CN104430321A - Environment-friendly pesticide adjuvant - Google Patents

Environment-friendly pesticide adjuvant Download PDF

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Publication number
CN104430321A
CN104430321A CN201410713074.XA CN201410713074A CN104430321A CN 104430321 A CN104430321 A CN 104430321A CN 201410713074 A CN201410713074 A CN 201410713074A CN 104430321 A CN104430321 A CN 104430321A
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Prior art keywords
parts
nano
environmental protection
auxiliary agent
agricultural chemical
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CN201410713074.XA
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Chinese (zh)
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CN104430321B (en
Inventor
王建良
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Suzhou favourite son's Information technology company limited
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Xiangcheng District Suzhou City Sheng Hu Special Cultivation Specialty Co-Operative Organization
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Priority to CN201410713074.XA priority Critical patent/CN104430321B/en
Publication of CN104430321A publication Critical patent/CN104430321A/en
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Publication of CN104430321B publication Critical patent/CN104430321B/en
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Abstract

The invention discloses an environment-friendly pesticide adjuvant, comprising the following components in parts by weight: 10-15 parts of talcum powder, 5-8 parts of sodium dodecyl benzene sulfonate, 5-10 parts of alkylphenol polyoxyethylene, 3-6 parts of a dispersing agent, 2-5 parts of a wetting agent, 4-5 parts of a diffusing agent, 2-3 parts of nano-zinc oxide and 1-3 parts of nano titanium oxide. The environment-friendly pesticide adjuvant disclosed by the invention is good in biological degradability, long in pesticide effect, free of release of toxic substances and beneficial to environment protection.

