CN104393041B - High-electron-mobility transistor of T-shaped gate field plate and manufacturing method of high-electron-mobility transistor - Google Patents
High-electron-mobility transistor of T-shaped gate field plate and manufacturing method of high-electron-mobility transistor Download PDFInfo
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Abstract
本发明公开了一种T形栅场板高电子迁移率晶体管及其制作方法,主要解决现有场板技术在实现高击穿电压时工艺复杂的问题。其结构自下而上包括:衬底(1)、过渡层(2)、势垒层(3)、钝化层(8)和保护层(11),势垒层(3)的上面淀积有源极(4)、漏极(5)与栅极(7),势垒层(3)的侧面刻有台面(6),钝化层(8)内刻有凹槽(9),钝化层(8)与保护层(11)之间淀积有T形栅场板(10),该T形栅场板与栅极(7)电气连接,且下端完全填充在凹槽(9)内。本发明具有制作工艺简单、击穿电压高、可靠性高和成品率高的优点。
The invention discloses a T-shaped gate field plate high electron mobility transistor and a manufacturing method thereof, which mainly solves the problem of complicated process when the existing field plate technology realizes high breakdown voltage. Its structure includes from bottom to top: substrate (1), transition layer (2), barrier layer (3), passivation layer (8) and protective layer (11), deposited on the barrier layer (3) There are source (4), drain (5) and gate (7), mesas (6) are engraved on the side of the barrier layer (3), grooves (9) are engraved in the passivation layer (8), passivation A T-shaped grid field plate (10) is deposited between the chemical layer (8) and the protective layer (11), the T-shaped grid field plate is electrically connected to the grid (7), and the lower end is completely filled in the groove (9) Inside. The invention has the advantages of simple manufacturing process, high breakdown voltage, high reliability and high yield.
Description
技术领域technical field
本发明属于微电子技术领域,涉及半导体器件,特别是T形栅场板高电子迁移率晶体管,可作为电力电子系统的基本器件。The invention belongs to the technical field of microelectronics, and relates to a semiconductor device, especially a T-shaped gate field plate high electron mobility transistor, which can be used as a basic device of a power electronic system.
技术背景technical background
功率半导体器件是电力电子系统的重要元件,是进行电能处理的有效工具。近年来,随着能源和环境问题的日益突出,研发新型高性能、低损耗功率器件已成为提高电能利用率、节约能源、缓解能源危机的有效途径之一。然而,在功率器件研究中,高速、高压与低导通电阻之间存在着严重的制约关系,合理、有效地改进这种制约关系是提高器件整体性能的关键。随着市场不断对功率系统提出更高效率、更小体积、更高频率的要求,传统Si基半导体功率器件性能已逼近其理论极限。为了能进一步减少芯片面积、提高工作频率、提高工作温度、降低导通电阻、提高击穿电压、降低整机体积、提高整机效率,以氮化镓为代表的宽禁带半导体材料,凭借其更大的禁带宽度、更高的临界击穿电场和更高的电子饱和漂移速度,且化学性能稳定、耐高温、抗辐射等突出优点,在制备高性能功率器件方面脱颖而出,应用潜力巨大。特别是采用GaN基异质结结构的高电子迁移率晶体管,即GaN基HEMT器件,更是因其低导通电阻、高工作频率等特性,能满足下一代电子装备对功率器件更大功率、更高频率、更小体积和更恶劣高温工作的要求,在经济和军事领域具有广阔和特殊的应用前景。Power semiconductor devices are important components of power electronic systems and effective tools for power processing. In recent years, as energy and environmental issues have become increasingly prominent, research and development of new high-performance, low-loss power devices has become one of the effective ways to improve power utilization, save energy, and alleviate energy crises. However, in the research of power devices, there is a serious constraint relationship between high speed, high voltage and low on-resistance. Reasonable and effective improvement of this constraint relationship is the key to improving the overall performance of the device. As the market continues to put forward higher efficiency, smaller size, and higher frequency requirements for power systems, the performance of traditional Si-based semiconductor power devices has approached its theoretical limit. In order to further reduce the chip area, increase the operating frequency, increase the operating temperature, reduce the on-resistance, increase the breakdown voltage, reduce the volume of the whole machine, and improve the efficiency of the whole machine, the wide bandgap semiconductor material represented by gallium nitride, with its Larger bandgap width, higher critical breakdown electric field and higher electron saturation drift velocity, as well as outstanding advantages such as stable chemical properties, high temperature resistance, and radiation resistance, stand out in the preparation of high-performance power devices and have great application potential. In particular, high electron mobility transistors using GaN-based heterojunction structures, that is, GaN-based HEMT devices, can meet the needs of next-generation electronic equipment for higher power, The requirements of higher frequency, smaller volume and harsher high temperature work have broad and special application prospects in the economic and military fields.
然而,常规GaN基HEMT器件结构上存在固有缺陷,会导致器件沟道电场强度呈畸形分布,尤其是在器件栅极靠近漏极附近存在极高电场峰值。导致实际的GaN基HEMT器件的击穿电压往往远低于理论期望值,且存在电流崩塌、逆压电效应等可靠性问题,严重制约了在电力电子领域中的应用和发展。为了解决以上问题,国内外研究者们提出了众多方法,而场板结构是其中效果最为显著、应用最为广泛的一种。2000年美国UCSB的N.Q.Zhang等人首次将场板结构成功应用于GaN基HEMT功率器件中,研制出交叠栅器件,饱和输出电流为500mA/mm,关态击穿电压可达570V,这是当时所报道击穿电压最高的GaN器件,参见Highbreakdown GaN HEMT with overlapping gate structure,IEEE Electron DeviceLetters,Vol.21,No.9,pp.421-423,2000。随后,各国研究机构纷纷展开了相关的研究工作,而美国和日本是该领域中的主要领跑者。在美国,主要是UCSB、南卡大学、康奈尔大学以及著名的电力电子器件制造商IR公司等从事该项研究。日本相对起步较晚,但他们对这方面的工作非常重视,资金投入力度大,从事机构众多,包括:东芝、古河、松下、丰田和富士等大公司。随着研究的深入,研究者们发现相应地增加场板长度,可以提高器件击穿电压。但场板长度的增加会使场板效率,即击穿电压比场板长度,不断减小,也就是场板提高器件击穿电压的能力随着场板长度的增加逐渐趋于饱和,参见Enhancement of breakdownvoltage in AlGaN/GaN high electron mobility transistors using a field plate,IEEE Transactions on Electron Devices,Vol.48,No.8,pp.1515-1521,2001,以及Development and characteristic analysis of a field-plated Al2O3/AlInN/GaN MOSHEMT,Chinese Physics B,Vol.20,No.1,pp.0172031-0172035,2011。因此,为了进一步提高器件击穿电压,同时兼顾场板效率,2004年UCSB的H.L.Xing等人提出了一种双层场板结构,他们研制的双层栅场板GaN基HEMT器件可获得高达900V的击穿电压,最大输出电流700mA/mm,参见High breakdown voltage AlGaN-GaN HEMTs achieved by multiplefield plates,IEEE Electron Device Letters,Vol.25,No.4,pp.161-163,2004。这种双层场板结构已成为当前国际上用来改善GaN基功率器件击穿特性,提高器件整体性能的主流场板技术。然而,GaN基双层场板HEMT器件的工艺复杂,制造成本更高,每一层场板的制作都需要光刻、淀积金属、淀积钝化介质等工艺步骤。而且要优化各层场板下介质材料厚度以实现击穿电压最大化,必须进行繁琐的工艺调试和优化,因此大大增加了器件制造的难度,降低了器件的成品率。However, there are inherent defects in the structure of conventional GaN-based HEMT devices, which will lead to a distorted distribution of the electric field intensity in the device channel, especially the extremely high electric field peak near the device gate and drain. As a result, the breakdown voltage of the actual GaN-based HEMT device is often far lower than the theoretical expectation, and there are reliability problems such as current collapse and inverse piezoelectric effect, which seriously restrict the application and development in the field of power electronics. In order to solve the above problems, researchers at home and abroad have proposed many methods, and the field plate structure is the most effective and widely used one among them. In 2000, NQ Zhang and others from UCSB in the United States successfully applied the field plate structure to GaN-based HEMT power devices for the first time, and developed an overlapping gate device with a saturated output current of 500mA/mm and an off-state breakdown voltage of 570V. For the GaN device with the highest reported breakdown voltage, see Highbreakdown GaN HEMT with overlapping gate structure, IEEE Electron Device Letters, Vol.21, No.9, pp.421-423, 2000. Subsequently, research institutions in various countries have launched related research work, and the United States and Japan are the main leaders in this field. In the United States, UCSB, University of South Carolina, Cornell University, and IR Corporation, a well-known manufacturer of power electronic devices, are mainly engaged in this research. Japan started relatively late, but they attach great importance to the work in this area, with large capital investment and a large number of institutions, including: Toshiba, Furukawa, Panasonic, Toyota and Fuji and other large companies. With the deepening of the research, the researchers found that increasing the length of the field plate can increase the breakdown voltage of the device. However, the increase of the field plate length will make the field plate efficiency, that is, the breakdown voltage ratio of the field plate length, continue to decrease, that is, the ability of the field plate to increase the breakdown voltage of the device gradually tends to saturation with the increase of the field plate length, see Enhancement of breakdown voltage in AlGaN/GaN high electron mobility transistors using a field plate, IEEE Transactions on Electron Devices, Vol.48, No.8, pp.1515-1521, 2001, and Development and characteristic analysis of a field-plated Al 2 O 3 /AlInN/GaN MOSHEMT, Chinese Physics B, Vol.20, No.1, pp.0172031-0172035, 2011. Therefore, in order to further improve the breakdown voltage of the device while taking into account the efficiency of the field plate, HL Xing et al. of UCSB proposed a double-layer field plate structure in 2004. The double-layer gate field plate GaN-based HEMT device they developed can obtain up to 900V Breakdown voltage, maximum output current 700mA/mm, see High breakdown voltage AlGaN-GaN HEMTs achieved by multiplefield plates, IEEE Electron Device Letters, Vol.25, No.4, pp.161-163, 2004. This double-layer field plate structure has become the mainstream field plate technology used internationally to improve the breakdown characteristics of GaN-based power devices and improve the overall performance of the device. However, the process of GaN-based double-layer field plate HEMT devices is complex and the manufacturing cost is higher. The fabrication of each layer of field plate requires process steps such as photolithography, metal deposition, and passivation dielectric deposition. Moreover, in order to optimize the thickness of the dielectric material under the field plates of each layer to maximize the breakdown voltage, tedious process debugging and optimization must be carried out, which greatly increases the difficulty of device manufacturing and reduces the yield of devices.
