CN1044766C - Chinese herbal pesticide without envirenmental pollution and preparation thereof - Google Patents
Chinese herbal pesticide without envirenmental pollution and preparation thereof Download PDFInfo
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- CN1044766C CN1044766C CN93100659A CN93100659A CN1044766C CN 1044766 C CN1044766 C CN 1044766C CN 93100659 A CN93100659 A CN 93100659A CN 93100659 A CN93100659 A CN 93100659A CN 1044766 C CN1044766 C CN 1044766C
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- medicinal herbs
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- 239000000575 pesticide Substances 0.000 title claims abstract description 34
- 238000002360 preparation method Methods 0.000 title description 5
- 241000411851 herbal medicine Species 0.000 claims description 7
- 244000307697 Agrimonia eupatoria Species 0.000 claims description 6
- 241000296615 Celastrus strigillosus Species 0.000 claims description 6
- 241000931143 Gleditsia sinensis Species 0.000 claims description 6
- 235000008291 Poterium sanguisorba Nutrition 0.000 claims description 6
- 235000008282 Sanguisorba officinalis Nutrition 0.000 claims description 6
- 241000316658 Sauromatum giganteum Species 0.000 claims description 6
- 235000000125 common agrimony Nutrition 0.000 claims description 6
- 240000004064 Poterium sanguisorba Species 0.000 claims description 4
- 241000598860 Garcinia hanburyi Species 0.000 claims description 3
- 241000208134 Nicotiana rustica Species 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- 229940037003 alum Drugs 0.000 claims description 3
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 3
- 239000011790 ferrous sulphate Substances 0.000 claims description 3
- 229940117709 gamboge Drugs 0.000 claims description 3
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 3
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 239000011593 sulfur Substances 0.000 claims description 3
- 241000196324 Embryophyta Species 0.000 abstract description 11
- 241000238631 Hexapoda Species 0.000 abstract description 11
- 229920000742 Cotton Polymers 0.000 abstract description 8
- 241001124076 Aphididae Species 0.000 abstract description 7
- 239000002689 soil Substances 0.000 abstract description 7
- 241001465754 Metazoa Species 0.000 abstract description 6
- 241000255969 Pieris brassicae Species 0.000 abstract description 5
- 239000003795 chemical substances by application Substances 0.000 abstract description 5
- 241000607479 Yersinia pestis Species 0.000 abstract description 4
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- 239000000843 powder Substances 0.000 abstract description 3
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- 210000002784 stomach Anatomy 0.000 abstract description 2
- 235000008216 herbs Nutrition 0.000 abstract 3
- 241001243087 Gryllotalpidae Species 0.000 abstract 1
- 241000282414 Homo sapiens Species 0.000 abstract 1
- 241000488583 Panonychus ulmi Species 0.000 abstract 1
- 231100000674 Phytotoxicity Toxicity 0.000 abstract 1
- 230000008092 positive effect Effects 0.000 abstract 1
- 231100000331 toxic Toxicity 0.000 abstract 1
- 230000002588 toxic effect Effects 0.000 abstract 1
- 239000003905 agrochemical Substances 0.000 description 12
- 239000003814 drug Substances 0.000 description 12
- 239000000126 substance Substances 0.000 description 12
- 230000000694 effects Effects 0.000 description 9
- 239000007921 spray Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- NYPJDWWKZLNGGM-UHFFFAOYSA-N fenvalerate Chemical compound C=1C=C(Cl)C=CC=1C(C(C)C)C(=O)OC(C#N)C(C=1)=CC=CC=1OC1=CC=CC=C1 NYPJDWWKZLNGGM-UHFFFAOYSA-N 0.000 description 6
- 239000007788 liquid Substances 0.000 description 5
- 230000003449 preventive effect Effects 0.000 description 5
- 235000013311 vegetables Nutrition 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000011160 research Methods 0.000 description 4
- 240000007124 Brassica oleracea Species 0.000 description 3
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 description 3
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 description 3
- 241000255967 Helicoverpa zea Species 0.000 description 3
- 241000255972 Pieris <butterfly> Species 0.000 description 3
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- 238000007689 inspection Methods 0.000 description 3
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- 241000241125 Gryllotalpa gryllotalpa Species 0.000 description 2
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- 240000008042 Zea mays Species 0.000 description 2
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- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- 230000007059 acute toxicity Effects 0.000 description 2
- 231100000403 acute toxicity Toxicity 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- 235000005822 corn Nutrition 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 231100000225 lethality Toxicity 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- BULVZWIRKLYCBC-UHFFFAOYSA-N phorate Chemical compound CCOP(=S)(OCC)SCSCC BULVZWIRKLYCBC-UHFFFAOYSA-N 0.000 description 2
