CN104263105A - Anti-aging waterproof coating - Google Patents
Anti-aging waterproof coating Download PDFInfo
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- CN104263105A CN104263105A CN201410446226.4A CN201410446226A CN104263105A CN 104263105 A CN104263105 A CN 104263105A CN 201410446226 A CN201410446226 A CN 201410446226A CN 104263105 A CN104263105 A CN 104263105A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses an anti-aging waterproof coating. The anti-aging waterproof coating is prepared from the following raw materials in parts by weight: 1-2 parts of tar residue, 2-3 parts of 2-butoxyethanol, 1-2 parts of guanidine sulfamate, 3-6 parts of polypropylene powder, 2-3 parts of alkenyl succinate, 0.6-1 part of benzotriazole, 0.1-0.2 part of dibasic lead phosphate, 2-4 parts of calcium hydrophosphate, 1-2 parts of barium metaborate, 10-14 parts of precipitated barium sulphate, 4-7 parts of pentaerythritol, 140-200 parts of styrene, 500-600 parts of deionized water, 140-200 parts of butyl acrylate, 3-6 parts of sodium persulfate, 2-4 parts of sorbitan trioleate, 2-4 parts of polyoxyethylene laurate and 4-5 parts of bonding auxiliaries. The anti-aging waterproof coating has excellent waterproofness, wear resistance, crack resistance and impact resistance, and good weather fastness; the formed film is high in surface strength, lasting in protection effect on a substrate, and less in cracking possibility.
Description
?
Technical field
The present invention relates generally to paint field, particularly relates to a kind of ageing-resistant waterproof coating.
Background technology
Be applied to body surface can be formed there is protection, the class I liquid I of solid-state film of decoration or property (as insulation, anticorrosion, mark etc.) or the general name of solid material, comprise oil (property) paint, water-miscible paint, powder coating.Paint is flowable liquid coating, comprises oil (property) paint and water-miscible paint.Paint take organic solvent as medium or high solid, solvent-free oil-base paint.Water-miscible paint is used water dissolving or the coating with water-dispersion.Coating is as one of the main material of house decoration, and the large percentage accounted in decorations, buys the whether qualified environment directly having influence on overall finishing effect and room of coating, sometimes even can produce harm greatly to the health of human body.At present along with the generation of various coating, the quality requirements of coating is also improved constantly, and improve constantly coating quality and can play very large help for building, life.
Summary of the invention
The object of the invention is just to provide a kind of ageing-resistant waterproof coating.
The present invention is achieved by the following technical solutions:
A kind of ageing-resistant waterproof coating, is characterized in that what it was made up of the raw material of following weight parts:
Coke tar refuse 1-2, butoxy ethanol 2-3, Guanidine Sulfamate 99 1-2, polypropylene powder 3-6, alkenyl succinic acid ester 2-3, benzotriazole 0.6-1, dibasic lead phosphite 0.1-0.2, secondary calcium phosphate 2-4, barium metaborate 1-2, process white 10-14, tetramethylolmethane 4-7, vinylbenzene 140-200, deionized water 500-600, butyl acrylate 140-200, Sodium Persulfate 3-6, Witconol AL 69-66 2-4, lauric acid polyoxyethylene ester 2-4, adhesive aid 4-5;
Described adhesive aid is made up of each raw material of following weight parts:
Alumina gel 20-30, exsiccated ammonium alum 1-3, lanolin 1-2, polyethylene glycol dimethacrylate 0.6-1, dehydrated alcohol 3-4, Isooctyl acrylate monomer 2-4, Potassium Persulphate 2-3, emulsifier op-10 0.5-1, Camphorwood micro mist 2-4, deionized water 15-20;
Dehydrated alcohol is heated to 70-75 DEG C, adds lanolin, stir, obtain alcohol lipoprotein solution;
Join in Alumina gel by Camphorwood micro mist, add polyethylene glycol dimethacrylate, raised temperature is 55-60 DEG C, 100-200 rev/min of dispersed with stirring 3-5 minute, obtains dispersion liquid;
Potassium Persulphate is mixed with Isooctyl acrylate monomer, 2-3 minute is uniformly mixed at 60-70 DEG C, add dispersion liquid, be stirred to normal temperature, add above-mentioned alcohol lipoprotein solution, 60-100 rev/min is uniformly mixed 5-10 minute, adds each raw material of residue, 200-400 rev/min of dispersed with stirring 3-5 minute, obtains described adhesive aid.
