CN104449405A - Multifunctional liquid shoe polish and preparation method thereof - Google Patents

Multifunctional liquid shoe polish and preparation method thereof Download PDF

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Publication number
CN104449405A
CN104449405A CN201510004581.0A CN201510004581A CN104449405A CN 104449405 A CN104449405 A CN 104449405A CN 201510004581 A CN201510004581 A CN 201510004581A CN 104449405 A CN104449405 A CN 104449405A
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China
Prior art keywords
shoe polish
liquid shoe
leather
essence
water
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CN201510004581.0A
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CN104449405B (en
Inventor
孙淑萍
侯东晓
安书祥
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Wannan Medical College
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Wannan Medical College
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09GPOLISHING COMPOSITIONS; SKI WAXES
    • C09G1/00Polishing compositions
    • C09G1/04Aqueous dispersions

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  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)

Abstract

The invention discloses multifunctional liquid shoe polish and a preparation method of the multifunctional liquid shoe polish. The multifunctional liquid shoe polish comprises carnauba wax, synthetic paraffin, beewax, alkyl phenol polyoxyethylene OP-10, silicone oil, lanum, octadecanol, cetanol, ethyl alcohol, turpentine, fatty alcohol-polyoxyethylene ether AESA, oil-soluble nigrosine, glycerol, 5% ethyl p-hydroxy benzoate alcoholic solution, essence and distilled water. The prepared multifunctional liquid shoe polish can deeply moisten, maintain and clean leather, leather shoes can be kept glossy for a long time, and the multifunctional liquid shoe polish has the function of deeply moistening leather and the waterproof function, enables the leather to be flexible, tough and high in elasticity and prolongs aging of the leather.

