CN104387919A - Low-fading-tendency crease-proof antirust paint and preparation method thereof - Google Patents
Low-fading-tendency crease-proof antirust paint and preparation method thereof Download PDFInfo
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- CN104387919A CN104387919A CN201410630489.0A CN201410630489A CN104387919A CN 104387919 A CN104387919 A CN 104387919A CN 201410630489 A CN201410630489 A CN 201410630489A CN 104387919 A CN104387919 A CN 104387919A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a low-fading-tendency crease-proof antirust paint. The invention is characterized in that the antirust paint is prepared from the following raw materials in parts by weight: 3-5 parts of fine sheet glass, 2-3 parts of zirconia, 4-6 parts of titanium white, 3-4 parts of potassium silicate, 1-2 parts of triallyl isocyanurate, 1-2 parts of fumarate, 1-2 parts of 2,6-di-tert-butyl-para-cresol, 4-6 parts of aluminum tripolyphosphate, 2-3 parts of amine benzoate, 12-14 parts of melamine formaldehyde resin, 32-35 parts of E-44 epoxy resin, 1-2 parts of zinc cyanurate, 14-17 parts of amino resin, 10-13 parts of xylene, 10-15 parts of ethyl formate and 4-7 parts of assistant. The paint film has the advantages of high adhesive force, high hardness, high smoothness, low fading tendency, crease proofness and rust prevention; and the added assistant has the sound insulation function, and can reduce the injury of noise to the human body. The paint has the advantages of high cost performance and favorable decoration performance, and is worthy of popularization.
Description
Technical field
The present invention relates to a kind of paint and preparation method thereof, particularly one not wrinkle resistant rust-inhibiting paint of fugitive color and preparation method thereof.
Background technology
Coating, is called paint in Chinese tradition name.China's coating circle more authoritative " coating process " book is definition like this: " coating is a kind of material, and this material can be coated in article surface by different construction technologies, forms adhere well, has some strength, continuous print solid film.The film common name film of such formation, also known as paint film or coating." equipment box such as present many power transformation boxes, switch box is in outdoor; Working environment and severe; often expose to the sun and rain by wind; we varnish with lacquer on its surface usually for high temperature resistant, cold-resistant, the resistance to illumination of raising casing, the performance such as antirust; extend its work-ing life; the maintaining in reduction later stage obtains expense, but existing paint cannot meet the different requirements of distinct device.
Summary of the invention
The object of this invention is to provide one not wrinkle resistant rust-inhibiting paint of fugitive color and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
One is the wrinkle resistant rust-inhibiting paint of fugitive color not, be made up of the raw material of following weight part: trickle sheet glass 3-5, zirconium white 2-3, titanium dioxide 4-6, potassium silicate 3-4, iso-cyanuric acid triallyl ester 1-2, fumarate 1-2,2,6 ditertiary butyl p cresol 1-2, aluminium triphosphate 4-6, Ammonium benzoate 2-3, terpolycyantoamino-formaldehyde resin 12-14, E-44 epoxy resin 32-35, cyanuric acid zinc 1-2, aminoresin 14-17, dimethylbenzene 10-13, ethyl formate 10-15, auxiliary agent 4-7;
Described auxiliary agent is made up of the raw material of following weight part: urotropine 3-5, tallow amine 3-4, benzotriazole 5-7, methyl acrylate 3-5, β-dimethyl-aminoethylmethacrylate 8-12,2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate 1-2, ethanol 15-20, shellac 4-6, organobentonite 8-12, fatty alcohol-polyoxyethylene ether 0.4-0.8, propylene glycol fatty acid ester 1-2, diethylenetriamine 1-2, di-t-butyl peroxide 1-2, corundum-mullite powder 7-11, glass fibre 7-10, carbon fiber 3-5, polyoxyethylene 2-4, deionized water 4-6; Preparation method is that organobentonite, corundum-mullite powder, shellac and ethanol are added in high-speed mixer by (1), high-speed stirring 10-20 minute, be heated to 60-80 ° of C, add diethylenetriamine, di-t-butyl peroxide, methyl acrylate and β-dimethyl-aminoethylmethacrylate again, continue stirring reaction 1-2 hour; (2) glass fibre, carbon fiber, fatty alcohol-polyoxyethylene ether, polyoxyethylene and deionized water are mixed, high speed shear forms liquid mixture; (3) product of step (2) to be added in fluidized-bed with Air Fluidized, to be sprayed on the product of step (1), then add all the other surplus materialss and fully grind.
