CN104403530A - Coating with acrylic modified alkyd resin - Google Patents
Coating with acrylic modified alkyd resin Download PDFInfo
- Publication number
- CN104403530A CN104403530A CN201410638038.1A CN201410638038A CN104403530A CN 104403530 A CN104403530 A CN 104403530A CN 201410638038 A CN201410638038 A CN 201410638038A CN 104403530 A CN104403530 A CN 104403530A
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- CN
- China
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- parts
- alkyd resin
- modified alkyd
- coating
- acrylic acid
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/20—Polyesters having been prepared in the presence of compounds having one reactive group or more than two reactive groups
- C08G63/21—Polyesters having been prepared in the presence of compounds having one reactive group or more than two reactive groups in the presence of unsaturated monocarboxylic acids or unsaturated monohydric alcohols or reactive derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention relates to a chemical industrial product, and especially relates to a coating with acrylic modified alkyd resin. The coating with the acrylic modified alkyd resin comprises the following components by weight: 15-17% of wax ester, 10-16% of epoxy resin, 20-30% of the acrylic modified alkyd resin, 12-16% of palm olein fine ester, 5-8% of methyl acrylic resin, 1-3% of a semi matt acrylic paint, 3-6% of a photo initiator, 5-10% of polyvinyl butyral, 2-4% of a polyether modified polysiloxane defoamer, 2-4% of a dispersant and balance of a thinner, and has the advantages of light resistance, good weatherability, tinting strength, strong covering power, strong adhesion, and low tendency to crack after use.
Description
Technical field
The present invention relates to a kind of chemical industries, especially a kind of coating with acrylic acid modified alkyd resin.
Background technology
There is the crackle that depth size is different in coating surface, as seen underlying surfaces from cracks, is then called " cracking "; As paint film presents the fine cracks of curvature of the spinal column decorative pattern sample, be then called " be full of cracks ".
Questions and prospect: one, priming paint and finish paint do not match, film produces string stress by ectocine (mechanical effect, temperature variation etc.), causes Alligatoring or cracking.Two, priming paint does not parch and namely applies (spray, brush, roller coat) finish paint, or the first layer finish paint is blocked up, without parching and be coated with second layer finish paint, makes external extension in two-layer paint inconsistent.Three, indoor paint is used for timber for outdoor or metallic surface priming paint.Four, wooden ground contains rosin without removing and process, with the passing of time can ooze out paint film, causes local be full of cracks.Five, moisture content is too high, and with the passing of time deforming causes cracking; Six, solidifying agent adds too much, or the solidifying agent of mistake in; Seven, construct blocked up; Eight, construction environment is severe, and the temperature difference is large, high humidity, and paint film, by cold and hot and flexible, causes be full of cracks.
Summary of the invention
The present invention is intended to solve the problems of the technologies described above, and provides a kind of coating with acrylic acid modified alkyd resin, its photostabilization, good weatherability, tinting strength, strong covering power, and strong adhesion is not easy to crack after using, and its technical scheme adopted is as follows:
A kind of coating with acrylic acid modified alkyd resin, it is characterized in that: its composition weight proportioning is: wax ester 15 ~ 17%, epoxy resin 10 ~ 16%, acrylic acid modified alkyd resin 20 ~ 30%, palm olein ester 12 ~ 16%, methacrylic resin 5 ~ 8%, half sub-light acrylic paints 1 ~ 3%, light trigger 3 ~ 6%, polyvinyl butyral acetal 5 ~ 10%, Polyether Modified Polysiloxanes Defoaming Agent 2 ~ 4%, dispersion agent 2 ~ 4%, all the other are solvent or diluent, described light trigger is prepared by following methods: all represent with molar fraction below, by 1 part of light base benzophenone of 4-, 1 ~ 3 part of formaldehyde joins in reaction vessel, after mixing, add 0.0102 ~ 0.012 part of alkali and make catalyzer, under agitation, heating keeps micro-boiling (90 ~ 99 DEG C) 1h ~ 3h, then increase the temperature to 140 ~ 160 DEG C, carry out Depressor response 10 ~ 15 minutes, be cooled to 90 DEG C ~ 110 DEG C to collect product after reaction terminates, product joined in the deionized water of 10 ~ 20 parts and precipitate, obtain after suction filtration.Organic silicon modified by polyether is that in siloxane molecule, introduce the obtained polyether siloxane copolymers of polyether segment (being called for short silicon ether copolymer) Polyether Modified Polysiloxanes Defoaming Agent be the new and effective defoamer of one both advantages combined.It is select to have press down more by force the polyethers of bubble ability and hydrophobicity strong, broken to steep dimethyl silicone oil be rapidly the defoamer that main component becomes to be grouped into the emulsifying agent that silicone oil and polyethers can be made to combine, stablizer etc.It has that surface tension is low, froth breaking rapidly, press down the features such as bubble time long, cost is low, consumption is few, wide application.Carry out polyether-modified to organosilicon, make it the advantage with two defoamers, become a kind of excellent property, the defoamer had wide application prospects.
