CN103172949A - Door PVC (Polyvinyl Chloride) plastic plate and manufacturing method thereof - Google Patents
Door PVC (Polyvinyl Chloride) plastic plate and manufacturing method thereof Download PDFInfo
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- CN103172949A CN103172949A CN2013100825851A CN201310082585A CN103172949A CN 103172949 A CN103172949 A CN 103172949A CN 2013100825851 A CN2013100825851 A CN 2013100825851A CN 201310082585 A CN201310082585 A CN 201310082585A CN 103172949 A CN103172949 A CN 103172949A
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Abstract
The invention discloses a door PVC (Polyvinyl Chloride) plastic plate. The PVC plastic plate comprises the following materials in parts by weight: 94-100 parts of polyvinyl chloride, 12-16 parts of mica powder, 3-5 parts of calcium stearate, 2-4 parts of tributyl citrate, 3-4 parts of dioctyl grease, 2-3 parts of phthalic acid ester, 4-6 parts of polyethylene wax, 1-3 parts of polyacrylamide, 1-2 parts of diethanol amine, 1-2 parts of 2,2'-methylene bi(4-methyl-6-tertiary butyl phenol), 2-3 parts of sodium tripolyphosphate, 2-3 parts of stearic acid, 2-4 parts of dimethyl di-sulfydryl isooctyl acetate tin and 13-16 parts of modifying auxiliaries. According to the door PVC plastic plate and the manufacturing method thereof disclosed by the invention, the materials are reasonably matched, so that the produced plastic profiled bar is smooth in surface, high in physical strength, strong in impact resistance and good in heat resistance; moreover, the added modifying auxiliaries are used for effectively improving the wettability of the filler in the material mixing, improving the dispersion and fluidity of the mixture system and strengthening the toughness and bending resistance of the finished product. Besides, the added diethanol amine and the 2,2'-methylene bi(4-methyl-6- tertiary butyl phenol) can be used for further improving the comprehensive performance of the product.
Description
Technical field
The present invention relates generally to a kind of PVC plastic irregular profile, relates in particular to a kind of and uses the PVC plastic plate.
Background technology
The advantage such as polyvinyl chloride (PVC) plastics have good rigidly, intensity is high, fire-retardant, corrosion-resistant, electric insulating quality good and soft or hard is adjustable, just be suitable for the finishing material of indoor wall, therefore by adding the auxiliary agents such as softening agent, lubricant can improve the poor processability of polyvinyl chloride, the shortcomings such as heat-drawn wire is low, the further performance of Reinforced PVC plastic irregular profile.
Summary of the invention
The object of the invention just is to provide a kind of and uses the PVC plastic plate.
The present invention is achieved by the following technical solutions:
A kind of indoor wall PVC plastic plate, it is comprised of the raw material of following weight parts:
Polyvinyl chloride 94-100, mica powder 12-16, calcium stearate 3-5, tributyl citrate 2-4, dibutyl ester 3-4, phthalic ester 2-3, polyethylene wax 4-6, polyacrylamide 1-3, diethanolamine 1-2,2,2`-methylene-bis (4-methyl-6-tert-butylphenol) 1-2, tripoly phosphate sodium STPP 2-3, stearic acid 2-3, dimethyl dimercapto 2-ethyl hexyl ethanoate tin 2-4, modified additive 13-16;
Described modified additive is comprised of the raw material of following weight parts:
Concentration is calcium hydroxide suspension 50-60, nano silicon 60-70, magnesium chloride 4-5, sorbitan monooleate 1-3, Xylo-Mucine 2-3, b diammonium edta 1-2, N-β-(aminoethyl)-γ-aminopropyl front three (second) the TMOS 1-2,1 of 70-80%, two (triethoxy is silica-based) ethane 1-2 of 2-, epoxy tetrahydro-2-ethylhexyl phthalate 2-3, di-t-butyl peroxide 0.8-1, deionized water 200-300;
The preparation method of described modified additive comprises the following steps:
Add above-mentioned sorbitan monooleate in above-mentioned calcium hydroxide suspension, add above-mentioned magnesium chloride, b diammonium edta, N-β-(aminoethyl)-γ-aminopropyl front three (second) TMOS after dispersed with stirring, stir in rear immigration carbonization reactor, pass into from CO
2The pure CO of steel cylinder
2With the air from air compressor machine, be mixed into and contain volume fraction 25-30%CO
2Gas react, stopped reaction when pH=6.5-7.0, the nano silicon, 1 that adds above-mentioned weight part, two (triethoxy the is silica-based) ethane of 2-, Xylo-Mucine and deionized water, 600-800 rev/min was disperseed 3-5 minute, then added each raw material of residue, high speed 1500-2000 rev/min centrifugal mixer 20-30 minute, oven dry is ground into ultrafine powder, is described properties-correcting agent.