- 244000144977 poultry Species 0.000 description 2
- 235000006008 Brassica napus var napus Nutrition 0.000 description 1
- 241001674939 Caulanthus Species 0.000 description 1
- ZSBXGIUJOOQZMP-UHFFFAOYSA-N Isomatrine Natural products C1CCC2CN3C(=O)CCCC3C3C2N1CCC3 ZSBXGIUJOOQZMP-UHFFFAOYSA-N 0.000 description 1
- ZSBXGIUJOOQZMP-JLNYLFASSA-N Matrine Chemical compound C1CC[C@H]2CN3C(=O)CCC[C@@H]3[C@@H]3[C@H]2N1CCC3 ZSBXGIUJOOQZMP-JLNYLFASSA-N 0.000 description 1
- 241001012098 Omiodes indicata Species 0.000 description 1
- 241000283973 Oryctolagus cuniculus Species 0.000 description 1
- 241000255129 Phlebotominae Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 235000014443 Pyrus communis Nutrition 0.000 description 1
- 241001454293 Tetranychus urticae Species 0.000 description 1
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- 229930013930 alkaloid Natural products 0.000 description 1
- 150000003797 alkaloid derivatives Chemical class 0.000 description 1
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- 238000011010 flushing procedure Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 235000012055 fruits and vegetables Nutrition 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000001727 in vivo Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 231100000021 irritant Toxicity 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229930014456 matrine Natural products 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- PZXOQEXFMJCDPG-UHFFFAOYSA-N omethoate Chemical compound CNC(=O)CSP(=O)(OC)OC PZXOQEXFMJCDPG-UHFFFAOYSA-N 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000011218 segmentation Effects 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to nuisance free pesticide with Chinese medicinal herbs, which prepares Chinese medicinal herbs in the forms of roots, stems and leaves into aqueous agents and powder. Each form is prepared from eleven kinds of Chinese medicinal herbs. The aqueous agents are mainly sprayed on leaves to prevent and kill aphids, cabbage worms, red spiders and cotton earworms, and the powder is mainly used for dressing seeds and can prevent and kill various soil insects, such as cutworm, grubs, mole crickets, etc. The pesticide has the advantages of high efficiency, low toxicity, no odor, no residue, strong action on killing pests through stomach poisoning and contact killing, no toxic action on both human beings and domestic animals, no phytotoxicity to plants, no damage to natural enemies, stable drug effect, long duration time and positive action on protecting the ecological balance of the natural environment.
Description
The invention belongs to agricultural chemicals, be specifically related to a kind of natural plant agricultural chemicals, by seed dressing, soil land disposal or foliage spray, the various pests that can prevent and treat vegetables, fruit tree and cereal crops effectively with the Chinese herbal medicine preparation.
The insecticide pesticide that uses generally is chemicals at present, these chemical pesticides have stronger lethality to insect, but often cause vegetables, fruit to have remains of pesticide, and chemical pesticide has also caused injury to natural enemy-beneficial insect of insect, insect loses the nature restrained force, and activity is more rampant, causes spray medicine number of times and dosage to increase, residue of pesticide surpass acceptable dose, jeopardize the person poultry safety.
Contain noxious materials such as organic phosphor, organochlorine in the chemical pesticide, these are liposoluble substance, can not be digested in vivo, more can not be absorbed decomposition, but, in people's carcass, produce enrichment along with the circulation and the diffusion of food chain, influence health.
In addition, in use, the direct contaminated soil of chemical pesticide, water source, cause the deterioration of the ecological environment, become the world's one big public hazards.
The Chinese herbal medicine agricultural chemicals of new generation that the purpose of this invention is to provide a kind of efficient, low toxicity, odorlessness, noresidue; this agricultural chemicals has stronger stomach to kill and the function of tagging to insect; nontoxic to people and animals; plant there is not poisoning; do not injure natural enemy; drug effect is steady, and longer duration plays positive role to conservation of nature environmental ecology balance.
Technical solution of the present invention is: utilize contained chemical composition of a part of Chinese herbal medicine and alkaloid that there is stronger lethality in agricultural insect pest, at different types of insect, these Chinese herbal medicine roots, stem, leaf are made aqua and two kinds of formulations of pulvis.