发明内容Contents of the invention
本发明的目的在于克服上述已有技术的不足,提供一种制造工艺简单、击穿电压高、场板效率高和可靠性高的T形栅场板高电子迁移率晶体管及其制作方法,以减小器件的制作难度,改善器件的击穿特性和可靠性,提高器件的成品率。The purpose of the present invention is to overcome the deficiencies of the above-mentioned prior art, to provide a T-shaped gate field plate high electron mobility transistor with simple manufacturing process, high breakdown voltage, high field plate efficiency and high reliability and a manufacturing method thereof, to The manufacturing difficulty of the device is reduced, the breakdown characteristic and reliability of the device are improved, and the yield of the device is increased.
为实现上述目的,本发明提供的器件结构采用GaN基宽禁带半导体材料构成的异质结结构,自下而上包括:衬底、过渡层、势垒层、钝化层和保护层,势垒层的上面淀积有源极、漏极与栅极,势垒层的侧面刻有台面,且台面深度大于势垒层厚度,其特征在于,钝化层内刻有凹槽,钝化层与保护层之间淀积有T形栅场板,该T形栅场板与栅极电气连接,且下端完全填充凹槽。In order to achieve the above object, the device structure provided by the present invention adopts a heterojunction structure composed of GaN-based wide bandgap semiconductor materials, including from bottom to top: substrate, transition layer, barrier layer, passivation layer and protective layer, potential A source, a drain, and a gate are deposited on the barrier layer, and a mesa is engraved on the side of the barrier layer, and the depth of the mesa is greater than the thickness of the barrier layer. It is characterized in that a groove is engraved in the passivation layer, and the passivation layer A T-shaped grid field plate is deposited between the protection layer, and the T-shaped grid field plate is electrically connected to the gate, and the lower end of the T-shaped grid field plate completely fills the groove.
作为优选,所述的凹槽深度s为0.11~8.2μm,宽度b为0.42~6.3μm。Preferably, the groove depth s is 0.11-8.2 μm, and the width b is 0.42-6.3 μm.
作为优选,所述的凹槽底部与势垒层之间的距离d为0.057~0.29μm。Preferably, the distance d between the bottom of the groove and the barrier layer is 0.057-0.29 μm.
作为优选,所述的T形栅场板靠近漏极一侧边缘与凹槽靠近漏极一侧边缘之间的距离c为0.62~7.9μm。Preferably, the distance c between the edge of the T-shaped gate field plate near the drain and the edge of the groove near the drain is 0.62-7.9 μm.
作为优选,所述的凹槽靠近栅极一侧边缘与栅极靠近漏极一侧边缘之间的距离a为s×(d)0.5,其中s为凹槽深度,d为凹槽底部与势垒层之间的距离。Preferably, the distance a between the edge of the groove near the gate and the edge of the gate near the drain is s×(d) 0.5 , where s is the depth of the groove, and d is the distance between the bottom of the groove and the potential distance between layers.
为实现上述目的,本发明制作T形栅场板高电子迁移率晶体管的方法,包括如下过程:In order to achieve the above object, the present invention makes the method for T-shaped gate field plate high electron mobility transistor, comprises following process:
第一步,在衬底上外延GaN基宽禁带半导体材料,形成过渡层;The first step is to epitaxially GaN-based wide bandgap semiconductor material on the substrate to form a transition layer;
第二步,在过渡层上外延GaN基宽禁带半导体材料,形成势垒层;The second step is to epitaxially GaN-based wide bandgap semiconductor material on the transition layer to form a barrier layer;
第三步,在势垒层上第一次制作掩膜,利用该掩膜在势垒层的两端淀积金属,再在N2气氛中进行快速热退火,分别制作源极和漏极;The third step is to make a mask on the barrier layer for the first time, use the mask to deposit metal on both ends of the barrier layer, and then perform rapid thermal annealing in N2 atmosphere to make the source and drain respectively;
第四步,在势垒层上第二次制作掩膜,利用该掩膜在源极左侧、漏极右侧的势垒层上进行刻蚀,且刻蚀区深度大于势垒层厚度,形成台面;The fourth step is to make a mask on the barrier layer for the second time, and use the mask to etch the barrier layer on the left side of the source and the right side of the drain, and the depth of the etching area is greater than the thickness of the barrier layer. form a table;
第五步,在势垒层上第三次制作掩膜,利用该掩膜在源极与漏极之间的势垒层上淀积金属,制作栅极;The fifth step is to make a mask on the barrier layer for the third time, and use the mask to deposit metal on the barrier layer between the source and the drain to make the gate;
第六步,分别在源极上部、漏极上部、栅极上部、栅极与源极之间的势垒层上部,以及栅极与漏极之间的势垒层上部淀积钝化层;The sixth step is to deposit a passivation layer on the upper part of the source, the upper part of the drain, the upper part of the gate, the upper part of the barrier layer between the gate and the source, and the upper part of the barrier layer between the gate and the drain;
第七步,在钝化层上第四次制作掩膜,利用该掩膜在栅极与漏极之间的钝化层内进行刻蚀,以制作深度s为0.11~8.2μm,宽度b为0.42~6.3μm的凹槽,凹槽底部与势垒层之间的距离d为0.057~0.29μm,该凹槽靠近栅极一侧边缘与栅极靠近漏极一侧边缘之间的距离a为s×(d)0.5,其中s为凹槽深度,d为凹槽底部与势垒层之间的距离;The seventh step is to make a mask on the passivation layer for the fourth time, and use the mask to etch in the passivation layer between the gate and the drain to make a depth s of 0.11-8.2 μm and a width b of For a groove of 0.42-6.3 μm, the distance d between the bottom of the groove and the barrier layer is 0.057-0.29 μm, and the distance a between the edge of the groove near the gate and the edge of the gate near the drain is s×(d) 0.5 , where s is the depth of the groove, and d is the distance between the bottom of the groove and the barrier layer;
第八步,在钝化层上第五次制作掩膜,利用该掩膜在凹槽内和源极与漏极之间的钝化层上淀积金属,所淀积的金属要完全填充凹槽,以形成厚度为0.11~8.2μm的T形栅场板,凹槽靠近漏极一侧边缘与T形栅场板靠近漏极一侧边缘之间的距离c为0.62~7.9μm,并将T形栅场板与栅极电气连接;The eighth step is to make a mask for the fifth time on the passivation layer, using the mask to deposit metal in the groove and on the passivation layer between the source and the drain, the deposited metal should completely fill the cavity groove to form a T-shaped grid field plate with a thickness of 0.11-8.2 μm, the distance c between the edge of the groove on the side close to the drain and the edge of the T-shaped grid field plate close to the drain is 0.62-7.9 μm, and The T-shaped grid field plate is electrically connected to the grid;
第九步,在T形栅场板上部和钝化层的其它区域上部淀积绝缘介质材料,形成保护层,完成整个器件的制作。In the ninth step, an insulating dielectric material is deposited on the upper part of the T-shaped gate field plate and other regions of the passivation layer to form a protective layer and complete the fabrication of the entire device.
