CN104448547A - Insect and corrosion prevention plastic sheet - Google Patents
Insect and corrosion prevention plastic sheet Download PDFInfo
- Publication number
- CN104448547A CN104448547A CN201410634778.8A CN201410634778A CN104448547A CN 104448547 A CN104448547 A CN 104448547A CN 201410634778 A CN201410634778 A CN 201410634778A CN 104448547 A CN104448547 A CN 104448547A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses an insect and corrosion prevention plastic sheet. The insect and corrosion prevention plastic sheet is characterized by comprising the following raw materials in parts by weight: 107-120 parts of polypropylene, 12-20 part of broken non-woven fabrics, 1-2 parts of aluminum isopropoxide, 0.1-0.2 part of permethrin, 1-2 parts of alkyl phosphate diethanolamine salt, 0.5-1 part of ammonium paratungstate, 1-2 parts of decabromodiphenyl ethane, 0.5-1 part of potassium iodide, 1-3 parts of diphenyl silanediol, 0.4-1 part of sodium sorbate, 12-18 parts of ultra-fine barium sulfate, 2-4 parts of borax, 0.3-1 part of nonylphenol, 3-5 parts of epoxidized soybean oil, 0.1-0.2 part of zinc pyrithione and 1-2 parts of a corrosion prevention additive. Due to the added permethrin, the nonylphenol and the corrosion prevention additive, the finished plastic sheet has good insect and corrosion prevention performance, long service life and good anti-aging strength. The insect and corrosion prevention plastic sheet disclosed by the invention has high elongation and high tensile strength and has a wide range of application.
Description
Technical field
The present invention relates generally to plastic applications, particularly relates to a kind of pest control and anticorrosion plastics sheet.
Background technology
Along with development and the progress of society, a large amount of bonded fabric products has protection against the tide because of it, ventilative, pliable and tough, light weight, not combustion-supporting, easy decomposition, nontoxic nonirritant, rich color, cheap, the feature such as to use again capable of circulation, and be widely applied to life, work, each production is local, simultaneously again because its low price, a lot of quality product is not high, therefore a large amount of waste products is formed, because of its light weight, recovery for non-woven fabrics is fairly simple again, and yield is large, so based on consideration that is energy-conservation and reduction production cost, our company adopts the non-woven fabrics broken material reclaimed, make new plastics sheet.
Summary of the invention
The object of the invention is just to provide a kind of pest control and anticorrosion plastics sheet.
The present invention is achieved by the following technical solutions:
A kind of pest control and anticorrosion plastics sheet, is characterized in that what it was made up of the raw material of following weight parts:
Polypropylene 107-120, non-woven fabrics broken material 12-20, aluminum isopropylate 1-2, permethrin 0.1-0.2, alkyl phosphate diethanolamine salt 1-2, ammonium paratungstate 0.5-1, decabromodiphenyl ethane 1-2, potassiumiodide 0.5-1, Diphenylsilanediol 1-3, sodium sorbate 0.4-1, ultra-fine barium sulfate 12-18, borax 2-4, nonylphenol 0.3-1, epoxy soybean oil 3-5, Zinc Pyrithione 0.1-0.2, anti-corrosive aids 1-2;
Described anti-corrosive aids is made up of the raw material of following weight parts:
Polymethylmethacrylate 30-40, diacetone-acryloamide(DAA) 0.3-1, tetraethyl silicate 1-2, calcium propionate 3-5, dehydroacetic acid (DHA) 2-3, ammonium meta-vanadate 0.8-1, dehydrated alcohol 4-6, lauryl dimethyl amine oxide 0.3-1;
Tetraethyl silicate is joined in dehydrated alcohol, stir, obtain alcohol ester solution;
Mixed with calcium propionate by dehydroacetic acid (DHA), ball milling is even, joins in 6-10 times of deionized water, adds lauryl dimethyl amine oxide, stir, obtain dispersion liquid after stirring;
Polymethylmethacrylate is heated to 100-105 DEG C, add alcohol ester solution, stir, add diacetone-acryloamide(DAA), insulated and stirred 1-2 hour, add dispersion liquid, 200-300 rev/min is uniformly mixed 10-20 minute, adds each raw material of residue, dehydration after fully stirring, dry 3-5 minute at 70-80 DEG C, obtains described anti-corrosive aids.
2, a preparation method for pest control and anticorrosion plastics sheet as claimed in claim 1, is characterized in that comprising the following steps:
(1) joined by sodium sorbate in 6-10 times of water, add Diphenylsilanediol, add borax, aluminum isopropylate after stirring, insulated and stirred 10-20 minute at 60-65 DEG C, obtains dispersion liquid;
(2) permethrin, nonylphenol are mixed with epoxy soybean oil, insulated and stirred 4-5 minute at 50-60 DEG C, adds ultra-fine barium sulfate, is uniformly mixed 10-20 minute, obtains esterification barium sulfate;
(3) by non-woven fabrics broken material preheating 10-20 minute at 100-105 DEG C, add esterification barium sulfate, be uniformly mixed 10-20 minute, add dispersion liquid, stir, dehydration, dry, melt extrude, cooling, abrasive dust, obtain powder;
(4) by above-mentioned powder and each raw material of residue, fully mix, melting, by sheet extruder extrusion moulding.