Description

A kind of environmental protection type agricultural chemical auxiliary agent
Technical field:
The present invention relates to pesticide field, be specifically related to a kind of environmental protection type agricultural chemical auxiliary agent.
Background technology:
Along with the development of China's plant husbandry, increasing problem is also following, and especially a large amount of uses of agricultural chemicals, make pesticide producing can not meet the needs of agricultural, forestry, fruit insecticide sterilizing, supply falls short of demand.At present, most of orchard worker be all directly by the pesticide spraying bought on fruit tree, but agricultural chemicals itself is poor to fruit tree wettability of the surface, adhesivity, and not easily degrades, this just makes drug effect and the deterioration of safety of agricultural chemicals, healthy to people of serious threat.
Summary of the invention:
A kind of environmental protection type agricultural chemical auxiliary agent is the invention provides for solving the problem.Environmental protection type agricultural chemical auxiliary agent provided by the invention, biological degradability is good, and drug effect is long, without noxious material release, is conducive to environmental protection.
For achieving the above object, the present invention is by the following technical solutions:
A kind of environmental protection type agricultural chemical auxiliary agent, with parts by weight, comprises following component:
Talcum powder 10-15 part, neopelex 5-8 part,
Alkylphenol polyoxyethylene 5-10 part, dispersant 3-6 part,
Wetting agent 2-5 part, spreader-sticker 4-5 part,
Nano zine oxide 2-3 part, nano-titanium oxide 1-3 part.
Preferred as technique scheme, a kind of environmental protection type agricultural chemical auxiliary agent, with parts by weight, comprises following component:
Talcum powder 15 parts, neopelex 7 parts,
Alkylphenol polyoxyethylene 8 parts, dispersant 5 parts,
Wetting agent 3 parts, spreader-sticker 4 parts,
Nano zine oxide 2 parts, nano-titanium oxide 1 part.
Preferred as technique scheme, described dispersant is sodium sulphate.
Preferred as technique scheme, described wetting agent is spaonin powder.
Preferred as technique scheme, described spreader-sticker is casein.
Preferred as technique scheme, described Particle Size of Nanometer ZnO is 25nm.
Preferred as technique scheme, described nano-titanium oxide particle diameter is 12nm.
The present invention has following beneficial effect:
Environmental protection type agricultural chemical auxiliary agent provided by the invention, raw material is all biodegradable, and environmental sound, is conducive to environmental protection.On the one hand, nano zine oxide is distributed in insecticides adjuvant, and it has good shielding action to the ultraviolet light below 400nm wavelength, thus reaches the object that agricultural chemicals delays degraded, makes the drug effect of agricultural chemicals longer; On the other hand, nano-titanium oxide has catalytic action to organic degraded under light illumination, the pesticide species that this is long due to degradative phase for some and affect second stubble crop seems particular importance, and it can also reduce residual in crop and soil of agricultural chemicals, thus improves the safety of crop.
Embodiment:
For a better understanding of the present invention, be further detailed the present invention below by several case study on implementation, embodiment is only used for explaining the present invention, can not form any restriction to the present invention.
Embodiment 1
A kind of environmental protection type agricultural chemical auxiliary agent, with parts by weight, comprises following component:
Talcum powder 10 parts, neopelex 5 parts,
Alkylphenol polyoxyethylene 5 parts, dispersant 3 parts,
Wetting agent 2 parts, spreader-sticker 4 parts,
Nano zine oxide 2 parts, nano-titanium oxide 1 part.
Its preparation method comprises the following steps:
(1) 5 parts of neopelexes, 3 parts of dispersants are water-soluble, stir and make dissolution of solid, obtain mixed solution;
(2), in the mixed solution obtained to step (1), add 10 parts of talcum powder, 2 parts of wetting agents, ultrasonic 2h, make talcum powder be dispersed in mixed solution;
(3) add 5 parts of alkylphenol polyoxyethylene, 4 parts of spreader-stickers, mixed solution is warming up to 50 DEG C, ultrasonic 30min;
(4) mixed solution is cooled to room temperature, adds 1 part of nano-titanium oxide, 2 parts of nano zine oxides, ultrasonic 60min, until nano zine oxide, nano-titanium oxide are uniformly dispersed, obtain liquid type environmental-friendly type insecticides adjuvant.
Embodiment 2
A kind of environmental protection type agricultural chemical auxiliary agent, with parts by weight, comprises following component:
Talcum powder 15 parts, neopelex 8 parts,
Alkylphenol polyoxyethylene 10 parts, dispersant 6 parts,
Wetting agent 5 parts, spreader-sticker 5 parts,
Nano zine oxide 3 parts, nano-titanium oxide 3 parts.
Its preparation method comprises the following steps:
(1) 8 parts of neopelexes, 6 parts of dispersants are water-soluble, stir and make dissolution of solid, obtain mixed solution;
(2), in the mixed solution obtained to step (1), add 15 parts of talcum powder, 5 parts of wetting agents, ultrasonic 5h, make talcum powder be dispersed in mixed solution;
(3) add 10 parts of alkylphenol polyoxyethylene, 5 parts of spreader-stickers, mixed solution is warming up to 50 DEG C, ultrasonic 60min;
(4) mixed solution is cooled to room temperature, adds 3 parts of nano-titanium oxides, 3 parts of nano zine oxides, ultrasonic 100min, until nano zine oxide, nano-titanium oxide are uniformly dispersed, obtain liquid type environmental-friendly type insecticides adjuvant.
Embodiment 3
A kind of environmental protection type agricultural chemical auxiliary agent, with parts by weight, comprises following component:
Talcum powder 11 parts, neopelex 6 parts,
Alkylphenol polyoxyethylene 6 parts, dispersant 4 parts,
Wetting agent 3 parts, spreader-sticker 4 parts,
Nano zine oxide 2 parts, nano-titanium oxide 2 parts.
Its preparation method comprises the following steps:
(1) 6 parts of neopelexes, 4 parts of dispersants are water-soluble, stir and make dissolution of solid, obtain mixed solution;
(2), in the mixed solution obtained to step (1), add 11 parts of talcum powder, 3 parts of wetting agents, ultrasonic 3h, make talcum powder be dispersed in mixed solution;
(3) add 6 parts of alkylphenol polyoxyethylene, 4 parts of spreader-stickers, mixed solution is warming up to 50 DEG C, ultrasonic 40min;
(4) mixed solution is cooled to room temperature, adds 2 parts of nano-titanium oxides, 2 parts of nano zine oxides, ultrasonic 70min, until nano zine oxide, nano-titanium oxide are uniformly dispersed, obtain liquid type environmental-friendly type insecticides adjuvant.
Embodiment 4
A kind of environmental protection type agricultural chemical auxiliary agent, with parts by weight, comprises following component:
Talcum powder 12 parts, neopelex 7 parts,
Alkylphenol polyoxyethylene 7 parts, dispersant 5 parts,
Wetting agent 4 parts, spreader-sticker 5 parts,
Nano zine oxide 2 parts, nano-titanium oxide 3 parts.
Its preparation method comprises the following steps:
(1) 7 parts of neopelexes, 5 parts of dispersants are water-soluble, stir and make dissolution of solid, obtain mixed solution;
(2), in the mixed solution obtained to step (1), add 12 parts of talcum powder, 4 parts of wetting agents, ultrasonic 4h, make talcum powder be dispersed in mixed solution;
(3) add 7 parts of alkylphenol polyoxyethylene, 5 parts of spreader-stickers, mixed solution is warming up to 50 DEG C, ultrasonic 50min;
(4) mixed solution is cooled to room temperature, adds 3 parts of nano-titanium oxides, 2 parts of nano zine oxides, ultrasonic 80min, until nano zine oxide, nano-titanium oxide are uniformly dispersed, obtain liquid type environmental-friendly type insecticides adjuvant.
Embodiment 5
A kind of environmental protection type agricultural chemical auxiliary agent, with parts by weight, comprises following component:
Talcum powder 13 parts, neopelex 6 parts,
Alkylphenol polyoxyethylene 9 parts, dispersant 5 parts,
Wetting agent 4 parts, spreader-sticker 5 parts,
Nano zine oxide 3 parts, nano-titanium oxide 1 part.
Its preparation method comprises the following steps:
(1) 6 parts of neopelexes, 5 parts of dispersants are water-soluble, stir and make dissolution of solid, obtain mixed solution;
(2), in the mixed solution obtained to step (1), add 13 parts of talcum powder, 4 parts of wetting agents, ultrasonic 4h, make talcum powder be dispersed in mixed solution;
(3) add 9 parts of alkylphenol polyoxyethylene, 5 parts of spreader-stickers, mixed solution is warming up to 50 DEG C, ultrasonic 55min;
(4) mixed solution is cooled to room temperature, adds 1 part of nano-titanium oxide, 3 parts of nano zine oxides, ultrasonic 90min, until nano zine oxide, nano-titanium oxide are uniformly dispersed, obtain liquid type environmental-friendly type insecticides adjuvant.
The using method of environmental protection type agricultural chemical auxiliary agent provided by the invention is: be first diluted to mother liquor with a small amount of water during use, is joined by the mother liquor of dilution in the agricultural chemicals prepared, and wherein mother liquor is 1:3000 with the mass ratio preparing agricultural chemicals.