本发明器件与采用传统栅场板的高电子迁移率晶体管比较具有以下优点:The device of the present invention has the following advantages compared with the high electron mobility transistor using the traditional gate field plate:
1.进一步提高了击穿电压。1. Further increase the breakdown voltage.
本发明由于采用T形栅场板结构,使器件在处于工作状态尤其是处于关态的工作状态时,势垒层表面电势从栅极到漏极逐渐升高,从而增加了势垒层中耗尽区,即高阻区,的面积,改善了耗尽区的分布,促使栅极与漏极之间势垒层中的耗尽区承担更大的漏源电压,从而大大提高了器件的击穿电压。Because the present invention adopts the T-shaped gate field plate structure, when the device is in the working state, especially in the off state, the surface potential of the barrier layer gradually increases from the gate to the drain, thereby increasing the power consumption in the barrier layer. The area of the depletion region, that is, the high resistance region, improves the distribution of the depletion region, and promotes the depletion region in the barrier layer between the gate and the drain to bear a larger drain-source voltage, thereby greatly improving the device's strike wear voltage.
2.进一步减小了栅极泄漏电流,提高了器件的可靠性。2. The gate leakage current is further reduced, and the reliability of the device is improved.
本发明由于采用T形栅场板结构,使器件势垒层耗尽区中电场线的分布得到了更有效的调制,器件中栅极靠近漏极一侧边缘、T形栅场板靠近漏极一侧边缘以及凹槽靠近漏极一侧边缘都会产生一个电场峰值,而且通过调整T形栅场板下方钝化层的厚度、凹槽深度和宽度、T形栅场板靠近漏极一侧边缘与凹槽靠近漏极一侧边缘之间的距离以及凹槽靠近栅极一侧边缘与栅极靠近漏极一侧边缘之间的距离,可以使得上述各个电场峰值相等且小于GaN基宽禁带半导体材料的击穿电场,从而最大限度地减少了栅极靠近漏极一侧的边缘所收集的电场线,有效地降低了该处的电场,大大减小了栅极泄漏电流,使得器件的可靠性和击穿特性均得到了显著增强。Because the present invention adopts the T-shaped gate field plate structure, the distribution of electric field lines in the depletion region of the device barrier layer is more effectively modulated, and the gate in the device is close to the edge of the drain side, and the T-shaped gate field plate is close to the drain. An electric field peak will be generated on one side of the edge and the edge of the groove near the drain, and by adjusting the thickness of the passivation layer under the T-shaped gate field plate, the depth and width of the groove, the edge of the T-shaped gate field plate near the drain The distance between the edge of the groove near the drain and the distance between the edge of the groove near the gate and the edge of the gate near the drain can make the above-mentioned electric field peaks equal and smaller than the GaN-based wide bandgap The breakdown electric field of the semiconductor material, thereby minimizing the electric field lines collected by the edge of the gate close to the drain side, effectively reducing the electric field there, greatly reducing the gate leakage current, making the device reliable Both performance and breakdown characteristics have been significantly enhanced.
3.工艺简单,易于实现,提高了成品率。3. The process is simple, easy to implement, and the yield rate is improved.
本发明器件结构中T形栅场板的制作只需一步工艺便可完成,避免了传统的堆层场板结构所带来的工艺复杂化问题,大大提高了器件的成品率。The manufacture of the T-shaped grid field plate in the device structure of the present invention can be completed in only one process, which avoids the problem of complicated process brought about by the traditional stacked layer field plate structure, and greatly improves the yield of the device.
仿真结果表明,本发明器件的击穿电压远远大于采用传统栅场板的高电子迁移率晶体管的击穿电压。Simulation results show that the breakdown voltage of the device of the invention is far greater than that of a high electron mobility transistor using a traditional gate field plate.
以下结合附图和实施例进一步说明本发明的技术内容和效果。The technical contents and effects of the present invention will be further described below in conjunction with the accompanying drawings and embodiments.
附图说明Description of drawings
图1是采用传统栅场板的高电子迁移率晶体管的结构图;Figure 1 is a structural diagram of a high electron mobility transistor using a conventional gate field plate;
图2是本发明T形栅场板高电子迁移率晶体管的结构图;Fig. 2 is the structural diagram of the T-shaped gate field plate high electron mobility transistor of the present invention;
图3是本发明T形栅场板高电子迁移率晶体管的制作流程图;Fig. 3 is the fabrication flowchart of T-shaped gate field plate high electron mobility transistor of the present invention;
图4是对传统器件及本发明器件仿真所得的势垒层中电场曲线图。Fig. 4 is a graph of the electric field in the barrier layer obtained by simulating the conventional device and the device of the present invention.
具体实施方式detailed description
参照图2,本发明T形栅场板高电子迁移率晶体管是基于GaN基宽禁带半导体异质结结构,其包括:衬底1、过渡层2、势垒层3、源极4、漏极5、台面6、栅极7、钝化层8、凹槽9、T形栅场板10与保护层11。衬底1、过渡层2与势垒层3为自下而上分布,源极4和漏极5淀积在势垒层3上,栅极7淀积在源极4和漏极5之间的势垒层上,台面6制作在源极左侧及漏极右侧的势垒层上,该台面深度大于势垒层厚度;钝化层8分别覆盖在源极上部、漏极上部、栅极上部、栅极与源极之间的势垒层上部,以及栅极与漏极之间的势垒层上部。凹槽9位于钝化层8内,该凹槽深度s为0.11~8.2μm,宽度b为0.42~6.3μm,凹槽底部与势垒层之间的距离d为0.057~0.29μm,凹槽靠近栅极一侧边缘与栅极靠近漏极一侧边缘之间的距离a、凹槽深度s以及凹槽底部与势垒层之间的距离d满足关系a=s×(d)0.5。钝化层8与保护层11之间淀积有T形栅场板10,该T形栅场板与栅极7电气连接,且下端完全填充凹槽9。T形栅场板靠近漏极一侧边缘与凹槽靠近漏极一侧边缘之间的距离c为0.62~7.9μm。保护层11位于T形栅场板10上部和钝化层8的其它区域上部。Referring to Figure 2, the T-shaped gate field plate high electron mobility transistor of the present invention is based on a GaN-based wide bandgap semiconductor heterojunction structure, which includes: a substrate 1, a transition layer 2, a barrier layer 3, a source 4, a drain pole 5, mesa 6, gate 7, passivation layer 8, groove 9, T-shaped gate field plate 10 and protective layer 11. The substrate 1, the transition layer 2 and the barrier layer 3 are distributed from bottom to top, the source 4 and the drain 5 are deposited on the barrier layer 3, and the gate 7 is deposited between the source 4 and the drain 5 On the barrier layer, the mesa 6 is made on the barrier layer on the left side of the source and the right side of the drain, and the depth of the mesa is greater than the thickness of the barrier layer; the passivation layer 8 covers the upper part of the source, the upper part of the drain, and the gate respectively. The upper part of the electrode, the upper part of the barrier layer between the gate and the source, and the upper part of the barrier layer between the gate and the drain. The groove 9 is located in the passivation layer 8, the depth s of the groove is 0.11-8.2 μm, the width b is 0.42-6.3 μm, the distance d between the bottom of the groove and the barrier layer is 0.057-0.29 μm, and the groove is close to The distance a between the edge of the gate side and the edge of the gate close to the drain, the depth s of the groove, and the distance d between the bottom of the groove and the barrier layer satisfy the relationship a=s×(d) 0.5 . A T-shaped grid field plate 10 is deposited between the passivation layer 8 and the protective layer 11 , the T-shaped grid field plate is electrically connected to the gate 7 , and the lower end of the T-shaped grid field plate completely fills the groove 9 . The distance c between the edge of the T-shaped gate field plate near the drain and the edge of the groove near the drain is 0.62-7.9 μm. The protection layer 11 is located on the upper part of the T-shaped gate field plate 10 and on other regions of the passivation layer 8 .
上述器件的衬底1采用蓝宝石或碳化硅或硅材料;过渡层2由若干层相同或不同的GaN基宽禁带半导体材料组成,其厚度为1~5μm;势垒层3由若干层相同或不同的GaN基宽禁带半导体材料组成,其厚度为5~50nm;钝化层8和保护层11均采用SiO2、SiN、Al2O3、Sc2O3、HfO2、TiO2中的任意一种或其它绝缘介质材料,钝化层的厚度为凹槽深度s和凹槽底部与势垒层之间的距离d之和,即0.167~8.49μm;保护层的厚度为0.12~8μm;T形栅场板10采用三层不同金属的组合构成,其厚度为0.11~8.2μm。The substrate 1 of the above-mentioned device is made of sapphire or silicon carbide or silicon material; the transition layer 2 is composed of several layers of the same or different GaN-based wide bandgap semiconductor materials, and its thickness is 1-5 μm; the barrier layer 3 is composed of several layers of the same or different Composition of different GaN-based wide bandgap semiconductor materials, the thickness of which is 5-50nm; passivation layer 8 and protective layer 11 are made of SiO 2 , SiN, Al 2 O 3 , Sc 2 O 3 , HfO 2 , TiO 2 Any one or other insulating dielectric material, the thickness of the passivation layer is the sum of the depth s of the groove and the distance d between the bottom of the groove and the barrier layer, that is, 0.167-8.49 μm; the thickness of the protective layer is 0.12-8 μm; The T-shaped grid field plate 10 is composed of three layers of different metals, and its thickness is 0.11-8.2 μm.