A preparation method for ageing-resistant waterproof coating, is characterized in that comprising the following steps:
(1) get above-mentioned vinylbenzene, butyl acrylate mixing, obtain monomer a;
(2) by Witconol AL 69-66, the mixing of lauric acid polyoxyethylene ester, add the 30-40% of above-mentioned deionized water weight, at 50-70 DEG C of insulated and stirred 15-20 minute, add tetramethylolmethane, be stirred to normal temperature, obtain pre-emulsion;
(3) get Sodium Persulfate, add the 10-20% of residue deionized water weight, stir, obtain initiator solution;
(4) get 70-80%, the 40-50% of pre-emulsion weight, the 50-60% of initiator solution weight of above-mentioned monomer a weight, mixing, adds Guanidine Sulfamate 99, insulated and stirred 10-20 minute at 75-80 DEG C, obtains premix monomer;
(5) by remaining monomer a, remaining pre-emulsion, the mixing of remaining initiator solution, insulated and stirred 30-50 minute at 70-90 DEG C, drip above-mentioned premix monomer, time for adding is 2-3 hour, at 80-85 DEG C, 2-3 hour is incubated after dropwising, reduce temperature to 40-50 DEG C, regulate pH value to 7-8, filter with 200-250 order filter sieve;
(6) material above-mentioned steps (5) obtained mixes with each raw material of residue, and 800-1200 rev/min of dispersed with stirring 20-30 minute, obtains described ageing-resistant waterproof coating.
Advantage of the present invention is:
Coating resistance to deterioration of the present invention is strong, and have excellent waterproof, wear-resistant, cracking resistance, shock resistance, good weatherability, film coated surface intensity is high, lasting, not easy to crack to the protected effect of base material.The Camphorwood micro mist added in adhesive aid of the present invention has good resistance to abrasion, Heat stability is good chemical stability, Alumina gel mixes with exsiccated ammonium alum, lanolin, Isooctyl acrylate monomer, Potassium Persulphate, there is excellent adhesive property, coatingsurface resistance and stability can be strengthened.
Embodiment
Embodiment 1
A kind of ageing-resistant waterproof coating, is characterized in that what it was made up of the raw material of following weight parts:
Coke tar refuse 2, butoxy ethanol 3, Guanidine Sulfamate 99 2, polypropylene powder 6, alkenyl succinic acid ester 2, benzotriazole 0.6, dibasic lead phosphite 0.2, secondary calcium phosphate 4, barium metaborate 2, process white 14, tetramethylolmethane 4, vinylbenzene 200, deionized water 600, butyl acrylate 200, Sodium Persulfate 6, Witconol AL 69-66 2, lauric acid polyoxyethylene ester 2, adhesive aid 4;
Described adhesive aid is made up of each raw material of following weight parts:
Alumina gel 30, exsiccated ammonium alum 3, lanolin 1, polyethylene glycol dimethacrylate 0.6, dehydrated alcohol 4, Isooctyl acrylate monomer 2, Potassium Persulphate 3, emulsifier op-10 0.5, Camphorwood micro mist 4, deionized water 20;
Dehydrated alcohol is heated to 75 DEG C, adds lanolin, stir, obtain alcohol lipoprotein solution;
Join in Alumina gel by Camphorwood micro mist, add polyethylene glycol dimethacrylate, raised temperature is 60 DEG C, and 200 revs/min of dispersed with stirring 3 minutes, obtain dispersion liquid;
Potassium Persulphate is mixed with Isooctyl acrylate monomer, at 70 DEG C, is uniformly mixed 3 minutes, adds dispersion liquid, be stirred to normal temperature, add above-mentioned alcohol lipoprotein solution, 100 revs/min are uniformly mixed 10 minutes, add each raw material of residue, 200-400 rev/min of dispersed with stirring 3 minutes, obtains described adhesive aid.
