CN104451740A - Water-based cleaning solution for punching oil on surface of steel - Google Patents
Water-based cleaning solution for punching oil on surface of steel Download PDFInfo
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- CN104451740A CN104451740A CN201410518940.XA CN201410518940A CN104451740A CN 104451740 A CN104451740 A CN 104451740A CN 201410518940 A CN201410518940 A CN 201410518940A CN 104451740 A CN104451740 A CN 104451740A
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- amine salt
- parts
- alcohol amine
- water
- punching oil
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/24—Cleaning or pickling metallic material with solutions or molten salts with neutral solutions
- C23G1/26—Cleaning or pickling metallic material with solutions or molten salts with neutral solutions using inhibitors
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a water-based cleaning solution for punching oil on the surface of steel. The water-based cleaning solution comprises a cationic surfactant, polyoxyethylene fatty alcohol sodium sulfate, fatty acid diethanolamide, a gemini surfactant, a cleaning assistant, triazine-triaminocaproic acid alcohol amine salt, n-dodecane dicarboxylic acid alcohol amine salt, polyether modified organic silicone defoamer and deionized water. Because the cationic surfactant, the polyoxyethylene fatty alcohol sodium sulfate and the fatty acid diethanolamide are used as main cleaning surfactants, the gemini surfactant is further compounded with the main cleaning surfactants, and the corrosion inhibitor, the cleaning assistant and the defoaming agent are added, the effects of cleaning the punching oil on the surface of steel by using the water-based cleaning solution and protecting the surface of steel against rust can be achieved.
Description
Technical field
The present invention relates to cleaning metal surface technical field, espespecially a kind of steel surface punching oil water-base cleaning liquid.
Background technology
In intermetallic composite coating and manufacture course of products, corrosion is necessary problems faced, corrosion be metal in an atmosphere with oxygen, moisture and other impurity and the corrosion caused, its corrosion product is called rust, the metal loss amount caused by getting rusty is very little, but cause intermetallic composite coating to become the indirect loss after product much bigger, body surface is subject to physics, chemical or biological effect and the pollution layer formed or tectum are called dirt, remove these pollutents or tectum and make its process recovering original surface situation be called cleaning, in intermetallic composite coating and manufacture course of products, cleaning and corrosion are must problems faced.Iron and steel is in impact briquetting process, and punching oil and dust etc. can form grease and spot at steel material surface, and these all need cleaning, cleaning and antirust be the very important operation of twice affecting the following process of stamping products, surface appearance and quality product.Water-base cleaning liquid, be applicable to making an addition to as the cleaning to ferrous materials in water, having good cleanup action to dirts such as punching oils, is that a class cleaning speed is fast, without phosphorus, the water-base cleaning liquid of asepsis environment-protecting.
Summary of the invention
A kind of steel surface punching oil of the present invention water-base cleaning liquid, it is characterized in that: adopt cats product, polyoxyethylenated alcohol sodium sulfate and fatty diglycollic amide as main wash tensio-active agent, utilize the geminal surfactant composite and mode of inhibiter, washing assistant and defoamer of interpolation further, realize carrying out aqueous-base cleaning and antirust object to steel surface punching oil.