Advantage of the present invention is:
In anti-corrosive aids of the present invention, calcium propionate, dehydroacetic acid (DHA) are mixed with alcohol ester solution, finally by dispersion liquid and polymethylmethacrylate drying and moulding, make finished product have high strength, high durable, lightweight, the good characteristic such as anticorrosion.
The permethrin that plastics sheet of the present invention adds, nonylphenol, anti-corrosive aids etc., finished product is made to have good pest control and anticorrosion, improve the work-ing life of sheet material and anti-aging intensity, sheet material elongation of the present invention is high, tensile strength is high, and use range is wide.
Embodiment
Embodiment 1
A kind of pest control and anticorrosion plastics sheet, is characterized in that what it was made up of the raw material of following weight parts:
Polypropylene 120, non-woven fabrics broken material 20, aluminum isopropylate 2, permethrin 0.2, alkyl phosphate diethanolamine salt 1, ammonium paratungstate 0.5-1, decabromodiphenyl ethane 2, potassiumiodide 0.5, Diphenylsilanediol 1, sodium sorbate 0.4, ultra-fine barium sulfate 18, borax 2, nonylphenol 0.3, epoxy soybean oil 5, Zinc Pyrithione 0.2, anti-corrosive aids 2;
Described anti-corrosive aids is made up of the raw material of following weight parts:
Polymethylmethacrylate 40, diacetone-acryloamide(DAA) 0.3, tetraethyl silicate 2, calcium propionate 5, dehydroacetic acid (DHA) 3, ammonium meta-vanadate 0.8, dehydrated alcohol 6, lauryl dimethyl amine oxide 0.3;
Tetraethyl silicate is joined in dehydrated alcohol, stir, obtain alcohol ester solution;
Mixed with calcium propionate by dehydroacetic acid (DHA), ball milling is even, joins in 10 times of deionized waters, adds lauryl dimethyl amine oxide, stir, obtain dispersion liquid after stirring;
Polymethylmethacrylate is heated to 105 DEG C, add alcohol ester solution, stir, add diacetone-acryloamide(DAA), insulated and stirred 1 hour, add dispersion liquid, 300 revs/min are uniformly mixed 20 minutes, add each raw material of residue, dehydration after fully stirring, dry 3-5 minute at 80 DEG C, obtains described anti-corrosive aids.
A preparation method for pest control and anticorrosion plastics sheet, is characterized in that comprising the following steps:
(1) joined by sodium sorbate in 10 times of water, add Diphenylsilanediol, add borax, aluminum isopropylate after stirring, at 65 DEG C, insulated and stirred 10 minutes, obtains dispersion liquid;
(2) permethrin, nonylphenol are mixed with epoxy soybean oil, at 60 DEG C, insulated and stirred 5 minutes, adds ultra-fine barium sulfate, is uniformly mixed 20 minutes, obtains esterification barium sulfate;
(3) by the preheating 20 minutes at 105 DEG C of non-woven fabrics broken material, add esterification barium sulfate, be uniformly mixed 20 minutes, add dispersion liquid, stir, dehydration, dry, melt extrude, cooling, abrasive dust, obtain powder;
(4) by above-mentioned powder and each raw material of residue, fully mix, melting, by sheet extruder extrusion moulding.
Performance test:
Tensile yield strength: 301kg/cm
2
Elongation at break: 317%.
Claims (2)
1. a pest control and anticorrosion plastics sheet, is characterized in that what it was made up of the raw material of following weight parts:
Polypropylene 107-120, non-woven fabrics broken material 12-20, aluminum isopropylate 1-2, permethrin 0.1-0.2, alkyl phosphate diethanolamine salt 1-2, ammonium paratungstate 0.5-1, decabromodiphenyl ethane 1-2, potassiumiodide 0.5-1, Diphenylsilanediol 1-3, sodium sorbate 0.4-1, ultra-fine barium sulfate 12-18, borax 2-4, nonylphenol 0.3-1, epoxy soybean oil 3-5, Zinc Pyrithione 0.1-0.2, anti-corrosive aids 1-2;
Described anti-corrosive aids is made up of the raw material of following weight parts:
Polymethylmethacrylate 30-40, diacetone-acryloamide(DAA) 0.3-1, tetraethyl silicate 1-2, calcium propionate 3-5, dehydroacetic acid (DHA) 2-3, ammonium meta-vanadate 0.8-1, dehydrated alcohol 4-6, lauryl dimethyl amine oxide 0.3-1;
Tetraethyl silicate is joined in dehydrated alcohol, stir, obtain alcohol ester solution;
Mixed with calcium propionate by dehydroacetic acid (DHA), ball milling is even, joins in 6-10 times of deionized water, adds lauryl dimethyl amine oxide, stir, obtain dispersion liquid after stirring;
Polymethylmethacrylate is heated to 100-105 DEG C, add alcohol ester solution, stir, add diacetone-acryloamide(DAA), insulated and stirred 1-2 hour, add dispersion liquid, 200-300 rev/min is uniformly mixed 10-20 minute, adds each raw material of residue, dehydration after fully stirring, dry 3-5 minute at 70-80 DEG C, obtains described anti-corrosive aids.
