CN104452321A - 一种生态型pvc装饰人造革 - Google Patents

一种生态型pvc装饰人造革 Download PDF

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CN104452321A
CN104452321A CN201410777630.XA CN201410777630A CN104452321A CN 104452321 A CN104452321 A CN 104452321A CN 201410777630 A CN201410777630 A CN 201410777630A CN 104452321 A CN104452321 A CN 104452321A
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林斌生
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GUANGDONG FION LEATHER PRODUCT Co Ltd
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    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/06—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
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    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
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    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
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    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
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    • D06N2203/00—Macromolecular materials of the coating layers
    • D06N2203/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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    • D06N2211/00—Specially adapted uses
    • D06N2211/12—Decorative or sun protection articles
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Abstract

本发明涉及一种生态型PVC装饰人造革，属于人造革材料技术领域，其中各组分的重量份为PVC树脂粉80~120份、增塑剂40~80份、非重金属色饼2~10份、稳定剂1~10粉末、发泡剂1~5份、抗氧化剂1~10份、二氧化硅10~50份；该人造革具有较好的机械性能，柔软性和手感较好，且生产成本低，适于工业化生产。

Description

一种生态型PVC装饰人造革
技术领域
本发明涉及一种人造革，具体涉及一种生态型PVC装饰人造革，属于人造革材料技术领域。
背景技术
皮革是经脱毛和鞣制等物理、化学加工所得到的已经变性不易腐烂的动物皮。皮革行业涵盖了制革、制鞋、皮衣、皮件、毛皮及其制品等主体行业，以及皮革化工、皮革五金、皮革机械、辅料等配套行业。上下游关联度高，依靠市场拉动，产品常青，集创汇、富民、就业为一体的特点。
中国皮革行业，经过调整优化结构，在全国已初步形成了一批专业化分工明确、特色突出、对拉动当地经济起着举足轻重作用的皮革生产特色区域和专业市场。它们的形成，奠定了中国皮革行业发展的基础。
    但是由于皮革的原料来源于动物，处理工艺较复杂、生产成本较高，因此造成价格较贵，所以一些替代产品应运而生。
人造革是一种外观、手感似皮革并可代替其使用的塑料制品。我国人造革合成革工业是建国后新兴的工业，于五十年代末起步发展，是塑料工业中发展较早的行业之一。经过近几十年的建设，人造革合成革行业已具有相当的经济规模；随着国内外高科技的发展与先进工艺设备的应用，行业管理、技术水平、产品档次都有了根本性的质的飞跃，人造革合成革已发展成为日常消费制品工业中重要的行业之一，与整个加工工业同步迈入世界大国行列，是世界上的生产大国、消费大国，进出口贸易大国之一。
1948年出现的聚氯乙烯人造革(PVC人造革)是在织物上涂覆PVC树脂、增塑剂、稳定剂等助剂制成的糊.或者再覆合一层PVC膜，然后经一定的工艺过程加工制成的。制品强度高，加工容易，成本低廉，可做各种箱包、座套、衬里、杂物等。但耐油性、耐高温性差，低温柔软性和手感较差。
CN201010184586.3公开了一种生态型PVC装饰人造革及其制备方法，该人造革利用生态型PVC浆料采用压延法制备而成，所述生态型PVC浆料由以下重量份的组分配成：PVC树脂粉100份，环氧大豆油40~80份，非重金属色饼2~10份，稳定剂和发泡剂3~7份，贝壳粉20~40份，该发明的人造革不仅具有较好的机械性能，还具有较佳的耐折牢度老化性能，该皮革还具有吸附甲醛、分解甲醛、调节空气温度的效果。
虽然已是专利在一定程度上改善了传统PVC人造革存在的一些缺点，但是由于其制备成本较高，工业化生产有一定限制。
发明内容
本发明针对现有技术存在的问题，提供一种生态型PVC装饰人造革，该人造革具有较好的机械性能，柔软性和手感较好，且生产成本低，适于工业化生产。
为了解决上述问题，本发明所采用的技术方案是：
一种生态型PVC装饰人造革，各组分的重量份为：
PVC树脂粉80~120份、增塑剂40~80份、非重金属色饼2~10份、稳定剂1~10粉末、发泡剂1~5份、抗氧化剂1~10份、二氧化硅10 ~ 50份；
所述的PVC装饰人造革料采用压延法制备而成；
所述的增塑剂为菜籽油与甲醇交换后制得菜籽油脂肪酸甲酯，然后与马来酸二丁酯共聚；
所述的二氧化硅为纳米二氧化硅粉。
本发明相对于现有技术的有益效果是：
（1）本发明提供的一种生态型PVC装饰人造革，该人造革具有较好的机械性能，柔软性和手感较好，且生产成本低，适于工业化生产。
（2）本发明提供的生态型PVC装饰人造革，各种性能如下：
经向拉伸负荷300N，纬向拉伸负荷200N，经向断裂伸长率10%，纬向断裂伸长率20%，经向撕裂负荷25N，纬向撕裂负荷20N，剥离负荷23N，表面颜色牢度6级，通过30000次耐折牢度试验，老化性测试不开裂。且具有一定的耐油性、耐高温性差。
具体实施方式
下面通过实施例对本发明做进一步详细说明，这些实施例仅用来说明本发明，并不限制本发明的范围。
实施例1
一种生态型PVC装饰人造革，各组分的重量份为：
PVC树脂粉80份、增塑剂40份、非重金属色饼2份、稳定剂1粉末、发泡剂1份、抗氧化剂1份、二氧化硅10份。
实施例2
一种生态型PVC装饰人造革，各组分的重量份为：
PVC树脂粉120份、增塑剂80份、非重金属色饼10份、稳定剂10粉末、发泡剂5份、抗氧化剂10份、二氧化硅50份。
实施例3
一种生态型PVC装饰人造革，各组分的重量份为：
PVC树脂粉100、0份、增塑剂60份、非重金属色饼6份、稳定剂5粉末、发泡剂3份、抗氧化剂5份、二氧化硅30份。
实施例4
一种生态型PVC装饰人造革，各组分的重量份为：
PVC树脂粉90份、增塑剂50份、非重金属色饼4份、稳定剂3粉末、发泡剂2份、抗氧化剂4份、二氧化硅20份。
实施例5
一种生态型PVC装饰人造革，各组分的重量份为：
PVC树脂粉110份、增塑剂75份、非重金属色饼8份、稳定剂7粉末、发泡剂4份、抗氧化剂9份、二氧化硅45份。