参照图3,本发明制作T形栅场板高电子迁移率晶体管的过程,给出如下三种实施例:Referring to Fig. 3, the process of making T-shaped gate field plate high electron mobility transistor in the present invention provides the following three embodiments:
实施例一:制作衬底为蓝宝石,钝化层为Al2O3,保护层为SiN,T形栅场板为Ti/Mo/Au金属组合的T形栅场板高电子迁移率晶体管。Embodiment 1: The substrate is sapphire, the passivation layer is Al 2 O 3 , the protective layer is SiN, and the T-gate field plate is a T-gate field plate high electron mobility transistor composed of Ti/Mo/Au metal.
步骤1.在蓝宝石衬底1上自下而上外延GaN材料制作过渡层2,如图3a。Step 1. Epitaxial GaN material on the sapphire substrate 1 from bottom to top to form the transition layer 2, as shown in FIG. 3a.
使用金属有机物化学气相淀积技术在蓝宝石衬底1上外延厚度为1μm的未掺杂过渡层2,该过渡层自下而上由厚度分别为30nm和0.97μm的GaN材料构成。外延下层GaN材料采用的工艺条件为:温度为530℃,压强为45Torr,氢气流量为4400sccm,氨气流量为4400sccm,镓源流量为22μmol/min;外延上层GaN材料采用的工艺条件为:温度为960℃,压强为45Torr,氢气流量为4400sccm,氨气流量为4400sccm,镓源流量为120μmol/min。An undoped transition layer 2 with a thickness of 1 μm is epitaxially formed on the sapphire substrate 1 by metal organic chemical vapor deposition technology, and the transition layer is composed of GaN materials with thicknesses of 30 nm and 0.97 μm from bottom to top. The process conditions used for the epitaxial lower layer GaN material are: temperature 530°C, pressure 45 Torr, hydrogen gas flow rate 4400 sccm, ammonia gas flow rate 4400 sccm, gallium source flow rate 22 μmol/min; the process conditions for the epitaxial upper layer GaN material are: temperature 960°C, pressure 45 Torr, hydrogen flow rate 4400 sccm, ammonia gas flow rate 4400 sccm, gallium source flow rate 120 μmol/min.
步骤2.在GaN过渡层2上淀积未掺杂的Al0.5Ga0.5N制作势垒层3,如图3b。Step 2. Deposit undoped Al 0.5 Ga 0.5 N on the GaN transition layer 2 to form a barrier layer 3, as shown in FIG. 3b.
使用金属有机物化学气相淀积技术在GaN过渡层2上淀积厚度为5nm,且铝组分为0.5的未掺杂Al0.5Ga0.5N势垒层3,其采用的工艺条件为:温度为980℃,压强为45Torr,氢气流量为4400sccm,氨气流量为4400sccm,镓源流量为35μmol/min,铝源流量为7μmol/min。Deposit an undoped Al 0.5 Ga 0.5 N barrier layer 3 with a thickness of 5 nm and an aluminum composition of 0.5 on the GaN transition layer 2 using metal organic chemical vapor deposition technology. The process conditions used are: the temperature is 980 °C, the pressure is 45 Torr, the flow rate of hydrogen gas is 4400 sccm, the flow rate of ammonia gas is 4400 sccm, the flow rate of gallium source is 35 μmol/min, and the flow rate of aluminum source is 7 μmol/min.
步骤3.在势垒层3的两端淀积金属Ti/Al/Ni/Au制作源极4与漏极5,如图3c。Step 3. Deposit metal Ti/Al/Ni/Au on both ends of the barrier layer 3 to make the source 4 and the drain 5, as shown in FIG. 3c.
在Al0.5Ga0.5N势垒层3上第一次制作掩膜,使用电子束蒸发技术在其两端淀积金属,再在N2气氛中进行快速热退火,制作源极4和漏极5,其中所淀积的金属为Ti/Al/Ni/Au金属组合,即自下而上分别为Ti、Al、Ni与Au,其厚度为0.018μm/0.135μm/0.046μm/0.052μm。淀积金属采用的工艺条件为:真空度小于1.8×10-3Pa,功率范围为200~1000W,蒸发速率小于快速热退火采用的工艺条件为:温度为850℃,时间为35s。Make a mask on the Al 0.5 Ga 0.5 N barrier layer 3 for the first time, use electron beam evaporation technology to deposit metal on both ends, and then perform rapid thermal annealing in N 2 atmosphere to make source 4 and drain 5 , where the deposited metal is a Ti/Al/Ni/Au metal combination, that is, Ti, Al, Ni and Au from bottom to top, and its thickness is 0.018μm/0.135μm/0.046μm/0.052μm. The process conditions used for depositing metal are: the degree of vacuum is less than 1.8×10 -3 Pa, the power range is 200-1000W, and the evaporation rate is less than The technological conditions adopted for the rapid thermal annealing are: the temperature is 850° C., and the time is 35 s.
步骤4.在源极左边与漏极右边的势垒层上进行刻蚀制作台面6,如图3d。Step 4. Etching the barrier layer on the left side of the source and the right side of the drain to form the mesa 6, as shown in FIG. 3d.
在Al0.5Ga0.5N势垒层3上第二次制作掩膜,使用反应离子刻蚀技术在源极左边与漏极右边的势垒层上进行刻蚀,形成台面6,刻蚀深度为10nm。刻蚀采用的工艺条件为:Cl2流量为15sccm,压强为10mTorr,功率为100W。Make a mask for the second time on the Al 0.5 Ga 0.5 N barrier layer 3, and use reactive ion etching technology to etch the barrier layer on the left side of the source and the right side of the drain to form a mesa 6 with an etching depth of 10nm . The process conditions used for etching are as follows: the flow rate of Cl 2 is 15 sccm, the pressure is 10 mTorr, and the power is 100 W.
步骤5.在源极4和漏极5之间的势垒层上淀积金属Ni/Au制作栅极7,如图3e。Step 5. Deposit metal Ni/Au on the barrier layer between the source 4 and the drain 5 to make the gate 7, as shown in FIG. 3e.
在Al0.5Ga0.5N势垒层3上第三次制作掩膜,使用电子束蒸发技术在源极4和漏极5之间的势垒层上淀积金属,制作栅极7,其中所淀积的金属为Ni/Au金属组合,即下层为Ni、上层为Au,其厚度为0.046μm/0.21μm。淀积金属采用的工艺条件为:真空度小于1.8×10-3Pa,功率范围为200~1000W,蒸发速率小于 Make a mask on the Al 0.5 Ga 0.5 N barrier layer 3 for the third time, use electron beam evaporation technology to deposit metal on the barrier layer between the source 4 and the drain 5, and make the gate 7, where the deposited The deposited metal is a Ni/Au metal combination, that is, the lower layer is Ni and the upper layer is Au, and its thickness is 0.046μm/0.21μm. The process conditions used for depositing metal are: the degree of vacuum is less than 1.8×10 -3 Pa, the power range is 200-1000W, and the evaporation rate is less than
步骤6.在源极上部、漏极上部、栅极上部、栅极与源极之间的Al0.5Ga0.5N势垒层上部,以及栅极与漏极之间的Al0.5Ga0.5N势垒层上部淀积Al2O3钝化层8,如图3f。Step 6. On the upper part of the source, the upper part of the drain, the upper part of the gate, the upper part of the Al 0.5 Ga 0.5 N barrier layer between the gate and the source, and the Al 0.5 Ga 0.5 N barrier between the gate and the drain Deposit an Al 2 O 3 passivation layer 8 on top of the layer, as shown in Figure 3f.
使用原子层淀积技术分别覆盖源极上部、漏极上部、栅极上部、栅极与源极之间的Al0.5Ga0.5N势垒层上部,以及栅极与漏极之间的Al0.5Ga0.5N势垒层上部,完成淀积厚度为0.167μm的Al2O3钝化层8。淀积钝化层采用的工艺条件为:以TMA和H2O为反应源,载气为N2,载气流量为200sccm,衬底温度为300℃,气压为700Pa。Use atomic layer deposition technology to cover the upper part of the source, the upper part of the drain, the upper part of the gate, the upper part of the Al 0.5 Ga 0.5 N barrier layer between the gate and the source, and the Al 0.5 Ga between the gate and the drain On the top of the 0.5 N barrier layer, an Al 2 O 3 passivation layer 8 with a thickness of 0.167 μm is deposited. The process conditions for depositing the passivation layer are as follows: TMA and H 2 O are used as reaction sources, the carrier gas is N 2 , the flow rate of the carrier gas is 200 sccm, the substrate temperature is 300° C., and the pressure is 700 Pa.