Aqua is mainly used in foliage spray, can prevent and treat aphid, cabbage caterpillar, two spotted spider mite and the cotton sandfly worm etc. of various crops.The aqua prescription is composed as follows:
Typhonium giganteum 5-10% radix aconiti agrestis 0.5-3% rhizoma arisaematis 0.5-2%
Celastrus orbiculatus 5-20% gamboge 5-20% kuh-seng 10-15%
Hairyvein agrimony 10-20% garden burnet 5-20% Chinese honey locust 5-15%
Asafoetide 5-15% Aztec tobacco 10-20%;
Its manufacture craft flow process is: ingredient inspection preparation → flushing → decoction → concentrate → precipitation → filtration → quality inspection, chemical examination → bottling → packing.
Pulvis is mainly used in seed dressing and soil land disposal, can prevent and treat various soil insects, as cutworm, grub, mole cricket etc.The pulvis prescription is composed as follows:
Typhonium giganteum 5-10% radix aconiti agrestis 0.5-3% rhizoma arisaematis 0.5-2%
Celastrus orbiculatus 5-20% kuh-seng 10-15% hairyvein agrimony 10-20%
Garden burnet 5-20% Chinese honey locust 5-15% alum 10-20%
Sulfur 10-30% ferrous sulfate 5-20%.
Its manufacture craft flow process is: preparation raw material → shred → clean → dry → pulverize → sieve → quality inspection → pack → packing in proportion.
Technical target of the product of the present invention requires:
| Title | Physical and chemical index | PH value | Contain matrine (C 15H 24N 2O) | Concentration |
| The medicinal herb pesticide pulvis | Pale brown look pressed powder (by 70 mesh standard sieves) | 5.0-6.5 | 0.10％ | Water content≤3% |
| The medicinal herb pesticide aqua | Pale brown look thickness suspendible liquid | 5.0-6.5 | Contain 0.04% | Baume degrees is 15-20% |
According to the requirement of the agriculture and animal husbandry Room, Shanxi Province plant protection master station, specify in flat water agent such as the agriculture and animal husbandry Room, Hubei Province plant protection master station and academy of agricultural sciences, Shanxi Province, Vegetable Research Institute, Cotton Research Institute, agriculture and animal husbandry Room plant protection master station, Yuncheng Prefecture's plant protection unit, Xia County plant protection unit and pulvis carries out two places test in 2 years, effect is all very good.Seeds such as pulvis seed dressing corn, wheat, cotton, soil insects such as control of grubs, mole cricket, cutworm effectively; Aqua is used for foliage spray, can prevent and treat cotten aphid, cotton bollworm, vegetable aphid, cabbage caterpillar, fruit aphid, heart-eating worm, mite class, pear leaf worm etc. effectively.
Medicinal herb pesticide of the present invention carries out acute toxicity experience through Shanxi Medical College to big white mouse per os, skin, observe after the administration not have in two weeks and poison and death, according to China's agricultural chemicals acute toxicity classification tentative standard, this agricultural chemicals belongs to low toxicity, through Shanxi Medical College to the mucocutaneous irritant test that carries out of rabbit, skin irritatin reacts on the 3rd day and recovers normal, and according to " criterion of skin irritatin intensity ", this agricultural chemicals is the minimal irritation effect to skin.
In sum, medicinal herb pesticide of the present invention has efficiently, low toxicity, free from environmental pollution, odorlessness, nuisanceless, to advantages such as people, animal, fowl safety, this application often, for optimizing natural environment, maintaining ecological balance, reduce production costs, improve the fruits and vegetables grain and oil quality.Increase economic benefit, promoting health all has great benefit, is desirable novel agrochemical.
Further specify the present invention below in conjunction with embodiment:
The used aqua prescription of the embodiment of the invention consists of:
Typhonium giganteum 1% radix aconiti agrestis 2% rhizoma arisaematis 1%
Celastrus orbiculatus 10% gamboge 10% kuh-seng 12%
Hairyvein agrimony 12% garden burnet 15% Chinese honey locust 10%
Asafoetide 10% Aztec tobacco 10%;
With above-mentioned medicament according to the technological process decocting and concentrating after, carry out Baume degrees and measure, qualified index is 15-20%.
The used pulvis prescription of the embodiment of the invention consists of:
Typhonium giganteum 8% radix aconiti agrestis 2% rhizoma arisaematis 1%
Celastrus orbiculatus 10% kuh-seng 12% hairyvein agrimony 12%
Garden burnet 15% Chinese honey locust 10% alum 10%
Sulfur 10% ferrous sulfate 10%.
Above-mentioned medicament is dried grinding and sieving according to technological process, and granularity is the 70-120 order.
