | 2015-01-06 | 2015-01-06 | A kind of rose crystal bead blank and preparation method thereof |
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| CN104496178B true CN104496178B (en) | 2016-03-23 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108558219A (en) * | 2018-04-18 | 2018-09-21 | 浙江工业大学 | A kind of noctilucence crystal bead blank and preparation method thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109111109A (en) * | 2018-08-28 | 2019-01-01 | 浙江工业大学 | A kind of antibacterial artificial crystal and preparation method and application |
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| CN1095696A (en) * | 1993-05-22 | 1994-11-30 | 陈才 | A kind of crystal glass |
| US5656559A (en) * | 1994-06-23 | 1997-08-12 | Saint-Gobain Vitrage | Clear glass composition intended for the production of panes |
| CN101648773A (en) * | 2009-09-04 | 2010-02-17 | 常熟市万利特种玻璃厂 | Processing technology of Chinese red glass metal |
| CN102211869A (en) * | 2011-04-12 | 2011-10-12 | 姚晓春 | Primary pressure-sizing molding crystalloid glass and preparation method thereof |
| CN102503126A (en) * | 2011-10-08 | 2012-06-20 | 浙江伟兴水晶有限公司 | Preparation method for smoky yellow crystal bead blanks |
| CN102837251A (en) * | 2012-09-17 | 2012-12-26 | 江苏锦程集团科技有限公司 | Diamond bead blank fire polishing furnace |
| CN102838277A (en) * | 2012-09-17 | 2012-12-26 | 江苏锦程集团科技有限公司 | Production process of honey peach CZ diamond |
| CN103641301A (en) * | 2013-12-06 | 2014-03-19 | 辽宁红山玉科技有限公司 | Red microcrystalline glass color agent and red microcrystalline glass |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2010083721A (en) * | 2008-09-30 | 2010-04-15 | Reiseki:Kk | Method for storing granulate or powdery object to be stored |
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2015
- 2015-01-06 CN CN201510003622.4A patent/CN104496178B/en active Active
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| US5656559A (en) * | 1994-06-23 | 1997-08-12 | Saint-Gobain Vitrage | Clear glass composition intended for the production of panes |
| CN101648773A (en) * | 2009-09-04 | 2010-02-17 | 常熟市万利特种玻璃厂 | Processing technology of Chinese red glass metal |
| CN102211869A (en) * | 2011-04-12 | 2011-10-12 | 姚晓春 | Primary pressure-sizing molding crystalloid glass and preparation method thereof |
| CN102503126A (en) * | 2011-10-08 | 2012-06-20 | 浙江伟兴水晶有限公司 | Preparation method for smoky yellow crystal bead blanks |
| CN102837251A (en) * | 2012-09-17 | 2012-12-26 | 江苏锦程集团科技有限公司 | Diamond bead blank fire polishing furnace |
| CN102838277A (en) * | 2012-09-17 | 2012-12-26 | 江苏锦程集团科技有限公司 | Production process of honey peach CZ diamond |
| CN103641301A (en) * | 2013-12-06 | 2014-03-19 | 辽宁红山玉科技有限公司 | Red microcrystalline glass color agent and red microcrystalline glass |
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| CN108558219A (en) * | 2018-04-18 | 2018-09-21 | 浙江工业大学 | A kind of noctilucence crystal bead blank and preparation method thereof |
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| CN104496178A (en) | 2015-04-08 |
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Effective date of registration: 20220207 Address after: 321000 No. 668, Xuecheng East Road, Hanxiang Industrial Park, Tangya Town, Jindong District, Jinhua City, Zhejiang Province Patentee after: Zhejiang xinweixing crystal Co.,Ltd. Address before: 321000 Jindong comprehensive development park, Jinhua City, Zhejiang Province Patentee before: ZHEJIANG WEIXING CRYSTAL Co.,Ltd. |
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