In the molecule of silicon ether copolymer, siloxanes section is oleophilic group, and polyethers section is hydrophilic group.In polyether segment, polyethylene oxide chain Energy Conservation is for wetting ability and whipability, and poly(propylene oxide) chain is energy-conservation provides hydrophobicity and seepage force, has stronger effect to reduction surface tension.The performance of group to silicon ether copolymer of the polyethers end of the chain also has a great impact.Common end group has hydroxyl, alkoxyl group etc.Regulate the relative molecular mass of siloxanes section in multipolymer, multipolymer can be made to give prominence to or weaken organosilyl characteristic.Equally, change the relative molecular mass of polyethers section, can increase or reduce organosilyl ratio in molecule, also can have an impact to the performance of multipolymer.
Old dyeing, general application dimethyl polysiloxane defoamer, just can reach satisfied defoamer effect, and ensure even dyeing.But new dyeing, employs High Temperature High Pressure machinery, in this machinery, pollutant moves by the injection of staining fluid, is colored simultaneously.Though the foam produced can by common silicone antifoam agent froth breaking, at high temperature under high pressure, general silicone antifoam agent can produce film like precipitation and make pollutant produce spot.Application segmented copolymer just can overcome above shortcoming, because these component of antifoam agent can be dissolved in cold water, and is insoluble to hot water, so can play froth breaking effect.But only unsatisfactory with the defoaming effect of this multipolymer defoamer, if add a certain amount of vaporific SiO2 in the copolymer, just can reach gratifying defoaming effect, and produce the fabric of even dyeing.
Polyether Modified Polysiloxanes Defoaming Agent is easy to emulsification in water, is also called " self-emulsifying type defoamer ".Time more than its cloud point temperature, lose the solvability to water and mechanical stability, and acid-and base-resisting and inorganic salt, can be used for the froth breaking under severe condition, be widely used in the froth breaking in polyester piece good high-temperature dyeing process, zymotechnique.In addition, also can be used for the froth breaking of the system such as froth breaking and various finish, cutting fluid, non-freezing solution, water color ink of diethanolamine desulfurization system, also after being applicable to the plate-making of printing industry photosensitive resin, washing the froth breaking of uncured resin off, is that one is very representative, excellent property, broad-spectrum silicone antifoam agent.
For improving lipophilicity for water-based inks, coating, cutting fluid, in the copolymer molecule of organic silicon modified by polyether, part methyl chain alkyl replaces, and more effectively can play defoaming effect.For making also can have good defoaming below cloud point temperature, usually be all furnished with dimethyl silicone oil-white carbon black paste in self-emulsifying type defoamer, at this moment under cloud point temperature, organic silicon modified by polyether tensio-active agent can be used as again the emulsifying agent of dimethyl silicone oil and plays dispersion, emulsifying effect.
On technique scheme basis, described solvent or diluent by n-butyl acetate, ethyl acetate, propyl carbinol, ethanol, acetone, benzene, dimethylbenzene by weight percentage for 1:2:2:1:2:1:1 forms.
On technique scheme basis, described alkali is sodium hydroxide, hydrated barta, ammoniacal liquor or zinc oxide.
On technique scheme basis, described dispersion agent is tripoly phosphate sodium STPP, Sodium hexametaphosphate 99 or trisodium phosphate.
On technique scheme basis, described acrylic acid modified alkyd resin is made by following steps, all represents with molar fraction below:
A) by 8 ~ 12 parts, the lipid acid of short chain, terephthalic acid 2 ~ 4 parts, octadecane alkene vegetable oil acid 6 ~ 10 parts, monopentaerythritol 10 ~ 15 parts, phthalic anhydride 23 ~ 28 parts, glycerine 1 ~ 4 part, dibasic alcohol 6 ~ 10 parts, agent 0.05 ~ 0.2 part of losing lustre, dimethylbenzene 3 ~ 6 parts of input reactors, be uniformly mixed;
B) in reactor, nitrogen or carbon-dioxide protecting gas is passed into, oxygen in removing reactor, then be warming up to 180 ~ 190 degree, insulation esterification 3 ~ 4 hours, be then warming up to 190 degree ~ 210 degree carry out esterification until reach acid number be less than 10 (Gu);
C) be cooled to 160 ~ 170 degree, add latting drown aromatic solvent 20 ~ 25 parts, continue to be cooled to 75 ~ 85 degree, add latting drown low boiling ester kind solvent 4 ~ 8 parts, filtration obtains.
