CN104351991B - The production method of the water soluble adhesive lining of the extremely low washing shrinkage of the feature of environmental protection easy to operate - Google Patents

The production method of the water soluble adhesive lining of the extremely low washing shrinkage of the feature of environmental protection easy to operate Download PDF

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Publication number
CN104351991B
CN104351991B CN201410677109.9A CN201410677109A CN104351991B CN 104351991 B CN104351991 B CN 104351991B CN 201410677109 A CN201410677109 A CN 201410677109A CN 104351991 B CN104351991 B CN 104351991B
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water
during
inch
cloth
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CN104351991A (en
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曹平
杨杰
朱红耀
黄�俊
曾燕
姜伟
吴亮亮
王春梅
陈美云
黄新华
黄玉良
杨静新
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NANTONG HAIHUI GARMENT ACCESSORIES Co Ltd
Nantong University
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NANTONG HAIHUI GARMENT ACCESSORIES Co Ltd
Nantong University
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    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D27/00Details of garments or of their making
    • A41D27/02Linings
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D13/00Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B15/00Removing liquids, gases or vapours from textile materials in association with treatment of the materials by liquids, gases or vapours
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/10Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
    • D06B3/18Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics combined with squeezing, e.g. in padding machines

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatment Of Fiber Materials (AREA)

Abstract

The invention discloses a kind of production method of water soluble adhesive lining of extremely low washing shrinkage of the feature of environmental protection easy to operate, is-0.6% ~ 0.5% through broadwise washing size changing rate; After thermal smelting adesive lining is combined with fabric pressing, process and fabric disengaging time < 15 seconds in 35 DEG C of water; Dissociate and hydrolysis formaldehyde≤35mg/kg.Production method of the present invention comprise successively turn over seam, singe, destarch, kiering, bleaching, multiple drift or dyeing, post processing, liquid ammonia finishing, shiinkproof finish, machine shrunk, powder point coating step.The present invention is extremely low through broadwise washing shrinkage, and water soluble characteristic is good, free and hydrolysis formaldehyde is minimum, and production method is easy to operate.

Description

The production method of the water soluble adhesive lining of the extremely low washing shrinkage of the feature of environmental protection easy to operate
The application is application number: 201310439365.X, title: the divisional application of " the water-soluble hot melt adhesive lining of extremely low washing shrinkage and production method thereof ".
Technical field:
The present invention relates to a kind of lining cloth and production method.
Background technology:
Existing lining cloth, it is large through broadwise washing shrinkage, and formaldehyde amount that is free and hydrolysis is large, and after thermal smelting adesive lining is combined with fabric, separating property is not good, affects high-grade leisure clothes serviceability and result of use.
Summary of the invention:
One is the object of the present invention is to provide to be-0.6% ~ 0.5% through broadwise washing size changing rate; After thermal smelting adesive lining is combined with fabric pressing, process and fabric disengaging time < 15 seconds in 35 DEG C of water; The production method of the water-soluble hot melt adhesive lining of the extremely low washing shrinkage of free and hydrolysis formaldehyde≤35mg/kg.
Technical solution of the present invention is:
A water-soluble hot melt adhesive lining for extremely low washing shrinkage, is characterized in that: washing size changing rate through broadwise is-0.6% ~ 0.5%; After thermal smelting adesive lining is combined with fabric pressing, process and fabric disengaging time < 15 seconds in 35 DEG C of water; Dissociate and hydrolysis formaldehyde≤35mg/kg.
