CN104312356A - High-temperature-resistant anti-aging coating - Google Patents
High-temperature-resistant anti-aging coating Download PDFInfo
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- CN104312356A CN104312356A CN201410521958.5A CN201410521958A CN104312356A CN 104312356 A CN104312356 A CN 104312356A CN 201410521958 A CN201410521958 A CN 201410521958A CN 104312356 A CN104312356 A CN 104312356A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a high-temperature-resistant anti-aging coating which is prepared from the following raw materials in parts by weight: 0.6-1 part of tar residues, 2-3 parts of polyethylene ether, 2-3 parts of tricalcium silicate, 0.3-0.5 part of manganese iso-octoate, 1-2 parts of tri(nonylphenyl) phosphate, 1-2 parts of 1, 2-dimethylimidazole, 3-4 parts of oxidized polyethlene wax, 3-5 parts of jade powder, 10-13 parts of titanium dioxide, 3-4 parts of butyl benzyl phthalate, 80-100 parts of hexamethylcyclotrisiloxane, 120-150 parts of methyl methacrylate, 130-200 parts of isooctyl acrylate, 6-10 parts of dodecyl acrylate, 500-600 parts of deionized water, 2-4 parts of ammonium persulfate, 4-6 parts of op-10 and 3-6 parts of a bonding aid. The high-temperature-resistant anti-aging coating disclosed by the invention is good in anti-aging property. Through an ultra-temperature test for 500 hours, the coating is not pulverized or bubbled, free of cracks and falling and good in high-temperature resistance, is particularly suitable for walls in tropical zones and plays a long protective role.
Description
?
Technical field
The present invention relates generally to paint field, particularly relates to a kind of high temperature resistant anti-aging coating.
Background technology
Be applied to body surface can be formed there is protection, the class I liquid I of solid-state film of decoration or property (as insulation, anticorrosion, mark etc.) or the general name of solid material, comprise oil (property) paint, water-miscible paint, powder coating.Paint is flowable liquid coating, comprises oil (property) paint and water-miscible paint.Paint take organic solvent as medium or high solid, solvent-free oil-base paint.Water-miscible paint is used water dissolving or the coating with water-dispersion.Coating is as one of the main material of house decoration, and the large percentage accounted in decorations, buys the whether qualified environment directly having influence on overall finishing effect and room of coating, sometimes even can produce harm greatly to the health of human body.At present along with the generation of various coating, the quality requirements of coating is also improved constantly, and improve constantly coating quality and can play very large help for building, life.
Summary of the invention
The object of the invention is just to provide a kind of high temperature resistant anti-aging coating.
The present invention is achieved by the following technical solutions:
A kind of high temperature resistant anti-aging coating, is characterized in that what it was made up of the raw material of following weight parts:
Coke tar refuse 0.6-1, polyvinyl ether 2-3, tricalcium silicate 2-3, manganese iso-octoate 0.3-0.5, trisnonyl phenyl phosphite 1-2,1,2 dimethylimidazole 1-2, oxidized polyethlene wax 3-4, jade powder 3-5, titanium dioxide 10-13, butyl benzyl phthalate 3-4, hexamethyl cyclotrisiloxane 80-100, methyl methacrylate 120-150, Isooctyl acrylate monomer 130-200, dodecyl acrylate 6-10, deionized water 500-600, ammonium persulphate 2-4, op-10 4-6, adhesive aid 3-6;
Described adhesive aid is made up of each raw material of following weight parts:
Methyl methacrylate 5-10, acrylate and vinyl acetate emulsion 20-25, aluminate coupling agent 2-3, Camphorwood micro mist 1-2, iso-borneol methacrylic ester 2-3, Potassium Persulphate 1-2, Sodium dodecylbenzene sulfonate 0.6-1, deionized water 13-20;
Above-mentioned methyl methacrylate is mixed with aluminate coupling agent, adds Sodium dodecylbenzene sulfonate, iso-borneol methacrylic ester after stirring, insulated and stirred 3-5 minute at 50-60 DEG C;
Camphorwood micro mist is joined in deionized water, after stirring, adds Potassium Persulphate, stir;
By each raw material mixing after above-mentioned process, join in acrylate and vinyl acetate emulsion, 300-400 rev/min of dispersed with stirring 15-20 minute, obtains described adhesive aid.