A preparation method for ageing-resistant waterproof coating, is characterized in that comprising the following steps:
(1) get above-mentioned vinylbenzene, butyl acrylate mixing, obtain monomer a;
(2) by Witconol AL 69-66, the mixing of lauric acid polyoxyethylene ester, add 30% of above-mentioned deionized water weight, 70 DEG C of insulated and stirred 20 minutes, add tetramethylolmethane, be stirred to normal temperature, obtain pre-emulsion;
(3) get Sodium Persulfate, add 20% of residue deionized water weight, stir, obtain initiator solution;
(4) get 70% of above-mentioned monomer a weight, 40% of pre-emulsion weight, the 50-60% of initiator solution weight, mixing, add Guanidine Sulfamate 99, at 80 DEG C, insulated and stirred 20 minutes, obtains premix monomer;
(5) by remaining monomer a, remaining pre-emulsion, the mixing of remaining initiator solution, insulated and stirred 50 minutes at 90 DEG C, drip above-mentioned premix monomer, time for adding is 3 hours, at 85 DEG C, 3 hours are incubated after dropwising, reduce temperature to 50 DEG C, regulate pH value to 8, filter with 250 order filter sieve;
(6) material above-mentioned steps (5) obtained mixes with each raw material of residue, and 1200 revs/min of dispersed with stirring 30 minutes, obtain described ageing-resistant waterproof coating.
Performance test:
Unit elongation: >=300%;
Watertightness: 0.3MPa (one hour waterproof).
Claims (2)
1. an ageing-resistant waterproof coating, is characterized in that what it was made up of the raw material of following weight parts:
Coke tar refuse 1-2, butoxy ethanol 2-3, Guanidine Sulfamate 99 1-2, polypropylene powder 3-6, alkenyl succinic acid ester 2-3, benzotriazole 0.6-1, dibasic lead phosphite 0.1-0.2, secondary calcium phosphate 2-4, barium metaborate 1-2, process white 10-14, tetramethylolmethane 4-7, vinylbenzene 140-200, deionized water 500-600, butyl acrylate 140-200, Sodium Persulfate 3-6, Witconol AL 69-66 2-4, lauric acid polyoxyethylene ester 2-4, adhesive aid 4-5;
Described adhesive aid is made up of each raw material of following weight parts:
Alumina gel 20-30, exsiccated ammonium alum 1-3, lanolin 1-2, polyethylene glycol dimethacrylate 0.6-1, dehydrated alcohol 3-4, Isooctyl acrylate monomer 2-4, Potassium Persulphate 2-3, emulsifier op-10 0.5-1, Camphorwood micro mist 2-4, deionized water 15-20;
Dehydrated alcohol is heated to 70-75 DEG C, adds lanolin, stir, obtain alcohol lipoprotein solution;
Join in Alumina gel by Camphorwood micro mist, add polyethylene glycol dimethacrylate, raised temperature is 55-60 DEG C, 100-200 rev/min of dispersed with stirring 3-5 minute, obtains dispersion liquid;
Potassium Persulphate is mixed with Isooctyl acrylate monomer, 2-3 minute is uniformly mixed at 60-70 DEG C, add dispersion liquid, be stirred to normal temperature, add above-mentioned alcohol lipoprotein solution, 60-100 rev/min is uniformly mixed 5-10 minute, adds each raw material of residue, 200-400 rev/min of dispersed with stirring 3-5 minute, obtains described adhesive aid.