The grey cloth of lining cloth is heavy weave, middle flat fabric; Wherein said heavy weave is the one in following two kinds of specifications: the first door width is 48.5 inches, yarn count is 12 s× 12 s, density is 49 × 43 pieces/inch, twist per unit is 46 sth. made by twisting/10cm, the door width of the second is 48.5 inches, yarn count is 16 s× 16 s, density is 60 × 58 pieces/inch, twist per unit is 58 sth. made by twisting/10cm; Described middle flat fabric is the one in following seven kinds of specifications: the first door width is 48.5 inches, yarn count is 20 s× 20 s, density is 60 × 60 pieces/inch, twist per unit is 64 sth. made by twisting/10cm, the door width of the second is 48.5 inches, yarn count is 20 s× 20 s, density is 50 × 50 pieces/inch, twist per unit is 64 sth. made by twisting/10cm, the third door width is 48.5 inches, yarn count is 30 s× 30 s, density is 56 × 44 pieces/inch, twist per unit is 78 sth. made by twisting/10cm, the yarn count of the 4th kind is 30 s× 30 s, density is 68 × 68 pieces/inch, twist per unit is 78 sth. made by twisting/10cm, the door width of the 5th kind is 48.5 inches, yarn count is 30 s× 40 s, density is 64 × 56 pieces/inch, twist per unit is 78 or 90 sth. made by twisting/10cm, the door width of the 6th kind is 48.5 inches, yarn count is 40 s× 40 s, density is 52 × 40 pieces/inch, twist per unit is 90 sth. made by twisting/10cm, the door width of the 7th kind is 48.5 inches, yarn count is 40 s× 40 s, density is 58 × 50 pieces/inch, twist per unit is 90 sth. made by twisting/10cm.
A production method for the water-soluble hot melt adhesive lining of extremely low washing shrinkage, is characterized in that: comprise successively turn over seam, singe, destarch is concise, bleaching, multiple drift or dyeing, post processing, liquid ammonia finishing, shiinkproof finish, machine shrunk, powder point coating step.
During wherein destarch refining processing, fabric open width pads the concise liquid of destarch, then at 100 ~ 102 DEG C decatize 60 ~ 100 minutes, open width is washed, and what wherein destarch seminal fluid was practiced consists of: NaOH 25 ~ 35g/L, scouring agent A-114 6 ~ 8g/L, and all the other are water; During bleaching, open width pads oxygen bleaching liquid, decatize 60 ~ 75 minutes at 100 ~ 102 DEG C, and open width is washed, wherein oxygen bleaching liquid consists of: hydrogen peroxide 4 ~ 6.5g/L, waterglass 10 ~ 12g/L, scouring agent A-114 4g/L, intercalating agent 540 3g/L, and all the other are water; During multiple drift process, pad oxygen bleaching liquid, decatize 55 ~ 60 minutes at 100 ~ 102 DEG C by open width, open width is washed, and wherein oxygen bleaching liquid consists of: hydrogen peroxide 2 ~ 3.5g/L, waterglass 3 ~ 5g/L, scouring agent A-114 2g/L; During post processing, being neutralized to pH with the acetic acid that concentration is 2 ~ 3g/L is 5.5 ~ 6.5; During liquid ammonia finishing by open width enter cloth, dry dry, liquefied ammonia encapsulation process, decatize deammoniation, cropping step; Enter cloth by open width during shiinkproof finish, needle plate on shiinkproof finish liquid, 80 ~ 100 DEG C of loose formula dryings, overfeeding is rolled in two leachings two, eight lattice, 170 ~ 175 DEG C of hot blasts bake, cropping step; During machine shrunk process, enter cloth by open width, water dewing, cloth surface humidity are 10% ~ 20%, and rubber blanket pre-shrinking, preshrunk amount are 2% ~ 5%, heating bearing roller temperature is 50 ~ 95 DEG C, and drying cylinder pine formula is dried, cropping; During dyeing, for grey yarn dyed fabric reducing dye dyeing flow process and condition be:
Open width is entered cloth → evenness calender and is padded dye liquor → two and arrange infrared preliminary drying → two groups of 70 ~ 80 DEG C hot blast preliminary drying → mono-group cylinder oven dry → cropping → evenness calenders and pad reductive steam box decatize 2 minutes → two lattice 5 ~ 30 DEG C of cold wash → ventilative oxidation at reducing solution → 102 DEG C → with the hydrogen peroxide oxidation of 0.5 ~ 1g/L concentration → carry out two lattice soap boilings with the soap boiling agent of concentration 2 ~ 3g/L, → six lattice flat wash troughs single-frame flow backwards washing, every Ge Wendu is respectively 90 ~ 95 DEG C, 80 ~ 90 DEG C, 70 ~ 80 DEG C, 70 ~ 80 DEG C, 60 ~ 70 DEG C, 5 ~ 30 DEG C → two rows totally 24 cylinder oven dry → croppings, wherein dye liquor consists of:
Vat black RB 10 g/L
Vat Brown BR 7 g/L
Threne olive T 1 g/L
All the other are water;
Reducing solution consists of:
NaOH 18 ~ 20 g/L
Sodium hydrosulfite 16 ~ 18 g/L of 85% weight content
All the other are water;
During dyeing, for black fabric reactive dyeing process flow process and condition be:
Open width is entered cloth → evenness calender and is padded dye liquor → two and arrange infrared preliminary drying → two groups of 70 ~ 80 DEG C hot blast preliminary drying → mono-group cylinder ovens dry → cropping → evenness calenders and pad that fixation liquid → 102 DEG C reductive steam box decatize 2 minutes fixation → two lattice, 5 ~ 30 DEG C of cold wash → two lattice 50 ~ 60 DEG C of hot water wash → carrying out two lattice soap boiling → six lattice flat wash troughs with the soap boiling agent of concentration 2 ~ 3g/L single-frame flows backwards washing, and every Ge Wendu is respectively 90 ~ 95 DEG C, 80 ~ 90 DEG C, 70 ~ 80 DEG C, 70 ~ 80 DEG C, 60 ~ 70 DEG C, 5 ~ 30 DEG C → two and arranges totally 24 cylinder oven dry → croppings;
Wherein dye liquor consists of:
Active black MES 24 g/L
Active yellow MES 8.8 g/L
Active red MES 2.6 g/L
All the other are water;
Fixation liquid consists of:
Soda ash 8g/L
Glauber salt 200 g/L
All the other are water.
The concrete steps of liquid ammonia finishing are followed successively by: the single-column drying cylinder that open width enters cloth, employing drying cylinder vapour pressure is 0.15Mpa is dried, cool through cold water roller again, then liquefied ammonia encapsulation process is carried out, liquefied ammonia encapsulation process enters cloth from slit, makes cloth enter liquefied ammonia reative cell, and with three rolling car immersion liquid ammonia, ammonia is removed again with the 50 DEG C of xeothermic deammoniations of single-column blanket drying cylinder, admission steam room spray vapour, the temperature of steaming vessel is 95 ~ 105 DEG C, then goes out steaming vessel, with ventilative frame air cooling, the dry cropping of open width.
Liquefied ammonia reative cell vapour pressure is negative pressure 5 ~ 10mmH 2o; Steaming vessel vapour pressure is negative pressure 5 ~ 10mmH 2o; During Liquid Ammonia Treatment, the pressure of three rolling cars is 0.08Mpa, and after padding liquefied ammonia, cloth cover warp-wise tension force is 0.03Mpa.
The dried liquid carrying rate of loose formula of shiinkproof finish is 30% ~ 40%.
During middle flat fabric anti-shrinking, consisting of of shiinkproof finish liquid:
Arkofix NDF liq c 80~90 g/L
MgCl 2·6H 2O 14~15 g/L
Ethylene urea 2.0 g/L
NON IONIC SOFTNER V-12 3.5 g/L
Brightening agent MST 0 ~ 2.15g/L
Brightening agent MST-B 0 ~ 4.22g/L
All the other are water, and adjust pH to 4.0 with citric acid;
During middle flat fabric anti-shrinking, overfeeding 2% ~ 3%, when baking, the speed of a motor vehicle is 40m/ minute.
During heavy weave anti-shrinking, consisting of of shiinkproof finish liquid:
Arkofix NDF liq c 100~120 g/L
MgCl 2·6H 2O 16 ~18 g/L
Ethylene urea 2.0 g/L
NON IONIC SOFTNER V-12 3.5 g/L
Brightening agent MST 0 ~ 2.15g/L
Brightening agent MST-B 0 ~ 4.22g/L,
All the other are water, and adjust pH to 4.0 with citric acid;
During heavy weave anti-shrinking, overfeeding 1.5% ~ 3%, when baking, the speed of a motor vehicle is 30m/ minute.