步骤7.在栅极7与漏极5之间的钝化层内进行刻蚀制作凹槽9,如图3g。Step 7. Etching the passivation layer between the gate 7 and the drain 5 to form a groove 9, as shown in FIG. 3g.
在钝化层8上第四次制作掩膜,使用反应离子刻蚀技术在栅极7与漏极5之间的钝化层内进行刻蚀,以制作凹槽9,其中凹槽深度s为0.11μm,宽度b为0.42μm,凹槽底部与势垒层之间的距离d为0.057μm,凹槽靠近栅极一侧边缘与栅极靠近漏极一侧边缘之间的距离a为0.026μm。刻蚀采用的工艺条件为:CF4流量为45sccm,O2流量为5sccm,压强为15mTorr,功率为250W。Make a mask for the fourth time on the passivation layer 8, and use reactive ion etching technology to etch in the passivation layer between the grid 7 and the drain 5 to make a groove 9, wherein the groove depth s is 0.11 μm, the width b is 0.42 μm, the distance d between the bottom of the groove and the barrier layer is 0.057 μm, and the distance a between the edge of the groove near the gate and the edge of the gate near the drain is 0.026 μm . The process conditions used for etching are as follows: the flow rate of CF 4 is 45 sccm, the flow rate of O 2 is 5 sccm, the pressure is 15 mTorr, and the power is 250W.
步骤8.在凹槽内和源极4与漏极5之间的钝化层上淀积金属Ti/Mo/Au制作T形栅场板10,如图3h。Step 8. Deposit metal Ti/Mo/Au in the groove and on the passivation layer between the source 4 and the drain 5 to make a T-shaped gate field plate 10, as shown in FIG. 3h.
在钝化层8上第五次制作掩膜,使用电子束蒸发技术在凹槽内和源极4与漏极5之间的钝化层上淀积金属制作T形栅场板10,并将T形栅场板与栅极电气连接,所淀积的金属为Ti/Mo/Au金属组合,即下层为Ti、中层为Mo、上层为Au,其厚度为0.05μm/0.05μm/0.01μm。其中所淀积的金属要完全填充凹槽9,T形栅场板10靠近漏极一侧边缘与凹槽9靠近漏极一侧边缘之间的距离c为0.62μm。淀积金属采用的工艺条件为:真空度小于1.8×10-3Pa,功率范围为200~1000W,蒸发速率小于 Make a mask for the fifth time on the passivation layer 8, use electron beam evaporation technology to deposit metal on the passivation layer in the groove and between the source electrode 4 and the drain electrode 5 to make the T-shaped grid field plate 10, and The T-shaped gate field plate is electrically connected to the gate, and the deposited metal is a metal combination of Ti/Mo/Au, that is, the lower layer is Ti, the middle layer is Mo, and the upper layer is Au, and its thickness is 0.05 μm/0.05 μm/0.01 μm. The deposited metal should completely fill the groove 9, and the distance c between the edge of the T-shaped gate field plate 10 near the drain and the edge of the groove 9 near the drain is 0.62 μm. The process conditions used for depositing metal are: the degree of vacuum is less than 1.8×10 -3 Pa, the power range is 200-1000W, and the evaporation rate is less than
步骤9.在T形栅场板10上部以及钝化层8的其它区域上部淀积SiN制作保护层11,如图3i。Step 9. Deposit SiN on the top of the T-shaped gate field plate 10 and other areas of the passivation layer 8 to form a protective layer 11, as shown in FIG. 3i.
使用等离子体增强化学气相淀积技术在T形栅场板10上部以及钝化层8的其它区域上部淀积SiN制作保护层11,其厚度为0.12μm,从而完成整个器件的制作,淀积保护层采用的工艺条件为:气体为NH3、N2及SiH4,气体流量分别为2.5sccm、950sccm和250sccm,温度、RF功率和压强分别为300℃、25W和950mTorr。Use plasma-enhanced chemical vapor deposition technology to deposit SiN on the top of the T-shaped gate field plate 10 and other regions of the passivation layer 8 to make a protective layer 11, and its thickness is 0.12 μm, thereby completing the production of the entire device. The process conditions used in the layer are: the gas is NH 3 , N 2 and SiH 4 , the gas flow rates are 2.5 sccm, 950 sccm and 250 sccm respectively, and the temperature, RF power and pressure are 300°C, 25W and 950mTorr respectively.
实施例二:制作衬底为碳化硅,钝化层为SiN,保护层为SiO2,T形栅场板为Ti/Ni/Au金属组合的T形栅场板高电子迁移率晶体管。Embodiment 2: The substrate is silicon carbide, the passivation layer is SiN, the protective layer is SiO 2 , and the T-gate field plate is a T-gate field plate high electron mobility transistor composed of Ti/Ni/Au metal.
步骤一.在碳化硅衬底1上自下而上外延AlN与GaN材料制作过渡层2,如图3a。Step 1. Epitaxially AlN and GaN materials on the silicon carbide substrate 1 from bottom to top to form a transition layer 2, as shown in FIG. 3a.
1.1)使用金属有机物化学气相淀积技术在碳化硅衬底1上外延厚度为50nm的未掺杂的AlN材料;其外延的工艺条件为:温度为1000℃,压强为45Torr,氢气流量为4600sccm,氨气流量为4600sccm,铝源流量为5μmol/min;1.1) Using metal-organic chemical vapor deposition technology to epitaxially undoped AlN material with a thickness of 50nm on the silicon carbide substrate 1; the process conditions for the epitaxy are: temperature is 1000°C, pressure is 45Torr, hydrogen flow rate is 4600sccm, The flow rate of ammonia gas is 4600 sccm, and the flow rate of aluminum source is 5 μmol/min;
1.2)使用金属有机物化学气相淀积技术在AlN材料上外延厚度为2.45μm的GaN材料,完成过渡层2的制作;其外延的工艺条件为:温度为1000℃,压强为45Torr,氢气流量为4600sccm,氨气流量为4600sccm,镓源流量为120μmol/min。1.2) Using metal-organic chemical vapor deposition technology to epitaxially GaN material with a thickness of 2.45 μm on the AlN material to complete the fabrication of the transition layer 2; the epitaxy process conditions are: temperature 1000 ° C, pressure 45 Torr, hydrogen flow rate 4600 sccm , the flow rate of ammonia gas is 4600 sccm, and the flow rate of gallium source is 120 μmol/min.
本步骤的外延不局限于金属有机物化学气相淀积技术,也可以采用分子束外延技术或氢化物气相外延技术。The epitaxy in this step is not limited to metal-organic chemical vapor deposition technology, and molecular beam epitaxy technology or hydride vapor phase epitaxy technology can also be used.
步骤二.在过渡层2上自下而上外延Al0.3Ga0.7N和GaN材料制作势垒层3,如图3b。Step 2. Epitaxially Al 0.3 Ga 0.7 N and GaN materials on the transition layer 2 from bottom to top to form a barrier layer 3 , as shown in FIG. 3 b .
2.1)使用金属有机物化学气相淀积技术在GaN过渡层2上淀积厚度为27nm、铝组分为0.3的Al0.3Ga0.7N材料;其外延的工艺条件为:温度为1100℃,压强为45Torr,氢气流量为4600sccm,氨气流量为4600sccm,镓源流量为16μmol/min,铝源流量为8μmol/min;2.1) Deposit an Al 0.3 Ga 0.7 N material with a thickness of 27nm and an aluminum composition of 0.3 on the GaN transition layer 2 by metal-organic chemical vapor deposition technology; the epitaxy process conditions are: temperature 1100°C, pressure 45Torr , the flow rate of hydrogen gas is 4600 sccm, the flow rate of ammonia gas is 4600 sccm, the flow rate of gallium source is 16 μmol/min, and the flow rate of aluminum source is 8 μmol/min;
2.2)使用金属有机物化学气相淀积技术在Al0.3Ga0.7N材料上外延厚度为3nm的GaN材料,完成势垒层3的制作;其外延的工艺条件为:温度为1050℃,压强为40Torr,氢气流量为4200sccm,氨气流量为4200sccm,镓源流量为12μmol/min。2.2) Using metal-organic chemical vapor deposition technology to epitaxially GaN material with a thickness of 3nm on the Al 0.3 Ga 0.7 N material to complete the fabrication of the barrier layer 3; the epitaxy process conditions are: temperature 1050°C, pressure 40Torr, The flow rate of hydrogen gas is 4200 sccm, the flow rate of ammonia gas is 4200 sccm, and the flow rate of gallium source is 12 μmol/min.
