CN104425457B - Testing structure and testing method for monitoring nitrogen doping quantity drifting of gate oxide layer - Google Patents

Testing structure and testing method for monitoring nitrogen doping quantity drifting of gate oxide layer Download PDF

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CN104425457B
CN104425457B CN201310413057.XA CN201310413057A CN104425457B CN 104425457 B CN104425457 B CN 104425457B CN 201310413057 A CN201310413057 A CN 201310413057A CN 104425457 B CN104425457 B CN 104425457B
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pmos
gate oxide
nmos tube
voltage
current
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CN104425457A (en
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黄晨
张进创
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Semiconductor Manufacturing International Shanghai Corp
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Semiconductor Manufacturing International Shanghai Corp
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Abstract

The application discloses a testing structure and a testing method for monitoring nitrogen doping quantity drifting of a gate oxide layer. The testing structure is positioned in a wafer cutting path and comprises an amplifier, a PMOS (P-channel Metal Oxide Semiconductor) pipe with a nitrogen doped gate oxide layer, an NMOS (N-channel metal oxide semiconductor) pipe with a nitrogen doped gate oxide layer, a first resistor and a second resistor. Current/voltage difference between the PMOS pipe and the NMOS pipe is amplified and the nitrogen doping quantity drifting of the gate oxide layer on an MOS (Metal Oxide Semiconductor) pipe can be monitored in real time.