Water-soluble powder point coating comprises open width and enters cloth, 210 ~ 245 DEG C of preheatings of No. 1 oily hot-rolling, 200 ~ 250 DEG C of preheatings of No. 2 oily hot-rollings, engraved roll polyethylene glycol PUR powder point coating, 210 ~ 250 DEG C of heating of No. 3 oily hot-rollings, 140 ~ 160 DEG C of tentering setting, temperature≤25 DEG C water cooling, package step; Engraved roll order number: 30 adopted for middle flat fabric, 33,35 orders/inch, 28 adopted for heavy weave, 30,33 orders/inch.The arrangement of the carved pattern of engraved roll regularly arranged or computer random; In, heavy weave powder point coating amount 22 ± 2g/m 2, prevent reverse side from permeating; During powder point coating, engraved roll inside normal temperature or cooling water in line.
The present invention is-0.6% ~ 0.5% through broadwise washing size changing rate; After thermal smelting adesive lining is combined with fabric pressing, process and fabric disengaging time < 15 seconds in 35 DEG C of water; Dissociate and hydrolysis formaldehyde≤35mg/kg.Good environmental protection of the present invention, production method is easy to operate.
Below in conjunction with embodiment, the invention will be further described.
Detailed description of the invention:
Embodiment 1:
A production method for the water-soluble hot melt adhesive lining of extremely low washing shrinkage, comprise successively seam turned over to thick or middle flat fabric grey cloth, singe, destarch is concise, bleaching, multiple drift, post processing, liquid ammonia finishing, shiinkproof finish, machine shrunk, powder point coating step; Wherein during the concise reason of destarch, fabric open width pads the concise liquid of destarch, decatize 60 ~ 100 minutes (example 60,80,100 minutes) at 100 ~ 102 DEG C again, open width is washed, what wherein destarch seminal fluid was practiced consists of: NaOH 25 ~ 35g/L(example 25 g/L, 30 g/L, 35 g/L), scouring agent A-114 6 ~ 8g/L(example 6 g/L, 8 g/L), all the other are water; During bleaching, open width pads oxygen bleaching liquid, decatize 60 ~ 75 minutes at 100 ~ 102 DEG C, open width is washed, wherein oxygen bleaching liquid consists of: hydrogen peroxide 4.5 ~ 6.5g/(example 5 g/L, 5.5 g/L, 6 g/L), waterglass 10 ~ 12g/L, scouring agent A-114 4g/L, intercalating agent 540 3g/L, all the other are water; During multiple drift process, pad oxygen bleaching liquid, decatize 55 ~ 60 minutes at 100 ~ 102 DEG C by open width, open width is washed, and make cloth cover pH be 6, wherein oxygen bleaching liquid consists of: hydrogen peroxide 2 ~ 3.5g/L, waterglass 3 ~ 5g/L, scouring agent A-114 2g/L; The concrete steps of liquid ammonia finishing are followed successively by: the single-column drying cylinder that open width enters cloth, employing drying cylinder vapour pressure is 0.15Mpa is dried, cool through cold water roller again, then liquefied ammonia encapsulation process is carried out, liquefied ammonia encapsulation process enters cloth from slit, makes cloth enter liquefied ammonia reative cell, and with three rolling car immersion liquid ammonia, ammonia is removed again with the 50 DEG C of xeothermic deammoniations of single-column blanket drying cylinder, admission steam room spray vapour, the temperature of steaming vessel is 95 ~ 105 DEG C, then goes out steaming vessel, with ventilative frame air cooling, the dry cropping of open width; Liquefied ammonia reative cell vapour pressure is negative pressure 5 ~ 10mmH 2o; Steaming vessel vapour pressure is negative pressure 5 ~ 10mmH 2o; During Liquid Ammonia Treatment, the pressure of three rolling cars is 0.08Mpa, and after padding liquefied ammonia, cloth cover warp-wise tension force is 0.03Mpa.During post processing, being neutralized to pH with the acetic acid that concentration is 2 ~ 3g/L is 5.5 ~ 6.5; Enter cloth by open width during shiinkproof finish, needle plate on shiinkproof finish liquid, 80 ~ 100 DEG C of loose formula dryings, overfeeding is rolled in two leachings two, eight lattice, 170 ~ 175 DEG C of hot blasts bake, cropping step; During machine shrunk process, enter cloth by open width, water dewing, cloth surface humidity are 10% ~ 20%(example 10%, 15%, 20%), rubber blanket pre-shrinking, preshrunk amount are 2% ~ 5%, heating bearing roller temperature be 50 ~ 95 DEG C (example 60 DEG C, 70 DEG C, 80 DEG C), drying cylinder pine formula is dried, cropping step.
