CN104382758B - One kind zero adds emulsion and preparation method thereof - Google Patents
One kind zero adds emulsion and preparation method thereof Download PDFInfo
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- CN104382758B CN104382758B CN201410695958.7A CN201410695958A CN104382758B CN 104382758 B CN104382758 B CN 104382758B CN 201410695958 A CN201410695958 A CN 201410695958A CN 104382758 B CN104382758 B CN 104382758B
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- deionized water
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Abstract
Emulsion is added the invention provides one kind zero, it is characterised in that including following components in percentage by weight：Isononyl isononanoate 8.0%~14.0%, tocopherol acetate 0.5%, olive oil 3.0%~8.0%, pectin 0.8%, xanthans 0.3%~0.5%, gellan gum 0.4%~0.6%, glycerine 6%, pungent glycol 0.8%, beta glucan 2.0%, sodium hydroxide 0.05%, deionized water surplus.The emulsion of the present invention is free of emulsifying agent, and natural green, stability is splendid.
Description
Technical field
The invention belongs to cosmetic field, and in particular to it is a kind of zero addition emulsion, and the emulsion preparation method.
Background technology
Emulsion cosmetic is also known as emulsified body cosmetics, and it under a kind of white class cosmetics of liquid, normal temperature is in fluid state to be, is
The mixture mixed by a variety of water-soluble components and oil-soluble constitents, acts on good moisturizing, both can be skin
Moisture content is supplemented, can also be prevented moisture evaporation in skin surface formation oil film, maintain skin appropriate aqueous amount, can also be carried for skin
For nutrition, alleviate outside stimulus, delay skin aging.
Generally, in order to form stable emulsion, it is often necessary to emulsifying agent or surfactant are added, so as to drop
The surface tension of low two-phase liquid, makes one of which liquid uniformly and stably be dispersed in another liquid, it is to avoid point of emulsion
The problems such as layer, sedimentation, flocculation, coalescence, occurs.However, emulsifying agent and surfactant often produce certain excitant, hold
Easily sensitive skin is set to occur stimulating and dehydration problem.Simultaneously as the presence of emulsifying agent, add emulsion sprawls resistance, show
Obtain texture more thick and heavy and sticky.
The content of the invention
It is an object of the invention to the technical problem to be solved for more than, there is provided a kind of without emulsifying agent, natural
, green, the emulsion of good stability.
It is a further object to provide the preparation method of above-mentioned emulsion.
To achieve the above objectives, the invention provides following technical scheme：
One kind zero adds emulsion, it is characterised in that consist of the following components in percentage by weight：
Isononyl isononanoate 8.0%~14.0%,
Tocopherol acetate 0.5%,
Olive oil 3.0%~8.0%,
Pectin 0.8%,
Xanthans 0.3%~0.5%,
Gellan gum 0.4%~0.6%,
Glycerine 6%,
Pungent glycol 0.8%,
Beta glucan 2.0%,
Sodium hydroxide 0.05%,
Deionized water surplus.
Preferably, zero addition emulsion of the invention is consisted of the following components in percentage by weight：
Isononyl isononanoate 8.0%~12.0%,
Tocopherol acetate 0.5%,
Olive oil 5.0%~8.0%,
Pectin 0.8%,
Xanthans 0.3%~0.5%,
Gellan gum 0.4%~0.6%,
Glycerine 6%,
Pungent glycol 0.8%,
Beta glucan 2.0%,
Sodium hydroxide 0.05%,
Deionized water surplus.
Present invention also offers the preparation method of described zero addition emulsion, its step is as follows：
(1) pectin, xanthans and gellan gum are added in isononyl isononanoate, tocopherol acetate and olive oil, together
Oil phase pot is added, stirring is opened, 80 DEG C are warming up to, 5 minutes are incubated；
(2) appropriate amount of deionized water is reserved, remaining deionized water and glycerine are sequentially added in emulsification pot, stirring is opened mixed
Close uniform, and be warming up to 80 DEG C, be incubated 20 minutes, the material of step (1) is slowly pumped into emulsification pot, homogeneous 10 minutes, cooling；
(3) sodium hydroxide is well mixed with above-mentioned reserved appropriate amount of deionized water, when pot to be emulsified is cooled to 60 DEG C, plus
Enter and emulsify pot, and stir, pH value is 4.5~6.5；
(4) when stirring is cooled to less than 45 DEG C, pungent glycol and beta glucan are added, homogeneous simultaneously stirs；It is down to 38 DEG C
When discharge.