2. a preparation method for ageing-resistant waterproof coating as claimed in claim 1, is characterized in that comprising the following steps:
(1) get above-mentioned vinylbenzene, butyl acrylate mixing, obtain monomer a;
(2) by Witconol AL 69-66, the mixing of lauric acid polyoxyethylene ester, add the 30-40% of above-mentioned deionized water weight, at 50-70 DEG C of insulated and stirred 15-20 minute, add tetramethylolmethane, be stirred to normal temperature, obtain pre-emulsion;
(3) get Sodium Persulfate, add the 10-20% of residue deionized water weight, stir, obtain initiator solution;
(4) get 70-80%, the 40-50% of pre-emulsion weight, the 50-60% of initiator solution weight of above-mentioned monomer a weight, mixing, adds Guanidine Sulfamate 99, insulated and stirred 10-20 minute at 75-80 DEG C, obtains premix monomer;
(5) by remaining monomer a, remaining pre-emulsion, the mixing of remaining initiator solution, insulated and stirred 30-50 minute at 70-90 DEG C, drip above-mentioned premix monomer, time for adding is 2-3 hour, at 80-85 DEG C, 2-3 hour is incubated after dropwising, reduce temperature to 40-50 DEG C, regulate pH value to 7-8, filter with 200-250 order filter sieve;
(6) material above-mentioned steps (5) obtained mixes with each raw material of residue, and 800-1200 rev/min of dispersed with stirring 20-30 minute, obtains described ageing-resistant waterproof coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410446226.4A CN104263105A (en) | 2014-09-04 | 2014-09-04 | Anti-aging waterproof coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410446226.4A CN104263105A (en) | 2014-09-04 | 2014-09-04 | Anti-aging waterproof coating |
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| Publication Number | Publication Date |
|---|---|
| CN104263105A true CN104263105A (en) | 2015-01-07 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410446226.4A Pending CN104263105A (en) | 2014-09-04 | 2014-09-04 | Anti-aging waterproof coating |
Country Status (1)
| Country | Link |
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| CN (1) | CN104263105A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104774383A (en) * | 2015-03-26 | 2015-07-15 | 安徽海纳川塑业科技有限公司 | Bursting-resistant and heat-resistant polypropylene composite material |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1386809A (en) * | 2002-05-23 | 2002-12-25 | 中国建筑材料科学研究院 | Water-proof polymer-cement paint with low polymer/cement ratio and high performance and its preparing process |
| CN102173648A (en) * | 2011-01-11 | 2011-09-07 | 上海胜星树脂涂料有限公司 | Water-based high-temperature-resistant oxidation-resistant inorganic paint and preparation method thereof |
| CN103602194A (en) * | 2013-10-25 | 2014-02-26 | 安徽工贸职业技术学院 | Acrylate waterproof coating material |
-
2014
- 2014-09-04 CN CN201410446226.4A patent/CN104263105A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1386809A (en) * | 2002-05-23 | 2002-12-25 | 中国建筑材料科学研究院 | Water-proof polymer-cement paint with low polymer/cement ratio and high performance and its preparing process |
| CN102173648A (en) * | 2011-01-11 | 2011-09-07 | 上海胜星树脂涂料有限公司 | Water-based high-temperature-resistant oxidation-resistant inorganic paint and preparation method thereof |
| CN103602194A (en) * | 2013-10-25 | 2014-02-26 | 安徽工贸职业技术学院 | Acrylate waterproof coating material |
Non-Patent Citations (1)
| Title |
|---|
| 冯胜: "《精细化工手册（下）》", 31 March 1995, 广东科技出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104774383A (en) * | 2015-03-26 | 2015-07-15 | 安徽海纳川塑业科技有限公司 | Bursting-resistant and heat-resistant polypropylene composite material |
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Application publication date: 20150107 |
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