Described heavy weave is the one in following two kinds of specifications: the first door width is 48.5 inches, yarn count is 12 s× 12 s, density is 49 × 43 pieces/inch, twist per unit is 46 sth. made by twisting/10cm, the door width of the second is 48.5 inches, yarn count is 16 s× 16 s, density is 60 × 58 pieces/inch, twist per unit is 58 sth. made by twisting/10cm; Described middle flat fabric is the one in following seven kinds of specifications: the first door width is 48.5 inches, yarn count is 20 s× 20 s, density is 60 × 60 pieces/inch, twist per unit is 64 sth. made by twisting/10cm, the door width of the second is 48.5 inches, yarn count is 20 s× 20 s, density is 50 × 50 pieces/inch, twist per unit is 64 sth. made by twisting/10cm, the third door width is 48.5 inches, yarn count is 30 s× 30 s, density is 56 × 44 pieces/inch, twist per unit is 78 sth. made by twisting/10cm, the yarn count of the 4th kind is 30 s× 30 s, density is 68 × 68 pieces/inch, twist per unit is 78 sth. made by twisting/10cm, the door width of the 5th kind is 48.5 inches, yarn count is 30 s× 40 s, density is 64 × 56 pieces/inch, twist per unit is 78 or 90 sth. made by twisting/10cm, the door width of the 6th kind is 48.5 inches, yarn count is 40 s× 40 s, density is 52 × 40 pieces/inch, twist per unit is 90 sth. made by twisting/10cm, the door width of the 7th kind is 48.5 inches, yarn count is 40 s× 40 s, density is 58 × 50 pieces/inch, twist per unit is 90 sth. made by twisting/10cm.
The dried liquid carrying rate of loose formula of shiinkproof finish is 30% ~ 40%.
During middle flat fabric anti-shrinking, consisting of of shiinkproof finish liquid:
Arkofix NDF liq c 80~90 g/L
MgCl 2·6H 2O 14~15 g/L
Ethylene urea 2.0 g/L
NON IONIC SOFTNER V-12 3.5 g/L
Brightening agent MST 0 ~ 2.15g/L
Brightening agent MST-B 0 ~ 4.22g/L
All the other are water, and adjust pH to 4.0 with citric acid;
During middle flat fabric anti-shrinking, overfeeding 2% ~ 3%, when baking, the speed of a motor vehicle is 40m/ minute.
During heavy weave anti-shrinking, consisting of of shiinkproof finish liquid:
Arkofix NDF liq c 100~120 g/L
MgCl 2·6H 2O 16 ~18 g/L
Ethylene urea 2.0 g/L
NON IONIC SOFTNER V-12 3.5 g/L
Brightening agent MST 0 ~ 2.15g/L
Brightening agent MST-B 0 ~ 4.22g/L,
All the other are water, and adjust pH to 4.2 with citric acid;
During heavy weave anti-shrinking, overfeeding 1.5% ~ 3%, when baking, the speed of a motor vehicle is 30m/ minute.
Water-soluble powder point coating comprises open width and enters cloth, No. 1 oily hot-rolling 210-245 DEG C preheating, 200 ~ 250 DEG C of preheatings of No. 2 oily hot-rollings, engraved roll polyethylene glycol PUR powder point coating, 210 ~ 250 DEG C of heating of No. 3 oily hot-rollings, 140-160 DEG C tentering setting, temperature≤25 DEG C water cooling, package step; Engraved roll order number: 30 adopted for middle flat fabric, 33,35 orders/inch, 28 adopted for heavy weave, 30,33 orders/inch.The arrangement of the carved pattern of engraved roll regularly arranged or computer random; In, heavy weave powder point coating amount 22 ± 2g/m 2, prevent reverse side from permeating; In powder point coating process, tension force is low as far as possible, can not occur jumping powder, leak source, half head.During powder point coating, engraved roll inside normal temperature or cooling water in line.