A kind of indoor wall preparation method of PVC plastic plate comprises the following steps:
(1) mica powder, dimethyl dimercapto 2-ethyl hexyl ethanoate tin, tributyl citrate, the dibutyl ester with above-mentioned weight part is mixed under 85-90 ℃ and stirs, and must expect a;
(2) above-mentioned polyvinyl chloride, modified additive are mixed with polyethylene wax, in Banbury mixer mixing 2-3 minute, melting temperature was 124-140 ℃, adds pan feeding a and leftover materials, stirs;
(3) inject twin screw extruder by feed screw, extrude through twin screw extruder, after mould molding, typing, then cut off, overlay film gets described indoor wall PVC plastic plate.
A kind of indoor wall PVC plastic plate, PVC plastic plate of the present invention mainly are used in the indoor wall decoration, also can be used on the veneer of wardrobe and cabinet.
Advantage of the present invention is:
The present invention is by the raw material of reasonably arranging in pairs or groups, make the modified additive that plastic irregular profile any surface finish, the physical strength produced are high, shock resistance is strong, resistance to elevated temperatures is good, add, effectively raise the wettability of filler in batch mixing, dispersiveness and the mobility of mixture systems have been improved, toughness, resistance to bending of finished product etc. have been strengthened, the diethanolamine that adds, 2,2`-methylene-bis (4-methyl-6-tert-butylphenol) has further improved the over-all properties of product.
Embodiment
Embodiment 1
A kind of indoor wall PVC plastic plate, it is comprised of the raw material of following weight parts (kilogram):
Polyvinyl chloride 100, mica powder 16, calcium stearate 5, tributyl citrate 4, dibutyl ester 4, phthalic ester 3, polyethylene wax 6, polyacrylamide 3, diethanolamine 2,2,2`-methylene-bis (4-methyl-6-tert-butylphenol) 2, tripoly phosphate sodium STPP 3, stearic acid 3, dimethyl dimercapto 2-ethyl hexyl ethanoate tin 4, modified additive 16;
Described modified additive is comprised of the raw material of following weight parts:
Concentration is 80% calcium hydroxide suspension 60, nano silicon 70, magnesium chloride 5, sorbitan monooleate 3, Xylo-Mucine 3, b diammonium edta 2, N-β-(aminoethyl)-γ-aminopropyl front three (second) TMOS 2,1, two (triethoxy the is silica-based) ethane 2 of 2-, epoxy tetrahydro-2-ethylhexyl phthalate 3, di-t-butyl peroxide 0.8, deionized water 200-300;
The preparation method of described modified additive comprises the following steps:
Add above-mentioned sorbitan monooleate in above-mentioned calcium hydroxide suspension, add above-mentioned magnesium chloride, b diammonium edta, N-β-(aminoethyl)-γ-aminopropyl front three (second) TMOS after dispersed with stirring, stir in rear immigration carbonization reactor, pass into from CO
2The pure CO of steel cylinder
2With the air from air compressor machine, be mixed into and contain volume fraction 30%CO
2Gas react, stopped reaction when pH=7.0, the nano silicon, 1 that adds above-mentioned weight part, two (triethoxy the is silica-based) ethane of 2-, Xylo-Mucine and deionized water, 800 rev/mins were disperseed 5 minutes, then added each raw material of residue, 2000 rev/mins of centrifugal mixers of high speed 30 minutes, oven dry is ground into ultrafine powder, is described properties-correcting agent.
A kind of the preparation method with the PVC plastic plate comprises the following steps:
(1) mica powder, dimethyl dimercapto 2-ethyl hexyl ethanoate tin, tributyl citrate, the dibutyl ester with above-mentioned weight part is mixed under 85-90 ℃ and stirs, and must expect a;
(2) above-mentioned polyvinyl chloride, modified additive are mixed with polyethylene wax, in Banbury mixer mixing 2-3 minute, melting temperature was 124-140 ℃, adds pan feeding a and leftover materials, stirs;
(3) inject twin screw extruder by feed screw, extrude through twin screw extruder, after mould molding, typing, then cut off, overlay film gets described indoor wall PVC plastic plate.
A kind of indoor wall PVC plastic plate, PVC plastic plate of the present invention mainly are used in the indoor wall decoration, also can be used on the veneer of wardrobe and cabinet.
Performance test:
Tensile strength (MPa) 48;
Elongation at break (%) 19.2;
Flexural strength (MPa) 74.6;
Vicat softening point (℃) 86;
Flame retardant resistance: namely put out from fire, there is no black smoke.