Claims (7)

1. an environmental protection type agricultural chemical auxiliary agent, is characterized in that, with parts by weight, comprises following component:
Talcum powder 10-15 part, neopelex 5-8 part,
Alkylphenol polyoxyethylene 5-10 part, dispersant 3-6 part,
Wetting agent 2-5 part, spreader-sticker 4-5 part,
Nano zine oxide 2-3 part, nano-titanium oxide 1-3 part.
2. a kind of environmental protection type agricultural chemical auxiliary agent as claimed in claim 1, is characterized in that, with parts by weight, comprises following component:
Talcum powder 15 parts, neopelex 7 parts,
Alkylphenol polyoxyethylene 8 parts, dispersant 5 parts,
Wetting agent 3 parts, spreader-sticker 4 parts,
Nano zine oxide 2 parts, nano-titanium oxide 1 part.
3. a kind of environmental protection type agricultural chemical auxiliary agent as claimed in claim 1, is characterized in that, described dispersant is sodium sulphate.
4. a kind of environmental protection type agricultural chemical auxiliary agent as claimed in claim 1, is characterized in that, described wetting agent is spaonin powder.
5. a kind of environmental protection type agricultural chemical auxiliary agent as claimed in claim 1, is characterized in that, described spreader-sticker is casein.
6. a kind of environmental protection type agricultural chemical auxiliary agent as claimed in claim 1, is characterized in that, described Particle Size of Nanometer ZnO is 25nm.
7. a kind of environmental protection type agricultural chemical auxiliary agent as claimed in claim 1, is characterized in that, described nano-titanium oxide particle diameter is 12nm.
CN201410713074.XA 2014-12-01 2014-12-01 A kind of environmental protection type agricultural chemical auxiliary agent Expired - Fee Related CN104430321B (en)

