Background technology
Soil is the valuable source that the mankind depend on for existence, but saline Land causes the destruction of resource, and the massive losses of agriculture production and the threat to biosphere and ecotope, show the harm of environment and economy two aspect.Salination process is normal with the association of Desertification Process phase in addition, even mutually promotes and mutually transforms, bring a series of environmental problem, the sustainable development of impact agricultural, and final life and the health affecting the mankind.And develop saltings and not only can bring more land under cultivation, increase yield per unit, thus improve total output of grain, alleviate crisis in food; And can green coverage be expanded, improvement ecotope, improves the life of people, brings economic benefit and environmental benefit.
Saltings is a kind of salt aggregation, and refer to that salinity contained inside soil has influence on the normal growth of crop, saltings is utilizing in the middle of process, briefly, can be divided into light saltings, moderate saline-alkali soil and heavy saline.Light saltings refers to that its seedling rate is at 70%-80%, and its saltiness is below 3/1000ths; Heavy saline refers to that its saltiness is more than 6/1000ths, and seedling rate is lower than 50%; This block middle is exactly that (be expressed as by pH value: slight alkaline land pH value is: 7.1-8.5, moderate saline-alkali soil pH value is moderate saline-alkali soil: 8.5-9.5, and heavy salinized ground pH value is: more than 9.5).At present along with the development of science and technology, should only not see disadvantageous one side, more it should be regarded as very precious land resources, because there are many biologies to comprise plant, comprise microorganism, can adapt to this environment, and increasing scientific worker is just putting into the enthusiasm of having one's bosom filled with among the work in improvement saltings, the work of administering saltings is bound to obtain final triumph.
According to UNESCO and food and agricultural organization's incomplete statistics, the area in saltings, the whole world is 9.5438 hundred million hectares, wherein China is 9,913 ten thousand hectares, for a long time, extensive and deep research has all been carried out in the domestic improvement to saline and alkaline soil, also improvement and the administering method in multiple saline and alkaline soil has been explored, these methods can be divided into physically improved method substantially, chemical modifying method, biological modification method and synthesis improvement method, although these methods all achieve certain achievement, but ubiquity engineering cost is high, improved effect is not obvious, can not durable applications, be difficult to the technical problems such as spread, therefore be necessary to work out one fast, efficiently, the saline-alkali soil conditioner of persistent.
In view of this, special proposition the present invention.
Summary of the invention
The object of the present invention is to provide the saline-alkali soil conditioner of a kind of environmental protection, economy, efficient, persistent, improvement and the improvement in various saltings can be adapted to, have raw material resources enrich, with low cost, be easy to the advantage that configures.
In order to realize above-mentioned purpose of the present invention, spy by the following technical solutions:
A kind of saline-alkali soil conditioner, by quality ratio, formulated by following water soluble ingredient: ureasulfuric acid 3-13%, organic acid 8-18%, calcium superphosphate 2-8%, poly aspartic acid compounds 3-12%, surplus is water.
The present invention is raw materials used is component soluble in water, is convenient to preparation and uses, reasonable ratio of the present invention, science, and each component is coordinated together, discharges hydrogen ion fast, the alkalescence during energy is rapid and in salt affected soil, thus realizes " falling alkali " object; The present invention had both comprised organic constituents and had also comprised inorganics component, each component is coordinated together, reduce the content activating sodium ion in soil, thus realize " desalination " object, the osmotic pressure in saltings can be improved, increase enzyme activity in plant materials, polymer-metal complex can be formed with the heavy metal ion in salt affected soil, reduce heavy metal to the pollution of soil, the content of Nitrogen In Soils, phosphorus, sulphur can be increased, can promote that farm crop are to absorption of trace elements such as iron, zinc, manganese.
Saline-alkali soil conditioner low cost of raw materials of the present invention, environmental protection, can not only realize falling alkali desalination to salt affected soil, the physico-chemical property of soil can also be improved, increase soil fertility, for plant root system development creates good growing environment, reach maintenance, improve the effect of soil.
Preferably, above-mentioned saline-alkali soil conditioner, by quality ratio, formulated by following water soluble ingredient: ureasulfuric acid 6-10%, organic acid 10-15%, calcium superphosphate 3-8%, poly aspartic acid compounds 7-10%, surplus is water.
Preferably, above-mentioned saline-alkali soil conditioner, by quality ratio, formulated by following water soluble ingredient: ureasulfuric acid 7-9%, organic acid 10-13%, calcium superphosphate 4-6%, poly aspartic acid compounds 7-9%, surplus is water.
Preferably, organic acid described in above-mentioned saline-alkali soil conditioner is low molecular weight organic acid.
Preferably, above-mentioned saline-alkali soil conditioner, described low molecular weight organic acid is oxysuccinic acid, citric acid, and in oxalic acid, any one, be preferably oxysuccinic acid.
The preferred low molecular weight organic acid of saline-alkali soil conditioner of the present invention, dissociate rapidly place a large amount of hydrionic while, also can provide a large amount of carboxyl, demonstrate stronger complexing action, and be the normocrinic material of root system of plant, can not the problems such as soil compaction be caused.