One of the present invention is the wrinkle resistant rust-inhibiting paint of fugitive color not, is made up of following concrete steps:
(1) trickle sheet glass, zirconium white, titanium dioxide, aluminium triphosphate are added in the mixing solutions of dimethylbenzene and ethyl formate, ultrasonic disperse 20-30 minute, 2,6 ditertiary butyl p cresol, fumarate, auxiliary agent continuation stirring reaction 30-40 minute is added when being heated to 50-80 ° of C;
(2) product of step (1) is continued raised temperature to 70-90 ° of C, add terpolycyantoamino-formaldehyde resin, E-44 epoxy resin, aminoresin, iso-cyanuric acid triallyl ester, 1200-1400 rev/min of lower high-speed mixing stirring reaction 1-2 hour;
(3) surplus materials is added in the product of step (2), is added to grinding machine for grinding after mixing and is uniformly dispersed, filter and obtain the material that fineness is 20-40 μm, pack.
Advantage of the present invention is: paint film forming postadhesion power of the present invention is high, hardness is high, paint film is smooth, and not fugitive color, wrinkle resistant and antirust function, and the auxiliary agent that the present invention adds also has the function of noise elimination, can reduce the injury of noise to human body.Paint cost performance of the present invention is high, and decorate properties is good, is worthy to be popularized.
specific embodiments
Below by specific examples, the present invention is described in detail.
One is the wrinkle resistant rust-inhibiting paint of fugitive color not, be made up of the raw material of following weight part (kilogram): trickle sheet glass 4, zirconium white 3, titanium dioxide 4, potassium silicate 4, iso-cyanuric acid triallyl ester 1, fumarate 1,2,6 ditertiary butyl p cresol 2, aluminium triphosphate 4, Ammonium benzoate 2, terpolycyantoamino-formaldehyde resin 13, E-44 epoxy resin 33, cyanuric acid zinc 2, aminoresin 16, dimethylbenzene 12, ethyl formate 14, auxiliary agent 5;
Described auxiliary agent is made up of the raw material of following weight part (kilogram): urotropine 3, tallow amine 4, benzotriazole 5, methyl acrylate 4, β-dimethyl-aminoethylmethacrylate 10,2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate 2, ethanol 18, shellac 4, organobentonite 10, fatty alcohol-polyoxyethylene ether 0.7, propylene glycol fatty acid ester 1, diethylenetriamine 1, di-t-butyl peroxide 1, corundum-mullite powder 7, glass fibre 8, carbon fiber 5, polyoxyethylene 4, deionized water 6; Preparation method is that organobentonite, corundum-mullite powder, shellac and ethanol are added in high-speed mixer by (1), high-speed stirring 10-20 minute, be heated to 60-80 ° of C, add diethylenetriamine, di-t-butyl peroxide, methyl acrylate and β-dimethyl-aminoethylmethacrylate again, continue stirring reaction 1-2 hour; (2) glass fibre, carbon fiber, fatty alcohol-polyoxyethylene ether, polyoxyethylene and deionized water are mixed, high speed shear forms liquid mixture; (3) product of step (2) to be added in fluidized-bed with Air Fluidized, to be sprayed on the product of step (1), then add all the other surplus materialss and fully grind.