The water-soluble hot melt adhesive lining of the extremely low washing shrinkage obtained is-0.6% ~ 0.5% through broadwise washing size changing rate; After thermal smelting adesive lining is combined with fabric pressing, process and fabric disengaging time < 15 seconds in 35 DEG C of water; Dissociate and hydrolysis formaldehyde≤35mg/kg.
Embodiment 2:
Change multiple drift step into staining procedure, all the other are with embodiment 1;
During dyeing, for grey yarn dyed fabric reducing dye dyeing flow process and condition be:
Open width is entered cloth → evenness calender and is padded dye liquor → two and arrange infrared preliminary drying → two groups of 70 ~ 80 DEG C hot blast preliminary drying → mono-group cylinder oven dry → cropping → evenness calenders and pad reductive steam box decatize 2 minutes → two lattice 5 ~ 30 DEG C of cold wash → ventilative oxidation at reducing solution → 102 DEG C → with the hydrogen peroxide oxidation of 0.5 ~ 1g/L concentration → carry out two lattice soap boilings with the soap boiling agent of concentration 2 ~ 3g/L, → six lattice flat wash troughs single-frame flow backwards washing, every Ge Wendu is respectively 90 ~ 95 DEG C, 80 ~ 90 DEG C, 70 ~ 80 DEG C, 70 ~ 80 DEG C, 60 ~ 70 DEG C, 5 ~ 30 DEG C → two rows totally 24 cylinder oven dry → croppings, wherein dye liquor consists of:
Vat black RB 10 g/L
Vat Brown BR 7 g/L
Threne olive T 1 g/L
All the other are water;
Reducing solution consists of:
NaOH 18 ~ 20 g/L
Sodium hydrosulfite 16 ~ 18 g/L of 85% weight content
All the other are water;
During dyeing, for black fabric reactive dyeing process flow process and condition be:
Open width is entered cloth → evenness calender and is padded dye liquor → two and arrange infrared preliminary drying → two groups of 70 ~ 80 DEG C hot blast preliminary drying → mono-group cylinder ovens dry → cropping → evenness calenders and pad that fixation liquid → 102 DEG C reductive steam box decatize 2 minutes fixation → two lattice, 5 ~ 30 DEG C of cold wash → two lattice 50 ~ 60 DEG C of hot water wash → carrying out two lattice soap boiling → six lattice flat wash troughs with the soap boiling agent of concentration 2 ~ 3g/L single-frame flows backwards washing, and every Ge Wendu is respectively 90 ~ 95 DEG C, 80 ~ 90 DEG C, 70 ~ 80 DEG C, 70 ~ 80 DEG C, 60 ~ 70 DEG C, 5 ~ 30 DEG C → two and arranges totally 24 cylinder oven dry → croppings;
Wherein dye liquor consists of:
Active black MES 24 g/L
Active yellow MES 8.8 g/L
Active red MES 2.6 g/L
All the other are water;
Fixation liquid consists of:
Soda ash 8g/L
Glauber salt 200 g/L
All the other are water.