To achieve these goals, technical solution of the present invention is: a kind of steel surface punching oil water-base cleaning liquid comprises cats product, polyoxyethylenated alcohol sodium sulfate, fatty diglycollic amide, Gemini surface active agent, washing assistant, triazine triamino caproic acid alcohol amine salt, n-dodecane di-carboxylic acid alcohol amine salt, Polyether Modified Polysiloxanes Defoaming Agent and deionized water, and each component and mass parts thereof are:
Cats product 4 ~ 6 parts
Polyoxyethylenated alcohol sodium sulfate 4 ~ 6 parts
Fatty diglycollic amide 1.5 ~ 3 parts
Gemini surface active agent 0.8 ~ 1.2 part
Washing assistant 2 ~ 5 parts
1 ~ 3 part, triazine triamino caproic acid alcohol amine salt
1 ~ 4 part, n-dodecane di-carboxylic acid alcohol amine salt
Polyether Modified Polysiloxanes Defoaming Agent 1 ~ 2 part
65 ~ 75 parts, water
Further, the preferred dodecyl benzyl dimethyl ammonium chloride of described cats product, dodecyl dimethyl benzyl amine oxide;
The preferred lauric acid diethyl amide of described fatty diglycollic amide, coconut acid diethanolamide, ricinolic acid diglycollic amide;
The preferred dimethylene of described Gemini surface active agent-1,2-two (Dodecydimethylammonium bronides), to phenoxy group two ethoxylated dodecyl alcohol, pendent succinic acid ricinolic acid macrogol ester and butynediol double focusing glycol ether;
The preferred sodium ammonium triacetate of described washing assistant, Trisodium Citrate and disodium EDTA;
Described triazine triamino caproic acid alcohol amine salt is triazine triamino caproic acid and the trolamine triazine triamino caproic acid alcohol amine salt that synthesizes of 1:3 in molar ratio;
Described n-dodecane di-carboxylic acid and trolamine be the n-dodecane di-carboxylic acid alcohol amine salt that synthesizes of 1:2.5 in molar ratio.
Preparation method of the present invention is: under the condition stirred, add cats product 4 ~ 6 parts, polyoxyethylenated alcohol sodium sulfate 4 ~ 6 parts, fatty diglycollic amide 1.5 ~ 3 parts, Gemini surface active agent 0.8 ~ 1.2 part, washing assistant 2 ~ 5 parts, 1 ~ 3 part, triazine triamino caproic acid alcohol amine salt, 1 ~ 4 part, n-dodecane di-carboxylic acid alcohol amine salt, Polyether Modified Polysiloxanes Defoaming Agent 1 ~ 2 part, deionized water 65 ~ 75 parts successively, after each component mixes, stop stirring, obtained steel surface punching oil water-base cleaning liquid.
Advantage and disadvantage of the present invention is: adopt cats product, polyoxyethylenated alcohol sodium sulfate and fatty diglycollic amide as main wash tensio-active agent, utilizing the geminal surfactant composite mode with adding inhibiter, washing assistant and defoamer further, reaching and aqueous-base cleaning and antirust effect are carried out to steel surface punching oil.
Embodiment
Embodiment 1
A kind of steel surface punching oil water-base cleaning liquid comprises dodecyl benzyl dimethyl ammonium chloride, polyoxyethylenated alcohol sodium sulfate, lauric acid diethyl amide, pendent succinic acid ricinolic acid macrogol ester, Trisodium Citrate, triazine triamino caproic acid alcohol amine salt, n-dodecane di-carboxylic acid alcohol amine salt, Polyether Modified Polysiloxanes Defoaming Agent and water, and each component and mass parts thereof are:
Dodecyl benzyl dimethyl ammonium chloride 4 kilograms
Polyoxyethylenated alcohol sodium sulfate 6 kilograms
Lauric acid diethyl amide 1.5 kilograms
Pendent succinic acid ricinolic acid macrogol ester 1.2 kilograms
Trisodium Citrate 2 kilograms
3 kilograms, triazine triamino caproic acid alcohol amine salt
1 kilogram, n-dodecane di-carboxylic acid alcohol amine salt
Polyether Modified Polysiloxanes Defoaming Agent 2 kilograms
65 kilograms, water
In a kettle., under the condition stirred, add cats product 4 kilograms, polyoxyethylenated alcohol sodium sulfate 6 kilograms, fatty diglycollic amide 1.5 kilograms, Gemini surface active agent 1.2 kilograms, washing assistant 2 kilograms, 1 kilogram, triazine triamino caproic acid alcohol amine salt, 1 kilogram, n-dodecane di-carboxylic acid alcohol amine salt, Polyether Modified Polysiloxanes Defoaming Agent 2 kilograms, 65 kilograms, water successively, after each component mixes, stop stirring, obtained steel surface punching oil water-base cleaning liquid.
Embodiment 2
A kind of steel surface punching oil water-base cleaning liquid comprises dodecyl dimethyl benzyl amine oxide, polyoxyethylenated alcohol sodium sulfate, ricinolic acid diglycollic amide, sodium ammonium triacetate, to phenoxy group two ethoxylated dodecyl alcohol, Sunmorl N 60S, triazine triamino caproic acid alcohol amine salt, n-dodecane di-carboxylic acid alcohol amine salt, Polyether Modified Polysiloxanes Defoaming Agent and water, each component and mass parts thereof are:
Dodecyl dimethyl benzyl amine oxide 6 kilograms
Polyoxyethylenated alcohol sodium sulfate 4 kilograms
Ricinolic acid diglycollic amide 3 kilograms
To the two ethoxylated dodecyl alcohol 0.8 kilogram of phenoxy group
Sodium ammonium triacetate 5 kilograms
1 kilogram, triazine triamino caproic acid alcohol amine salt
4 kilograms, n-dodecane di-carboxylic acid alcohol amine salt
Polyether Modified Polysiloxanes Defoaming Agent 1 kilogram
75 kilograms, water
In a kettle., under the condition stirred, add successively dodecyl dimethyl benzyl amine oxide 6 kilograms, polyoxyethylenated alcohol sodium sulfate 4 kilograms, ricinolic acid diglycollic amide 3 kilograms, to phenoxy group two ethoxylated dodecyl alcohol 0.8 kilogram, sodium ammonium triacetate 5 kilograms, 1 kilogram, triazine triamino caproic acid alcohol amine salt, 4 kilograms, n-dodecane di-carboxylic acid alcohol amine salt, Polyether Modified Polysiloxanes Defoaming Agent 1 kilogram, 75 kilograms, water, after each component mixes, stop stirring, obtained steel surface punching oil water-base cleaning liquid.
Embodiment 3
A kind of steel surface punching oil water-base cleaning liquid comprises dodecyl benzyl dimethyl ammonium chloride, polyoxyethylenated alcohol sodium sulfate, coconut acid diethanolamide, dimethylene-1,2-two (Dodecydimethylammonium bronides), disodium EDTA, triazine triamino caproic acid alcohol amine salt, n-dodecane di-carboxylic acid alcohol amine salt, Polyether Modified Polysiloxanes Defoaming Agent and water, each component and mass parts thereof are:
Dodecyl benzyl dimethyl ammonium chloride 5 kilograms
Polyoxyethylenated alcohol sodium sulfate 5 kilograms
Coconut acid diethanolamide 2.5 kilograms
Two (Dodecydimethylammonium bronides) 1 kilogram of dimethylene-1,2-
Disodium EDTA 3 kilograms
2 kilograms, triazine triamino caproic acid alcohol amine salt
2 kilograms, n-dodecane di-carboxylic acid alcohol amine salt
Polyether Modified Polysiloxanes Defoaming Agent 1.5 kilograms
70 kilograms, water
In a kettle., under the condition stirred, add dodecyl benzyl dimethyl ammonium chloride 5 kilograms, polyoxyethylenated alcohol sodium sulfate 5 kilograms, coconut acid diethanolamide 2.5 kilograms, dimethylene-1 successively, 2-two (Dodecydimethylammonium bronides) 1 kilogram, disodium EDTA 3 kilograms, 2 kilograms, triazine triamino caproic acid alcohol amine salt, 2 kilograms, n-dodecane di-carboxylic acid alcohol amine salt, Polyether Modified Polysiloxanes Defoaming Agent 1.5 kilograms, 70 kilograms, water, after each component mixes, stop stirring, obtained steel surface punching oil water-base cleaning liquid.
The above; embodiment is only be described the preferred embodiment of the present invention; not scope of the present invention is limited; under the prerequisite of spirit not departing from the technology of the present invention; the various distortion that this area engineering technical personnel make technical scheme of the present invention and improvement, all should fall in protection domain that claims of the present invention determine.
Claims (3)
1. a steel surface punching oil water-base cleaning liquid, it is characterized in that: described steel surface punching oil water-base cleaning liquid comprises cats product, polyoxyethylenated alcohol sodium sulfate, fatty diglycollic amide, Gemini surface active agent, washing assistant, triazine triamino caproic acid alcohol amine salt, n-dodecane di-carboxylic acid alcohol amine salt, Polyether Modified Polysiloxanes Defoaming Agent and deionized water, and each component and mass parts thereof are:
Cats product 4 ~ 6 parts
Polyoxyethylenated alcohol sodium sulfate 4 ~ 6 parts
Fatty diglycollic amide 1.5 ~ 3 parts
Gemini surface active agent 0.8 ~ 1.2 part
Washing assistant 2 ~ 5 parts
1 ~ 3 part, triazine triamino caproic acid alcohol amine salt
1 ~ 4 part, n-dodecane di-carboxylic acid alcohol amine salt
Polyether Modified Polysiloxanes Defoaming Agent 1 ~ 2 part
65 ~ 75 parts, water.
2. a kind of steel surface punching oil water-base cleaning liquid according to claim 1, is characterized in that: the preferred dodecyl benzyl dimethyl ammonium chloride of described cats product, dodecyl dimethyl benzyl amine oxide; The preferred lauric acid diethyl amide of described fatty diglycollic amide, coconut acid diethanolamide, ricinolic acid diglycollic amide; The preferred dimethylene of described Gemini surface active agent-1,2-two (Dodecydimethylammonium bronides), to phenoxy group two ethoxylated dodecyl alcohol, pendent succinic acid ricinolic acid macrogol ester and butynediol double focusing glycol ether; The preferred sodium ammonium triacetate of described washing assistant, Trisodium Citrate and disodium EDTA; Described triazine triamino caproic acid alcohol amine salt is triazine triamino caproic acid and the trolamine triazine triamino caproic acid alcohol amine salt that synthesizes of 1:3 in molar ratio; Described n-dodecane di-carboxylic acid and trolamine be the n-dodecane di-carboxylic acid alcohol amine salt that synthesizes of 1:2.5 in molar ratio.
3. a kind of steel surface punching oil water-base cleaning liquid according to claim 1, it is characterized in that: the preparation method of described steel surface punching oil water-base cleaning liquid is: under the condition stirred, add cats product 4 ~ 6 parts successively, polyoxyethylenated alcohol sodium sulfate 4 ~ 6 parts, fatty diglycollic amide 1.5 ~ 3 parts, Gemini surface active agent 0.8 ~ 1.2 part, washing assistant 2 ~ 5 parts, 1 ~ 3 part, triazine triamino caproic acid alcohol amine salt, 1 ~ 4 part, n-dodecane di-carboxylic acid alcohol amine salt, Polyether Modified Polysiloxanes Defoaming Agent 1 ~ 2 part, deionized water 65 ~ 75 parts, after each component mixes, stop stirring, obtained steel surface hydraulic efficiency oil water-base cleaning liquid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410518940.XA CN104451740A (en) | 2014-10-06 | 2014-10-06 | Water-based cleaning solution for punching oil on surface of steel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410518940.XA CN104451740A (en) | 2014-10-06 | 2014-10-06 | Water-based cleaning solution for punching oil on surface of steel |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104451740A true CN104451740A (en) | 2015-03-25 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410518940.XA Withdrawn CN104451740A (en) | 2014-10-06 | 2014-10-06 | Water-based cleaning solution for punching oil on surface of steel |
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| Country | Link |
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| CN (1) | CN104451740A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106929859A (en) * | 2017-01-23 | 2017-07-07 | 中国第汽车股份有限公司 | A kind of water-based antirust of residual less and preparation method thereof |
| CN114752942A (en) * | 2022-04-29 | 2022-07-15 | 泰伦特生物工程股份有限公司 | Industrial cleaning agent containing gemini surfactant and preparation method thereof |
-
2014
- 2014-10-06 CN CN201410518940.XA patent/CN104451740A/en not_active Withdrawn
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106929859A (en) * | 2017-01-23 | 2017-07-07 | 中国第汽车股份有限公司 | A kind of water-based antirust of residual less and preparation method thereof |
| CN114752942A (en) * | 2022-04-29 | 2022-07-15 | 泰伦特生物工程股份有限公司 | Industrial cleaning agent containing gemini surfactant and preparation method thereof |
| CN114752942B (en) * | 2022-04-29 | 2023-09-22 | 泰伦特生物工程股份有限公司 | Industrial cleaning agent containing gemini structure surfactant and preparation method thereof |
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| C06 | Publication | ||
| PB01 | Publication | ||
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| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20150325 |