Oxysuccinic acid, citric acid, oxalic acid is non-volatile low molecular weight organic acid, it can be used as raw material of the present invention, effect has more advantage, and not volatile, water-soluble rear effective constituent is able to maximum reservation, wherein, in water, solubleness is maximum, and the oxysuccinic acid of stable in properties is best.
Preferably, above-mentioned saline-alkali soil conditioner, described poly aspartic acid compounds comprises poly aspartic acid, poly aspartic acid sodium salt, poly aspartic acid sylvite, and in poly aspartic acid ammonium salt, any one, be preferably poly aspartic acid.
Saline-alkali soil conditioner raw material of the present invention is all soluble in water, and the product be mixed with is aqua, after water dissolution mixing, discharges each raw material active principle, can enter in soil fast and play a role.
The preparation method of saline-alkali soil conditioner of the present invention, comprise, calcium superphosphate, poly aspartic acid compounds and water are placed in reactor, start and stir and start to be warming up to 25-40 DEG C, keep 0.5-1 hour, then add ureasulfuric acid and organic acid, stirring is warming up to 50-60 DEG C, keep being cooled to 25-40 DEG C after 0.5-1 hour, finally, after inspection by sampling is qualified, carry out metering packing.
The standard of described inspection is: pH value is 2.0-3.0, water insoluble matter content <0.03g/L.
The application method of saline-alkali soil conditioner of the present invention, the usage quantity of saline-alkali soil conditioner is 0.5-10kg/ mu, and using method, for saline-alkali soil conditioner being added 100 times of weight water dilutions, joins after dilution in drip irrigation pipe to carry out dripping to soil and executes.
Compared with prior art, beneficial effect of the present invention is:
(1) salt affected soil is improved, improve soil physico-chemical characteristic, increase soil fertility, for plant root system development creates good growing environment, reach maintenance, improve the effect of soil, show as saltiness decline in soil, pH value declines, crop yield increases;
(2) product environment-protecting asepsis, cheap and easy to get, and save peasant's cost, increasing both production and income, produce huge society, economy and zoology benifit, development significance is great.
Embodiment
Below in conjunction with embodiment, embodiment of the present invention are described in detail, but it will be understood to those of skill in the art that the following example only for illustration of the present invention, and should not be considered as limiting the scope of the invention.Unreceipted actual conditions person in embodiment, the condition of conveniently conditioned disjunction manufacturers suggestion is carried out.Agents useful for same or the unreceipted production firm person of instrument, be and can buy by commercially available the conventional products obtained.
Embodiment 1
Raw material forms: ureasulfuric acid 3%, oxysuccinic acid 8%, calcium superphosphate 2%, poly aspartic acid 3%, water 84%.
Calcium superphosphate, poly aspartic acid and water are placed in reactor, start and stir and start to be warming up to 25-40 DEG C, keep 0.5 hour, then ureasulfuric acid and oxysuccinic acid is added, stirring is warming up to 50-60 DEG C, keep being cooled to 25-40 DEG C after 0.5 hour, finally, after inspection by sampling is qualified, carry out metering packing.
Embodiment 2
Raw material forms: ureasulfuric acid 5%, oxysuccinic acid 10%, calcium superphosphate 5%, poly-aspartic potassium 5%, water 75%.
Calcium superphosphate, poly-aspartic potassium and water are placed in reactor, start and stir and start to be warming up to 25-40 DEG C, keep 1 hour, then ureasulfuric acid and oxysuccinic acid is added, stirring is warming up to 50-60 DEG C, keep being cooled to 25-40 DEG C after 0.5 hour, finally, after inspection by sampling is qualified, carry out metering packing.
Embodiment 3
Raw material forms: ureasulfuric acid 6%, oxalic acid 10%, calcium superphosphate 8%, poly aspartic acid ammonium 7%, water 69%.
Calcium superphosphate, poly aspartic acid ammonium and water are placed in reactor, start and stir and start to be warming up to 25-40 DEG C, keep 0.5 hour, then add ureasulfuric acid and oxalic acid, stir and be warming up to 50-60 DEG C, keep being cooled to 25-40 DEG C after 1 hour, finally, inspection by sampling qualified after carry out metering packing.
Embodiment 4
Raw material forms: ureasulfuric acid 7%, citric acid 10%, calcium superphosphate 6%, poly aspartic acid 9%, water 68%.
Calcium superphosphate, poly aspartic acid and water are placed in reactor, start and stir and start to be warming up to 25-40 DEG C, keep 1 hour, then add ureasulfuric acid and citric acid, stir and be warming up to 50-60 DEG C, keep being cooled to 25-40 DEG C after 1 hour, finally, inspection by sampling qualified after carry out metering packing.
Embodiment 5
Raw material forms: ureasulfuric acid 9%, oxysuccinic acid 13%, calcium superphosphate 4%, poly-aspartic potassium 9%, water 65%.
Calcium superphosphate, poly-aspartic potassium and water are placed in reactor, start and stir and start to be warming up to 25-40 DEG C, keep 1 hour, then ureasulfuric acid and oxysuccinic acid is added, stirring is warming up to 50-60 DEG C, keep being cooled to 25-40 DEG C after 0.5 hour, finally, after inspection by sampling is qualified, carry out metering packing.