Tool of the present invention has the following advantages: photostabilization, good weatherability, tinting strength, strong covering power, and strong adhesion is not easy to crack after using.
Embodiment
Embodiment 1
A kind of coating with acrylic acid modified alkyd resin, it is characterized in that: its composition weight proportioning is: wax ester 17%, epoxy resin 16%, acrylic acid modified alkyd resin 30%, palm olein ester 16%, methacrylic resin 8%, half sub-light acrylic paints 3%, light trigger 6%, polyvinyl butyral acetal 10%, Polyether Modified Polysiloxanes Defoaming Agent 4%, dispersion agent 4%, all the other are solvent or diluent, described light trigger is prepared by following methods: all represent with molar fraction below, by 1 part of light base benzophenone of 4-, 1 ~ 3 part of formaldehyde joins in reaction vessel, after mixing, add 0.012 part of alkali and make catalyzer, under agitation, heating keeps micro-boiling 99 DEG C of 3h, then increase the temperature to 140 ~ 160 DEG C, carry out Depressor response 15 minutes, be cooled to 110 DEG C to collect product after reaction terminates, product joined in the deionized water of 20 parts and precipitate, obtain after suction filtration.
Preferably, described solvent or diluent by n-butyl acetate, ethyl acetate, propyl carbinol, ethanol, acetone, benzene, dimethylbenzene by weight percentage for 1:2:2:1:2:1:1 forms.
Preferably, described alkali is sodium hydroxide, and described dispersion agent is tripoly phosphate sodium STPP, and described acrylic acid modified alkyd resin is made by following steps, all represents with molar fraction below:
A) by 8 ~ 12 parts, the lipid acid of short chain, terephthalic acid 2 ~ 4 parts, octadecane alkene vegetable oil acid 6 ~ 10 parts, monopentaerythritol 10 ~ 15 parts, phthalic anhydride 23 ~ 28 parts, glycerine 1 ~ 4 part, dibasic alcohol 6 ~ 10 parts, agent 0.05 ~ 0.2 part of losing lustre, dimethylbenzene 3 ~ 6 parts of input reactors, be uniformly mixed;
B) in reactor, nitrogen or carbon-dioxide protecting gas is passed into, oxygen in removing reactor, then be warming up to 180 ~ 190 degree, insulation esterification 3 ~ 4 hours, be then warming up to 190 degree ~ 210 degree carry out esterification until reach acid number be less than 10 (Gu);
C) be cooled to 160 ~ 170 degree, add latting drown aromatic solvent 20 ~ 25 parts, continue to be cooled to 75 ~ 85 degree, add latting drown low boiling ester kind solvent 4 ~ 8 parts, filtration obtains.
Photostabilization: pigment keeps its former coloured performance under certain illumination.General employing eight grades of tabulations are shown, eight grades best.
Weathering resistance: pigment, under certain natural or artificial climate condition, keeps the ability of its original performance.General employing Pyatyi tabulation is shown, Pyatyi is best.
Tinting strength: tinting pigment absorbs the ability of incident light.The available relative percentage being equivalent to normal pigment sample tinting strength represents.
Opacifying power: the ability covering substrate surface color in filmogen.In the colored paint of conventional covering 1 square area, the grams of contained pigment represents.
Its photostabilization is six grades by experiment, and weathering resistance is level Four, and tinting strength is 40%, and opacifying power is 4 grams/m.
Embodiment 2
A kind of coating with acrylic acid modified alkyd resin, it is characterized in that: its composition weight proportioning is: wax ester 15%, epoxy resin 10%, acrylic acid modified alkyd resin 20%, palm olein ester 12 ~ 16%, methacrylic resin 5%, half sub-light acrylic paints 1%, light trigger 3%, polyvinyl butyral acetal 5%, Polyether Modified Polysiloxanes Defoaming Agent 2%, dispersion agent 2%, all the other are solvent or diluent, described light trigger is prepared by following methods: all represent with molar fraction below, by 1 part of light base benzophenone of 4-, 1 ~ 3 part of formaldehyde joins in reaction vessel, after mixing, add 0.0102 ~ 0.012 part of alkali and make catalyzer, under agitation, heating keeps micro-boiling (90 DEG C) 1h, then increase the temperature to 140 DEG C, carry out Depressor response 10 minutes, be cooled to 900C to collect product after reaction terminates, product joined in the deionized water of 10 parts and precipitate, obtain after suction filtration.