Preferably, the appropriate amount of deionized water and the mass ratio of sodium hydroxide that the step (2) is reserved are 4：1.
Compared with prior art, emulsion of the invention has advantages below：
(1) any emulsifying agent and surfactant is not contained, compared with traditional emulsifying product, with higher peace
Quan Xing；
(2) traditional emulsifying technology and theory are breached, be made it is stable, can industrialized production oil-in-water type product；
(3) suspension thick stabilization system used in this product is natural, green, environmental protection, renewable and can be complete
Degradable；
(4) zero addition emulsion skin sense of the invention is splendid, slim and graceful soft and smooth, moistens and is easy to absorb.
Embodiment
Technical scheme is described in further detail with reference to specific embodiment, but protection scope of the present invention
It is not limited in following examples.
Each component is weighed according to following percentage by weight, following each component can be bought by commercial channel and be obtained.
The emulsion described in embodiment 1~3 is prepared, its step is as follows：
1. pectin, xanthans and gellan gum are added in isononyl isononanoate, tocopherol acetate and olive oil, add together
Enter oil phase pot, open stirring, be warming up to 80 DEG C, be incubated 5 minutes；
2. the raw material of B component is sequentially added in emulsification pot, unlatching is uniformly mixed, and is warming up to 80 DEG C, insulation 20
Minute, the raw material of component A is slowly pumped into emulsification pot, homogeneous 10 minutes, cooling；
3. component C is well mixed, when emulsification pot drops to 60 DEG C, adds in emulsification pot, stir；PH value range：
4.5~6.5；
4. stirring is cooled to less than 45 DEG C, D components are added, homogeneous simultaneously stirs；Discharged when being down to 38 DEG C.
Product stability is assessed
1. temperature stability test
(1) 48 DEG C of stability test：
Test sample：1 or more
Testing time：4 weeks method of testings：Product (content) is fitted into 30mL PET bottle, it is labelled, indicate production
The information such as the name of an article claims, be formulated number, test condition, testDate, are placed in the heat-resisting steady of test product in 48 DEG C of biochemical cultivation case
It is qualitative, (recovered to room temperature) to observe the outward appearance of product, smell, pH, the change of viscosity respectively at 24 hours, 1 week, 2 weeks, 4 weeks,
And the change of day part is recorded into report.
(2) 40 DEG C of stability tests：
Test sample：1 or more
Testing time：12 weeks
Method of testing：Product (content) is fitted into 30ML PET bottle, it is labelled, indicate name of product, formula
Number, the information such as test condition, testDate, be placed in the heat-resistant stability of test product in 40 DEG C of biochemical cultivation case, exist respectively
The outward appearance of (recovery to room temperature) observation product, smell, pH, the change of viscosity at 24 hours, 1 week, 2 weeks, 4 weeks, 8 weeks and 12 weeks,
And the change of day part is recorded into report.
(3) room temperature (Ambient) stability test：
Test sample：1 or more
Testing time：12 weeks
Method of testing：Product (content) is fitted into 30ML PET bottle, it is labelled, indicate name of product, formula
Number, the information such as test condition, testDate, be placed in sample cabinet, respectively 24 hours (surveying pH value, viscosimetric), 1 week, 2 weeks, 4
The outward appearance of observation product, smell, pH, the change of viscosity when week, 8 weeks and 12 weeks (survey pH value), and by the change of day part, record
Enter in report.
(4) -18 DEG C of stability tests：
Test sample：1 or more
Testing time：12 weeks
Method of testing：Product (content) is fitted into 30ML PET bottle, it is labelled, indicate name of product, formula
Number, the information such as test condition, testDate, be placed in the cold-resistant stability of test product in -18 DEG C of refrigerators, respectively 24 hours, 1
The outward appearance of (recovery to room temperature) observation product, smell, pH, the change of viscosity when week, 2 weeks, 4 weeks, 8 weeks and 12 weeks, and when will be each
The change of section, is recorded into report.