Claims (3)
1. indoor wall PVC plastic plate is characterized in that what it was comprised of the raw material of following weight parts:
Polyvinyl chloride 94-100, mica powder 12-16, calcium stearate 3-5, tributyl citrate 2-4, dibutyl ester 3-4, phthalic ester 2-3, polyethylene wax 4-6, polyacrylamide 1-3, diethanolamine 1-2,2,2`-methylene-bis (4-methyl-6-tert-butylphenol) 1-2, tripoly phosphate sodium STPP 2-3, stearic acid 2-3, dimethyl dimercapto 2-ethyl hexyl ethanoate tin 2-4, modified additive 13-16;
Described modified additive is comprised of the raw material of following weight parts:
Concentration is calcium hydroxide suspension 50-60, nano silicon 60-70, magnesium chloride 4-5, sorbitan monooleate 1-3, Xylo-Mucine 2-3, b diammonium edta 1-2, N-β-(aminoethyl)-γ-aminopropyl front three (second) the TMOS 1-2,1 of 20-25%, two (triethoxy is silica-based) ethane 1-2 of 2-, epoxy tetrahydro-2-ethylhexyl phthalate 2-3, di-t-butyl peroxide 0.8-1, deionized water 200-300;
The preparation method of described modified additive comprises the following steps:
Add above-mentioned sorbitan monooleate in above-mentioned calcium hydroxide suspension, add above-mentioned magnesium chloride, b diammonium edta, N-β-(aminoethyl)-γ-aminopropyl front three (second) TMOS after dispersed with stirring, stir in rear immigration carbonization reactor, pass into from CO
2The pure CO of steel cylinder
2With the air from air compressor machine, be mixed into and contain volume fraction 25-30%CO
2Gas react, stopped reaction when pH=6.5-7.0, the nano silicon, 1 that adds above-mentioned weight part, two (triethoxy the is silica-based) ethane of 2-, Xylo-Mucine and deionized water, 600-800 rev/min was disperseed 3-5 minute, then added each raw material of residue, high speed 1500-2000 rev/min centrifugal mixer 20-30 minute, oven dry is ground into ultrafine powder, is described properties-correcting agent.
2. an indoor wall as claimed in claim 1 with the preparation method of PVC plastic plate, is characterized in that comprising the following steps:
(1) mica powder, dimethyl dimercapto 2-ethyl hexyl ethanoate tin, tributyl citrate, the dibutyl ester with above-mentioned weight part is mixed under 85-90 ℃ and stirs, and must expect a;
(2) above-mentioned polyvinyl chloride, modified additive are mixed with polyethylene wax, in Banbury mixer mixing 2-3 minute, melting temperature was 124-140 ℃, adds pan feeding a and leftover materials, stirs;
(3) inject twin screw extruder by feed screw, extrude through twin screw extruder, after mould molding, typing, then cut off, overlay film gets described indoor wall PVC plastic plate.
3. a kind of indoor wall PVC plastic plate according to claim 1, is characterized in that, PVC plastic plate of the present invention mainly is used in the indoor wall decoration, also can be used on the veneer of wardrobe and cabinet.
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CN201310082585.1A CN103172949B (en) | 2013-03-14 | 2013-03-14 | A kind of PVC plastic plate and preparation method thereof for indoor wall |
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CN201310082585.1A CN103172949B (en) | 2013-03-14 | 2013-03-14 | A kind of PVC plastic plate and preparation method thereof for indoor wall |
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CN103172949B CN103172949B (en) | 2016-05-18 |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104448547A (en) * | 2014-11-12 | 2015-03-25 | 合肥市瑞宏重型机械有限公司 | Insect and corrosion prevention plastic sheet |
CN104448550A (en) * | 2014-11-12 | 2015-03-25 | 合肥市瑞宏重型机械有限公司 | Plastic composite sheet |
CN112937004A (en) * | 2021-02-04 | 2021-06-11 | 浙江欧飞新材料集团有限公司 | PVC (polyvinyl chloride) coated sheet material for indoor wall surface and preparation method thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62129335A (en) * | 1985-11-29 | 1987-06-11 | Dainichi Color & Chem Mfg Co Ltd | Deodorant polyvinyl chloride sheet material |
CN1276393A (en) * | 1999-06-02 | 2000-12-13 | 兖州矿业(集团)有限责任公司新世纪集团公司 | Composition used for fire resistant industrial wall slab and its production technology |
CN101012328A (en) * | 2007-02-16 | 2007-08-08 | 宋惠强 | PVC resin particle for producing wallpaper and preparing method thereof |
CN102719034A (en) * | 2012-06-13 | 2012-10-10 | 濮阳市东宝科技发展有限公司 | Wallboard and preparation method thereof |
-
2013
- 2013-03-14 CN CN201310082585.1A patent/CN103172949B/en not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62129335A (en) * | 1985-11-29 | 1987-06-11 | Dainichi Color & Chem Mfg Co Ltd | Deodorant polyvinyl chloride sheet material |
CN1276393A (en) * | 1999-06-02 | 2000-12-13 | 兖州矿业(集团)有限责任公司新世纪集团公司 | Composition used for fire resistant industrial wall slab and its production technology |
CN101012328A (en) * | 2007-02-16 | 2007-08-08 | 宋惠强 | PVC resin particle for producing wallpaper and preparing method thereof |
CN102719034A (en) * | 2012-06-13 | 2012-10-10 | 濮阳市东宝科技发展有限公司 | Wallboard and preparation method thereof |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104448547A (en) * | 2014-11-12 | 2015-03-25 | 合肥市瑞宏重型机械有限公司 | Insect and corrosion prevention plastic sheet |
CN104448550A (en) * | 2014-11-12 | 2015-03-25 | 合肥市瑞宏重型机械有限公司 | Plastic composite sheet |
CN112937004A (en) * | 2021-02-04 | 2021-06-11 | 浙江欧飞新材料集团有限公司 | PVC (polyvinyl chloride) coated sheet material for indoor wall surface and preparation method thereof |
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CN103172949B (en) | 2016-05-18 |
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