CN104351208A - Picoxystrobin and famoxadone containing bactericidal composition and application thereof - Google Patents
Picoxystrobin and famoxadone containing bactericidal composition and application thereof Download PDFInfo
- Publication number
- CN104351208A CN104351208A CN201410629418.9A CN201410629418A CN104351208A CN 104351208 A CN104351208 A CN 104351208A CN 201410629418 A CN201410629418 A CN 201410629418A CN 104351208 A CN104351208 A CN 104351208A
- Authority
- CN
- China
- Prior art keywords
- famoxadone
- zen
- bactericidal composition
- application
- picoxystrobin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a picoxystrobin and famoxadone containing bactericidal composition and application thereof. The main effective ingredients of the picoxystrobin and famoxadone containing bactericidal composition comprise picoxystrobin and famoxadone in a weight ratio of (1-90) to (1-90). The bactericidal composition can be applied to prevention and control of diseases of cereals, fruit trees and vegetables, has the high synergistic interaction, can be used for overcoming and delaying the drug resistance of bacteria, has the high bactericidal speed and the long lasting period, can be used for reducing the application cost and has the good prevention and control effect superior to that of single agents. The bactericidal composition can be used for preventing and controlling the fungal diseases of crops, can be particularly suitable for treating and preventing fungal diseases such as powdery mildew, rust, glume blight, net blotch, downy mildew, gray mold, Sphaceloma ampelinum, anthracnose, epidemic diseases, and damping off, and has the good effect superior to that of the single agents.
Description
Technical field
The present invention relates to a kind of bactericidal composition and application thereof, especially a kind of with ZEN 90160 with famoxadone be main active bactericidal composition and application thereof.
Background technology
ZEN 90160 (Picoxystrobin), chemical name: (E)-3-methoxyl group-2-{2-[6-(trifluoromethyl)-2-pyridine oxygen methyl] phenyl } methyl acrylate, molecular formula: C
18h
16f
3nO
4.Structural formula is as follows:
The mechanism of action and feature: mitochondrial respiratory inhibitor, namely suppress mitochondrial breathing by electro transfer between cytochrome b and C1.Prevent and treat the bacterial strain of 14-demethylation enzyme inhibitor, benzamides, tri carboxylic acid amide class and benzimidazole generation resistance effective.ZEN 90160, once be absorbed by blade, will move, flow with current in transportation system in xylem; It also flows and flows in xylem again after absorption enters blade from gas phase in the gas phase of blade surface.Due to systemic activity and the fumigation activity of ZEN 90160, thus after dispenser, active ingredient can effectively be reallocated and fully transmit, and therefore ZEN 90160 has extraordinary therapeutic activity.Break and recommend under dosage to crop safety, without poisoning.ZEN 90160 controlling object wide spectrum, interior absorption are strong, resistance of rainwater washing against.Be mainly used in preventing and treating Cereal, fruit tree and vegetables foliage disease as leaf blight, leaf rust, glume blight, brown spot, powdery mildew, scab, anthracnose, brown spot etc.
Famoxadone (Famoxadone), chemical name: 3-anilino--5-methyl-5-(4-Phenoxyphenyl)-1,3-azoles quinoline-2,4-diketone, molecular formula: C
22h
18n
2o
4, chemical structural formula is as follows:
Famoxadone Shu oxazole series bactericidal agent, has protection, treats, roots out, permeates, systemic activity.Mechanism of action is inhibitor of energy, and namely Mitochondrial electron transmission suppresses system.For wheat, barley, pea, beet, rape, tomato, capsicum, melon, potato.Prevent and treat the important disease in Ascomycetes, Basidiomycetes, Oomycete, as powdery mildew, downy mildew, net blotch, rust, glume blight, late blight etc., and can be composite with other protective fungicides.Yin Er, famoxadone is widely used a kind of bactericide.
The difficulty of prevention and cure of current phytopathogen is increasing, and on the one hand, along with the change of pattern of farming, the economic crops such as melon and fruit, vegetables cultivated area progressively expands, and disease occurrence degree, generation quantity all increase, and in control, difficulty strengthens; On the other hand, the resistance of pathogen rises year by year under the medicament selection pressure continued, and the control efficiency of single dose is had a greatly reduced quality, and control of plant disease is faced with significant challenge.