(5) 48 DEG C and -18 DEG C of cyclical stability tests
Test sample：1 or more
Testing time：Continuous three loop tests (after first being placed 24 hours in 48 DEG C of biochemical cultivation cases, are put at room temperature
Put 24 hours, be then placed within -18 DEG C of refrigerators 24 hours, then recover to be one to room temperature again to circulate and observe result).
Method of testing：Product (content) is fitted into 30ML PET bottle, it is labelled, indicate name of product, formula
Number, the information such as test condition, testDate, be placed in 48 DEG C of biochemical cultivation case 24 hours, place 24 hours at room temperature, so
After be placed in -18 DEG C of refrigerators 24 hours, then recover again to room temperature.Observe product when resisting cold heat-resisting alternate cycles product it is outer
The change of sight, smell, PH, viscosity etc., and be recorded into report.
2. sun light stability test
Test sample：1 or more
Testing time：4 weeks
Sun light stability test：Product (content) is fitted into 30ML PET bottle, it is labelled, indicate ProductName
The information such as title, formula number, test condition, testDate, is placed on west place near the window (label facing away from sunshine), respectively
(recovered to room temperature) outward appearance, the change of smell of observation product at 24 hours, 1 week, 2 weeks, 4 weeks, and by the change of day part,
It is recorded into report.
Stability result：Zero addition emulsion of the gained of embodiment 1 to 3 is carried out using above-mentioned 6 kinds of stability test methods
Test, by the stability test of 12 weeks, every stability test result was shown, zero addition stability of emulsion of embodiment 1 to 3
Preferably, the provisions of laws and regulations of correlation is complied fully with.
Product Safety assesses (human skin patch result)
1. tested material：Cosmetics finished product (emulsion).
2. negative control：Blank control.
3. subject：Totally 40 people, male 15 people, the people of female 25,18~30 years old age, meet subject's aspiration inclusion criteria.
4. spot method for testing：Try device from qualified spot, in closed patch test method, by tested material about 0.02ml~
0.025ml is applied in spot examination device, and external application special adhesive tape is pasted on the bent side of subject's forearm, and tested material is removed after 24 hours, in going
Except 30min after tested material spot examination device, after observing dermoreaction after impression disappearance, press《Cosmetics health specification》In (version in 2007)
Dermoreaction grade scale records its result.
5. evaluation of result：According to the form below (skin adverse reaction grade scale) records reaction result.
6. result of the test (see the table below)：
Human skin patch result is shown：In embodiments of the invention 1~3,40 subjects skins are all in the moon
Property reaction (grading system：0 grade).Foundation《Cosmetics health specification》(version in 2007) human body skin class patch experiment criterion,
Sample is to human body without skin adverse reaction.And reference examples (commercially available domestic famous brand name emulsion) have 2 subjects to occur 1 grade instead
Should.
According to the reflection of user, zero addition emulsion skin sense of the invention is splendid, slim and graceful soft and smooth, moistens and is easy to absorb.
Claims (2)
1. one kind zero adds emulsion, it is characterised in that consist of the following components in percentage by weight：
Isononyl isononanoate 8.0%~14.0%,
Tocopherol acetate 0.5%,
Olive oil 3.0%~8.0%,
Pectin 0.8%,
Xanthans 0.3%~0.5%,
Gellan gum 0.4%~0.6%,
Glycerine 6%,
Pungent glycol 0.8%,
Beta glucan 2.0%,
Sodium hydroxide 0.05%,
Deionized water surplus；
The preparation method of zero described addition emulsion, its step is as follows：
（1）Pectin, xanthans and gellan gum are added in isononyl isononanoate, tocopherol acetate and olive oil, added together
Oil phase pot, opens stirring, is warming up to 80 DEG C, is incubated 5 minutes；
（2）Reserved appropriate amount of deionized water, remaining deionized water and glycerine are sequentially added in emulsification pot, open stirring mixing equal
It is even, and it is warming up to 80 DEG C, insulation 20 minutes, by step（1）Material be slowly pumped into emulsification pot, homogeneous 10 minutes, cooling；
（3）Sodium hydroxide is well mixed with above-mentioned reserved appropriate amount of deionized water, when pot to be emulsified is cooled to 60 DEG C, breast is added
Change pot, and stir, pH value is 4.5~6.5；
（4）When stirring is cooled to less than 45 DEG C, pungent glycol and beta glucan are added, homogeneous simultaneously stirs；Go out when being down to 38 DEG C
Material.