One of the present invention is the wrinkle resistant rust-inhibiting paint of fugitive color not, is made up of following concrete steps:
(1) trickle sheet glass, zirconium white, titanium dioxide, aluminium triphosphate are added in the mixing solutions of dimethylbenzene and ethyl formate, ultrasonic disperse 20-30 minute, 2,6 ditertiary butyl p cresol, fumarate, auxiliary agent continuation stirring reaction 30-40 minute is added when being heated to 50-80 ° of C;
(2) product of step (1) is continued raised temperature to 70-90 ° of C, add terpolycyantoamino-formaldehyde resin, E-44 epoxy resin, aminoresin, iso-cyanuric acid triallyl ester, 1200-1400 rev/min of lower high-speed mixing stirring reaction 1-2 hour;
(3) surplus materials is added in the product of step (2), is added to grinding machine for grinding after mixing and is uniformly dispersed, filter and obtain the material that fineness is 20-40 μm, pack.
Paint outward appearance of the present invention is without the phenomenon of skinning and lump, snappiness is tested: 50mm, experiment of hardness: 3H, sticking power experiment (cross-hatching)≤1 grade, resistance to salt water experiment (sodium-chlor of 3%, 15d): bubble-free, nothing are peeled off, thermotolerance experiment (100 ± 2 DEG C, 4h): no sag, nothing cracking wrinkling without foaming, recombination loss factor: 20 ° of C:0.087,40 ° of C:0.113.
Claims (2)
1. the not wrinkle resistant rust-inhibiting paint of fugitive color, it is characterized in that, be made up of the raw material of following weight part: trickle sheet glass 3-5, zirconium white 2-3, titanium dioxide 4-6, potassium silicate 3-4, iso-cyanuric acid triallyl ester 1-2, fumarate 1-2,2,6 ditertiary butyl p cresol 1-2, aluminium triphosphate 4-6, Ammonium benzoate 2-3, terpolycyantoamino-formaldehyde resin 12-14, E-44 epoxy resin 32-35, cyanuric acid zinc 1-2, aminoresin 14-17, dimethylbenzene 10-13, ethyl formate 10-15, auxiliary agent 4-7;
Described auxiliary agent is made up of the raw material of following weight part: urotropine 3-5, tallow amine 3-4, benzotriazole 5-7, methyl acrylate 3-5, β-dimethyl-aminoethylmethacrylate 8-12,2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate 1-2, ethanol 15-20, shellac 4-6, organobentonite 8-12, fatty alcohol-polyoxyethylene ether 0.4-0.8, propylene glycol fatty acid ester 1-2, diethylenetriamine 1-2, di-t-butyl peroxide 1-2, corundum-mullite powder 7-11, glass fibre 7-10, carbon fiber 3-5, polyoxyethylene 2-4, deionized water 4-6; Preparation method is that organobentonite, corundum-mullite powder, shellac and ethanol are added in high-speed mixer by (1), high-speed stirring 10-20 minute, be heated to 60-80 ° of C, add diethylenetriamine, di-t-butyl peroxide, methyl acrylate and β-dimethyl-aminoethylmethacrylate again, continue stirring reaction 1-2 hour; (2) glass fibre, carbon fiber, fatty alcohol-polyoxyethylene ether, polyoxyethylene and deionized water are mixed, high speed shear forms liquid mixture; (3) product of step (2) to be added in fluidized-bed with Air Fluidized, to be sprayed on the product of step (1), then add all the other surplus materialss and fully grind.