Summary of the invention
The object of the invention is for above-mentioned technical problem provide a kind of applied widely, cost low, effective containing ZEN 90160 Yu the plant bactericidal composition of famoxadone.
A further object of the invention is the application of this bactericidal composition as preparation control fungal diseases of plants medicine, and especially this bactericidal composition prevents and treats the application of powdery mildew, rust, Ying's rot, net blotch, downy mildew, gray mold, anthrachose of grape, anthracnose, epidemic disease and damping off medicine as preparation.
The object of the invention is to be realized by following measures:
Containing ZEN 90160 with a bactericidal composition for famoxadone, the active ingredient of this bactericidal composition be ZEN 90160 with famoxadone, wherein, ZEN 90160 is Yu the weight ratio of famoxadone is 1 ~ 90:1 ~ 90; Preferably described ZEN 90160 is Yu the weight ratio of famoxadone is 1 ~ 20:1 ~ 45; ZEN 90160 preferably described is further Yu the weight ratio of famoxadone is 1 ~ 10:1 ~ 8.
The ZEN 90160 that contains of the present invention is with the bactericidal composition of famoxadone, and described ZEN 90160 is with the weight percentage that both famoxadones account for bactericidal composition is 2 ~ 90%; Preferably described ZEN 90160 is with the weight percentage that both famoxadones account for bactericidal composition is 10 ~ 80%; ZEN 90160 preferably described is further with the weight percentage that both famoxadones account for bactericidal composition is 10 ~ 60%.
Bactericidal composition Yi famoxadone of the present invention and ZEN 90160 are mixed with any one formulation that agricultural chemicals allows for active ingredient and insecticides adjuvant, excipients; Described formulation is any one in water dispersible granules, wetting powder, wet seed dressing, missible oil, wetting powder, suspending agent, oil suspending agent, suspension emulsion, suspension seed-coating agent, aqueous emulsion and microemulsion.
These known auxiliary agents have emulsifier, wetting dispersing agent, suspending agent, defoamer, disintegrant, binding agent etc.
Wherein, described emulsifier is selected from calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, Ben-zylphenol Polyoxyethyl Ether, phenethyl phenol polyethenoxy ether, fatty alcohol-polyoxyethylene ether and similar products thereof, aliphatic amine polyoxyethylene ether, fatty acid ethylene oxide addition product, the rare block compound of polyoxyethylene polyoxy third, castor oil polyoxyethylene ether, neopelex, lauryl sulfate, TWEEN Series, fatty alcohol-polyoxyethylene ether, polyethylene glycol series, Sulfonates, carboxylate, sulphate, phosphate, phosphite, lignosulfonates, phenol formaldehyde condensate, ammonium salt, one or more combinations in quaternary etc.
It is aforementioned that to can be applicable to excipient of the present invention be one or more in water, solvent or filler.
Described solvent includes, but are not limited to one or more of toluene, dimethylbenzene, solvent naphtha series, mixed methylnaphthalene, turpentine oil, vegetable oil, methyl oleate, carrene, chloroform, methyl alcohol, ethanol, isopropyl alcohol, n-butanol, cyclohexanone, isophorone, pyrrolidones, tetrahydrofurfuryl alcohol, acetic acid dimethyl ester, acetophenone, ethyl acetate, DMF, dimethyl sulfoxide (DMSO) etc.
Described filler is selected from one or more of white carbon, kaolin, precipitated calcium carbonate, diatomite, corn starch, quartz sand, talcum powder, ammonium sulfate, sodium sulphate, sodium chloride, potassium chloride etc.
As required, also the functional aids such as antifreezing agent, thickener, stabilizing agent, defoamer can be added.
Described antifreezing agent is selected from one or more of ethylene glycol, propane diols, urea, diethylene glycol (DEG), glycerine etc.
Described thickener be selected from xanthans, polyvinyl alcohol, bentonite, CMC, aluminium-magnesium silicate one or more.
Described formulation preferred water dispersible granule, wetting powder, wet seed dressing, missible oil, wetting powder, suspending agent, oil suspending agent, suspension emulsion, suspension seed-coating agent, aqueous emulsion or microemulsion.