Description

A kind of test structure and method of monitoring gate oxide itrogen content of getter with nitrogen doped drift
Technical field
The application is related to IC manufacturing field, more particularly to a kind of test knot of monitoring gate oxide itrogen content of getter with nitrogen doped drift Structure and method.
Background technology
At present, in the manufacturing process of semiconductor device, P-type mos(PMOS)Pipe, NMOS tube or The CMOS complementary metal-oxide-semiconductor collectively formed by PMOS and NMOS tube(Complementary Metal-Oxide- Semiconductor, CMOS)Pipe becomes the basic device for constituting chip.
The manufacture method of metal-oxide-semiconductor, comprises the following steps in prior art:
Step 11, in the Semiconductor substrate 100 with trap 101 sequentially form gate oxide 102 and polysilicon gate 103;
Specifically, trap injection is carried out to Semiconductor substrate 100, trap 101 is formed;Grow successively on a semiconductor substrate 100 Gate oxide and deposit polycrystalline silicon layer, subsequently in the surface coating photoresist layer of polysilicon layer(Do not show in figure), exposure imaging Patterning photoresist layer, defines the position of grid, with photoetching offset plate figure as mask, is sequentially etched polysilicon layer and gate oxidation Layer, forms gate oxide 102 and polysilicon gate 103.
For PMOS transistor, trap is injected to N-type element boron fluoride(BF2)Or boron(B)If what is made is NMOS crystal Pipe, trap is injected to p-type element phosphor(P)Or arsenic(As).
Step 12, the polysilicon gate 103 both sides formed side wall layer 104;
Step 13, with polysilicon gate 103 and side wall layer 104 Semiconductor substrate 100 with trap 101 is carried out as mask Ion implanting, forms source-drain electrode 105;
Wherein, because PMOS hole is used as majority carrier, so the source electrode of PMOS and drain electrode are p-type;Due to NMOS tube electronics is used as majority carrier, so the source electrode of NMOS tube and drain electrode are N-type.
Step 14, the annealing for carrying out source-drain electrode 105.
According to foregoing description, Fig. 1 is the structural representation that prior art forms metal-oxide-semiconductor.
In order to control short-channel effect, smaller szie requirement on devices further improves gate electrode electric capacity.This can be by not Break thinning gate oxide thickness and realize, but the thing followed is the lifting of gate electrode leakage current.Research finds, in gate oxidation Nitrating formation silicon oxynitride in layer, i.e., the nitrating in silicon oxide layer, compared with simple silicon oxide layer, its equivalent oxide thickness (EOT)Less, this point can improve gate electrode electric capacity just.But, according to prior art, nitrating forms nitrogen in silicon oxide Silicon oxide, the bad control of the content of nitrogen in silicon oxynitride, and the control of the content of nitrogen bad is easy to cause semiconductor device to open Voltage Vt changes, and the serious problems such as mobility change.
Prior art is to monitor the drift of nitrogen content, can only be online weekly(inline)Monitor once, if nitrogen content is super Permissible range is crossed, illustrates that this batch of product falls short of specifications, but the method for this monitoring nitrogen content drift, it is impossible to and reflection in time is asked Topic, production efficiency is than relatively low.
The content of the invention
This application discloses the test structure and method of a kind of monitoring gate oxide itrogen content of getter with nitrogen doped drift, with monitor in real time MOS The drift of gate oxide itrogen content of getter with nitrogen doped on pipe.
The technical scheme of the application is as follows:
This application discloses a kind of test structure of monitoring gate oxide itrogen content of getter with nitrogen doped drift, the test structure is positioned at wafer In Cutting Road, the test structure includes:Amplifier, the PMOS with nitrating gate oxide, with nitrating gate oxide NMOS tube, first resistor and second resistance;
The amplifier, it is poor for amplifying the current/voltage between PMOS and NMOS tube, with first input end, the Two inputs, the first outfan and the second outfan;Its first input end and the first outfan connect respectively the two of first resistor End;Its second input and the second outfan connect respectively the two ends of second resistance;First input end connects with the source electrode of PMOS Connect;Second input is connected with the drain electrode of NMOS tube;
The PMOS, for being input into the current/voltage of the PMOS, the PMOS in the first input end of amplifier The drain electrode of pipe connects supply voltage;
The NMOS tube, for being input into the current/voltage of the NMOS tube, the NMOS in the second input of amplifier The source ground of pipe.
Disclosed herein as well is a kind of method of structure control gate oxide itrogen content of getter with nitrogen doped drift tested as described above, the method Including:
The current/voltage of PMOS and NMOS tube is input into respectively in the first input end and the second input of amplifier;
After amplified device signal amplifies, the current/voltage of PMOS and NMOS tube after being amplified is poor;
Whether permissible range is exceeded according to the current/voltage difference after the amplification, judges whether gate oxide itrogen content of getter with nitrogen doped floats Move.
With the change of the gate oxide itrogen content of getter with nitrogen doped, the current/voltage between the PMOS and NMOS tube has phase Anti- variation tendency.
When gate oxide itrogen content of getter with nitrogen doped is raised, the current reduction of PMOS, the electric current of NMOS tube is raised;
When gate oxide itrogen content of getter with nitrogen doped is reduced, the electric current of PMOS is raised, the current reduction of NMOS tube.
When gate oxide itrogen content of getter with nitrogen doped is raised, the voltage of PMOS is raised, and the voltage of NMOS tube is reduced;
When gate oxide itrogen content of getter with nitrogen doped is reduced, the voltage of PMOS is reduced, and the voltage of NMOS tube is raised.
By the technical scheme of the application, the PMOS with nitrating gate oxide and the NMOS with nitrating gate oxide The current/voltage of pipe allows model after amplifier amplification, according to whether the current/voltage difference after amplification between the two exceedes Enclose, judge whether gate oxide itrogen content of getter with nitrogen doped drifts about.This is because, with the change of gate oxide itrogen content of getter with nitrogen doped, PMOS and NMOS Current/voltage between pipe has a contrary variation tendency, and itrogen content of getter with nitrogen doped change is bigger, and current/voltage difference is bigger, therefore just can be with Current/voltage after monitoring is amplified between PMOS and NMOS tube is poor, and then monitors whether gate oxide itrogen content of getter with nitrogen doped drifts about. With prior art, the method that weekly whether on-line measurement gate oxide itrogen content of getter with nitrogen doped drifts about compares, and the solution of the present invention can be real-time Reflect the drift of gate oxide itrogen content of getter with nitrogen doped exactly, better control over the content of nitrogen in silicon oxynitride.