Claims (4)

1.一种生态型PVC装饰人造革，其特征在于：各组分的重量份为：
PVC树脂粉80~120份、增塑剂40~80份、非重金属色饼2~10份、稳定剂1~10粉末、发泡剂1~5份、抗氧化剂1~10份、二氧化硅10 ~ 50份。
2.根据权利要求1所述的一种生态型PVC装饰人造革，其特征在于：所述的PVC装饰人造革料采用压延法制备而成。
3.根据权利要求1所述的一种生态型PVC装饰人造革，其特征在于：所述的增塑剂为菜籽油与甲醇交换后制得菜籽油脂肪酸甲酯，然后与马来酸二丁酯共聚。
4.根据权利要求1所述的一种生态型PVC装饰人造革，其特征在于：所述的二氧化硅为纳米二氧化硅粉。
CN201410777630.XA 2014-12-17 2014-12-17 一种生态型pvc装饰人造革 Pending CN104452321A (zh)

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Cited By (2)

* Cited by examiner, † Cited by third party
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CN105239415A (zh) * 2015-08-26 2016-01-13 安徽冠宜箱包有限公司 一种自带清香的人造皮革箱包及其制备方法
CN107100013A (zh) * 2017-05-12 2017-08-29 佛山高明骏宏塑胶有限公司 一种防霉pvc人造革及其制备方法

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CN101838937A (zh) * 2010-05-27 2010-09-22 江苏国信合成革有限公司 一种生态型pvc装饰人造革及其制备方法
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105239415A (zh) * 2015-08-26 2016-01-13 安徽冠宜箱包有限公司 一种自带清香的人造皮革箱包及其制备方法
CN107100013A (zh) * 2017-05-12 2017-08-29 佛山高明骏宏塑胶有限公司 一种防霉pvc人造革及其制备方法

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