Of the present invention containing ZEN 90160 with the bactericidal composition of famoxadone is as the application of preparation control resistance plant fungal disease medicine.Especially the application of powdery mildew, rust, Ying's rot, net blotch, downy mildew, gray mold, anthrachose of grape, anthracnose, epidemic disease and damping off medicine is prevented and treated as preparation.
Beneficial effect of the present invention:
Bactericidal composition of the present invention is in the application of preparation control refractory fungal disease medicine, and the application that especially this compound prevents and treats powdery mildew, rust, Ying's rot, net blotch, downy mildew, gray mold, anthrachose of grape, anthracnose, epidemic disease and damping off medicine as preparation all has significant effect.Above-mentioned bactericidal composition can produce higher synergistic function, and the consumption of the independent reactive compound of the amount ratio of this mixture reduces greatly, and namely the activity of mixture is greater than the activity of independent component.
Compared with prior art beneficial effect of the present invention:
(1) compared with single dose, said composition antagonism fungal disease such as powdery mildew, rust, Ying's rot, net blotch, downy mildew, anthracnose, epidemic disease, damping off fungal disease have obvious synergistic function, overcome and delayed pesticide resistance, expanding prevention is composed, and significantly improves control efficiency;
(2) control recruitment, drug cost is reduced;
(3) alternative routine and the easy agricultural chemicals producing resistance;
(4) compared with single dose, produce and use cost reduction;
(5) the drug-fast generation of Antifungi, its successful uses higher than its single dose.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described, but protection scope of the present invention is not limited thereto.
Two kinds of reactive compounds can be processed into any one formulation that agricultural chemicals allows, and with specific embodiment, the preparation that two kinds of active ingredients are processed into are described below, but the preparation that these two kinds of active components can be processed be not limited only to following listed by.
Embodiment 1
By ZEN 90160 30g, famoxadone 3g, sodium lignin sulfonate 4, lauryl sodium sulfate 2g, white carbon 2g, corn starch adds to 100g, and it is 33% water dispersible granules that formulation method is conveniently mixed with mass percentage.
Embodiment 2
Take 10g ZEN 90160,2g famoxadone, triphen ethyl phenol polyoxyethylene ether phosphate 3g, alkylphenol polyoxyethylene 2g, solvent naphtha 13g, ethylene glycol 5g, adds water to 100g.Formulation method is conveniently mixed with the aqueous emulsion that mass percentage is 12%.
Embodiment 3
Take 15g ZEN 90160,5g famoxadone, calcium dodecyl benzene sulfonate 6g, neopelex 3g, alkylphenol polyoxyethylene 1g, solvent naphtha 15g, propane diols 10g, add water to 100g.It is 20% microemulsion that formulation method is conveniently mixed with mass percentage
Embodiment 4
Take 30g ZEN 90160,30g famoxadone, triphen ethyl phenol polyoxyethylene ether phosphate 3g, alkylphenol polyoxyethylene 1g, xanthans 0.1g, propane diols 5g, add water to 100g.It is 60% suspending agent that formulation method is conveniently mixed with mass percentage.
Embodiment 5
Take 10g ZEN 90160,20g famoxadone, sodium lignin sulfonate 5g, calcium dodecyl benzene sulfonate 2g, kaolin are to 100g.It is 30% wetting powder that formulation method is conveniently mixed with mass percentage.
Embodiment 6
Take 5g ZEN 90160,20g famoxadone, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, solvent naphtha are to 100g.It is 25% missible oil that formulation method is conveniently mixed with mass percentage.
Embodiment 7
Take 5g ZEN 90160,40g famoxadone, triphen ethyl phenol polyoxyethylene ether phosphate 3g, alkylphenol polyoxyethylene 1g, organobentonite 1g, propane diols 5g, vegetable oil complements to 100g.It is 45% oil suspending agent that formulation method is conveniently mixed with mass percentage.
Embodiment 8
Take 20g ZEN 90160,60g famoxadone, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, white carbon 3g, fine particle calcium carbonate complement to 100g, and it is 80% water dispersible granules that formulation method is conveniently mixed with mass percentage.