A preparation method for high temperature resistant anti-aging coating, is characterized in that comprising the following steps:
(1) get the 50-60% of above-mentioned methyl methacrylate weight, the 50-60% of Isooctyl acrylate monomer weight, dodecyl acrylate mixing, obtain monomer a;
(2) remaining methyl methacrylate, Isooctyl acrylate monomer are mixed with hexamethyl cyclotrisiloxane, butyl benzyl phthalate, insulated and stirred 3-5 minute at 60-70 DEG C, is cooled to normal temperature, obtains monomer b;
(3) get op-10 to mix with the 10-20% of above-mentioned deionized water weight, add ammonium persulphate, being increased to temperature is 60-70 DEG C, insulated and stirred 20-30 minute, drips above-mentioned monomer a, dripped off in 2-4 hour, be incubated 20-30 minute at the temperature disclosed above after dropwising, obtain seed emulsion;
(4) get oxidized polyethlene wax, be heated to 60-70 DEG C, add 1,2 dimethylimidazole, be stirred to normal temperature, add the 20-30% of residue deionized water weight, stir, obtain liquid a;
(5) in above-mentioned seed emulsion, add liquid a, stir, drip monomer b, time for adding is 100-120 minute, after dropwising, at 70-80 DEG C, is incubated 1-2 hour, and cooling filters discharging with 200-250 eye mesh screen;
(6) material above-mentioned steps (5) obtained mixes with each raw material of residue, and 800-1200 rev/min of dispersed with stirring 20-30 minute, obtains described high temperature resistant anti-aging coating.
Advantage of the present invention is:
Coating ageing resistance of the present invention is good, and through the test of 500 hours ultrahigh-temperature, coating is without efflorescence, peel off without bubbling, flawless, nothing, and high thermal resistance is good, is specially adapted to the body of wall use of torrid areas, can plays permanent protected effect.The methyl methacrylate that adhesive aid of the present invention adds can form colloidal state in water, mixed and modified with iso-borneol methacrylic ester, Potassium Persulphate, acrylate and vinyl acetate emulsion etc., has very strong bond effect, can improve film coated surface cohesiveness and stability.
Embodiment
Embodiment 1
A kind of high temperature resistant anti-aging coating, is characterized in that what it was made up of the raw material of following weight parts:
Coke tar refuse 0.6, polyvinyl ether 3, tricalcium silicate 2, manganese iso-octoate 0.5, trisnonyl phenyl phosphite 1,1,2 dimethylimidazole 1, oxidized polyethlene wax 3, jade powder 5, titanium dioxide 13, butyl benzyl phthalate 3, hexamethyl cyclotrisiloxane 100, methyl methacrylate 150, Isooctyl acrylate monomer 200, dodecyl acrylate 10, water 600, ammonium persulphate 2, op-10 4, adhesive aid 6;
Described adhesive aid is made up of each raw material of following weight parts:
Methyl methacrylate 10, acrylate and vinyl acetate emulsion 25, aluminate coupling agent 2, Camphorwood micro mist 2, iso-borneol methacrylic ester 2, Potassium Persulphate 2, Sodium dodecylbenzene sulfonate 0.6, deionized water 20;
Above-mentioned methyl methacrylate is mixed with aluminate coupling agent, after stirring, adds Sodium dodecylbenzene sulfonate, iso-borneol methacrylic ester, insulated and stirred 5 minutes at 60 DEG C;
Camphorwood micro mist is joined in deionized water, after stirring, adds Potassium Persulphate, stir;
By each raw material mixing after above-mentioned process, join in acrylate and vinyl acetate emulsion, 400 revs/min of dispersed with stirring 20 minutes, obtain described adhesive aid.