Embodiment 1: the present invention carries out the test of pesticide effectiveness through agriculture chemical examination place, the Shanxi Province Southern Suburb Jin Yuan of Taiyuan City to cabbage pieris, and reagent agent is the Chinese herbal medicine aqua, and the contrast medicament is 20% sumicidin missible oil (a SUMITOMO CHEMICAL product).Test method: the medicinal herb pesticide aqua restrains (stoste), 20 grams, 13 grams, sumicidin missible oil 20 grams for every mu 40, blank, and for five processing, three repetitions, randomized arrangement, sub-district area 70m
2, in the cabbage caterpillar occurance peak, with the manual sprayer foliar spray once, every mu adds 40 kilograms in water.Blank spray clear water.
Result of the test shows that medicinal herb pesticide aqua control cabbage pieris has very high insecticidal activity.Every mu 13 gram has all showed good preventive effect to 40 grams (stoste), and preventive effect is the highest be every mu 40 gram, dispenser one day after, preventive effect reaches 91.1%, contrasting medicament 20% Belmark is 93.4%, it is suitable that the two desinsection is knocked down the speed preventive effect.But the Chinese herbal medicine lasting period is long, and 10 days medicinal herb pesticide preventive effects are 97.9% behind the medicine, and Belmark is 92.6%.
Embodiment 2: the present invention carries out the test of pesticide effectiveness at the Southern Suburb Wu Su of Taiyuan City to cabbage pieris through Shanxi Province's plant protection master station, and the contrast medicament is 20% sumicidin missible oil (a SUMITOMO CHEMICAL product).40 kilograms of every mu of dispenser liquid, two days desinsection speed is lower than contrast agricultural chemicals Belmark behind the medicine, and control efficiency reaches 80-90% after five days, and near the contrast agricultural chemicals, effect still maintains 78-93% after 10 days, is better than contrasting agricultural chemicals.
Conclusion: adopt the 500-1000 times of cabbage caterpillar on the medicinal herb pesticide liquid control wild cabbage that the better prevention effect is arranged, suggestion is applied in vast vegetables district.
Embodiment 3: the present invention carries out the test of pesticide effectiveness in Yu Wangxiang Xiqin, Xia County, Shanxi Province village to cotten aphid through Xia County plant protection unit, the contrast medicament is 1000 times of liquid of 40% omethoate emulsifiable solution (commercially available Chongqing products), investigate 10 hours respectively behind the spray medicine, 24 hours, 48 hours, hundred strains, three tree louses after 72 hours are measured the rate that goes down, 500-800 times of liquid control efficiency of medicinal herb pesticide aqua is better, hundred strains, the three tree louses amount rate that goes down increases in time gradually, can reach 88.4% after 48 hours, still maintain 85-86% after 72 hours, drug effect continues steadily, and the contrast medicament rate that goes down after 24 hours also only is 89%, and reduces gradually later on.
Conclusion: the flolimat effect is seen and contrasted to the medicinal herb pesticide aqua on control cotten aphid effect approaching; though drug effect is slow, steadily continue, and specific investment is comparatively economical mutually with tester; to person poultry safety's noresidue, be the desirable medicament of protection environmental development nothing evil agricultural chemicals.
Embodiment 4: the present invention carries out the test of pesticide effectiveness in cotton region, south, Shanxi Province to cotton bollworm through academy of agricultural sciences, Shanxi Province Cotton Research Institute.Adopting medicinal herb pesticide and 5% to come the good fortune spirit (is japanese product, buy back in market) check experiment, repeat for three times, small plot experiment, district's group is arranged at random, and its conclusion is: use 500-1000 times of medicinal herb pesticide to come the good fortune spirit similar for 1500 times to the control efficiency fundamental sum of cotton bollworm, medicinal herb pesticide is safer to cotton field enemy, and free from environmental pollution, cost comes the good fortune spirit greatly to descend, and the suggestion large-scale demonstration is promoted.
Embodiment 5: the present invention has arranged the contrast plantation of corn, wheat seed dressing control soil insect in area just outside a city gate, Xia County town and low bank between fields palm Zhenan County through academy of agricultural sciences, Shanxi Province Cotton Research Institute, (" 3911 " plant the clothing agent to adopt medicinal herb pesticide, thimet, for commercially available), three treatment regions of blank, emergence rate and growing way are observed in segmentation.Conclusion is as follows: the existing pest-resistant effect of medicinal herb pesticide, can produce the physiological stimulation effect again, and promote the early stage effective tiller of wheat, with the medicinal herb pesticide seed dressing, compare full stand and healthy seedling, dark green leaf color, more, the well developed root system of secondary root with thimet.