Embodiment 9
Take 10g ZEN 90160,40g famoxadone, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, kaolin complements to 100g, and it is 50% wet seed dressing that formulation method is conveniently mixed with mass percentage.
Embodiment 10
Take 5g ZEN 90160,45g famoxadone, sodium lignin sulfonate 4g, polyoxyethylene poly-oxygen propylene aether 2g, xanthans 0.15g, propane diols 5g, aluminium-magnesium silicate 0.5g, complement to 100g with water, it is 50% suspension seed-coating agent that formulation method is conveniently mixed with mass percentage.
Embodiment 11
Take 10g ZEN 90160,20g famoxadone, calcium dodecyl benzene sulfonate 1g, alkylphenol polyoxyethylene phosphate 3g, aliphatic acid polyethenoxy ether 2g, organobentonite 1g, propane diols 5g, vegetable oil 10g, water complement to 100g.It is 30% suspension emulsion that formulation method is conveniently mixed with mass percentage.
Indoor biometrics is tested:
In indoor employing mycelial growth rate method, measure different agents to the EC of bacterial strain
50value, adopt co-toxicity coefficient computational methods, calculate the co-toxicity coefficient (CTC) of mixture, determine the building performance of mixture, circular is as follows:
With single dose a certain in mixture for standard agent (selects EC usually
50junior), calculate:
Single dose toxicity index=standard agent EC
50/ certain single dose EC
50× 100
Toxicity index × B single dose proportion in mixture of toxicity index × A single dose proportion+B single dose in mixture of theoretical toxicity index=A single dose
The EC of actual measurement toxicity index=standard single dose
50the EC of value/mixture
50value × 100
Co-toxicity coefficient=actual measurement toxicity index/theoretical toxicity index × 100
When co-toxicity coefficient classification: CTC is greater than 120, mixture has synergetic, and be antagonism when CTC is less than 80, CTC is summation action between 80-120.
Table 1 ZEN 90160+famoxadone different ratio is to the indoor biometrics result of wheat leaf rust
Result of the test illustrates, ZEN 90160 prevents and kill off wheat leaf rust Yu famoxadone is composite, and proportioning all has synergistic effect in said ratio, and wherein ZEN 90160 is Yu the synergistic effect of proportioning 1:2 of famoxadone is the most remarkable.
Table 2 ZEN 90160+famoxadone different ratio is to the indoor biometrics result of powdery mildew of cucumber
Table 2 result illustrates, ZEN 90160 Yu famoxadone adopts and above-mentionedly compositely has good synergistic function to powdery mildew of cucumber, wherein ZEN 90160 Yu time the proportioning of famoxadone is 1:2 synergistic effect the most remarkable.
Field control effectiveness test:
Invention has been actual field medicine effect test, field medicine effect test is the important means that whether final evaluation Pesticidal composition has using value under the impact of field integrated environment.Therefore, the field medicine effect test preventing and treating wheat leaf rust and powdery mildew of cucumber has been carried out with the pesticide mixed preparation that embodiment obtains in the basis of indoor biometrics.
(A) is with famoxadone (B) different ratio to test middle ZEN 90160 according to raw test, obtained ZEN 90160 is with the preparation of famoxadone different proportion carries out field control effectiveness test, and (A) is with famoxadone (B) different ratio is to the preventive effect of wheat leaf rust and powdery mildew of cucumber for contrast ZEN 90160.Testing each plot area is 66.7m
2, sample 7 points, 0.5 square metre often, check wheat leaf rust and powdery mildew of cucumber occurrence degree.In use, ZEN 90160 (A) is mixed with 25% ZEN 90160 SC ， famoxadone (B) and is mixed with 80% famoxadone WP.The quality of dosing to be active ingredient ZEN 90160 (A) with You imitate into Fen famoxadone (B) and, contrast medicament is 25% ZEN 90160 SC and 80% famoxadone WP.
Table 3: the two different ratio of Ding oxygen Jun Zhi famoxadone EC is to the field control effectiveness test of wheat leaf rust:
As shown in Table 3, adopt the field control effectiveness test of medicament of the present invention, known medicament of the present invention has good control efficiency to wheat leaf rust, and control efficiency uses significantly better than single dose.
