CN104437638A - 将饱和和不饱和醛氧化为不饱和羧酸的催化剂、其制备方法和使用方法 - Google Patents

将饱和和不饱和醛氧化为不饱和羧酸的催化剂、其制备方法和使用方法 Download PDF

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Publication number
CN104437638A
CN104437638A CN201410616173.6A CN201410616173A CN104437638A CN 104437638 A CN104437638 A CN 104437638A CN 201410616173 A CN201410616173 A CN 201410616173A CN 104437638 A CN104437638 A CN 104437638A
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CN
China
Prior art keywords
catalyst
heteropolyacid
compound
compounds
binder
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Pending
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CN201410616173.6A
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English (en)
Chinese (zh)
Inventor
梁五更
P·E·艾里斯
J·R·林泽尔
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Saudi Basic Industries Corp
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Saudi Basic Industries Corp
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Publication of CN104437638A publication Critical patent/CN104437638A/zh
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0036—Grinding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201410616173.6A 2007-02-05 2008-02-04 将饱和和不饱和醛氧化为不饱和羧酸的催化剂、其制备方法和使用方法 Pending CN104437638A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/702,395 US8178718B2 (en) 2007-02-05 2007-02-05 Catalyst for oxidation of saturated and unsaturated aldehydes to unsaturated carboxylic acid, method of making and method of using thereof
US11/702,395 2007-02-05

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
CNA2008800040459A Division CN101610841A (zh) 2007-02-05 2008-02-04 将饱和和不饱和醛氧化为不饱和羧酸的催化剂、其制备方法和使用方法

Publications (1)

Publication Number Publication Date
CN104437638A true CN104437638A (zh) 2015-03-25

Family

ID=39676744

Family Applications (2)

Application Number Title Priority Date Filing Date
CN201410616173.6A Pending CN104437638A (zh) 2007-02-05 2008-02-04 将饱和和不饱和醛氧化为不饱和羧酸的催化剂、其制备方法和使用方法
CNA2008800040459A Pending CN101610841A (zh) 2007-02-05 2008-02-04 将饱和和不饱和醛氧化为不饱和羧酸的催化剂、其制备方法和使用方法

Family Applications After (1)

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Country Status (6)

Country Link
US (1) US8178718B2 (https=)
EP (1) EP2117706A4 (https=)
JP (1) JP5192495B2 (https=)
KR (2) KR20090108121A (https=)
CN (2) CN104437638A (https=)
WO (1) WO2008097516A1 (https=)

Cited By (1)

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CN110142063A (zh) * 2018-02-11 2019-08-20 中国科学院大连化学物理研究所 用于异丁烷选择氧化制甲基丙烯酸催化剂及其制备方法

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WO2010074177A1 (ja) 2008-12-26 2010-07-01 株式会社日本触媒 アクリル酸の製造方法
US8481448B2 (en) 2010-07-19 2013-07-09 Saudi Basic Industries Corporation Catalyst for oxidation of saturated and unsaturated aldehydes to unsaturated carboxylic acid, method of making and method of using thereof
CN102652922B (zh) * 2012-03-23 2013-09-04 太原理工大学 一种负载型磷钒铯镧催化剂及其应用
EP2983818A1 (en) * 2013-04-08 2016-02-17 Saudi Basic Industries Corporation Catalyst for conversion of propylene to product comprising a carboxylic acid moiety
CN103801398A (zh) * 2014-01-02 2014-05-21 上海东化催化剂有限公司 用于制取甲基丙烯酸的催化剂的制备方法
US9115067B1 (en) 2014-12-22 2015-08-25 Novus International, Inc. Process for the manufacture of acrolein
WO2016147324A1 (ja) * 2015-03-17 2016-09-22 日本化薬株式会社 不飽和アルデヒドおよび／または不飽和カルボン酸製造用触媒およびその製造方法ならびに不飽和アルデヒドおよび／または不飽和カルボン酸の製造方法
KR20180055154A (ko) * 2016-11-16 2018-05-25 주식회사 엘지화학 촉매의 제조 방법
EP3348551A1 (en) * 2017-01-16 2018-07-18 Basf Se Process for preparing an organic heterocyclic compound
CN112058281B (zh) * 2020-05-14 2023-02-17 哈尔滨理工大学 锗钼多酸钴配合物衍生的双金属硫化物晶体的制备和应用
EP3945086B1 (de) * 2020-07-30 2022-10-26 Röhm GmbH C-4 basiertes verfahren zur herstellung von mma unter rückführung und recyclierung von methacrolein
US12106791B2 (en) * 2022-06-30 2024-10-01 Western Digital Technologies, Inc. Doped BiSb (012) or undoped BiSb (001) topological insulator with GeNiFe buffer layer and/or interlayer for SOT based sensor, memory, and storage devices
CN116510742B (zh) * 2023-04-06 2024-08-23 济南大学 一种钼钒氧簇修饰的碳基锰酸铁复合催化剂的制备方法及其应用

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EP0060066A1 (en) * 1981-03-02 1982-09-15 The Standard Oil Company Process for the production of methacrylic acid from isobutyraldehyde employing a catalyst
US4558029A (en) * 1982-09-13 1985-12-10 The Standard Oil Company Antimony-containing C4 oxidation catalysts
CN86102873A (zh) * 1985-03-26 1986-12-03 日本触媒化学工业株式会社 马来酸酐的生产方法
CN1795047A (zh) * 2003-05-30 2006-06-28 日本化药株式会社 制备甲基丙烯酸用的催化剂的制备方法
CN101175568A (zh) * 2005-03-29 2008-05-07 日本化药株式会社 用于制备甲基丙烯酸的催化剂及其制备方法

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EP0024954A1 (en) * 1979-09-04 1981-03-11 Ube Industries, Ltd. Catalyst for production of unsaturated carboxylic acid, preparation thereof and production of unsaturated carboxylic acid
EP0060066A1 (en) * 1981-03-02 1982-09-15 The Standard Oil Company Process for the production of methacrylic acid from isobutyraldehyde employing a catalyst
US4558029A (en) * 1982-09-13 1985-12-10 The Standard Oil Company Antimony-containing C4 oxidation catalysts
CN86102873A (zh) * 1985-03-26 1986-12-03 日本触媒化学工业株式会社 马来酸酐的生产方法
CN1795047A (zh) * 2003-05-30 2006-06-28 日本化药株式会社 制备甲基丙烯酸用的催化剂的制备方法
CN101175568A (zh) * 2005-03-29 2008-05-07 日本化药株式会社 用于制备甲基丙烯酸的催化剂及其制备方法

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110142063A (zh) * 2018-02-11 2019-08-20 中国科学院大连化学物理研究所 用于异丁烷选择氧化制甲基丙烯酸催化剂及其制备方法
CN110142063B (zh) * 2018-02-11 2021-12-17 中国科学院大连化学物理研究所 用于异丁烷选择氧化制甲基丙烯酸催化剂及其制备方法

Also Published As

Publication number Publication date
JP5192495B2 (ja) 2013-05-08
WO2008097516A1 (en) 2008-08-14
EP2117706A4 (en) 2011-10-26
US20080188681A1 (en) 2008-08-07
EP2117706A1 (en) 2009-11-18
CN101610841A (zh) 2009-12-23
JP2010517761A (ja) 2010-05-27
KR20150011391A (ko) 2015-01-30
KR101579702B1 (ko) 2015-12-23
KR20090108121A (ko) 2009-10-14
US8178718B2 (en) 2012-05-15

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Application publication date: 20150325