2. zero addition emulsion according to claim 1, it is characterised in that consist of the following components in percentage by weight：
Isononyl isononanoate 8.0%~12.0%,
Tocopherol acetate 0.5%,
Olive oil 5.0%~8.0%,
Pectin 0.8%,
Xanthans 0.3%~0.5%,
Gellan gum 0.4%~0.6%,
Glycerine 6%,
Pungent glycol 0.8%,
Beta glucan 2.0%,
Sodium hydroxide 0.05%,
Deionized water surplus.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410695958.7A CN104382758B (en) | 2014-11-25 | 2014-11-25 | One kind zero adds emulsion and preparation method thereof |
| HK15105694.1A HK1204957A1 (en) | 2014-11-25 | 2015-06-16 | Emulsifier-free emulsion and preparation method thereof |
| TW104119707A TWI604855B (en) | 2014-11-25 | 2015-06-18 | Emulsifier-free emulsion and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410695958.7A CN104382758B (en) | 2014-11-25 | 2014-11-25 | One kind zero adds emulsion and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104382758A CN104382758A (en) | 2015-03-04 |
| CN104382758B true CN104382758B (en) | 2017-08-22 |
Family
ID=52600793
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410695958.7A Expired - Fee Related CN104382758B (en) | 2014-11-25 | 2014-11-25 | One kind zero adds emulsion and preparation method thereof |
Country Status (3)
| Country | Link |
|---|---|
| CN (1) | CN104382758B (en) |
| HK (1) | HK1204957A1 (en) |
| TW (1) | TWI604855B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105168080B (en) * | 2015-08-27 | 2018-06-19 | 广州智媛生物科技有限公司 | A kind of dual whitening emulsion and preparation method thereof |
| CN105456052A (en) * | 2015-12-25 | 2016-04-06 | 肇庆迪彩日化科技有限公司 | Skin care composition |
| CN106214532B (en) * | 2016-07-26 | 2019-04-19 | 广州智媛生物科技有限公司 | Composition and preparation method thereof with oil-control bacteriostasis efficacy |
| CN107232581B (en) * | 2017-06-29 | 2020-08-14 | 河南鼎元食品科技有限公司 | Quick-frozen rice and flour food quality improver and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101410172A (en) * | 2005-11-23 | 2009-04-15 | 雀巢技术公司 | Oil-in-water emulsion for creating new product consistencies |
| CN103405379A (en) * | 2013-07-29 | 2013-11-27 | 广州丹奇日用化工厂有限公司 | Cosmetic composition rich in amino acids and application of cosmetic composition in skin care product |
| US20140271508A1 (en) * | 2013-03-15 | 2014-09-18 | Mary Kay Inc. | Cosmetic compositions and uses thereof |
| CN104146922A (en) * | 2014-08-26 | 2014-11-19 | 广州神采化妆品有限公司 | Sun-blocking and moisturizing composition and preparation method thereof |
-
2014
- 2014-11-25 CN CN201410695958.7A patent/CN104382758B/en not_active Expired - Fee Related
-
2015
- 2015-06-16 HK HK15105694.1A patent/HK1204957A1/en unknown
- 2015-06-18 TW TW104119707A patent/TWI604855B/en not_active IP Right Cessation
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101410172A (en) * | 2005-11-23 | 2009-04-15 | 雀巢技术公司 | Oil-in-water emulsion for creating new product consistencies |
| US20140271508A1 (en) * | 2013-03-15 | 2014-09-18 | Mary Kay Inc. | Cosmetic compositions and uses thereof |
| CN103405379A (en) * | 2013-07-29 | 2013-11-27 | 广州丹奇日用化工厂有限公司 | Cosmetic composition rich in amino acids and application of cosmetic composition in skin care product |
| CN104146922A (en) * | 2014-08-26 | 2014-11-19 | 广州神采化妆品有限公司 | Sun-blocking and moisturizing composition and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| TW201622692A (en) | 2016-07-01 |
| TWI604855B (en) | 2017-11-11 |
| CN104382758A (en) | 2015-03-04 |
| HK1204957A1 (en) | 2015-12-11 |
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