A preparation method for high temperature resistant anti-aging coating, is characterized in that comprising the following steps:
(1) get 60% of above-mentioned methyl methacrylate weight, Isooctyl acrylate monomer weight 60%, dodecyl acrylate mixing, obtain monomer a;
(2) remaining methyl methacrylate, Isooctyl acrylate monomer are mixed with hexamethyl cyclotrisiloxane, butyl benzyl phthalate, at 70 DEG C, insulated and stirred 5 minutes, is cooled to normal temperature, obtains monomer b;
(3) get op-10 to mix with 20% of above-mentioned deionized water weight, add ammonium persulphate, being increased to temperature is 70 DEG C, and insulated and stirred 20 minutes drips above-mentioned monomer a, dripped off in 4 hours, is incubated 30 minutes at the temperature disclosed above, obtains seed emulsion after dropwising;
(4) get oxidized polyethlene wax, be heated to 70 DEG C, add 1,2 dimethylimidazole, be stirred to normal temperature, add 30% of residue deionized water weight, stir, obtain liquid a;
(5) in above-mentioned seed emulsion, add liquid a, stir, drip monomer b, time for adding is 120 minutes, after dropwising, at 80 DEG C, be incubated 1 hour, and cooling filters discharging with 250 eye mesh screens;
(6) material above-mentioned steps (5) obtained mixes with each raw material of residue, and 1200 revs/min of dispersed with stirring 20-30 minute, obtain described high temperature resistant anti-aging coating.
Performance test:
Unit elongation: >=300%;
Watertightness: 0.3MPa (one hour waterproof).
Claims (2)
1. a high temperature resistant anti-aging coating, is characterized in that what it was made up of the raw material of following weight parts:
Coke tar refuse 0.6-1, polyvinyl ether 2-3, tricalcium silicate 2-3, manganese iso-octoate 0.3-0.5, trisnonyl phenyl phosphite 1-2,1,2 dimethylimidazole 1-2, oxidized polyethlene wax 3-4, jade powder 3-5, titanium dioxide 10-13, butyl benzyl phthalate 3-4, hexamethyl cyclotrisiloxane 80-100, methyl methacrylate 120-150, Isooctyl acrylate monomer 130-200, dodecyl acrylate 6-10, deionized water 500-600, ammonium persulphate 2-4, op-10 4-6, adhesive aid 3-6;
Described adhesive aid is made up of each raw material of following weight parts:
Methyl methacrylate 5-10, acrylate and vinyl acetate emulsion 20-25, aluminate coupling agent 2-3, Camphorwood micro mist 1-2, iso-borneol methacrylic ester 2-3, Potassium Persulphate 1-2, Sodium dodecylbenzene sulfonate 0.6-1, deionized water 13-20;
Above-mentioned methyl methacrylate is mixed with aluminate coupling agent, adds Sodium dodecylbenzene sulfonate, iso-borneol methacrylic ester after stirring, insulated and stirred 3-5 minute at 50-60 DEG C;
Camphorwood micro mist is joined in deionized water, after stirring, adds Potassium Persulphate, stir;
By each raw material mixing after above-mentioned process, join in acrylate and vinyl acetate emulsion, 300-400 rev/min of dispersed with stirring 15-20 minute, obtains described adhesive aid.
