CN104356776A - Anti-wear smooth internal wall coating - Google Patents

Anti-wear smooth internal wall coating Download PDF

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Publication number
CN104356776A
CN104356776A CN201410446206.7A CN201410446206A CN104356776A CN 104356776 A CN104356776 A CN 104356776A CN 201410446206 A CN201410446206 A CN 201410446206A CN 104356776 A CN104356776 A CN 104356776A
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China
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weight
minute
parts
mentioned
deionized water
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Pending
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CN201410446206.7A
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Chinese (zh)
Inventor
王和山
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Tianchang Kailin Chemical Co Ltd
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Tianchang Kailin Chemical Co Ltd
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Priority to CN201410446206.7A priority Critical patent/CN104356776A/en
Publication of CN104356776A publication Critical patent/CN104356776A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02—Homopolymers or copolymers of hydrocarbons
    • C09D125/04—Homopolymers or copolymers of styrene
    • C09D125/08—Copolymers of styrene
    • C09D125/14—Copolymers of styrene with unsaturated esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses an anti-wear smooth internal wall coating which comprises the following raw materials in parts by weight: 0.8-1 part of 2-adamantanol, 0.7-1 part of disodium octaborate tetrahydrate, 0.1-0.4 part of zinc pyrithione, 4-7 parts of fluorapatite, 10-12 parts of titanium dioxide, 120-160 parts of styrene, 80-100 parts of methyl acrylate, 40-60 parts of butyl methacrylate, 3-4 parts of ammonium persulfate, 0.7-1 part of ammonium metaborate, 6-8 parts of OP-10, 5-7 parts of a cementing assistant and 500-600 parts of de-ionized water. The coating is easy to construct, can be directly applied to a qualified base material, is high in surface hardness, good in wear resistance and impact resistance, smooth and comfortable in hand feel and good in safety and environmental protection property, and is especially suitable for serving as an internal wall coating.