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CN104430321B CN104430321B (en) 2016-05-25

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105994261A (en) * 2016-06-06 2016-10-12 佛山市聚成生化技术研发有限公司 Photodegradable organophosphorus pesticide insecticide preparation method and photodegradable organophosphorus pesticide insecticide prepared by method
CN106386793A (en) * 2016-09-07 2017-02-15 马鞍山纽泽科技服务有限公司 Efficient pesticide auxiliary
CN107410293A (en) * 2017-05-22 2017-12-01 陶圣香 A kind of plant source auxiliary agent and its synthetic method
CN107410294A (en) * 2017-06-08 2017-12-01 合肥龙滨化工科技有限公司 A kind of biological pesticide used additives
CN108271771A (en) * 2018-02-09 2018-07-13 北京交通大学 A kind of eco-friendly pesticide control helplessness agent and preparation method thereof
CN112335653A (en) * 2020-10-12 2021-02-09 莱芜职业技术学院 Environment-friendly pesticide adjuvant and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1185090A (en) * 1995-04-27 1998-06-17 杰尼克有限公司 Microcapsules contg. suspensions of biologically active compounds and ultraviolet protectant
CN1832684A (en) * 2003-06-03 2006-09-13 奥克松尼卡有限公司 Agricultural, horticultural and veterinary compositions
CN1926200A (en) * 2004-01-28 2007-03-07 奥克松尼卡有限公司 Surface-doped particles of TiO2 or ZnO and their use
CN102450253A (en) * 2010-10-15 2012-05-16 华北制药集团爱诺有限公司 Avermectin suspension concentrate and preparation method thereof
JP2012097031A (en) * 2010-11-02 2012-05-24 Hakugen:Kk Method for suppressing denaturation of dichlorobenzene and dichlorobenzene formulation

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1185090A (en) * 1995-04-27 1998-06-17 杰尼克有限公司 Microcapsules contg. suspensions of biologically active compounds and ultraviolet protectant
CN1832684A (en) * 2003-06-03 2006-09-13 奥克松尼卡有限公司 Agricultural, horticultural and veterinary compositions
CN1926200A (en) * 2004-01-28 2007-03-07 奥克松尼卡有限公司 Surface-doped particles of TiO2 or ZnO and their use
CN102450253A (en) * 2010-10-15 2012-05-16 华北制药集团爱诺有限公司 Avermectin suspension concentrate and preparation method thereof
JP2012097031A (en) * 2010-11-02 2012-05-24 Hakugen:Kk Method for suppressing denaturation of dichlorobenzene and dichlorobenzene formulation

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105994261A (en) * 2016-06-06 2016-10-12 佛山市聚成生化技术研发有限公司 Photodegradable organophosphorus pesticide insecticide preparation method and photodegradable organophosphorus pesticide insecticide prepared by method
CN106386793A (en) * 2016-09-07 2017-02-15 马鞍山纽泽科技服务有限公司 Efficient pesticide auxiliary
CN107410293A (en) * 2017-05-22 2017-12-01 陶圣香 A kind of plant source auxiliary agent and its synthetic method
CN107410294A (en) * 2017-06-08 2017-12-01 合肥龙滨化工科技有限公司 A kind of biological pesticide used additives
CN108271771A (en) * 2018-02-09 2018-07-13 北京交通大学 A kind of eco-friendly pesticide control helplessness agent and preparation method thereof
CN112335653A (en) * 2020-10-12 2021-02-09 莱芜职业技术学院 Environment-friendly pesticide adjuvant and preparation method thereof

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Effective date of registration: 20161228

Address after: 215200 Jiangsu City, Wujiang Province, Shengze Town, No. two West Ring Road, No. Shengze Textile Science and Technology Park, building 10, 1188

Patentee after: Suzhou favourite son's Information technology company limited

Address before: 215106 Jiangsu city of Suzhou Province Huang Dai Zhen Hu Qiao Cun, Xiangcheng District

Patentee before: Xiangcheng District, Suzhou City Sheng Hu special cultivation Specialty Co-operative Organization

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20160525

Termination date: 20201201