Table 4: Ding oxygen Jun Zhi famoxadone EC different ratio is to the field control effectiveness test of powdery mildew of cucumber:
As shown in Table 4, adopt the field control effectiveness test of medicament of the present invention, known medicament of the present invention has good control efficiency to powdery mildew of cucumber, and control efficiency uses significantly better than single dose.
To sum up: shown by the result of indoor biometrics and field medicine effect test, ZEN 90160 is with famoxadone composition has obvious synergistic function, the control efficiency of composition is excellent, and control efficiency is all better than single dose kind, in agricultural application, have good using value.
Claims (10)
1. contain a bactericidal composition for ZEN 90160 and famoxadone, it is characterized in that: the active ingredient of this bactericidal composition is ZEN 90160 and famoxadone, wherein, the weight ratio of ZEN 90160 and famoxadone is 1 ~ 90:1 ~ 90.
2. the ZEN 90160 that contains according to claim 1 is with the bactericidal composition of famoxadone, it is characterized in that: described ZEN 90160 is Yu the weight ratio of famoxadone is 1 ~ 20:1 ~ 45.
3. the ZEN 90160 that contains according to claim 2 is with the bactericidal composition of famoxadone, it is characterized in that: described ZEN 90160 is Yu the weight ratio of famoxadone is 1 ~ 10:1 ~ 8.
4. the ZEN 90160 that contains according to claim 1 is with the bactericidal composition of famoxadone, it is characterized in that: described ZEN 90160 is with the weight percentage that both famoxadones account for bactericidal composition is 2 ~ 90%.
5. the ZEN 90160 that contains according to claim 4 is with the bactericidal composition of famoxadone, it is characterized in that: described ZEN 90160 is with the weight percentage that both famoxadones account for bactericidal composition is 10 ~ 80%.
6. the ZEN 90160 that contains according to claim 5 is with the bactericidal composition of famoxadone, it is characterized in that: described ZEN 90160 is with the weight percentage that both famoxadones account for bactericidal composition is 10 ~ 60%.
7. according to claim 1 containing ZEN 90160 with the bactericidal composition of famoxadone, it is characterized in that: described bactericidal composition is with ZEN 90160 with famoxadone is mixed with any one formulation that agricultural chemicals allows for principle active component and insecticides adjuvant, excipients.
8. the bactericidal composition containing ZEN 90160 and famoxadone according to claim 7, is characterized in that: described formulation is any one in water dispersible granules, wetting powder, wet seed dressing, missible oil, oil suspending agent, suspension emulsion, suspension seed-coating agent, aqueous emulsion and microemulsion.
9. according to claim 1 containing ZEN 90160 with the bactericidal composition of famoxadone is as the application of preparation control resistance plant fungal disease medicine.
10. according to claim 9 containing ZEN 90160 with the application of bactericidal composition of famoxadone, it is characterized in that: described bactericidal composition prevents and treats the application of powdery mildew, rust, Ying's rot, net blotch, downy mildew, gray mold, anthrachose of grape, anthracnose, epidemic disease and damping off medicine as preparation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410629418.9A CN104351208B (en) | 2014-11-10 | 2014-11-10 | A kind of containing ZEN 90160 and the bactericidal composition of cycloheximide triazole and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410629418.9A CN104351208B (en) | 2014-11-10 | 2014-11-10 | A kind of containing ZEN 90160 and the bactericidal composition of cycloheximide triazole and application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104351208A true CN104351208A (en) | 2015-02-18 |
| CN104351208B CN104351208B (en) | 2016-08-10 |
Family
ID=52518602
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410629418.9A Active CN104351208B (en) | 2014-11-10 | 2014-11-10 | A kind of containing ZEN 90160 and the bactericidal composition of cycloheximide triazole and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104351208B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107787986A (en) * | 2016-08-29 | 2018-03-13 | 南京华洲药业有限公司 | It is a kind of containing ZEN 90160 He the bactericidal composition of famoxadone and its application |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101400260A (en) * | 2006-03-14 | 2009-04-01 | 巴斯夫欧洲公司 | Method of inducing tolerance of plants against bacterioses |