Claims (3)
1, a kind of nuisanceless medicinal herb pesticide adopts Chinese herbal medicine root, stem, leaf to make aqua and pulvis, and feature of the present invention is:
The aqua prescription consists of: Typhonium giganteum 5-10% radix aconiti agrestis 0.5-3% rhizoma arisaematis 0.5-2% celastrus orbiculatus 5-20% gamboge 5-20% kuh-seng 10-15% hairyvein agrimony 10-20% garden burnet 5-20% Chinese honey locust 5-15% asafoetide 5-15% Aztec tobacco 10-20%;
The pulvis prescription consists of: Typhonium giganteum 5-10% radix aconiti agrestis 0.5-3% rhizoma arisaematis 0.5-2% celastrus orbiculatus 5-20% kuh-seng 10-15% hairyvein agrimony 10-20% garden burnet 5-20% Chinese honey locust 5-15% alum 10-20% Sulfur 10-30% ferrous sulfate 5-20%.
2, nuisanceless medicinal herb pesticide according to claim 1 is characterized in that: aqua requires Baume degrees to reach 15-20%.
3, nuisanceless medicinal herb pesticide according to claim 1 is characterized in that: the granularity of pulvis is the 70-120 order.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN93100659A CN1044766C (en) | 1993-01-01 | 1993-01-01 | Chinese herbal pesticide without envirenmental pollution and preparation thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN93100659A CN1044766C (en) | 1993-01-01 | 1993-01-01 | Chinese herbal pesticide without envirenmental pollution and preparation thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1074337A CN1074337A (en) | 1993-07-21 |
| CN1044766C true CN1044766C (en) | 1999-08-25 |
Family
ID=4983161
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN93100659A Expired - Fee Related CN1044766C (en) | 1993-01-01 | 1993-01-01 | Chinese herbal pesticide without envirenmental pollution and preparation thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1044766C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100379344C (en) * | 2005-12-08 | 2008-04-09 | 倪建忠 | Green pesticide formula and production process |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101218926B (en) * | 2007-01-08 | 2011-05-25 | 闫双婷 | Chinese medicinal herb made biological pesticide |
| CN101396446B (en) * | 2008-10-06 | 2011-01-26 | 江苏省农业科学院 | Method for increasing the parasitism performance of parasitic wasp |
| CN102948433A (en) * | 2011-08-25 | 2013-03-06 | 天津益博生物技术开发有限公司 | Traditional Chinese medicine pesticide |
| CN102951951A (en) * | 2011-08-25 | 2013-03-06 | 天津益博生物技术开发有限公司 | Traditional Chinese medicine fertilizer |
| CN103694058B (en) * | 2013-12-03 | 2015-09-30 | 山东裕利蔬菜股份有限公司 | Pest control compound formulation and preparation technology thereof |
| CN103814719A (en) * | 2014-02-11 | 2014-05-28 | 宋光辉 | Lavender field planting method |
| CN104082358A (en) * | 2014-06-27 | 2014-10-08 | 匡铁铃 | Chinese herbal medicine pesticide |
| CN104322592A (en) * | 2014-10-31 | 2015-02-04 | 苏州多贝机械科技有限公司 | Insecticide pesticide powder containing traditional Chinese medicine components |
| CN107439620A (en) * | 2016-05-31 | 2017-12-08 | 肖范 | A kind of insecticide for preventing and treating subterranean pest-insect and preparation method thereof |
| CN106472610A (en) * | 2016-09-29 | 2017-03-08 | 青岛海之源智能技术有限公司 | A kind of Nicotiana tabacum L. oriental tobacco budworm Pesticidal combination and preparation method thereof |
-
1993
- 1993-01-01 CN CN93100659A patent/CN1044766C/en not_active Expired - Fee Related
Non-Patent Citations (4)
| Title |
|---|
| 中药大辞典，第一版 1986.6.1 江苏新医学院编 * |
| 化工辞典，第二版 1979.12.1 化工出版社，王箴编 * |
| 化工辞典，第二版 1979.12.1 化工出版社，王箴编;土农药及生物防治 1979.10.1 化工出版社;中药大辞典，第一版 1986.6.1 江苏新医学院编 * |
| 土农药及生物防治 1979.10.1 化工出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100379344C (en) * | 2005-12-08 | 2008-04-09 | 倪建忠 | Green pesticide formula and production process |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1074337A (en) | 1993-07-21 |
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