2. a preparation method for high temperature resistant anti-aging coating as claimed in claim 1, is characterized in that comprising the following steps:
(1) get the 50-60% of above-mentioned methyl methacrylate weight, the 50-60% of Isooctyl acrylate monomer weight, dodecyl acrylate mixing, obtain monomer a;
(2) remaining methyl methacrylate, Isooctyl acrylate monomer are mixed with hexamethyl cyclotrisiloxane, butyl benzyl phthalate, insulated and stirred 3-5 minute at 60-70 DEG C, is cooled to normal temperature, obtains monomer b;
(3) get op-10 to mix with the 10-20% of above-mentioned deionized water weight, add ammonium persulphate, being increased to temperature is 60-70 DEG C, insulated and stirred 20-30 minute, drips above-mentioned monomer a, dripped off in 2-4 hour, be incubated 20-30 minute at the temperature disclosed above after dropwising, obtain seed emulsion;
(4) get oxidized polyethlene wax, be heated to 60-70 DEG C, add 1,2 dimethylimidazole, be stirred to normal temperature, add the 20-30% of residue deionized water weight, stir, obtain liquid a;
(5) in above-mentioned seed emulsion, add liquid a, stir, drip monomer b, time for adding is 100-120 minute, after dropwising, at 70-80 DEG C, is incubated 1-2 hour, and cooling filters discharging with 200-250 eye mesh screen;
(6) material above-mentioned steps (5) obtained mixes with each raw material of residue, and 800-1200 rev/min of dispersed with stirring 20-30 minute, obtains described high temperature resistant anti-aging coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410521958.5A CN104312356A (en) | 2014-10-08 | 2014-10-08 | High-temperature-resistant anti-aging coating |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410521958.5A CN104312356A (en) | 2014-10-08 | 2014-10-08 | High-temperature-resistant anti-aging coating |
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| CN104312356A true CN104312356A (en) | 2015-01-28 |
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| CN201410521958.5A Pending CN104312356A (en) | 2014-10-08 | 2014-10-08 | High-temperature-resistant anti-aging coating |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104845497A (en) * | 2015-05-25 | 2015-08-19 | 湖州大周高分子材料有限公司 | Ageing-resistant coating |
| CN105949839A (en) * | 2016-05-04 | 2016-09-21 | 南京高崎电机有限公司 | Heat insulation paint |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3663650A (en) * | 1970-12-28 | 1972-05-16 | Gen Electric | Substantially transparent polydimethylsiloxane - polyalkylmethacrylate compositions and method for making same |
| CN101514271A (en) * | 2009-03-18 | 2009-08-26 | 辽宁一一三（集团）化工有限责任公司 | Polyacrylic ester wood lacquer emulsion and synthetic method thereof |
| CN101851454A (en) * | 2010-05-14 | 2010-10-06 | 青岛格尔美环保涂料有限公司 | Environmentally friendly high polymer composite coating material |
| CN102086245A (en) * | 2010-11-15 | 2011-06-08 | 湖南汇博化工科技有限公司 | Method for preparing organosilicon-acrylic acid copolymer emulsion |
| CN102241936A (en) * | 2011-05-26 | 2011-11-16 | 开平市日固力涂料有限公司 | High temperature resistant thermal insulation coating |
| CN103725141A (en) * | 2013-12-17 | 2014-04-16 | 江苏苏博特新材料股份有限公司 | Water-based emulsion for protecting external wall of building and preparation method for water-based emulsion |
-
2014
- 2014-10-08 CN CN201410521958.5A patent/CN104312356A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3663650A (en) * | 1970-12-28 | 1972-05-16 | Gen Electric | Substantially transparent polydimethylsiloxane - polyalkylmethacrylate compositions and method for making same |
| CN101514271A (en) * | 2009-03-18 | 2009-08-26 | 辽宁一一三（集团）化工有限责任公司 | Polyacrylic ester wood lacquer emulsion and synthetic method thereof |
| CN101851454A (en) * | 2010-05-14 | 2010-10-06 | 青岛格尔美环保涂料有限公司 | Environmentally friendly high polymer composite coating material |
| CN102086245A (en) * | 2010-11-15 | 2011-06-08 | 湖南汇博化工科技有限公司 | Method for preparing organosilicon-acrylic acid copolymer emulsion |
| CN102241936A (en) * | 2011-05-26 | 2011-11-16 | 开平市日固力涂料有限公司 | High temperature resistant thermal insulation coating |
| CN103725141A (en) * | 2013-12-17 | 2014-04-16 | 江苏苏博特新材料股份有限公司 | Water-based emulsion for protecting external wall of building and preparation method for water-based emulsion |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104845497A (en) * | 2015-05-25 | 2015-08-19 | 湖州大周高分子材料有限公司 | Ageing-resistant coating |
| CN105949839A (en) * | 2016-05-04 | 2016-09-21 | 南京高崎电机有限公司 | Heat insulation paint |
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Application publication date: 20150128 |
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