Description of the drawings
Fig. 1 is the structural representation that prior art forms metal-oxide-semiconductor.
Fig. 2 is the test structure schematic diagram that the embodiment of the present invention monitors the drift of gate oxide itrogen content of getter with nitrogen doped.
Specific embodiment
To make the purpose of the present invention, technical scheme and advantage become more apparent, develop simultaneously referring to the drawings embodiment, The present invention is described in more detail.
Fig. 2 is the test structure schematic diagram that the embodiment of the present invention monitors the drift of gate oxide itrogen content of getter with nitrogen doped.The test structure position In wafer Cutting Road, the test structure includes:Amplifier 201, the PMOS 202 with nitrating gate oxide, with nitrating The NMOS tube 203 of gate oxide, first resistor 204 and second resistance 205;
Wherein, amplifier 201, it is poor for amplifying the current/voltage between PMOS 202 and NMOS tube 203, with first Input, the second input, the first outfan and the second outfan;Its first input end and the first outfan connect respectively first The two ends of resistance 204;Its second input and the second outfan connect respectively the two ends of second resistance 205;First input end with The source electrode connection of PMOS 202;Second input is connected with the drain electrode of NMOS tube 203;
The PMOS 202, it is described for being input into the current/voltage of the PMOS in the first input end of amplifier The drain electrode of PMOS meets supply voltage Vdd;
The NMOS tube 203, it is described for being input into the current/voltage of the NMOS tube in the second input of amplifier The source ground Vss of NMOS tube.
Research shows, with the change of gate oxide itrogen content of getter with nitrogen doped, the current/voltage tool between the PMOS and NMOS tube There is contrary variation tendency.Specifically, when gate oxide itrogen content of getter with nitrogen doped is raised, the current reduction of PMOS, the electric current of NMOS tube Raise;When gate oxide itrogen content of getter with nitrogen doped is reduced, the electric current of PMOS is raised, the current reduction of NMOS tube.When gate oxide nitrating When amount is raised, the voltage of PMOS is raised, and the voltage of NMOS tube is reduced;When gate oxide itrogen content of getter with nitrogen doped is reduced, the electricity of PMOS Pressure drop is low, and the voltage of NMOS tube is raised.Therefore itrogen content of getter with nitrogen doped change is bigger, and current/voltage difference is bigger.So, when gate oxide is mixed When nitrogen quantity exceedes certain limit, the current/voltage between the PMOS and NMOS tube of amplified device amplification is poor, also beyond certain model Enclose, it is poor by electrical measurement current/voltage to therefore, it can, whether the drift of monitor in real time gate oxide itrogen content of getter with nitrogen doped exceedes is allowed Scope.
Test structure according to Fig. 2, the method for present invention monitoring gate oxide itrogen content of getter with nitrogen doped drift, including following step Suddenly:
Step 21, amplifier first input end and the second input be input into respectively the electric current of PMOS and NMOS tube/ Voltage;
After step 22, amplified device signal amplify, the current/voltage of PMOS and NMOS tube after being amplified is poor;
Step 23, whether permissible range is exceeded according to the current/voltage difference after the amplification, judge gate oxide itrogen content of getter with nitrogen doped Whether drift about.
Concrete scene is set forth below, the method for the present invention is described in detail.In the embodiment of the present invention, amplifier is put Big rate is 10, and the resistance of first resistor and second resistance is respectively 1K ohms, and supply voltage Vdd is 1.2 volts, the grid of PMOS External voltage is 0 volt, and the grid external voltage of NMOS tube is identical with supply voltage, is 1.2 volts.
PMOS and NMOS tube are 600 milliamperes per micron through the difference between current that amplifier amplifies(mA/um)When, gate oxide The drift of itrogen content of getter with nitrogen doped, i.e. Δ N=1.2 atoms/cubic centimetre.
Show through research, under the conditions of above-mentioned parameter, PMOS and NMOS tube are big through the difference between current that amplifier amplifies When 200mA/um, the drift of gate oxide itrogen content of getter with nitrogen doped just exceedes permissible range, now, Δ N=0.5 atoms/cubic centimetre, and just Need to readjust the itrogen content of getter with nitrogen doped of gate oxide, to return in permissible range.Because 600mA/um is more than 200mA/ Um, the drift for illustrating gate oxide itrogen content of getter with nitrogen doped alreadys exceed permissible range.It should be noted that different amplifiers, amplification Difference, the magnitude for amplifying the difference between current for obtaining is also different, and this needs the amplifier according to different amplifications, arranges different electric currents Difference permissible range.
In addition, out amplifier can be electric current, or voltage.So can directly by PMOS and NMOS tube Through the difference between current that amplifier amplifies, or voltage difference, it is compared with permissible range.Can also according to voltage be equal to electric current with The product of resistance, calculates respectively the voltage of PMOS and NMOS tube after amplification, and then calculates between PMOS and NMOS tube Voltage difference after amplification.
In the above-described embodiments, the voltage difference between PMOS and NMOS tube after amplification:
The electric current * that the resistance-NMOS tube of the electric current * first resistors that PMOS is amplified through amplifier is amplified through amplifier The resistance of second resistance.
To sum up, with the change of gate oxide itrogen content of getter with nitrogen doped, the current/voltage between PMOS and NMOS tube has contrary Variation tendency, itrogen content of getter with nitrogen doped change is bigger, and current/voltage difference is bigger.The present invention utilizes this variation relation, is amplified by amplifier Current/voltage between PMOS and NMOS tube is poor, carrys out the drift of gate oxide itrogen content of getter with nitrogen doped on monitor in real time metal-oxide-semiconductor.The present invention Electric measurement method, compared to prior art, can real-time and accurately reflect the drift of gate oxide itrogen content of getter with nitrogen doped, preferably control The content of nitrogen in silicon oxynitride processed.
The preferred embodiment of the application is the foregoing is only, not to limit the application, all essences in the application Within god and principle, any modification, equivalent substitution and improvements done etc. should be included within the scope of the application protection.