Description

A kind of wear-resistant smooth interior wall coating
Technical field
The present invention relates generally to paint field, particularly relates to a kind of wear-resistant smooth interior wall coating.
Background technology
Be applied to body surface can be formed there is protection, the class I liquid I of solid-state film of decoration or property (as insulation, anticorrosion, mark etc.) or the general name of solid material, comprise oil (property) paint, water-miscible paint, powder coating.Paint is flowable liquid coating, comprises oil (property) paint and water-miscible paint.Paint take organic solvent as medium or high solid, solvent-free oil-base paint.Water-miscible paint is used water dissolving or the coating with water-dispersion.Coating is as one of the main material of house decoration, and the large percentage accounted in decorations, buys the whether qualified environment directly having influence on overall finishing effect and room of coating, sometimes even can produce harm greatly to the health of human body.At present along with the generation of various coating, the quality requirements of coating is also improved constantly, and improve constantly coating quality and can play very large help for building, life.
Summary of the invention
The object of the invention is just to provide a kind of wear-resistant smooth interior wall coating.
The present invention is achieved by the following technical solutions:
A kind of wear-resistant smooth interior wall coating, is characterized in that what it was made up of the raw material of following weight parts:
2-adamantanol 0.8-1, four water eight borate two sodium 0.7-1, Zinc Pyrithione 0.1-0.4, fluorapatite 4-7, titanium dioxide 10-12, dinoctyl phthalate 2-4, Yatall MA 0.7-2, glass fibre 2-3, ammonium polyphosphate 1-2, vinylbenzene 120-160, methyl acrylate 80-100, butyl methacrylate 40-60, ammonium persulphate 3-4, ammonium metaborate 0.7-1, OP-10 6-8, adhesive aid 5-7, deionized water 500-600;
Described adhesive aid is made up of each raw material of following weight parts:
Isobornyl acrylate 6-8, organosilicon crylic acid latex 25-30, micro encapsulation Flos Rosae Rugosae quintessence oil 2-3, dimethylaminoethyl methacrylate 4-6, Potassium Persulphate 1-2, redwood micro mist 2-3, polyvinylpyrrolidone 0.6-1, deionized water 10-16;
Polyvinylpyrrolidone is mixed with Potassium Persulphate, adds the 70-80% of above-mentioned deionized water weight, stir;
Micro encapsulation Flos Rosae Rugosae quintessence oil is mixed with isobornyl acrylate, at 60-70 DEG C, is uniformly mixed 3-5 minute, join in organosilicon crylic acid latex, 100-200 rev/min of dispersed with stirring 5-10 minute;
Mixed with each raw material of residue by each raw material after above-mentioned process, 300-400 rev/min of dispersed with stirring 10-15 minute, obtains described adhesive aid.
A preparation method for wear-resistant smooth interior wall coating as claimed in claim 1, is characterized in that comprising the following steps:
(1) get the 80-90% of above-mentioned vinylbenzene weight, the 80-90% of methyl acrylate weight, the 70-80% mixing of butyl methacrylate weight, obtain monomer a;
(2) get OP-10, add the 30-40% of above-mentioned deionized water weight, stir, obtain pre-emulsion;
(3) get ammonium persulphate, add the 10-20% of residue deionized water weight, stir, add ammonium metaborate, insulated and stirred 3-5 minute at 50-60 DEG C, is cooled to normal temperature, obtains initiator solution;
(4) get above-mentioned monomer a, the 40-50% of pre-emulsion weight, the 50-60% of initiator solution weight, mixing, insulated and stirred 10-20 minute at 75-80 DEG C, obtains premix monomer;
(5) four water eight borate two sodium is got, add the 30-40% of residue deionized water weight, 2-adamantanol, dinoctyl phthalate is added after stirring, insulated and stirred 2-4 minute at 50-60 DEG C, add remaining vinylbenzene, methyl acrylate, butyl methacrylate, 100-200 rev/min of dispersed with stirring 10-20 minute, obtains modified monomer;
(6) above-mentioned modified monomer is mixed with remaining pre-emulsion, remaining initiator solution, insulated and stirred 30-50 minute at 70-90 DEG C, drip above-mentioned premix monomer, time for adding is 2-3 hour, at 80-85 DEG C, 2-3 hour is incubated after dropwising, reduce temperature to 40-50 DEG C, adjust ph, to 7-8, is filtered with 200-250 order filter sieve;
(7) material above-mentioned steps (6) obtained mixes with each raw material of residue, and 800-1200 rev/min of dispersed with stirring 20-30 minute, obtains described wear-resistant smooth interior wall coating.
Advantage of the present invention is:
Coating application of the present invention is simple, and can directly brush on qualified base material, surface hardness is high, and wear-resistant shock resistance is strong, and coating is smooth, hand sense of touch is smoothly comfortable, is particularly suitable as interior wall coating, and Safety and Environmental Protection is good.The micro encapsulation Flos Rosae Rugosae quintessence oil added in adhesive aid of the present invention has good flame retardant resistance, and isobornyl acrylate has good binding property, mixes with Potassium Persulphate, organosilicon crylic acid latex, can strengthen the cohesive strength of coatingsurface, increases flame retardant effect.
Embodiment
Embodiment 1
A kind of wear-resistant smooth interior wall coating, is characterized in that what it was made up of the raw material of following weight parts:
2-adamantanol 0.8, four water eight borate two sodium 0.7, Zinc Pyrithione 0.4, fluorapatite 4-7, titanium dioxide 12, dinoctyl phthalate 2, Yatall MA 0.7, glass fibre 3, ammonium polyphosphate 1, vinylbenzene 160, methyl acrylate 100, butyl methacrylate 60, ammonium persulphate 4, ammonium metaborate 0.7, OP-10 6, adhesive aid 5, deionized water 600;
Described adhesive aid is made up of each raw material of following weight parts:
Isobornyl acrylate 8, organosilicon crylic acid latex 30, micro encapsulation Flos Rosae Rugosae quintessence oil 2, dimethylaminoethyl methacrylate 4, Potassium Persulphate 1, redwood micro mist 2, polyvinylpyrrolidone 0.6, deionized water 16;
Polyvinylpyrrolidone is mixed with Potassium Persulphate, adds 80% of above-mentioned deionized water weight, stir;
Micro encapsulation Flos Rosae Rugosae quintessence oil is mixed with isobornyl acrylate, at 70 DEG C, is uniformly mixed 5 minutes, join in organosilicon crylic acid latex, 200 revs/min of dispersed with stirring 10 minutes;
Mixed with each raw material of residue by each raw material after above-mentioned process, 400 revs/min of dispersed with stirring 15 minutes, obtain described adhesive aid.
A preparation method for wear-resistant smooth interior wall coating, is characterized in that comprising the following steps:
(1) get the 80-90% of above-mentioned vinylbenzene weight, the 80-90% of methyl acrylate weight, the 70-80% mixing of butyl methacrylate weight, obtain monomer a;
(2) get OP-10, add 30% of above-mentioned deionized water weight, stir, obtain pre-emulsion;
(3) get ammonium persulphate, add 20% of residue deionized water weight, stir, add ammonium metaborate, at 60 DEG C, insulated and stirred 5 minutes, is cooled to normal temperature, obtains initiator solution;
(4) get above-mentioned monomer a, 50% of pre-emulsion weight, 60% of initiator solution weight, mixing, at 80 DEG C, insulated and stirred 20 minutes, obtains premix monomer;
(5) four water eight borate two sodium is got, add 40% of residue deionized water weight, 2-adamantanol, dinoctyl phthalate is added after stirring, insulated and stirred 4 minutes at 60 DEG C, add remaining vinylbenzene, methyl acrylate, butyl methacrylate, 200 revs/min of dispersed with stirring 20 minutes, obtain modified monomer;
(6) above-mentioned modified monomer is mixed with remaining pre-emulsion, remaining initiator solution, insulated and stirred 50 minutes at 90 DEG C, drip above-mentioned premix monomer, time for adding is 3 hours, at 80-85 DEG C, 2 hours are incubated after dropwising, reduce temperature to 50 DEG C, regulate pH value to 7, filter with 250 order filter sieve;
(7) material above-mentioned steps (6) obtained mixes with each raw material of residue, and 1200 revs/min of dispersed with stirring 30 minutes, obtain described wear-resistant smooth interior wall coating.
Performance test:
Unit elongation: >=300%;
Watertightness: 0.3MPa (one hour waterproof).