Preferably, described solvent or diluent by n-butyl acetate, ethyl acetate, propyl carbinol, ethanol, acetone, benzene, dimethylbenzene by weight percentage for 1:2:2:1:2:1:1 forms.
Preferably, described alkali is zinc oxide, and described dispersion agent is Sodium hexametaphosphate 99, and described acrylic acid modified alkyd resin is made by following steps, all represents with molar fraction below:
A) by 8 ~ 12 parts, the lipid acid of short chain, terephthalic acid 2 ~ 4 parts, octadecane alkene vegetable oil acid 6 ~ 10 parts, monopentaerythritol 10 ~ 15 parts, phthalic anhydride 23 ~ 28 parts, glycerine 1 ~ 4 part, dibasic alcohol 6 ~ 10 parts, agent 0.05 ~ 0.2 part of losing lustre, dimethylbenzene 3 ~ 6 parts of input reactors, be uniformly mixed;
B) in reactor, nitrogen or carbon-dioxide protecting gas is passed into, oxygen in removing reactor, then be warming up to 180 ~ 190 degree, insulation esterification 3 ~ 4 hours, be then warming up to 190 degree ~ 210 degree carry out esterification until reach acid number be less than 10 (Gu);
C) be cooled to 160 ~ 170 degree, add latting drown aromatic solvent 20 ~ 25 parts, continue to be cooled to 75 ~ 85 degree, add latting drown low boiling ester kind solvent 4 ~ 8 parts, filtration obtains.
Its photostabilization is six grades by experiment, and weathering resistance is level Four, and tinting strength is 45%, and opacifying power is 4 grams/m.
Describe the present invention by way of example above, but the invention is not restricted to above-mentioned specific embodiment, all any changes of doing based on the present invention or modification all belong to the scope of protection of present invention.
Claims (5)
1. one kind has the coating of acrylic acid modified alkyd resin, it is characterized in that: its composition weight proportioning is: wax ester 15 ~ 17%, epoxy resin 10 ~ 16%, acrylic acid modified alkyd resin 20 ~ 30%, palm olein ester 12 ~ 16%, methacrylic resin 5 ~ 8%, half sub-light acrylic paints 1 ~ 3%, light trigger 3 ~ 6%, polyvinyl butyral acetal 5 ~ 10%, Polyether Modified Polysiloxanes Defoaming Agent 2 ~ 4%, dispersion agent 2 ~ 4%, all the other are solvent or diluent, described light trigger is prepared by following methods: all represent with molar fraction below, by 1 part of light base benzophenone of 4-, 1 ~ 3 part of formaldehyde joins in reaction vessel, after mixing, add 0.0102 ~ 0.012 part of alkali and make catalyzer, under agitation, heating keeps micro-boiling (90 ~ 99 DEG C) 1h ~ 3h, then increase the temperature to 140 ~ 160 DEG C, carry out Depressor response 10 ~ 15 minutes, be cooled to 90 DEG C ~ 110 DEG C to collect product after reaction terminates, product joined in the deionized water of 10 ~ 20 parts and precipitate, obtain after suction filtration.
2. a kind of coating with acrylic acid modified alkyd resin according to claim 1, is characterized in that: described solvent or diluent by n-butyl acetate, ethyl acetate, propyl carbinol, ethanol, acetone, benzene, dimethylbenzene by weight percentage for 1:2:2:1:2:1:1 forms.
3. a kind of coating with acrylic acid modified alkyd resin according to claim 1, is characterized in that: described alkali is sodium hydroxide, hydrated barta, ammoniacal liquor or zinc oxide.
4. a kind of coating with acrylic acid modified alkyd resin according to claim 1, is characterized in that: described dispersion agent is tripoly phosphate sodium STPP, Sodium hexametaphosphate 99 or trisodium phosphate.