Claims (3)

1. a production method for the water soluble adhesive lining of the extremely low washing shrinkage of the feature of environmental protection easy to operate, is characterized in that: the water-soluble hot melt adhesive lining of described extremely low washing shrinkage through broadwise washing size changing rate be-0.6% ~ 0.5%; After thermal smelting adesive lining is combined with fabric pressing, process and fabric disengaging time < 15 seconds in 35 DEG C of water; Dissociate and hydrolysis formaldehyde≤35mg/kg;
Production method comprise successively turn over seam, singe, the step such as destarch is concise, bleaching, multiple drift or dyeing, post processing, liquid ammonia finishing, shiinkproof finish, machine shrunk, powder point coating;
During wherein destarch refining processing, fabric open width pads the concise liquid of destarch, then at 100 ~ 102 DEG C decatize 60 ~ 100 minutes, open width is washed, and what wherein destarch seminal fluid was practiced consists of: NaOH 25 ~ 35g/L, scouring agent A-114 6 ~ 8g/L, and all the other are water; During bleaching, open width pads oxygen bleaching liquid, decatize 60 ~ 75 minutes at 100 ~ 102 DEG C, and open width is washed, wherein oxygen bleaching liquid consists of: hydrogen peroxide 4 ~ 6.5g/L, waterglass 10 ~ 12g/L, scouring agent A-114 4g/L, intercalating agent 540 3g/L, and all the other are water; During multiple drift process, pad oxygen bleaching liquid, decatize 55 ~ 60 minutes at 100 ~ 102 DEG C by open width, open width is washed, and wherein oxygen bleaching liquid consists of: hydrogen peroxide 2 ~ 3.5g/L, waterglass 3 ~ 5g/L, scouring agent A-114 2g/L; During post processing, being neutralized to pH with the acetic acid that concentration is 2 ~ 3g/L is 5.5 ~ 6.5; During liquid ammonia finishing by open width enter cloth, dry dry, liquefied ammonia encapsulation process, decatize deammoniation, cropping step; Enter cloth by open width during shiinkproof finish, needle plate on shiinkproof finish liquid, 80 ~ 100 DEG C of loose formula dryings, overfeeding is rolled in two leachings two, eight lattice, 170 ~ 175 DEG C of hot blasts bake, cropping step; During machine shrunk process, enter cloth by open width, water dewing, cloth surface humidity are 10% ~ 20%, and rubber blanket pre-shrinking, preshrunk amount are 2% ~ 5%, heating bearing roller temperature is 50 ~ 95 DEG C, and drying cylinder pine formula is dried, cropping; During dyeing, for grey yarn dyed fabric reducing dye dyeing flow process and condition be:
Open width is entered cloth → evenness calender and is padded dye liquor → two and arrange infrared preliminary drying → two groups of 70 ~ 80 DEG C hot blast preliminary drying → mono-group cylinder ovens dry → cropping → evenness calenders and pad reductive steam box decatize 2 minutes → two lattice 5 ~ 30 DEG C of cold wash → ventilative oxidation at reducing solution → 102 DEG C → with the hydrogen peroxide oxidation of 0.5 ~ 1g/L concentration → carrying out two lattice soap boiling → six lattice flat wash troughs with the soap boiling agent of concentration 2 ~ 3g/L single-frame flows backwards washing, and every Ge Wendu is respectively 90 ~ 95 DEG C, 80 ~ 90 DEG C, 70 ~ 80 DEG C, 70 ~ 80 DEG C, 60 ~ 70 DEG C, 5 ~ 30 DEG C → two and arranges totally 24 cylinder oven dry → croppings; Wherein dye liquor consists of:
Vat black RB 10 g/L
Vat Brown BR 7 g/L
Threne olive T 1 g/L
All the other are water;
Reducing solution consists of:
NaOH 18 ~ 20 g/L
Sodium hydrosulfite 16 ~ 18 g/L of 85% weight content
All the other are water;
During dyeing, for black fabric reactive dyeing process flow process and condition be:
Open width is entered cloth → evenness calender and is padded dye liquor → two and arrange infrared preliminary drying → two groups of 70 ~ 80 DEG C hot blast preliminary drying → mono-group cylinder ovens dry → cropping → evenness calenders and pad that fixation liquid → 102 DEG C reductive steam box decatize 2 minutes fixation → two lattice, 5 ~ 30 DEG C of cold wash → two lattice 50 ~ 60 DEG C of hot water wash → carrying out two lattice soap boiling → six lattice flat wash troughs with the soap boiling agent of concentration 2 ~ 3g/L single-frame flows backwards washing, and every Ge Wendu is respectively 90 ~ 95 DEG C, 80 ~ 90 DEG C, 70 ~ 80 DEG C, 70 ~ 80 DEG C, 60 ~ 70 DEG C, 5 ~ 30 DEG C → two and arranges totally 24 cylinder oven dry → croppings;