2. a preparation method for pest control and anticorrosion plastics sheet as claimed in claim 1, is characterized in that comprising the following steps:
(1) joined by sodium sorbate in 6-10 times of water, add Diphenylsilanediol, add borax, aluminum isopropylate after stirring, insulated and stirred 10-20 minute at 60-65 DEG C, obtains dispersion liquid;
(2) permethrin, nonylphenol are mixed with epoxy soybean oil, insulated and stirred 4-5 minute at 50-60 DEG C, adds ultra-fine barium sulfate, is uniformly mixed 10-20 minute, obtains esterification barium sulfate;
(3) by non-woven fabrics broken material preheating 10-20 minute at 100-105 DEG C, add esterification barium sulfate, be uniformly mixed 10-20 minute, add dispersion liquid, stir, dehydration, dry, melt extrude, cooling, abrasive dust, obtain powder;
(4) by above-mentioned powder and each raw material of residue, fully mix, melting, by sheet extruder extrusion moulding.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410634778.8A CN104448547A (en) | 2014-11-12 | 2014-11-12 | Insect and corrosion prevention plastic sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410634778.8A CN104448547A (en) | 2014-11-12 | 2014-11-12 | Insect and corrosion prevention plastic sheet |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104448547A true CN104448547A (en) | 2015-03-25 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201410634778.8A Pending CN104448547A (en) | 2014-11-12 | 2014-11-12 | Insect and corrosion prevention plastic sheet |
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| CN (1) | CN104448547A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104761792A (en) * | 2015-04-10 | 2015-07-08 | 合肥环照高分子材料厂 | Biodegradable plastic taking egg shells as raw materials and preparation method of biodegradable plastic |
| CN104829967A (en) * | 2015-04-30 | 2015-08-12 | 王英英 | Anticorrosive flame-retardant plastic and preparation method thereof |
| CN106223114A (en) * | 2016-08-26 | 2016-12-14 | 袁华 | A kind of Advertising art design wrapping paper coating |
| GB2605166A (en) * | 2021-03-24 | 2022-09-28 | Symphony Env Ltd | Additive composition |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101352945A (en) * | 2008-09-11 | 2009-01-28 | 丹阳市华东工程塑料有限公司 | Micro-foaming polypropylene-nonwoven cloth composite panel for inner decoration of vehicle and preparation method thereof |
| CN101717544A (en) * | 2008-10-09 | 2010-06-02 | 金发科技股份有限公司 | Black polypropylene anti-corrosive material and method for preparing same |
| CN102382365A (en) * | 2011-08-09 | 2012-03-21 | 常熟市慧丰塑料制品有限公司 | Plastic formula |
| CN103172949A (en) * | 2013-03-14 | 2013-06-26 | 安徽天润塑业有限公司 | Door PVC (Polyvinyl Chloride) plastic plate and manufacturing method thereof |
-
2014
- 2014-11-12 CN CN201410634778.8A patent/CN104448547A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101352945A (en) * | 2008-09-11 | 2009-01-28 | 丹阳市华东工程塑料有限公司 | Micro-foaming polypropylene-nonwoven cloth composite panel for inner decoration of vehicle and preparation method thereof |
| CN101717544A (en) * | 2008-10-09 | 2010-06-02 | 金发科技股份有限公司 | Black polypropylene anti-corrosive material and method for preparing same |
| CN102382365A (en) * | 2011-08-09 | 2012-03-21 | 常熟市慧丰塑料制品有限公司 | Plastic formula |
| CN103172949A (en) * | 2013-03-14 | 2013-06-26 | 安徽天润塑业有限公司 | Door PVC (Polyvinyl Chloride) plastic plate and manufacturing method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104761792A (en) * | 2015-04-10 | 2015-07-08 | 合肥环照高分子材料厂 | Biodegradable plastic taking egg shells as raw materials and preparation method of biodegradable plastic |
| CN104829967A (en) * | 2015-04-30 | 2015-08-12 | 王英英 | Anticorrosive flame-retardant plastic and preparation method thereof |
| CN106223114A (en) * | 2016-08-26 | 2016-12-14 | 袁华 | A kind of Advertising art design wrapping paper coating |
| GB2605166A (en) * | 2021-03-24 | 2022-09-28 | Symphony Env Ltd | Additive composition |
| WO2022200777A1 (en) * | 2021-03-24 | 2022-09-29 | Symphony Environmental Ltd. | Antimicrobial additive composition |
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Application publication date: 20150325 |