| CN101703053A (en) * | 2009-11-13 | 2010-05-12 | 陕西上格之路生物科学有限公司 | Germicide composite containing famoxadone |
| WO2013062141A1 (en) * | 2011-10-27 | 2013-05-02 | Sumitomo Chemical Company, Limited | Composition and method for controlling plant diseases |
-
2014
- 2014-11-10 CN CN201410629418.9A patent/CN104351208B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101400260A (en) * | 2006-03-14 | 2009-04-01 | 巴斯夫欧洲公司 | Method of inducing tolerance of plants against bacterioses |
| CN101703053A (en) * | 2009-11-13 | 2010-05-12 | 陕西上格之路生物科学有限公司 | Germicide composite containing famoxadone |
| WO2013062141A1 (en) * | 2011-10-27 | 2013-05-02 | Sumitomo Chemical Company, Limited | Composition and method for controlling plant diseases |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107787986A (en) * | 2016-08-29 | 2018-03-13 | 南京华洲药业有限公司 | It is a kind of containing ZEN 90160 He the bactericidal composition of famoxadone and its application |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104351208B (en) | 2016-08-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105766952B (en) | The bactericidal composition and its application of a kind of Fluxapyroxad-containsterilization and folpet | |
| CN104642331A (en) | Bactericidal composition containing prothioconazole and tebuconazole and application thereof | |
| CN103563910B (en) | Bactericidal composition containing prothioconazole and validamycin and application thereof | |
| CN107771817A (en) | A kind of bactericidal composition and its application containing ZEN 90160 and prothioconazoles | |
| CN104621126A (en) | Sterilization composition containing prothioconazole and difenoconazole and application thereof | |
| CN104621125A (en) | Sterilization composition containing prothioconazole and trifloxystrobin and application thereof | |
| CN104621168A (en) | Sterilization composition containing prothioconazole and prochloraz-manganese chloride and application thereof | |
| CN103250702B (en) | Composite synergy sterilization composition containing boscalid and trifloxystrobin, and applications thereof | |
| CN103907614B (en) | A kind of composite synergistic bactericidal composition and application thereof containing biphenyl pyrrole bacterium amine and Difenoconazole | |
| CN103563909A (en) | Bactericidal composition containing prothioconazole and fenoxanil and application of bactericidal composition | |
| CN104285959A (en) | Synergistic bactericidal composition containing fluxapyroxad and isoprothiolane | |
| CN103891723A (en) | Bactericidal composition containing isopyrazam and picoxystrobin and application thereof | |
| CN104351208A (en) | Picoxystrobin and famoxadone containing bactericidal composition and application thereof | |
| CN104430389A (en) | Bactericidal composition comprising famoxadone and boscalid and application thereof | |
| CN103598194A (en) | Picoxystrobin and prochloraz containing sterilization composition and application thereof | |
| CN104621129A (en) | Sterilization composition containing prothioconazole and metalaxyl-M and application thereof | |
| CN105831131B (en) | A kind of bactericidal composition and its application of Fluxapyroxad-containsterilization and probenazole | |
| CN103891724B (en) | A kind of composite synergistic bactericidal composition and application thereof containing isopyrazam and oxime bacterium ester | |
| CN103598193B (en) | Picoxystrobin and thiram containing sterilization composition and application thereof | |
| CN104642367A (en) | Bactericidal composition containing prothioconazole and prochloraz and application thereof | |
| CN103891743B (en) | Bactericidal composition containing isopyrazam and pyraclostrobin and application thereof | |
| CN104351207A (en) | Cyazofamid and famoxadone containing bactericidal composition and application thereof | |
| CN105532721A (en) | Sterilization composition containing bixafen and ethirimol and application of sterilization composition | |
| CN106106502B (en) | A kind of bactericidal composition and its application of Fluxapyroxad-containsterilization and simeconazoles | |
| CN103907605A (en) | Composite synergic sterilization composition containing boscalid and bixafen and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Picoxystrobin and famoxadone containing bactericidal composition and application thereof Effective date of registration: 20191012 Granted publication date: 20160810 Pledgee: Jiangsu Jiangnan Rural Commercial Bank Limited by Share Ltd Pledgor: JIANGSU FENGDENG CROP SCIENCE CO., LTD. Registration number: Y2019320010015 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |