CN104231769A - Polyvinyl chloride paste resin coating - Google Patents
Polyvinyl chloride paste resin coating Download PDFInfo
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- CN104231769A CN104231769A CN201410445445.0A CN201410445445A CN104231769A CN 104231769 A CN104231769 A CN 104231769A CN 201410445445 A CN201410445445 A CN 201410445445A CN 104231769 A CN104231769 A CN 104231769A
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Abstract
The invention discloses a polyvinyl chloride paste resin coating, comprising the following raw materials in parts by weight: 2-3 polyvinyl chloride paste resin, 0.5-1 part of benzyltriphenylchlorophosphine, 0.5-1 part of ammonium paratungstate, 2-4 parts of boric oxide, 2-3 parts of rosewood micro powder, 0.4-1 part of dithiosalicylic acid, 1-2 parts of sa-hao seed gum, 3-4 parts of chlorinated paraffin, 2-3 parts of ethylhexyl methacrylate, 0.1-0.3 part of trimethyl hydroxyethyl ethylenediamine, 120-160 parts of styrene, 80-100 parts of methyl acrylate, 40-60 parts of butyl methacrylate, 3-4 parts of potassium peroxodisulfate, 6-8 parts of OP-10, 5-7 parts of bonding agent and 500-600 parts of deionized water. By the polyvinyl chloride paste resin added to the coating disclosed by the invention, the heat stability, the mechanical property and the chemical stability of the coating can be effectively improved, the bonding strength is improved, the compatibility between the materials is promoted, and the film-forming effect is improved.
Description
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Technical field
The present invention relates generally to paint field, particularly relates to a kind of pvc resin paste grade coating.
Background technology
Be applied to body surface can be formed there is protection, the class I liquid I of solid-state film of decoration or property (as insulation, anticorrosion, mark etc.) or the general name of solid material, comprise oil (property) paint, water-miscible paint, powder coating.Paint is flowable liquid coating, comprises oil (property) paint and water-miscible paint.Paint take organic solvent as medium or high solid, solvent-free oil-base paint.Water-miscible paint is used water dissolving or the coating with water-dispersion.Coating is as one of the main material of house decoration, and the large percentage accounted in decorations, buys the whether qualified environment directly having influence on overall finishing effect and room of coating, sometimes even can produce harm greatly to the health of human body.At present along with the generation of various coating, the quality requirements of coating is also improved constantly, and improve constantly coating quality and can play very large help for building, life.
Summary of the invention
The object of the invention is just to provide a kind of pvc resin paste grade coating.
The present invention is achieved by the following technical solutions:
A kind of pvc resin paste grade coating, is characterized in that what it was made up of the raw material of following weight parts:
Pvc resin paste grade 2-3, benzyl triphenyl phosphonium chloride phosphine 0.5-1, ammonium paratungstate 0.5-1, boron oxide 2-4, redwood micro mist 2-3, dithio-salicylic acid 0.4-1, artemisia glue 1-2, clorafin 3-4, Isooctyl methacrylate 2-3, trimethyl hydroxyethylammonium quadrol 0.1-0.3, vinylbenzene 120-160, methyl acrylate 80-100, butyl methacrylate 40-60, Potassium Persulphate 3-4, OP-10 6-8, adhesive aid 5-7, deionized water 500-600;
Described adhesive aid is made up of each raw material of following weight parts:
Isobornyl acrylate 6-8, organosilicon crylic acid latex 25-30, micro encapsulation Flos Rosae Rugosae quintessence oil 2-3, dimethylaminoethyl methacrylate 4-6, Potassium Persulphate 1-2, redwood micro mist 2-3, polyvinylpyrrolidone 0.6-1, deionized water 10-16;
Polyvinylpyrrolidone is mixed with Potassium Persulphate, adds the 70-80% of above-mentioned deionized water weight, stir;
Micro encapsulation Flos Rosae Rugosae quintessence oil is mixed with isobornyl acrylate, at 60-70 DEG C, is uniformly mixed 3-5 minute, join in organosilicon crylic acid latex, 100-200 rev/min of dispersed with stirring 5-10 minute;
Mixed with each raw material of residue by each raw material after above-mentioned process, 300-400 rev/min of dispersed with stirring 10-15 minute, obtains described adhesive aid.
2, a preparation method for pvc resin paste grade coating as claimed in claim 1, is characterized in that comprising the following steps:
(1) get the 70-80% mixing of the 50-60% of above-mentioned vinylbenzene weight, methyl acrylate weight, obtain monomer a;
(2) remaining vinylbenzene, methyl acrylate are mixed with butyl methacrylate, Isooctyl methacrylate, redwood micro mist, obtain monomer b;
(3) get OP-10, add the 30-40% of above-mentioned deionized water weight, stir, obtain pre-emulsion;
(4) get Potassium Persulphate, add the 10-20% of residue deionized water weight, stir, obtain initiator solution;
(5) get above-mentioned monomer a, the 40-50% of pre-emulsion weight, the 50-60% of initiator solution weight, mixing, adds ammonium paratungstate, insulated and stirred 10-20 minute at 75-80 DEG C, obtains premix monomer;
(6) above-mentioned monomer b is mixed with remaining pre-emulsion, remaining initiator solution, insulated and stirred 30-50 minute at 70-90 DEG C, drip above-mentioned premix monomer, time for adding is 2-3 hour, at 80-85 DEG C, 2-3 hour is incubated after dropwising, reduce temperature to 40-50 DEG C, regulate pH value to 7-8, filter with 200-250 order filter sieve;
(7) material above-mentioned steps (6) obtained mixes with each raw material of residue, and 800-1200 rev/min of dispersed with stirring 20-30 minute, obtains described pvc resin paste grade coating.
Advantage of the present invention is:
The pvc resin paste grade that coating of the present invention adds effectively can improve thermostability, mechanical property, chemical stability, the raising cohesive strength of coating, promotes the consistency of each storeroom, improves film-formation result.The micro encapsulation Flos Rosae Rugosae quintessence oil added in adhesive aid of the present invention has good flame retardant resistance, and isobornyl acrylate has good binding property, mixes with Potassium Persulphate, organosilicon crylic acid latex, can strengthen the cohesive strength of coatingsurface, increases flame retardant effect.
Embodiment
Embodiment 1
A kind of pvc resin paste grade coating, is characterized in that what it was made up of the raw material of following weight parts:
Pvc resin paste grade 2, benzyl triphenyl phosphonium chloride phosphine 0.5, ammonium paratungstate 0.5, boron oxide 4, redwood micro mist 3, dithio-salicylic acid 0.4, artemisia glue 2, clorafin 3, Isooctyl methacrylate 2, trimethyl hydroxyethylammonium quadrol 0.3, vinylbenzene 160, methyl acrylate 100, butyl methacrylate 40, Potassium Persulphate 4, OP-10 6, adhesive aid 7, deionized water 600;
Described adhesive aid is made up of each raw material of following weight parts:
Isobornyl acrylate 8, organosilicon crylic acid latex 30, micro encapsulation Flos Rosae Rugosae quintessence oil 2, dimethylaminoethyl methacrylate 6, Potassium Persulphate 1, redwood micro mist 3, polyvinylpyrrolidone 0.6, deionized water 16;
Polyvinylpyrrolidone is mixed with Potassium Persulphate, adds 80% of above-mentioned deionized water weight, stir;
Micro encapsulation Flos Rosae Rugosae quintessence oil is mixed with isobornyl acrylate, at 70 DEG C, is uniformly mixed 3 minutes, join in organosilicon crylic acid latex, 200 revs/min of dispersed with stirring 10 minutes;
Mixed with each raw material of residue by each raw material after above-mentioned process, 400 revs/min of dispersed with stirring 15 minutes, obtain described adhesive aid.
As a preparation method for pvc resin paste grade coating, it is characterized in that comprising the following steps:
(1) get 60% of above-mentioned vinylbenzene weight, 80% mixing of methyl acrylate weight, obtain monomer a;
(2) remaining vinylbenzene, methyl acrylate are mixed with butyl methacrylate, Isooctyl methacrylate, redwood micro mist, obtain monomer b;
(3) get OP-10, add 40% of above-mentioned deionized water weight, stir, obtain pre-emulsion;
(4) get Potassium Persulphate, add 20% of residue deionized water weight, stir, obtain initiator solution;
(5) get above-mentioned monomer a, 50% of pre-emulsion weight, 60% of initiator solution weight, mixing, add ammonium paratungstate, at 80 DEG C, insulated and stirred 20 minutes, obtains premix monomer;
(6) above-mentioned monomer b is mixed with remaining pre-emulsion, remaining initiator solution, insulated and stirred 50 minutes at 90 DEG C, drip above-mentioned premix monomer, time for adding is 2 hours, at 85 DEG C, 2 hours are incubated after dropwising, reduce temperature to 50 DEG C, regulate pH value to 8, filter with 250 order filter sieve;
(7) material above-mentioned steps (6) obtained mixes with each raw material of residue, and 1200 revs/min of dispersed with stirring 20-30 minute, obtain described pvc resin paste grade coating.
Performance test:
Unit elongation: >=300%;
Watertightness: 0.3MPa (one hour waterproof).
Claims (2)
1. a pvc resin paste grade coating, is characterized in that what it was made up of the raw material of following weight parts:
Pvc resin paste grade 2-3, benzyl triphenyl phosphonium chloride phosphine 0.5-1, ammonium paratungstate 0.5-1, boron oxide 2-4, redwood micro mist 2-3, dithio-salicylic acid 0.4-1, artemisia glue 1-2, clorafin 3-4, Isooctyl methacrylate 2-3, trimethyl hydroxyethylammonium quadrol 0.1-0.3, vinylbenzene 120-160, methyl acrylate 80-100, butyl methacrylate 40-60, Potassium Persulphate 3-4, OP-10 6-8, adhesive aid 5-7, deionized water 500-600;
Described adhesive aid is made up of each raw material of following weight parts:
Isobornyl acrylate 6-8, organosilicon crylic acid latex 25-30, micro encapsulation Flos Rosae Rugosae quintessence oil 2-3, dimethylaminoethyl methacrylate 4-6, Potassium Persulphate 1-2, redwood micro mist 2-3, polyvinylpyrrolidone 0.6-1, deionized water 10-16;
Polyvinylpyrrolidone is mixed with Potassium Persulphate, adds the 70-80% of above-mentioned deionized water weight, stir;
Micro encapsulation Flos Rosae Rugosae quintessence oil is mixed with isobornyl acrylate, at 60-70 DEG C, is uniformly mixed 3-5 minute, join in organosilicon crylic acid latex, 100-200 rev/min of dispersed with stirring 5-10 minute;
Mixed with each raw material of residue by each raw material after above-mentioned process, 300-400 rev/min of dispersed with stirring 10-15 minute, obtains described adhesive aid.
2. a preparation method for pvc resin paste grade coating as claimed in claim 1, is characterized in that comprising the following steps:
(1) get the 70-80% mixing of the 50-60% of above-mentioned vinylbenzene weight, methyl acrylate weight, obtain monomer a;
(2) remaining vinylbenzene, methyl acrylate are mixed with butyl methacrylate, Isooctyl methacrylate, redwood micro mist, obtain monomer b;
(3) get OP-10, add the 30-40% of above-mentioned deionized water weight, stir, obtain pre-emulsion;
(4) get Potassium Persulphate, add the 10-20% of residue deionized water weight, stir, obtain initiator solution;
(5) get above-mentioned monomer a, the 40-50% of pre-emulsion weight, the 50-60% of initiator solution weight, mixing, adds ammonium paratungstate, insulated and stirred 10-20 minute at 75-80 DEG C, obtains premix monomer;
(6) above-mentioned monomer b is mixed with remaining pre-emulsion, remaining initiator solution, insulated and stirred 30-50 minute at 70-90 DEG C, drip above-mentioned premix monomer, time for adding is 2-3 hour, at 80-85 DEG C, 2-3 hour is incubated after dropwising, reduce temperature to 40-50 DEG C, regulate pH value to 7-8, filter with 200-250 order filter sieve;
(7) material above-mentioned steps (6) obtained mixes with each raw material of residue, and 800-1200 rev/min of dispersed with stirring 20-30 minute, obtains described pvc resin paste grade coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410445445.0A CN104231769A (en) | 2014-09-03 | 2014-09-03 | Polyvinyl chloride paste resin coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410445445.0A CN104231769A (en) | 2014-09-03 | 2014-09-03 | Polyvinyl chloride paste resin coating |
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| CN104231769A true CN104231769A (en) | 2014-12-24 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410445445.0A Pending CN104231769A (en) | 2014-09-03 | 2014-09-03 | Polyvinyl chloride paste resin coating |
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| CN (1) | CN104231769A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105111850A (en) * | 2015-08-14 | 2015-12-02 | 安徽艳阳电气集团有限公司 | Anti-peeling LED heat-dissipation coating and preparation method therefor |
| CN106243897A (en) * | 2016-08-24 | 2016-12-21 | 安徽美景工艺品有限公司 | A kind of sericin polyurethane composite stalk treatment fluid and preparation method thereof |
| CN107760119A (en) * | 2017-09-29 | 2018-03-06 | 安徽德全新型建材科技有限公司 | A kind of preparation method for the thermal insulation coatings of resistance to cold water pipe |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102971387A (en) * | 2010-06-30 | 2013-03-13 | 大象株式会社 | Method for preparing adhesive material for aqueous paint |
| CN103897506A (en) * | 2013-10-29 | 2014-07-02 | 东南大学 | Water-based flame retardant anti-rusting paint |
-
2014
- 2014-09-03 CN CN201410445445.0A patent/CN104231769A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102971387A (en) * | 2010-06-30 | 2013-03-13 | 大象株式会社 | Method for preparing adhesive material for aqueous paint |
| CN103897506A (en) * | 2013-10-29 | 2014-07-02 | 东南大学 | Water-based flame retardant anti-rusting paint |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105111850A (en) * | 2015-08-14 | 2015-12-02 | 安徽艳阳电气集团有限公司 | Anti-peeling LED heat-dissipation coating and preparation method therefor |
| CN106243897A (en) * | 2016-08-24 | 2016-12-21 | 安徽美景工艺品有限公司 | A kind of sericin polyurethane composite stalk treatment fluid and preparation method thereof |
| CN107760119A (en) * | 2017-09-29 | 2018-03-06 | 安徽德全新型建材科技有限公司 | A kind of preparation method for the thermal insulation coatings of resistance to cold water pipe |
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Application publication date: 20141224 |
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