5. a kind of coating with acrylic acid modified alkyd resin according to claim 1, is characterized in that: described acrylic acid modified alkyd resin is made by following steps, all represents with molar fraction below:
A) by 8 ~ 12 parts, the lipid acid of short chain, terephthalic acid 2 ~ 4 parts, octadecane alkene vegetable oil acid 6 ~ 10 parts, monopentaerythritol 10 ~ 15 parts, phthalic anhydride 23 ~ 28 parts, glycerine 1 ~ 4 part, dibasic alcohol 6 ~ 10 parts, agent 0.05 ~ 0.2 part of losing lustre, dimethylbenzene 3 ~ 6 parts of input reactors, be uniformly mixed;
B) in reactor, nitrogen or carbon-dioxide protecting gas is passed into, oxygen in removing reactor, then be warming up to 180 ~ 190 degree, insulation esterification 3 ~ 4 hours, be then warming up to 190 degree ~ 210 degree carry out esterification until reach acid number be less than 10 (Gu);
C) be cooled to 160 ~ 170 degree, add latting drown aromatic solvent 20 ~ 25 parts, continue to be cooled to 75 ~ 85 degree, add latting drown low boiling ester kind solvent 4 ~ 8 parts, filtration obtains.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410638038.1A CN104403530A (en) | 2014-11-13 | 2014-11-13 | Coating with acrylic modified alkyd resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410638038.1A CN104403530A (en) | 2014-11-13 | 2014-11-13 | Coating with acrylic modified alkyd resin |
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| Publication Number | Publication Date |
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| CN104403530A true CN104403530A (en) | 2015-03-11 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201410638038.1A Pending CN104403530A (en) | 2014-11-13 | 2014-11-13 | Coating with acrylic modified alkyd resin |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105131793A (en) * | 2015-09-07 | 2015-12-09 | 王际宽 | Preparation method for paint for ion sheet material |
| CN106811033A (en) * | 2016-12-09 | 2017-06-09 | 芜湖天鸿汽车零部件有限公司 | A kind of car refinishing paint and preparation method thereof |
| CN109306203A (en) * | 2017-07-26 | 2019-02-05 | 精工爱普生株式会社 | Sublimation transfer inkjet ink composition and sublimation transfer ink jet recording method |
| CN113403865A (en) * | 2021-06-16 | 2021-09-17 | 红豆集团无锡红豆童装有限公司 | Organic cotton knitted fabric moxa liquor dyeing process |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101942063A (en) * | 2010-08-17 | 2011-01-12 | 华南理工大学 | Water-borne epoxy ester modified alkyd resin emulsion and preparation method thereof |
| CN102391395A (en) * | 2011-06-17 | 2012-03-28 | 北京化工大学常州先进材料研究院 | Macromolecular photoinitiator with benzophenone and preparation method thereof |
| CN103387785A (en) * | 2013-07-08 | 2013-11-13 | 吴江市物华五金制品有限公司 | Water-resistance finishing paint for pleasure boats, and preparation method thereof |
| CN104086712A (en) * | 2014-06-19 | 2014-10-08 | 华南理工大学 | Epoxy acrylate modified waterborne alkyd resin and preparation method and application thereof |
-
2014
- 2014-11-13 CN CN201410638038.1A patent/CN104403530A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101942063A (en) * | 2010-08-17 | 2011-01-12 | 华南理工大学 | Water-borne epoxy ester modified alkyd resin emulsion and preparation method thereof |
| CN102391395A (en) * | 2011-06-17 | 2012-03-28 | 北京化工大学常州先进材料研究院 | Macromolecular photoinitiator with benzophenone and preparation method thereof |
| CN103387785A (en) * | 2013-07-08 | 2013-11-13 | 吴江市物华五金制品有限公司 | Water-resistance finishing paint for pleasure boats, and preparation method thereof |
| CN104086712A (en) * | 2014-06-19 | 2014-10-08 | 华南理工大学 | Epoxy acrylate modified waterborne alkyd resin and preparation method and application thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105131793A (en) * | 2015-09-07 | 2015-12-09 | 王际宽 | Preparation method for paint for ion sheet material |
| CN106811033A (en) * | 2016-12-09 | 2017-06-09 | 芜湖天鸿汽车零部件有限公司 | A kind of car refinishing paint and preparation method thereof |
| CN109306203A (en) * | 2017-07-26 | 2019-02-05 | 精工爱普生株式会社 | Sublimation transfer inkjet ink composition and sublimation transfer ink jet recording method |
| CN113403865A (en) * | 2021-06-16 | 2021-09-17 | 红豆集团无锡红豆童装有限公司 | Organic cotton knitted fabric moxa liquor dyeing process |
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