Claims (5)

1. a kind of test structure that monitoring gate oxide itrogen content of getter with nitrogen doped drifts about, the test structure is located in wafer Cutting Road, and it is special Levy and be, the test structure includes:Amplifier, the PMOS with nitrating gate oxide, with nitrating gate oxide NMOS tube, first resistor and second resistance;
The amplifier, poor for amplifying the current/voltage between PMOS and NMOS tube, with first input end, second is defeated Enter end, the first outfan and the second outfan;Its first input end and the first outfan connect respectively the two ends of first resistor;Its Second input and the second outfan connect respectively the two ends of second resistance;First input end is connected with the source electrode of PMOS;The Two inputs are connected with the drain electrode of NMOS tube;
The PMOS, for being input into the current/voltage of the PMOS in the first input end of amplifier, the PMOS Drain electrode connects supply voltage;
The NMOS tube, for being input into the current/voltage of the NMOS tube in the second input of amplifier, the NMOS tube Source ground.
2. a kind of method that the monitoring gate oxide of test structure according to claim 1 itrogen content of getter with nitrogen doped drifts about, the method includes:
The current/voltage of PMOS and NMOS tube is input into respectively in the first input end and the second input of amplifier;
After amplified device signal amplifies, the current/voltage of PMOS and NMOS tube after being amplified is poor;
Whether permissible range is exceeded according to the current/voltage difference after the amplification, judges whether gate oxide itrogen content of getter with nitrogen doped drifts about.
3. method as claimed in claim 2, it is characterised in that with the change of the gate oxide itrogen content of getter with nitrogen doped, the PMOS Current/voltage between pipe and NMOS tube has contrary variation tendency.
4. method as claimed in claim 3, it is characterised in that when gate oxide itrogen content of getter with nitrogen doped is raised, the electric current drop of PMOS Low, the electric current of NMOS tube is raised;
When gate oxide itrogen content of getter with nitrogen doped is reduced, the electric current of PMOS is raised, the current reduction of NMOS tube.
5. method as claimed in claim 3, it is characterised in that when gate oxide itrogen content of getter with nitrogen doped is raised, the voltage liter of PMOS Height, the voltage of NMOS tube is reduced;
When gate oxide itrogen content of getter with nitrogen doped is reduced, the voltage of PMOS is reduced, and the voltage of NMOS tube is raised.
CN201310413057.XA 2013-09-11 2013-09-11 Testing structure and testing method for monitoring nitrogen doping quantity drifting of gate oxide layer Active CN104425457B (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7675134B2 (en) * 2008-04-07 2010-03-09 Microchip Technology Incorporated Temperature compensated work function based voltage reference
CN102024499A (en) * 2009-09-18 2011-04-20 杭州士兰集成电路有限公司 Readout structure and method for gate oxide breakdown type disposable programmable unit

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7675134B2 (en) * 2008-04-07 2010-03-09 Microchip Technology Incorporated Temperature compensated work function based voltage reference
CN102024499A (en) * 2009-09-18 2011-04-20 杭州士兰集成电路有限公司 Readout structure and method for gate oxide breakdown type disposable programmable unit

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