本步骤的外延不局限于金属有机物化学气相淀积技术,也可以采用分子束外延技术或氢化物气相外延技术。The epitaxy in this step is not limited to metal-organic chemical vapor deposition technology, and molecular beam epitaxy technology or hydride vapor phase epitaxy technology can also be used.
步骤三.在势垒层3的两端淀积金属Ti/Al/Ni/Au制作源极4与漏极5,如图3c。Step 3. Deposit metal Ti/Al/Ni/Au on both ends of the barrier layer 3 to form the source 4 and the drain 5, as shown in FIG. 3c.
3.1)在势垒层3上第一次制作掩膜,使用电子束蒸发技术在其两端淀积金属,淀积的金属为Ti/Al/Ni/Au金属组合,即自下而上分别为Ti、Al、Ni与Au,其厚度为0.018μm/0.135μm/0.046μm/0.052μm,其淀积金属工艺条件为:真空度小于1.8×10-3Pa,功率范围为200~1000W,蒸发速率小于 3.1) Make a mask on the barrier layer 3 for the first time, and use electron beam evaporation technology to deposit metal on its two ends. The deposited metal is a metal combination of Ti/Al/Ni/Au, that is, from bottom to top, respectively Ti, Al, Ni and Au, the thickness of which is 0.018μm/0.135μm/0.046μm/0.052μm, the metal deposition process conditions are: the vacuum degree is less than 1.8×10 -3 Pa, the power range is 200 ~ 1000W, the evaporation rate less than
3.2)在N2气氛中进行快速热退火,完成源极4和漏极5的制作,其快速热退火的工艺条件为:温度为850℃,时间为35s。3.2) Perform rapid thermal annealing in N 2 atmosphere to complete the fabrication of the source electrode 4 and the drain electrode 5 , the process conditions of the rapid thermal annealing are as follows: the temperature is 850° C., and the time is 35 s.
本步骤的金属淀积不局限于电子束蒸发技术,也可以采用溅射技术。The metal deposition in this step is not limited to the electron beam evaporation technique, and sputtering technique can also be used.
步骤四.在源极的左边与漏极的右边的势垒层3上进行刻蚀制作台面6,如图3d。Step 4. Etching the barrier layer 3 on the left side of the source and the right side of the drain to form a mesa 6, as shown in FIG. 3d.
在势垒层3上第二次制作掩膜,使用反应离子刻蚀技术在源极左边与漏极右边的势垒层3上进行刻蚀,形成台面6,其中刻蚀深度为100nm;反应离子刻蚀技术刻蚀台面6采用的工艺条件为:Cl2流量为15sccm,压强为10mTorr,功率为100W。Make a mask on the barrier layer 3 for the second time, and use reactive ion etching technology to etch the barrier layer 3 on the left side of the source and the right side of the drain to form a mesa 6, wherein the etching depth is 100nm; Etching technology The process conditions used for etching the mesa 6 are: the Cl 2 flow rate is 15 sccm, the pressure is 10 mTorr, and the power is 100 W.
本步骤的刻蚀不局限于反应离子刻蚀技术,也可以采用溅射技术或等离子体刻蚀技术。The etching in this step is not limited to the reactive ion etching technique, and sputtering technique or plasma etching technique may also be used.
步骤五.在源极和漏极之间的势垒层3上淀积金属Ni/Au制作栅极7,如图3e。Step 5. Deposit metal Ni/Au on the barrier layer 3 between the source and the drain to make the gate 7, as shown in FIG. 3e.
在势垒层3上第三次制作掩膜,使用电子束蒸发技术在源极4和漏极5之间的势垒层3上淀积金属,制作栅极7,其中所淀积的金属为Ni/Au金属组合,即下层为Ni、上层为Au,其厚度为0.046μm/0.21μm;电子束蒸发技术淀积Ni/Au采用的工艺条件为:淀积金属采用的工艺条件为:真空度小于1.8×10-3Pa,功率范围为200~1000W,蒸发速率小于 Make a mask on the barrier layer 3 for the third time, use electron beam evaporation technology to deposit metal on the barrier layer 3 between the source electrode 4 and the drain electrode 5, and make the gate 7, wherein the deposited metal is Ni/Au metal combination, that is, the lower layer is Ni and the upper layer is Au, and its thickness is 0.046μm/0.21μm; the process conditions used for depositing Ni/Au by electron beam evaporation technology are: the process conditions used for depositing metal are: vacuum degree Less than 1.8×10 -3 Pa, the power range is 200~1000W, and the evaporation rate is less than
本步骤的金属淀积不局限于电子束蒸发技术,也可以采用溅射技术。The metal deposition in this step is not limited to the electron beam evaporation technique, and sputtering technique can also be used.
步骤六.在源极上部、漏极上部、栅极上部、栅极与源极之间的势垒层3上部,以及栅极与漏极之间的势垒层3上部淀积SiN制作钝化层8,如图3f。Step 6. Deposit SiN on the top of the source, the top of the drain, the top of the gate, the top of the barrier layer 3 between the gate and the source, and the top of the barrier layer 3 between the gate and the drain to make passivation Layer 8, as shown in Figure 3f.
使用等离子体增强化学气相淀积技术分别覆盖源极上部、漏极上部、栅极上部、栅极与源极之间的势垒层3上部,以及栅极与漏极之间的势垒层3上部,完成淀积厚度为4.12μm的SiN钝化层8;其采用的工艺条件为:气体为NH3、N2及SiH4,气体流量分别为2.5sccm、950sccm和250sccm,温度、RF功率和压强分别为300℃、25W和950mTorr。Use plasma enhanced chemical vapor deposition technology to cover the upper part of the source, the upper part of the drain, the upper part of the gate, the upper part of the barrier layer 3 between the gate and the source, and the barrier layer 3 between the gate and the drain On the upper part, a SiN passivation layer 8 with a thickness of 4.12 μm is deposited; the process conditions used are: the gas is NH 3 , N 2 and SiH 4 , the gas flow rates are 2.5 sccm, 950 sccm and 250 sccm respectively, and the temperature, RF power and The pressures were 300°C, 25W and 950mTorr, respectively.
本步骤的钝化层的淀积不局限于等离子体增强化学气相淀积技术,也可以采用电子束蒸发技术或溅射技术或原子层淀积技术。The deposition of the passivation layer in this step is not limited to the plasma enhanced chemical vapor deposition technique, and electron beam evaporation technique, sputtering technique or atomic layer deposition technique may also be used.
步骤七.在栅极7和漏极5之间的钝化层8内进行刻蚀制作凹槽9,如图3g。Step 7. Etching and forming a groove 9 in the passivation layer 8 between the gate 7 and the drain 5, as shown in FIG. 3g.
在钝化层8上第四次制作掩膜,使用反应离子刻蚀技术在栅极7与漏极5之间的钝化层上进行刻蚀,以制作凹槽9,其中凹槽深度s为4μm,宽度b为3.5μm,凹槽底部与势垒层之间的距离d为0.12μm,凹槽靠近栅极一侧边缘与栅极靠近漏极一侧边缘之间的距离a为1.386μm;反应离子刻蚀技术刻蚀凹槽采用的工艺条件为:CF4流量为45sccm,O2流量为5sccm,压强为15mTorr,功率为250W。Make a mask for the fourth time on the passivation layer 8, use reactive ion etching technology to etch on the passivation layer between the grid 7 and the drain 5, to make the groove 9, wherein the groove depth s is 4 μm, the width b is 3.5 μm, the distance d between the bottom of the groove and the barrier layer is 0.12 μm, and the distance a between the edge of the groove near the gate and the edge of the gate near the drain is 1.386 μm; The process conditions used for etching grooves by reactive ion etching technology are: the flow rate of CF 4 is 45 sccm, the flow rate of O 2 is 5 sccm, the pressure is 15 mTorr, and the power is 250W.
本步骤的刻蚀不局限于反应离子刻蚀技术,也可以采用溅射技术或等离子体刻蚀技术。The etching in this step is not limited to the reactive ion etching technique, and sputtering technique or plasma etching technique may also be used.
步骤八.在凹槽内和源极4与漏极5之间的钝化层8上淀积金属Ti/Ni/Au制作T形栅场板10,如图3h。Step 8. Deposit metal Ti/Ni/Au in the groove and on the passivation layer 8 between the source 4 and the drain 5 to make a T-shaped gate field plate 10, as shown in FIG. 3h.