Claims (2)

1. a wear-resistant smooth interior wall coating, is characterized in that what it was made up of the raw material of following weight parts:
2-adamantanol 0.8-1, four water eight borate two sodium 0.7-1, Zinc Pyrithione 0.1-0.4, fluorapatite 4-7, titanium dioxide 10-12, dinoctyl phthalate 2-4, Yatall MA 0.7-2, glass fibre 2-3, ammonium polyphosphate 1-2, vinylbenzene 120-160, methyl acrylate 80-100, butyl methacrylate 40-60, ammonium persulphate 3-4, ammonium metaborate 0.7-1, OP-10 6-8, adhesive aid 5-7, deionized water 500-600;
Described adhesive aid is made up of each raw material of following weight parts:
Isobornyl acrylate 6-8, organosilicon crylic acid latex 25-30, micro encapsulation Flos Rosae Rugosae quintessence oil 2-3, dimethylaminoethyl methacrylate 4-6, Potassium Persulphate 1-2, redwood micro mist 2-3, polyvinylpyrrolidone 0.6-1, deionized water 10-16;
Polyvinylpyrrolidone is mixed with Potassium Persulphate, adds the 70-80% of above-mentioned deionized water weight, stir;
Micro encapsulation Flos Rosae Rugosae quintessence oil is mixed with isobornyl acrylate, at 60-70 DEG C, is uniformly mixed 3-5 minute, join in organosilicon crylic acid latex, 100-200 rev/min of dispersed with stirring 5-10 minute;
Mixed with each raw material of residue by each raw material after above-mentioned process, 300-400 rev/min of dispersed with stirring 10-15 minute, obtains described adhesive aid.
2. a preparation method for wear-resistant smooth interior wall coating as claimed in claim 1, is characterized in that comprising the following steps:
(1) get the 80-90% of above-mentioned vinylbenzene weight, the 80-90% of methyl acrylate weight, the 70-80% mixing of butyl methacrylate weight, obtain monomer a;
(2) get OP-10, add the 30-40% of above-mentioned deionized water weight, stir, obtain pre-emulsion;
(3) get ammonium persulphate, add the 10-20% of residue deionized water weight, stir, add ammonium metaborate, insulated and stirred 3-5 minute at 50-60 DEG C, is cooled to normal temperature, obtains initiator solution;
(4) get above-mentioned monomer a, the 40-50% of pre-emulsion weight, the 50-60% of initiator solution weight, mixing, insulated and stirred 10-20 minute at 75-80 DEG C, obtains premix monomer;
(5) four water eight borate two sodium is got, add the 30-40% of residue deionized water weight, 2-adamantanol, dinoctyl phthalate is added after stirring, insulated and stirred 2-4 minute at 50-60 DEG C, add remaining vinylbenzene, methyl acrylate, butyl methacrylate, 100-200 rev/min of dispersed with stirring 10-20 minute, obtains modified monomer;
(6) above-mentioned modified monomer is mixed with remaining pre-emulsion, remaining initiator solution, insulated and stirred 30-50 minute at 70-90 DEG C, drip above-mentioned premix monomer, time for adding is 2-3 hour, at 80-85 DEG C, 2-3 hour is incubated after dropwising, reduce temperature to 40-50 DEG C, regulate pH value to 7-8, filter with 200-250 order filter sieve;
(7) material above-mentioned steps (6) obtained mixes with each raw material of residue, and 800-1200 rev/min of dispersed with stirring 20-30 minute, obtains described wear-resistant smooth interior wall coating.
CN201410446206.7A 2014-09-03 2014-09-03 Anti-wear smooth internal wall coating Pending CN104356776A (en)

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CN201410446206.7A CN104356776A (en) 2014-09-03 2014-09-03 Anti-wear smooth internal wall coating

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Application Number Priority Date Filing Date Title
CN201410446206.7A CN104356776A (en) 2014-09-03 2014-09-03 Anti-wear smooth internal wall coating

Publications (1)

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CN104356776A true CN104356776A (en) 2015-02-18

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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103351675A (en) * 2013-06-20 2013-10-16 滁州麦斯特新型建材有限公司 Washing resistive exterior wall coating and preparation method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103351675A (en) * 2013-06-20 2013-10-16 滁州麦斯特新型建材有限公司 Washing resistive exterior wall coating and preparation method thereof

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Application publication date: 20150218

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