CN104356777A - Convenient coating with good construction property - Google Patents
Convenient coating with good construction property Download PDFInfo
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- CN104356777A CN104356777A CN201410446225.XA CN201410446225A CN104356777A CN 104356777 A CN104356777 A CN 104356777A CN 201410446225 A CN201410446225 A CN 201410446225A CN 104356777 A CN104356777 A CN 104356777A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a convenient coating with a good construction property. The convenient coating comprises the following raw materials in parts by weight: 1-2 parts of potassium titanate, 2-3 parts of boron nitride, 0.5-1 part of chlorhexidine, 12-20 parts of butyl methacrylate, 1-2 parts of 2-mercaptobenzimidazole, 1-2 parts of polyamide wax micropowder, 3-5 parts of hydrargillite powder, 6-9 parts of vermiculite powder, 0.8-1 part of polyacrylamide, 120-180 parts of vinyl benzene, 120-180 parts of methyl acrylate, 3-4 parts of potassium peroxodisulfate, 0.6-1 part of coco fatty acid diethanol amide, 6-8 parts of OP-10, 5-7 parts of a bonding aid and 500-600 parts of deionized water. The convenient coating has a good construction property, can be directly sprayed on a base material, and has a high bonding property and good adhesion; a surface layer does not empty and bloat, and during construction, the coating does not sag or flow down, so that energy consumption of the construction can be reduced; the coating is high in surface resistance, high in wear resistance and impact resistance and good in water-proof property.
Description
Technical field
The present invention relates generally to paint field, particularly relate to a kind of application property good facilitate coating.
Background technology
Be applied to body surface can be formed there is protection, the class I liquid I of solid-state film of decoration or property (as insulation, anticorrosion, mark etc.) or the general name of solid material, comprise oil (property) paint, water-miscible paint, powder coating.Paint is flowable liquid coating, comprises oil (property) paint and water-miscible paint.Paint take organic solvent as medium or high solid, solvent-free oil-base paint.Water-miscible paint is used water dissolving or the coating with water-dispersion.Coating is as one of the main material of house decoration, and the large percentage accounted in decorations, buys the whether qualified environment directly having influence on overall finishing effect and room of coating, sometimes even can produce harm greatly to the health of human body.At present along with the generation of various coating, the quality requirements of coating is also improved constantly, and improve constantly coating quality and can play very large help for building, life.
Summary of the invention
The object of the invention be just to provide a kind of application property good facilitate coating.
The present invention is achieved by the following technical solutions:
What application property was good facilitates a coating, it is characterized in that what it was made up of the raw material of following weight parts:
Potassium titanate 1-2, boron nitride 2-3, chlorhexidine 0.5-1, butyl methacrylate 12-20,2-thiol group benzimidazolyl 1-2, polyamide wax micropowder 1-2, gibbsite powder 3-5, vermiculite power 6-9, polyacrylamide 0.8-1, vinylbenzene 120-180, methyl acrylate 120-180, Potassium Persulphate 3-4, lauric acid amide of ethanol 0.6-1, OP-10 6-8, adhesive aid 5-7, deionized water 500-600;
Described adhesive aid is made up of each raw material of following weight parts:
Isobornyl acrylate 6-8, organosilicon crylic acid latex 25-30, micro encapsulation Flos Rosae Rugosae quintessence oil 2-3, dimethylaminoethyl methacrylate 4-6, Potassium Persulphate 1-2, redwood micro mist 2-3, polyvinylpyrrolidone 0.6-1, deionized water 10-16;
Polyvinylpyrrolidone is mixed with Potassium Persulphate, adds the 70-80% of above-mentioned deionized water weight, stir;
Micro encapsulation Flos Rosae Rugosae quintessence oil is mixed with isobornyl acrylate, at 60-70 DEG C, is uniformly mixed 3-5 minute, join in organosilicon crylic acid latex, 100-200 rev/min of dispersed with stirring 5-10 minute;
Mixed with each raw material of residue by each raw material after above-mentioned process, 300-400 rev/min of dispersed with stirring 10-15 minute, obtains described adhesive aid.
A preparation method for what application property as claimed in claim 1 was good facilitate coating, is characterized in that comprising the following steps:
(1) get the 70-80% mixing of the 70-80% of above-mentioned vinylbenzene weight, methyl acrylate weight, obtain monomer a;
(2) remaining vinylbenzene, methyl acrylate are mixed with the 80-90% of butyl methacrylate weight, raised temperature is 60-65 DEG C, insulated and stirred 5-10 minute, adds polyamide wax micropowder, is stirred to normal temperature, obtains monomer b;
(3) get OP-10, add the 30-40% of above-mentioned deionized water weight, stir, add lauric acid amide of ethanol, insulated and stirred 2-3 minute at 50-60 DEG C, is cooled to normal temperature, obtains pre-emulsion;
(4) get Potassium Persulphate, add the 10-20% of residue deionized water weight, stir, obtain initiator solution;
(5) get above-mentioned monomer a, the 40-50% of pre-emulsion weight, the 50-60% of initiator solution weight, mixing, insulated and stirred 10-20 minute at 75-80 DEG C, adds chlorhexidine, is stirred to normal temperature, obtains premix monomer;
(6) above-mentioned monomer b is mixed with remaining pre-emulsion, remaining initiator solution, insulated and stirred 30-50 minute at 70-90 DEG C, drip above-mentioned premix monomer, time for adding is 2-3 hour, at 80-85 DEG C, 2-3 hour is incubated after dropwising, reduce temperature to 40-50 DEG C, adjust ph, to 7-8, is filtered with 200-250 order filter sieve;
(7) material above-mentioned steps (6) obtained with residue each raw material mix, 800-1200 rev/min of dispersed with stirring 20-30 minute, obtain described application property good facilitate coating.
Advantage of the present invention is:
Coating application of the present invention is good, can directly spray on base material, and cohesiveness is strong, and sticking power is good, surface layer not hollowing, construction not sagging, not sagging, reduce Energy Consumption of Construction, surface resistive is high, and wear-resistant shock resistance is strong, good waterproof performance.The micro encapsulation Flos Rosae Rugosae quintessence oil added in adhesive aid of the present invention has good flame retardant resistance, and isobornyl acrylate has good binding property, mixes with Potassium Persulphate, organosilicon crylic acid latex, can strengthen the cohesive strength of coatingsurface, increases flame retardant effect.
Embodiment
Embodiment 1
What application property was good facilitates a coating, it is characterized in that what it was made up of the raw material of following weight parts:
Potassium titanate 2, boron nitride 2, chlorhexidine 0.5, butyl methacrylate 20,2-thiol group benzimidazolyl 2, polyamide wax micropowder 2, gibbsite powder 5, vermiculite power 9, polyacrylamide 0.8, vinylbenzene 180, methyl acrylate 180, Potassium Persulphate 3, lauric acid amide of ethanol 0.6, OP-10 8, adhesive aid 5, deionized water 600;
Described adhesive aid is made up of each raw material of following weight parts:
Isobornyl acrylate 6, organosilicon crylic acid latex 30, micro encapsulation Flos Rosae Rugosae quintessence oil 3, dimethylaminoethyl methacrylate 6, Potassium Persulphate 2, redwood micro mist 2, polyvinylpyrrolidone 0.6, deionized water 16;
Polyvinylpyrrolidone is mixed with Potassium Persulphate, adds 80% of above-mentioned deionized water weight, stir;
Micro encapsulation Flos Rosae Rugosae quintessence oil is mixed with isobornyl acrylate, at 70 DEG C, is uniformly mixed 5 minutes, join in organosilicon crylic acid latex, 200 revs/min of dispersed with stirring 10 minutes;
Mixed with each raw material of residue by each raw material after above-mentioned process, 400 revs/min of dispersed with stirring 15 minutes, obtain described adhesive aid.
A preparation method for what application property was good facilitate coating, is characterized in that comprising the following steps:
(1) get 80% of above-mentioned vinylbenzene weight, 80% mixing of methyl acrylate weight, obtain monomer a;
(2) remaining vinylbenzene, methyl acrylate are mixed with 90% of butyl methacrylate weight, raised temperature is 65 DEG C, and insulated and stirred 10 minutes, adds polyamide wax micropowder, be stirred to normal temperature, obtains monomer b;
(3) get OP-10, add 40% of above-mentioned deionized water weight, stir, add lauric acid amide of ethanol, at 60 DEG C, insulated and stirred 3 minutes, is cooled to normal temperature, obtains pre-emulsion;
(4) get Potassium Persulphate, add 20% of residue deionized water weight, stir, obtain initiator solution;
(5) get above-mentioned monomer a, the 40-50% of pre-emulsion weight, 60% of initiator solution weight, mixing, at 80 DEG C, insulated and stirred 20 minutes, adds chlorhexidine, is stirred to normal temperature, obtains premix monomer;
(6) above-mentioned monomer b is mixed with remaining pre-emulsion, remaining initiator solution, insulated and stirred 50 minutes at 90 DEG C, drip above-mentioned premix monomer, time for adding is 3 hours, at 85 DEG C, 3 hours are incubated after dropwising, reduce temperature to 50 DEG C, regulate pH value to 7, filter with 250 order filter sieve;
(7) material above-mentioned steps (6) obtained mixes with each raw material of residue, 1200 revs/min of dispersed with stirring 30 minutes, obtain described application property good facilitate coating.
Performance test:
Unit elongation: >=300%;
Watertightness: 0.3MPa (one hour waterproof).
Claims (2)
1. what application property was good facilitates a coating, it is characterized in that what it was made up of the raw material of following weight parts:
Potassium titanate 1-2, boron nitride 2-3, chlorhexidine 0.5-1, butyl methacrylate 12-20,2-thiol group benzimidazolyl 1-2, polyamide wax micropowder 1-2, gibbsite powder 3-5, vermiculite power 6-9, polyacrylamide 0.8-1, vinylbenzene 120-180, methyl acrylate 120-180, Potassium Persulphate 3-4, lauric acid amide of ethanol 0.6-1, OP-10 6-8, adhesive aid 5-7, deionized water 500-600;
Described adhesive aid is made up of each raw material of following weight parts:
Isobornyl acrylate 6-8, organosilicon crylic acid latex 25-30, micro encapsulation Flos Rosae Rugosae quintessence oil 2-3, dimethylaminoethyl methacrylate 4-6, Potassium Persulphate 1-2, redwood micro mist 2-3, polyvinylpyrrolidone 0.6-1, deionized water 10-16;
Polyvinylpyrrolidone is mixed with Potassium Persulphate, adds the 70-80% of above-mentioned deionized water weight, stir;
Micro encapsulation Flos Rosae Rugosae quintessence oil is mixed with isobornyl acrylate, at 60-70 DEG C, is uniformly mixed 3-5 minute, join in organosilicon crylic acid latex, 100-200 rev/min of dispersed with stirring 5-10 minute;
Mixed with each raw material of residue by each raw material after above-mentioned process, 300-400 rev/min of dispersed with stirring 10-15 minute, obtains described adhesive aid.
2. the preparation method facilitating coating that application property as claimed in claim 1 is good, is characterized in that comprising the following steps:
(1) get the 70-80% mixing of the 70-80% of above-mentioned vinylbenzene weight, methyl acrylate weight, obtain monomer a;
(2) remaining vinylbenzene, methyl acrylate are mixed with the 80-90% of butyl methacrylate weight, raised temperature is 60-65 DEG C, insulated and stirred 5-10 minute, adds polyamide wax micropowder, is stirred to normal temperature, obtains monomer b;
(3) get OP-10, add the 30-40% of above-mentioned deionized water weight, stir, add lauric acid amide of ethanol, insulated and stirred 2-3 minute at 50-60 DEG C, is cooled to normal temperature, obtains pre-emulsion;
(4) get Potassium Persulphate, add the 10-20% of residue deionized water weight, stir, obtain initiator solution;
(5) get above-mentioned monomer a, the 40-50% of pre-emulsion weight, the 50-60% of initiator solution weight, mixing, insulated and stirred 10-20 minute at 75-80 DEG C, adds chlorhexidine, is stirred to normal temperature, obtains premix monomer;
(6) above-mentioned monomer b is mixed with remaining pre-emulsion, remaining initiator solution, insulated and stirred 30-50 minute at 70-90 DEG C, drip above-mentioned premix monomer, time for adding is 2-3 hour, at 80-85 DEG C, 2-3 hour is incubated after dropwising, reduce temperature to 40-50 DEG C, regulate pH value to 7-8, filter with 200-250 order filter sieve;
(7) material above-mentioned steps (6) obtained with residue each raw material mix, 800-1200 rev/min of dispersed with stirring 20-30 minute, obtain described application property good facilitate coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410446225.XA CN104356777A (en) | 2014-09-03 | 2014-09-03 | Convenient coating with good construction property |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410446225.XA CN104356777A (en) | 2014-09-03 | 2014-09-03 | Convenient coating with good construction property |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104356777A true CN104356777A (en) | 2015-02-18 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410446225.XA Pending CN104356777A (en) | 2014-09-03 | 2014-09-03 | Convenient coating with good construction property |
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| Country | Link |
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| CN (1) | CN104356777A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102971387A (en) * | 2010-06-30 | 2013-03-13 | 大象株式会社 | Method for preparing adhesive material for aqueous paint |
| CN103724520A (en) * | 2013-12-31 | 2014-04-16 | 汕头市大千高新科技研究中心有限公司 | Styrene-acrylic emulsion for building coating and preparation method of styrene-acrylic emulsion |
-
2014
- 2014-09-03 CN CN201410446225.XA patent/CN104356777A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102971387A (en) * | 2010-06-30 | 2013-03-13 | 大象株式会社 | Method for preparing adhesive material for aqueous paint |
| CN103724520A (en) * | 2013-12-31 | 2014-04-16 | 汕头市大千高新科技研究中心有限公司 | Styrene-acrylic emulsion for building coating and preparation method of styrene-acrylic emulsion |
Non-Patent Citations (2)
| Title |
|---|
| 朱广军等: "《涂料新产品与新技术》", 30 September 2000 * |
| 胡飞燕等: "《涂料基础配方与工艺》", 30 June 2013, 东华大学出版社 * |
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Application publication date: 20150218 |