在钝化层8上第五次制作掩膜,使用电子束蒸发技术在凹槽内和源极4与漏极5之间的钝化层上淀积金属制作T形栅场板10,并将T形栅场板与栅极电气连接,所淀积的金属为Ti/Ni/Au金属组合,即下层为Ti、中层为Ni、上层为Au,其厚度为3μm/0.8μm/0.2μm。其中所淀积的金属要完全填充凹槽9,T形栅场板10靠近漏极一侧边缘与凹槽9靠近漏极一侧边缘之间的距离c为4μm;电子束蒸发技术淀积Ti/Ni/Au采用的工艺条件为:真空度小于1.8×10-3Pa,功率范围为200~1000W,蒸发速率小于 Make a mask for the fifth time on the passivation layer 8, use electron beam evaporation technology to deposit metal on the passivation layer in the groove and between the source electrode 4 and the drain electrode 5 to make the T-shaped grid field plate 10, and The T-shaped gate field plate is electrically connected to the gate, and the deposited metal is a metal combination of Ti/Ni/Au, that is, the lower layer is Ti, the middle layer is Ni, and the upper layer is Au, and its thickness is 3 μm/0.8 μm/0.2 μm. Wherein the deposited metal will completely fill the groove 9, and the distance c between the edge of the T-shaped gate field plate 10 near the drain and the edge of the groove 9 near the drain is 4 μm; electron beam evaporation technology deposits Ti The process conditions used for /Ni/Au are: the degree of vacuum is less than 1.8×10 -3 Pa, the power range is 200-1000W, and the evaporation rate is less than
本步骤的金属淀积不局限于电子束蒸发技术,也可以采用溅射技术。The metal deposition in this step is not limited to the electron beam evaporation technique, and sputtering technique can also be used.
步骤九.在T形栅场板10上部以及钝化层8的其它区域上部淀积SiO2制作保护层11,如图3i。Step 9. Deposit SiO 2 on the top of the T-shaped gate field plate 10 and other areas of the passivation layer 8 to form a protective layer 11 , as shown in FIG. 3 i .
使用等离子体增强化学气相淀积技术在T形栅场板10上部以及钝化层8的其它区域上部淀积SiO2制作保护层11,其厚度为4μm,从而完成整个器件的制作;其采用的工艺条件为:N2O流量为850sccm,SiH4流量为200sccm,温度为250℃,RF功率为25W,压强为1100mTorr。Use plasma-enhanced chemical vapor deposition technology to deposit SiO2 on the top of the T-shaped gate field plate 10 and other regions of the passivation layer 8 to make a protective layer 11, and its thickness is 4 μm, thereby completing the production of the entire device; The process conditions are as follows: the flow rate of N 2 O is 850 sccm, the flow rate of SiH 4 is 200 sccm, the temperature is 250° C., the RF power is 25 W, and the pressure is 1100 mTorr.
本步骤的保护层的淀积不局限于等离子体增强化学气相淀积技术,也可以采用电子束蒸发技术或溅射技术或原子层淀积技术。The deposition of the protective layer in this step is not limited to the plasma enhanced chemical vapor deposition technique, and electron beam evaporation technique, sputtering technique or atomic layer deposition technique may also be used.
实施例三:制作衬底为硅,钝化层为SiO2,保护层为SiN,T形栅场板为Ti/Pt/Au金属组合的T形栅场板高电子迁移率晶体管。Embodiment 3: Manufacturing a T-gate field plate high electron mobility transistor with a silicon substrate, a passivation layer of SiO 2 , a protective layer of SiN, and a T-gate field plate of Ti/Pt/Au metal combination.
步骤A.在硅衬底1上自下而上外延AlN与GaN材料制作过渡层2,如图3a。Step A. Epitaxially AlN and GaN materials on the silicon substrate 1 from bottom to top to form the transition layer 2, as shown in FIG. 3a.
A1)使用金属有机物化学气相淀积技术在温度为800℃,压强为40Torr,氢气流量为4000sccm,氨气流量为4000sccm,铝源流量为25μmol/min的工艺条件下,在硅衬底1上外延厚度为200nm的AlN材料;A1) Using metal-organic chemical vapor deposition technology at a temperature of 800° C., a pressure of 40 Torr, a flow rate of hydrogen gas of 4000 sccm, a flow rate of ammonia gas of 4000 sccm, and a flow rate of aluminum source of 25 μmol/min, the epitaxy on the silicon substrate 1 AlN material with a thickness of 200nm;
A2)使用金属有机物化学气相淀积技术在温度为980℃,压强为45Torr,氢气流量为4000sccm,氨气流量为4000sccm,镓源流量为120μmol/min的工艺条件下,在AlN材料上外延厚度为4.8μm的GaN材料,完成过渡层2的制作。A2) Using metal-organic chemical vapor deposition technology at a temperature of 980°C, a pressure of 45Torr, a flow rate of hydrogen gas of 4000 sccm, a flow rate of ammonia gas of 4000 sccm, and a source flow rate of gallium of 120 μmol/min, the epitaxial thickness on the AlN material is 4.8 μm GaN material to complete the fabrication of the transition layer 2 .
步骤B.在过渡层上自下而上淀积Al0.1Ga0.9N与GaN材料制作势垒层3,如图3b。Step B. Depositing Al 0.1 Ga 0.9 N and GaN materials from bottom to top on the transition layer to form a barrier layer 3 , as shown in FIG. 3 b .
B1)使用金属有机物化学气相淀积技术在温度为1000℃,压强为40Torr,氢气流量为4000sccm,氨气流量为4000sccm,镓源流量为12μmol/min,铝源流量为12μmol/min的工艺条件下,在GaN过渡层2上外延厚度为46nm、铝组分为0.1的Al0.1Ga0.9N材料;B1) Using metal-organic chemical vapor deposition technology at a temperature of 1000°C, a pressure of 40Torr, a hydrogen flow rate of 4000 sccm, an ammonia gas flow rate of 4000 sccm, a gallium source flow rate of 12 μmol/min, and an aluminum source flow rate of 12 μmol/min. , epitaxial Al 0.1 Ga 0.9 N material with a thickness of 46 nm and an aluminum composition of 0.1 on the GaN transition layer 2;
B2)使用金属有机物化学气相淀积技术在温度为1000℃,压强为40Torr,氢气流量为4000sccm,氨气流量为4000sccm,镓源流量为3μmol/min的工艺条件下,在Al0.1Ga0.9N材料上外延厚度为4nm的GaN材料,完成势垒层3的制作。B2) Using metal-organic chemical vapor deposition technology at a temperature of 1000°C, a pressure of 40Torr, a flow rate of hydrogen gas of 4000 sccm, a flow rate of ammonia gas of 4000 sccm, and a source flow rate of gallium of 3 μmol/min, on the Al 0.1 Ga 0.9 N material GaN material with a thickness of 4 nm is epitaxially applied to complete the fabrication of the barrier layer 3 .
步骤C.在势垒层3两端淀积金属Ti/Al/Ni/Au制作源极4与漏极5,如图3c。Step C. Deposit metal Ti/Al/Ni/Au on both ends of the barrier layer 3 to make the source 4 and the drain 5, as shown in FIG. 3c.
C1)在势垒层3上第一次制作掩膜,使用电子束蒸发技术在真空度小于1.8×10- 3Pa,功率范围为200~1000W,蒸发速率小于的工艺条件下,在其两端淀积金属,其中所淀积的金属为Ti/Al/Ni/Au金属组合,即自下而上分别为Ti、Al、Ni与Au,其厚度为0.018μm/0.135μm/0.046μm/0.052μm;C1) Make a mask on the barrier layer 3 for the first time, use electron beam evaporation technology at a vacuum degree of less than 1.8×10 - 3 Pa, a power range of 200-1000W, and an evaporation rate of less than Metals are deposited on both ends under the process conditions, and the deposited metals are Ti/Al/Ni/Au metal combination, that is, Ti, Al, Ni and Au from bottom to top, and the thickness is 0.018μm /0.135μm/0.046μm/0.052μm;
C2)在N2气氛,温度为850℃,时间为35s的工艺条件下进行快速热退火,完成源极4和漏极5的制作。C2) Perform rapid thermal annealing under the process conditions of N 2 atmosphere, temperature 850° C., and time 35 s, to complete the fabrication of source 4 and drain 5 .
步骤D.在源极左边与漏极右边的势垒层3上进行刻蚀制作台面6,如图3d。Step D. Etching the barrier layer 3 on the left side of the source and the right side of the drain to form a mesa 6, as shown in FIG. 3d.
在势垒层3上第二次制作掩膜,使用反应离子刻蚀技术在Cl2流量为15sccm,压强为10mTorr,功率为100W的工艺条件下,在源极左边与漏极右边的势垒层3上进行刻蚀,形成台面6,其中刻蚀深度为200nm。Make a mask on the barrier layer 3 for the second time, using reactive ion etching technology, under the process conditions of Cl 2 flow rate of 15 sccm, pressure of 10 mTorr, and power of 100 W, the barrier layer on the left side of the source and the right side of the drain 3 is etched to form a mesa 6, wherein the etching depth is 200 nm.