Embodiment 6
Raw material forms: ureasulfuric acid 8%, oxysuccinic acid 12%, calcium superphosphate 5%, poly (sodium aspartate) 8%, water 67%.
Calcium superphosphate, poly (sodium aspartate) and water are placed in reactor, start and stir and start to be warming up to 25-40 DEG C, keep 0.5 hour, then ureasulfuric acid and oxysuccinic acid is added, stirring is warming up to 50-60 DEG C, keep being cooled to 25-40 DEG C after 1 hour, finally, after inspection by sampling is qualified, carry out metering packing.
Embodiment 7
Raw material forms: ureasulfuric acid 10%, citric acid 15%, calcium superphosphate 8%, poly-asparagus fern ammonia ammonium 10%, water 57%.
Calcium superphosphate, poly aspartic acid ammonium and water are placed in reactor, start and stir and start to be warming up to 25-40 DEG C, keep 1 hour, then add ureasulfuric acid and citric acid, stir and be warming up to 50-60 DEG C, keep being cooled to 25-40 DEG C after 1 hour, finally, inspection by sampling qualified after carry out metering packing.
Embodiment 8
Raw material forms: ureasulfuric acid 13%, oxalic acid 18%, calcium superphosphate 8%, poly (sodium aspartate) 12%, water 49%.
Calcium superphosphate, poly (sodium aspartate) and water are placed in reactor, start and stir and start to be warming up to 25-40 DEG C, keep 1 hour, then add ureasulfuric acid and oxalic acid, stir and be warming up to 50-60 DEG C, keep being cooled to 25-40 DEG C after 1 hour, finally, inspection by sampling qualified after carry out metering packing.
Embodiment 9
Raw material forms: ureasulfuric acid 13%, oxysuccinic acid 18%, calcium superphosphate 8%, poly aspartic acid 12%, water 49%.
Calcium superphosphate, poly (sodium aspartate) and water are placed in reactor, start and stir and start to be warming up to 25-40 DEG C, keep 1 hour, then add ureasulfuric acid and oxalic acid, stir and be warming up to 50-60 DEG C, keep being cooled to 25-40 DEG C after 1 hour, finally, inspection by sampling qualified after carry out metering packing.
The saline-alkali soil conditioner prepared embodiment 1-9 respectively label is 1,2,3 ... 8,9, carry out inspection by sampling, result shows: the pH of 1-9 product is at 2.0-3.0, and the content of water-insoluble is all lower than 0.03g/L.
Experimental example 1
Promoted the use of in Alar region, Xinjiang by product of the present invention, in alura 200 mu of saltingss, plant 100 mu, Sunflower Receptacle, these 100 mu of ground are distinguished into each 25 mu of four bulk region, and its detected result is as follows.
The total salt of table 1 and pH detected result
From the detected result of table 1, after using saline-alkali soil conditioner of the present invention, the salt concn amount of decrease of salt affected soil is greater than 23%, pH amount of decrease and is greater than 20%, and along with increasing gradually of consumption, salt concn amount of decrease and pH amount of decrease also increase gradually, and improved effect is remarkable gradually.
Table 2 hybrid oil-sunflower production index chart
From the detected result of table 2, after using saline-alkali soil conditioner of the present invention, the average germination percentage of hybrid oil-sunflower, colored cake mean diameter and full grains degree do not use saline-alkali soil conditioner of the present invention all to increase, and along with increasing of consumption, effect is also more and more significant.
Table 3 eats certain herbaceous plants with big flowers production index chart
From the detected result of table 3, after using saline-alkali soil conditioner of the present invention, the edible each production index of certain herbaceous plants with big flowers all significantly increases, and especially average germination percentage, along with increasing of consumption, effect is also more and more significant.
Experimental example 2
Promoted the use of in Aksu, Xinjiang by product of the present invention, maize planting 100 mu in saltings, 200 mu, Aksu, these 100 mu of ground are distinguished into each 25 mu of four bulk region, and its detected result is as follows.
The total salt of table 4 and pH detected result
From the detected result of table 4, after using saline-alkali soil conditioner of the present invention, the salt concn amount of decrease of salt affected soil is greater than 20%, pH amount of decrease and is greater than 20%, and along with increasing gradually of consumption, salt concn amount of decrease and pH amount of decrease also increase gradually, and improved effect is remarkable gradually.
Table 5 corn yield index summary sheet
From the detected result of table 5, after using saline-alkali soil conditioner of the present invention, the each index of corn all significantly increases, average germination percentage amplification is more than 25%, corn plants grow is strengthened, and diameter amplification is more than 25%, and corn particle plumpness amplification is more than 50%, and increasing along with consumption, effect is more and more significant.
Although illustrate and describe the present invention with specific embodiment, however it will be appreciated that can to make when not deviating from the spirit and scope of the present invention many other change and amendment.Therefore, this means to comprise all such changes and modifications belonged in the scope of the invention in the following claims.