Wherein dye liquor consists of:
Active black MES 24 g/L
Active yellow MES 8.8 g/L
Active red MES 2.6 g/L
All the other are water;
Fixation liquid consists of:
Soda ash 8g/L
Glauber salt 200 g/L
All the other are water;
During middle flat fabric anti-shrinking, consisting of of shiinkproof finish liquid:
Arkofix NDF liq c 80~90 g/L
MgCl 2·6H 2O 14~15 g/L
Ethylene urea 2.0 g/L
NON IONIC SOFTNER V-12 3.5 g/L
Brightening agent MST 0 ~ 2.15g/L
Brightening agent MST-B 0 ~ 4.22g/L
All the other are water, and adjust pH to 4.0 with citric acid;
During middle flat fabric anti-shrinking, overfeeding 2% ~ 3%, when baking, the speed of a motor vehicle is 40m/ minute;
During heavy weave anti-shrinking, consisting of of shiinkproof finish liquid:
Arkofix NDF liq c 100~120 g/L
MgCl 2·6H 2O 16 ~18 g/L
Ethylene urea 2.0 g/L
NON IONIC SOFTNER V-12 3.5 g/L
Brightening agent MST 0 ~ 2.15g/L
Brightening agent MST-B 0 ~ 4.22g/L,
All the other are water, and adjust pH to 4.0 with citric acid;
During heavy weave anti-shrinking, overfeeding 1.5% ~ 3%, when baking, the speed of a motor vehicle is 30m/ minute;
Water-soluble powder point coating comprises open width and enters cloth, 210 ~ 245 DEG C of preheatings of No. 1 oily hot-rolling, 200 ~ 250 DEG C of preheatings of No. 2 oily hot-rollings, engraved roll polyethylene glycol PUR powder point coating, 210 ~ 250 DEG C of heating of No. 3 oily hot-rollings, 140 ~ 160 DEG C of tentering setting, temperature≤25 DEG C water cooling, package step; Engraved roll order number: 30 adopted for middle flat fabric, 33,35 orders/inch, 28 adopted for heavy weave, 30,33 orders/inch.The arrangement of the carved pattern of engraved roll regularly arranged or computer random; In, heavy weave powder point coating amount 22 ± 2g/m 2, prevent reverse side from permeating; During powder point coating, engraved roll inside normal temperature or cooling water in line.
2. the production method of the water soluble adhesive lining of the extremely low washing shrinkage of the feature of environmental protection easy to operate according to claim 1, is characterized in that: the grey cloth of lining cloth is heavy weave or middle flat fabric; Wherein said heavy weave is the one in following two kinds of specifications: the first door width is 48.5 inches, yarn count is 12 s× 12 s, density is 49 × 43 pieces/inch, twist per unit is 46 sth. made by twisting/10cm, the door width of the second is 48.5 inches, yarn count is 16 s× 16 s, density is 60 × 58 pieces/inch, twist per unit is 58 sth. made by twisting/10cm; Described middle flat fabric is the one in following seven kinds of specifications: the first door width is 48.5 inches, yarn count is 20 s× 20 s, density is 60 × 60 pieces/inch, twist per unit is 64 sth. made by twisting/10cm, the door width of the second is 48.5 inches, yarn count is 20 s× 20 s, density is 50 × 50 pieces/inch, twist per unit is 64 sth. made by twisting/10cm, the third door width is 48.5 inches, yarn count is 30 s× 30 s, density is 56 × 44 pieces/inch, twist per unit is 78 sth. made by twisting/10cm, the yarn count of the 4th kind is 30 s× 30 s, density is 68 × 68 pieces/inch, twist per unit is 78 sth. made by twisting/10cm, the door width of the 5th kind is 48.5 inches, yarn count is 30 s× 40 s, density is 64 × 56 pieces/inch, twist per unit is 78 or 90 sth. made by twisting/10cm, the door width of the 6th kind is 48.5 inches, yarn count is 40 s× 40 s, density is 52 × 40 pieces/inch, twist per unit is 90 sth. made by twisting/10cm, the door width of the 7th kind is 48.5 inches, yarn count is 40 s× 40 s, density is 58 × 50 pieces/inch, twist per unit is 90 sth. made by twisting/10cm.
3. the production method of the water soluble adhesive lining of the extremely low washing shrinkage of the feature of environmental protection easy to operate according to claim 1, is characterized in that: liquefied ammonia reative cell vapour pressure is negative pressure 5 ~ 10mmH 2o; Steaming vessel vapour pressure is negative pressure 5 ~ 10mmH 2o; During Liquid Ammonia Treatment, the pressure of three rolling cars is 0.08Mpa, and after padding liquefied ammonia, cloth cover warp-wise tension force is 0.03Mpa.
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