Description

A kind of Multifunction liquid shoe polish and preparation method thereof
Technical field
This product relates to genus household chemicals field, relates to a kind of Multifunction liquid shoe polish and preparation method thereof specifically.
Background technology
Along with the development of economy, improving constantly of people's living standard, a requisite part in the shoe chest that leather shoes have become every household, but hold rag and squat and wipe the behavior of leather shoes shoe chest is other, obviously do not conform to nowadays allegro life.Traditional solid and paste shoe polish expend people's too many time, and traditional shoe polish smear after often need first to dry, and then repeatedly can obtain certain luminosity with shoe brush polishing, and tint permanence is poor, non-watertight, antidusting effect is bad, life-time service also easily produces folding line, can not effectively soften and maintain cortex, and the liquid shoe polish of commercial type often can only play glazing, the one-side surface action such as clean, and leather shoes can not be given with the maintenance of comprehensive profound level, time one, long leather shoes high-grade more also there will be distortion, fade, scratch, the problem such as to come unglued, therefore people need a convenient to use, successful is lasting, and the shoe polish that profoundly can moisten leather shoes occurs.
Summary of the invention
For the shortcoming of above-mentioned prior art, the invention provides a kind of Multifunction liquid shoe polish and preparation method thereof, overcome to need after traditional shoe polish is smeared first to dry, tint permanence is poor, non-watertight, antidusting effect is bad, and the difficult problem that gloss is bad, the maintenance of leather shoes profound level can also be given simultaneously, slow down aging speed.
To achieve these goals, the invention provides a kind of Multifunction liquid shoe polish, described Multifunction liquid shoe polish contains following material and content thereof:
Can according to the needs different to essence fragrance, described essence can be one or more in lemon flavour, peach flavor, lily essence, osmanthus flower fragrance, rose compound, cucumber essence, flavoring pineapple essence.
Described Multifunction liquid shoe polish preparation method, comprises the steps:
Step one: get 1-5ml distilled water, adds 2-15ml ethanol, 0.5-3g fatty alcohol-polyoxyethylene ether AESA, stirring and dissolving, forms solution A;
Step 2: 3-10g is synthesized paraffin, 0.5-6g carnauba wax, 3-10g beeswax join in beaker to put in 60 ~ 95 DEG C of water-baths and heat, add 1-7g stearyl alcohol, 1-5g hexadecanol, 2-7g silicone oil, 5-15ml turps, 3-12g lanolin, 5-15g emulsifier op-10 until completely dissolved, continue to heat in water-bath, after the mixture in beaker melts completely, add 0.1-3g oil black nigrosine, be stirred for oil phase;
Step 3: the distilled water of remainder being placed in 60 ~ 95 DEG C of water-baths and heating, is aqueous phase;
Step 4: when oil phase, aqueous phase reach uniform temp, aqueous phase is poured in oil phase, and limit edged stirs towards same direction, obtains emulsion matrix;
Step 5: emulsion matrix is cooled to 45 ~ 50 DEG C, adds 0.05-0.7ml essence, 0.1-0.6g5% ethyl p-hydroxybenzoate alcoholic solution, 1-5ml glycerine, and stirring is cooled to room temperature and namely obtains liquid shoe polish.
Preferably, in described step 4, aqueous phase is that thread shape is poured in oil phase.
Preferably, the speed that limit edged stirs towards same direction described in step 4 is 75-85r/min.
Preferably, be all placed in 75 DEG C of water-baths in described step 2 and step 3 to heat.
Various compositions in the present invention are as follows:
Turps is the liquid that a kind of clear, colorless has aromatising flavour, and it is as a kind of excellent organic solvent, and its tack is comparatively strong, can be good at other system component to be attached on black leather shoes.Spreading upon on leather shoes can the soaking of effectively anti-sealing, and makes leather shoes totally not flower, coordinates beeswax effectively can improve water-repellancy.
Oil black nigrosine strong coloring force, photo absorption performance is strong, because in coating, cohesiveness is strong, so the firm performance of color is good.Wiping casting skin footwear color even, can not produce aberration, and oil black nigrosine can also produce extinction effect, makes casting skin footwear seem that outward appearance is soft.
Carnauba wax is a kind of nontoxic pure natural wax, has high gloss, very easily emulsification, has good Oil keeping, and its maximum advantage has the unexistent high glossiness of other wax.
Beeswax can make shoe polish be not easy to dry up, and it is convenient to preserve, and does not worry that shoe polish can become withered and harden, thus causes using.Beeswax can be absorbed by leather part and form layer protecting film at leather surface, and the flexibility that can strengthen leather also can slow down the aging speed of leather, has certain tint retention, do not affect clinging power when leather surface reuses to the former coating of leather surface.Environmentally friendly, there is biological degradability.
Excellent synthetic wax and lanolin combine and are dispersed into minimum micro-and nano-particles, penetrate into leather deep layer along with permeate agent glycerine thus play the effect of interior lubrication and nourishing, the softness that will show through the leather of process like this and sense of fullness, the mutual miscible infiltration leather coating of other wax phases simultaneously, after surperficial wax is worn, the wax of deep layer will slowly move out, thus wiping property is good lastingly, heavily to make this shoe polish luminance brightness.
Silicone oil is the general name of the polydimethylsiloxane of a series of differing molecular quality.It is colourless transparent oil liquid, odorless, tasteless, stable chemical nature, and hydrophobicity is strong, can mix with lanolin etc., and is easy to coating, has fabulous lubricant effect, to no skin irritation.
Beneficial effect: the present invention compared with prior art, the Multifunction liquid shoe polish made, can be profound moisten, maintenance, clean leather, not only have general liquid shoe polish and carry easy and convenient feature, and have Multifunctional shoe care composition, it can clean leather shoe surface, leather shoes are made to keep long-time gloss, and there is deep moist leather and water-proof function, make leather pliable, high resilience, thus delay the aging of leather.In a word, the nursing of shoe polish to leather shoes is the invention enables to settle at one go, once complete, time saving and energy saving, thus provide stable guarantee for the nursing of various medium-to-high grade leather shoes.
Embodiment
Below in conjunction with embodiment, the present invention will be further described.
Embodiment 1
The Multifunction liquid shoe polish of the present embodiment is prepared as follows:
Step one: get 3ml distilled water, adds 8ml ethanol, 2g fatty alcohol-polyoxyethylene ether AESA, stirring and dissolving, forms solution A;
Step 2: 5g is synthesized paraffin, 3g carnauba wax, 6g beeswax join in beaker to put in 85 DEG C of water-baths and heat, add 4g stearyl alcohol, 4g hexadecanol, 5g silicone oil, 8ml turps, 8g lanolin, 10g emulsifier op-10 until completely dissolved, continue to heat in water-bath, after the mixture in beaker melts completely, add 2g oil black nigrosine, be stirred for oil phase;
Step 3: 80ml distilled water being placed in 85 DEG C of water-baths and heating, is aqueous phase;
Step 4: when oil phase, aqueous phase reach uniform temp, aqueous phase becomes thread shape to pour in oil phase, and limit edged stirs towards same direction, and speed is 75r/min, obtains emulsion matrix;
Step 5: emulsion matrix is cooled to 50 DEG C, adds 0.09ml essence, 0.3g 5% ethyl p-hydroxybenzoate alcoholic solution, 3ml glycerine, and stirring is cooled to room temperature and namely obtains liquid shoe polish.Described essence can be one or more in lemon flavour, peach flavor, lily essence, osmanthus flower fragrance, rose compound, cucumber essence, flavoring pineapple essence.
Embodiment 2
The Multifunction liquid shoe polish of the present embodiment is prepared as follows:
Step one: get 5ml distilled water, adds 8ml ethanol, 3g fatty alcohol-polyoxyethylene ether AESA, stirring and dissolving, forms solution A;
Step 2: 6g is synthesized paraffin, 3g carnauba wax, 7g beeswax join in beaker to put in 75 DEG C of water-baths and heat, add 2g stearyl alcohol, 2g hexadecanol, 4g silicone oil, 10ml turps, 8g lanolin, 10g emulsifier op-10 until completely dissolved, continue to heat in water-bath, after the mixture in beaker melts completely, add 1g oil black nigrosine, be stirred for oil phase;
Step 3: 90ml distilled water being placed in 75 DEG C of water-baths and heating, is aqueous phase;
Step 4: when oil phase, aqueous phase reach uniform temp, aqueous phase becomes thread shape to pour in oil phase, and limit edged stirs towards same direction, and speed is 85r/min, obtains emulsion matrix;
Step 5: emulsion matrix is cooled to 50 DEG C, adds 0.2ml essence, 0.5g 5% ethyl p-hydroxybenzoate alcoholic solution, 4ml glycerine, and stirring is cooled to room temperature and namely obtains liquid shoe polish.Described essence can be one or more in lemon flavour, peach flavor, lily essence, osmanthus flower fragrance, rose compound, cucumber essence, flavoring pineapple essence.
Physical and chemical index and the result of embodiment 1,2 are as follows:
Proterties: this product is that viscosity is suitable for, and glossiness is suitable for, the pure and fresh simple and elegant black milk sap of smell.
The Multifunction liquid shoe polish that Example 1,2 is obtained, recording pH value is 6.5-7.5.
Multifunction liquid shoe polish obtained for embodiment 1,2 is packaged in transparent plastic bottle, within one month, observes without denaturalization phenomenon in the refrigerator cold-storage of 4 DEG C.24h in the thermostat container of 55 DEG C, shoe polish is without layering, the phenomenon such as rotten.
Shoe polish made for embodiment is placed in Plastic Bottle, and room temperature leaves standstill investigation 6 months, and without demixing phenomenon, unchanged by rear glossiness, smell is unchanged, without denaturalization phenomenon.
Shoe polish obtained by embodiment is packaged in 3000r/min in tool plug test tube, and centrifugal 20min, without demixing phenomenon.
Shoe polish obtained by embodiment is coated leather shoe surface, evenly and without obvious particle.
Described Multifunction liquid shoe polish net effect is investigated
The effect below utilizing leather shoes examination wiping to reach carrys out liquid shoe polish effect that Evaluation operation example 1,2 produces.Adopt opinion poll point system, the leather shoes choosing 80 pairs of different brands, as object on probation, are divided into arbitrarily two groups, polish shoes respectively with liquid shoe polish prepared by embodiment 1,2.Every day uses twice, two months duration of service.Every result of use total score is 5 points: 5 be divided into best result, represents very well, very satisfaction; 4 are divided into better; 3 are divided into and can accept; Less than 3 points is bad, can not accept.It is below every average.The results are shown in following table 1:
Table 1
Result of use The every average of embodiment 1 The every average of embodiment 2
Spatter property 4.9 4.9
Alimentary 4.7 4.8
Glossiness 4.9 4.9
Water-repellancy 4.7 4.8
In sum, the liquid shoe polish that the present invention is made has the effect such as good guard, dust-proof, waterproof, blast, nourishing.
The present invention is not limited to above-described embodiment; do not departing under the present invention's spirit and real situation thereof; those of ordinary skill in the art can make various corresponding change and distortion according to the present invention; these are tackled amendment that the present invention carries out mutually or equivalently to replace, and it all should be encompassed in the middle of the scope of claim of the present invention protection.

Claims (6)

1. a Multifunction liquid shoe polish, is characterized in that, described Multifunction liquid shoe polish contains following material and content thereof:
2. Multifunction liquid shoe polish according to claim 1, is characterized in that: described essence is one or more in lemon flavour, peach flavor, lily essence, osmanthus flower fragrance, rose compound, cucumber essence, flavoring pineapple essence.
3. a Multifunction liquid shoe polish preparation method described in claim 1, comprises the steps:
Step one: get 1-5ml distilled water, adds 2-15ml ethanol, 0.5-3g fatty alcohol-polyoxyethylene ether AESA, stirring and dissolving, forms solution A;
Step 2: 3-10g is synthesized paraffin, 0.5-6g carnauba wax, 3-10g beeswax join in beaker to put in 60 ~ 95 DEG C of water-baths and heat, add 1-7g stearyl alcohol, 1-5g hexadecanol, 2-7g silicone oil, 5-15ml turps, 3-12g lanolin, 5-15g emulsifier op-10 until completely dissolved, continue to heat in water-bath, after the mixture in beaker melts completely, add 0.1-3g oil black nigrosine, be stirred for oil phase;
Step 3: the distilled water of remainder being placed in 60 ~ 95 DEG C of water-baths and heating, is aqueous phase;
Step 4: when oil phase, aqueous phase reach uniform temp, aqueous phase is poured in oil phase, and limit edged stirs towards same direction, obtains emulsion matrix;
Step 5: emulsion matrix is cooled to 45 ~ 50 DEG C, adds 0.05-0.7ml essence, 0.1-0.6g5% ethyl p-hydroxybenzoate alcoholic solution, 1-5ml glycerine, and stirring is cooled to room temperature and namely obtains liquid shoe polish.
4. Multifunction liquid shoe polish preparation method according to claim 3, is characterized in that: in described step 4, aqueous phase is that thread shape is poured in oil phase.
5. Multifunction liquid shoe polish preparation method according to claim 3, is characterized in that: the speed that the edged of limit described in step 4 stirs towards same direction is 75-85r/min.
6. Multifunction liquid shoe polish preparation method according to any one of claim 3-5, is characterized in that: be all placed in 75 DEG C of water-baths in described step 2 and step 3 and heat.
CN201510004581.0A 2015-01-06 2015-01-06 A kind of Multifunction liquid shoe polish and preparation method thereof Active CN104449405B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105419649A (en) * 2015-12-01 2016-03-23 赵雅珺 Liquid shoe polish
CN106479734A (en) * 2016-10-14 2017-03-08 柳州立洁科技有限公司 A kind of leatherware cleaning-nursing agent
CN108330024A (en) * 2018-05-03 2018-07-27 上海奥威日化有限公司 Cleansing composition

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1265409A (en) * 1999-08-10 2000-09-06 戴紫风 Formulation and production process of multipurpose shoe cream
CN102634285A (en) * 2012-03-27 2012-08-15 河北永泰柯瑞特化工有限公司 Fur brightener composition and preparation method and application thereof
CN102876237A (en) * 2012-10-12 2013-01-16 苏州谷力生物科技有限公司 Leather care oil

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1265409A (en) * 1999-08-10 2000-09-06 戴紫风 Formulation and production process of multipurpose shoe cream
CN102634285A (en) * 2012-03-27 2012-08-15 河北永泰柯瑞特化工有限公司 Fur brightener composition and preparation method and application thereof
CN102876237A (en) * 2012-10-12 2013-01-16 苏州谷力生物科技有限公司 Leather care oil

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105419649A (en) * 2015-12-01 2016-03-23 赵雅珺 Liquid shoe polish
CN106479734A (en) * 2016-10-14 2017-03-08 柳州立洁科技有限公司 A kind of leatherware cleaning-nursing agent
CN108330024A (en) * 2018-05-03 2018-07-27 上海奥威日化有限公司 Cleansing composition

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Inventor after: Sun Shuping

Inventor after: Hou Dongxiao

Inventor after: An Shuxiang

Inventor after: He Xiaoyuan

Inventor after: Liu Jing

Inventor after: Sun Mei

Inventor before: Sun Shuping

Inventor before: Hou Dongxiao

Inventor before: An Shuxiang

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