2. the one not wrinkle resistant rust-inhibiting paint of fugitive color according to claim 1, is characterized in that, be made up of following concrete steps:
(1) trickle sheet glass, zirconium white, titanium dioxide, aluminium triphosphate are added in the mixing solutions of dimethylbenzene and ethyl formate, ultrasonic disperse 20-30 minute, 2,6 ditertiary butyl p cresol, fumarate, auxiliary agent continuation stirring reaction 30-40 minute is added when being heated to 50-80 ° of C;
(2) product of step (1) is continued raised temperature to 70-90 ° of C, add terpolycyantoamino-formaldehyde resin, E-44 epoxy resin, aminoresin, iso-cyanuric acid triallyl ester, 1200-1400 rev/min of lower high-speed mixing stirring reaction 1-2 hour;
(3) surplus materials is added in the product of step (2), is added to grinding machine for grinding after mixing and is uniformly dispersed, filter and obtain the material that fineness is 20-40 μm, pack.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410630489.0A CN104387919A (en) | 2014-11-11 | 2014-11-11 | Low-fading-tendency crease-proof antirust paint and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410630489.0A CN104387919A (en) | 2014-11-11 | 2014-11-11 | Low-fading-tendency crease-proof antirust paint and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN104387919A true CN104387919A (en) | 2015-03-04 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410630489.0A Pending CN104387919A (en) | 2014-11-11 | 2014-11-11 | Low-fading-tendency crease-proof antirust paint and preparation method thereof |
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| CN (1) | CN104387919A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105419502A (en) * | 2016-01-07 | 2016-03-23 | 苏州法斯特信息科技有限公司 | Method for preparing environment-friendly coating containing polyoxyethylene |
Citations (7)
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| WO2004048428A1 (en) * | 2002-11-27 | 2004-06-10 | The University Of Melbourne | Microgel composition and process for preparation thereof |
| CN101376790A (en) * | 2007-08-30 | 2009-03-04 | 比亚迪股份有限公司 | Anti-corrosive paint for magnesium alloy and preparation thereof |
| CN101781512A (en) * | 2010-01-29 | 2010-07-21 | 立邦涂料(常州)有限公司 | High acid-resistant environment coil steel coating |
| CN101935498A (en) * | 2010-09-25 | 2011-01-05 | 江门市制漆厂有限公司 | Heat-resisting organic silicon antiseptic inner tank coating |
| US20120295996A1 (en) * | 2011-04-08 | 2012-11-22 | Minji Wang | Fire Retardant Composition |
| CN103351738A (en) * | 2013-06-19 | 2013-10-16 | 天长市驰程电子科技有限公司 | Fluororesin heat dissipation coating and preparation method thereof |
| CN103382319A (en) * | 2013-06-27 | 2013-11-06 | 马鞍山采石矶涂料有限公司 | Epoxy impregnated resin and preparation method thereof |
-
2014
- 2014-11-11 CN CN201410630489.0A patent/CN104387919A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004048428A1 (en) * | 2002-11-27 | 2004-06-10 | The University Of Melbourne | Microgel composition and process for preparation thereof |
| CN101376790A (en) * | 2007-08-30 | 2009-03-04 | 比亚迪股份有限公司 | Anti-corrosive paint for magnesium alloy and preparation thereof |
| CN101781512A (en) * | 2010-01-29 | 2010-07-21 | 立邦涂料(常州)有限公司 | High acid-resistant environment coil steel coating |
| CN101935498A (en) * | 2010-09-25 | 2011-01-05 | 江门市制漆厂有限公司 | Heat-resisting organic silicon antiseptic inner tank coating |
| US20120295996A1 (en) * | 2011-04-08 | 2012-11-22 | Minji Wang | Fire Retardant Composition |
| CN103351738A (en) * | 2013-06-19 | 2013-10-16 | 天长市驰程电子科技有限公司 | Fluororesin heat dissipation coating and preparation method thereof |
| CN103382319A (en) * | 2013-06-27 | 2013-11-06 | 马鞍山采石矶涂料有限公司 | Epoxy impregnated resin and preparation method thereof |
Non-Patent Citations (1)
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105419502A (en) * | 2016-01-07 | 2016-03-23 | 苏州法斯特信息科技有限公司 | Method for preparing environment-friendly coating containing polyoxyethylene |
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Application publication date: 20150304 |