步骤E.在源极4与漏极5之间的势垒层3上淀积金属Ni/Au制作栅极7,如图3e。Step E. Deposit metal Ni/Au on the barrier layer 3 between the source 4 and the drain 5 to make the gate 7, as shown in FIG. 3e.
在势垒层3上第三次制作掩膜,使用电子束蒸发技术在真空度小于1.8×10-3Pa,功率范围为200~1000W,蒸发速率小于的工艺条件下,在源极4与漏极5之间的势垒层3上淀积金属,制作栅极7,所淀积的金属为Ni/Au金属组合,即下层为Ni、上层为Au,其厚度为0.046μm/0.21μm。Make a mask on the barrier layer 3 for the third time, using electron beam evaporation technology at a vacuum degree of less than 1.8×10 -3 Pa, a power range of 200-1000W, and an evaporation rate of less than Under the process conditions, metal is deposited on the barrier layer 3 between the source 4 and the drain 5 to make the gate 7. The deposited metal is a Ni/Au metal combination, that is, the lower layer is Ni and the upper layer is Au. , and its thickness is 0.046μm/0.21μm.
步骤F.在源极上部、漏极上部、栅极上部、栅极与源极之间的势垒层3上部,以及栅极与漏极之间的势垒层3上部淀积SiO2材料制作钝化层8,如图3f。Step F. Deposit SiO2 material on the upper part of the source, the upper part of the drain, the upper part of the gate, the upper part of the barrier layer 3 between the gate and the source, and the upper part of the barrier layer 3 between the gate and the drain. Passivation layer 8, as shown in Figure 3f.
使用等离子体增强化学气相淀积技术在N2O流量为850sccm,SiH4流量为200sccm,温度为250℃,RF功率为25W,压强为1100mTorr的工艺条件下,在源极上部、漏极上部、栅极上部、栅极与源极之间的势垒层3上部,以及栅极与漏极之间的势垒层3上部,淀积厚度为8.49μm的SiO2制作钝化层8。Using plasma-enhanced chemical vapor deposition technology, under the process conditions of N 2 O flow rate of 850 sccm, SiH 4 flow rate of 200 sccm, temperature of 250°C, RF power of 25W, and pressure of 1100mTorr, the upper part of the source, the upper part of the drain, On the top of the gate, the top of the barrier layer 3 between the gate and the source, and the top of the barrier layer 3 between the gate and the drain, SiO 2 with a thickness of 8.49 μm is deposited to make a passivation layer 8 .
步骤G.在栅极7与漏极5之间的钝化层8内进行刻蚀制作凹槽9,如图3g。Step G. Etching and forming a groove 9 in the passivation layer 8 between the gate 7 and the drain 5 , as shown in FIG. 3 g .
在钝化层8上第四次制作掩膜,使用反应离子刻蚀技术在CF4流量为20sccm,O2流量为2sccm,压强为20mTorr,偏置电压为100V的工艺条件下,在栅极7与漏极5之间的钝化层内进行刻蚀,以制作凹槽9,其中凹槽深度s为8.2μm,宽度b为6.3μm,凹槽底部与势垒层之间的距离d为0.29μm,凹槽靠近栅极一侧边缘与栅极靠近漏极一侧边缘之间的距离a为4.416μm。Make a mask on the passivation layer 8 for the fourth time, using reactive ion etching technology, under the process conditions that the flow rate of CF 4 is 20 sccm, the flow rate of O 2 is 2 sccm, the pressure is 20 mTorr, and the bias voltage is 100 V. Etching is carried out in the passivation layer between the drain electrode 5 to make a groove 9, wherein the groove depth s is 8.2 μm, the width b is 6.3 μm, and the distance d between the bottom of the groove and the barrier layer is 0.29 μm, the distance a between the edge of the groove near the gate and the edge of the gate near the drain is 4.416 μm.
步骤H.在凹槽内和源极4与漏极5之间的钝化层上淀积Ti/Pt/Au,制作T形栅场板10,如图3h。Step H. Deposit Ti/Pt/Au in the groove and on the passivation layer between the source 4 and the drain 5 to make a T-shaped gate field plate 10, as shown in FIG. 3h.
在钝化层8上第五次制作掩膜,使用电子束蒸发技术在真空度小于1.8×10-3Pa,功率范围为200~1000W,蒸发速率小于的工艺条件下,在凹槽内和源极4与漏极5之间的钝化层上淀积金属制作T形栅场板10,并将T形栅场板与栅极电气连接,所淀积的金属为厚度为Ti/Pt/Au金属组合,即下层为Ti、中层为Pt、上层为Au,其厚度为6μm/1.7μm/0.5μm,以制作T形栅场板10。其中所淀积的金属要完全填充凹槽9,T形栅场板10靠近漏极一侧边缘与凹槽9靠近漏极一侧边缘之间的距离c为7.9μm。Make a mask on the passivation layer 8 for the fifth time, using electron beam evaporation technology at a vacuum degree of less than 1.8×10 -3 Pa, a power range of 200-1000W, and an evaporation rate of less than Under the process conditions, metal is deposited in the groove and on the passivation layer between the source 4 and the drain 5 to make a T-shaped grid field plate 10, and the T-shaped grid field plate is electrically connected to the gate, and the deposited The deposited metal is a metal combination of Ti/Pt/Au in thickness, that is, the lower layer is Ti, the middle layer is Pt, and the upper layer is Au. The deposited metal should completely fill the groove 9, and the distance c between the edge of the T-shaped gate field plate 10 near the drain and the edge of the groove 9 near the drain is 7.9 μm.
步骤I.在T形栅场板10上部以及钝化层8的其它区域上部淀积SiN,制作保护层11,如图3i。Step I. Deposit SiN on the upper part of the T-shaped gate field plate 10 and other regions of the passivation layer 8 to form a protective layer 11, as shown in FIG. 3i.
使用等离子体增强化学气相淀积技术在气体为NH3、N2及SiH4,气体流量分别为2.5sccm、950sccm和250sccm,温度、RF功率和压强分别为300℃、25W和950mTorr的工艺条件下,在T形栅场板10上部以及钝化层8的其它区域上部淀积SiN制作保护层11,其厚度为8μm,从而完成整个器件的制作。Using plasma-enhanced chemical vapor deposition technology, the gas is NH 3 , N 2 and SiH 4 , the gas flow rate is 2.5sccm, 950sccm and 250sccm, and the temperature, RF power and pressure are 300℃, 25W and 950mTorr. SiN is deposited on the top of the T-shaped gate field plate 10 and other regions of the passivation layer 8 to make a protective layer 11 with a thickness of 8 μm, thereby completing the fabrication of the entire device.
本发明的效果可通过以下仿真进一步说明。The effect of the present invention can be further illustrated by the following simulation.
对采用传统栅场板的高电子迁移率晶体管的势垒层与本发明器件的势垒层中的电场进行仿真,结果如图4,其中传统栅场板有效长度L与本发明T形栅场板有效总长度相等。The electric field in the potential barrier layer of the high electron mobility transistor that adopts traditional grid field plate and the potential barrier layer of the device of the present invention is simulated, and the result is as shown in Figure 4, wherein the traditional grid field plate effective length L and the T-shaped grid field of the present invention The effective overall length of the plates is equal.
由图4可以看出:采用传统栅场板的高电子迁移率晶体管在势垒层中的电场曲线只形成了2个近似相等的电场峰值,其在势垒层中的电场曲线所覆盖的面积很小,而本发明器件在势垒层中的电场曲线形成了3个近似相等的电场峰值,使得本发明器件在势垒层中的电场曲线所覆盖的面积大大增加,由于在势垒层中的电场曲线所覆盖的面积近似等于器件的击穿电压,说明本发明器件的击穿电压远远大于采用传统栅场板的高电子迁移率晶体管的击穿电压。It can be seen from Figure 4 that the electric field curve of the high electron mobility transistor using the traditional gate field plate in the barrier layer only forms two approximately equal electric field peaks, and the area covered by the electric field curve in the barrier layer is is very small, and the electric field curve of the device of the present invention in the potential barrier layer forms 3 approximately equal electric field peaks, so that the area covered by the electric field curve of the device of the present invention in the potential barrier layer is greatly increased, because in the potential barrier layer The area covered by the electric field curve is approximately equal to the breakdown voltage of the device, indicating that the breakdown voltage of the device of the present invention is far greater than the breakdown voltage of a high electron mobility transistor using a traditional gate field plate.
对于本领域的专业人员来说,在了解了本发明内容和原理后,能够在不背离本发明的原理和范围的情况下,根据本发明的方法进行形式和细节上的各种修正和改变,但是这些基于本发明的修正和改变仍在本发明的权利要求保护范围之内。For those skilled in the art, after understanding the content and principles of the present invention, they can make various amendments and changes in form and details according to the methods of the present invention without departing from the principles and scope of the present invention. But these amendments and changes based on the present invention are still within the protection scope of the claims of the present invention.
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