CN104351186B - Effective ingredient is the compound disinfectant of garlicin and pyrimethanil - Google Patents

Effective ingredient is the compound disinfectant of garlicin and pyrimethanil Download PDF

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Publication number
CN104351186B
CN104351186B CN201410630370.3A CN201410630370A CN104351186B CN 104351186 B CN104351186 B CN 104351186B CN 201410630370 A CN201410630370 A CN 201410630370A CN 104351186 B CN104351186 B CN 104351186B
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China
Prior art keywords
pyrimethanil
garlicin
compound disinfectant
effective ingredient
present
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Expired - Fee Related
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CN201410630370.3A
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CN104351186A (en
Inventor
孙波
孙倩
穆柯晓
郝爱华
王蒙蒙
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Shuangliu Vegetable Planting Cooperative in Rongchang District of Chongqing
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Qingdao Qingzhi Enterprise Management Consulting Co Ltd
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Abstract

The present invention relates to the compound disinfectant that effective ingredient is garlicin and pyrimethanil, the dosage form of described compound disinfectant is water dispersible granules, effective ingredient is garlicin and pyrimethanil, auxiliary agent aryl phenol polyoxyethylene succinate sulfonate, dodecylbenzene sodium sulfonate, carbamide, and carrier is attapulgite.The present invention has extraordinary prevention effect to gray mold of cucumber, and the present invention utilizes the prevention to gray mold of cucumber of garlicin and pyrimethanil and the effect for the treatment of, instant effect, and the lasting period is long, on non-Target crops without impact.

Description

Effective ingredient is the compound disinfectant of garlicin and pyrimethanil
Technical field
The present invention relates to the compound disinfectant that effective ingredient is garlicin and pyrimethanil, be specifically related to compound disinfectant that effective ingredient is garlicin and pyrimethanil for preventing and treating gray mold of cucumber, belong to technical field of pesticide.
Background technology
Pyrimethanil has another name called Shi Jiale, and chemical name is N-(4,6-dimethyl pyrimidine-2-base) aniline, belong to anilino-pyrimidine new type bactericide, stop infecting and killing pathogenic bacteria of pathogenic bacteria by suppressing the generation of infection process enzyme.There is suction conduction and fumigation action, be rapidly reached the spraying such as the flower of plant, the young fruit position that is beyond one's reach after dispenser and kill pathogenic bacteria, drug effect faster, more stable.The ash arrhizus bacteria effect particularly developed immunity to drugs benzimidazole and carbamate fungicide is preferable, but pyrimethanil is used on some crop such as Fructus Solani melongenae, poisoning easily occurs, and when concentration is high or consumption is big, poisoning can be more serious.
Garlicin (Allicin) is a kind of organosulfur compound extracted from the bulb (Bulbus Allii head) of Liliaceae allium Bulbus Allii (Allium Sativum), exists in Bulbus Allii Cepae and other alliums.Formal name used at school GIUCOSinoate.Pale yellow oily liquid body.Boiling point 80-85 DEG C (0.2kPa), relative density 1.112(20/4 DEG C), index of refraction 1.561.It is dissolved in ethanol, chloroform or ether.Dissolubility 2.5% (quality) (10 DEG C) in water, its pH value of water solution is 6.5, has grease precipitate to be formed during standing.Can dissolve each other with ethanol, ether and benzene.Unstable to thermokalite, stable to acid.By in the bulb being present in liliaceous plant Bulbus Allii, the garlic aminoacid existed under big allinase effect, convert generation.Exist in the bulb of Herba Alii fistulosi.Having strong big garlic odour, taste is peppery.
Summary of the invention
The invention provides the compound disinfectant that a kind of effective ingredient is garlicin and pyrimethanil, be specifically related to compound disinfectant that effective ingredient is garlicin and pyrimethanil for preventing and treating gray mold of cucumber, field efficacy of the present invention is high, it is possible to reduce poisoning, and the lasting period is long.
Technical scheme is as follows:
A kind of effective ingredient is the compound disinfectant of garlicin and pyrimethanil, the dosage form of described compound disinfectant is water dispersible granules, effective ingredient is garlicin and pyrimethanil, auxiliary agent aryl phenol polyoxyethylene succinate sulfonate, dodecylbenzene sodium sulfonate, carbamide, and carrier is attapulgite.
Further, each raw material components of the present invention is by mass percentage:
Garlicin 0.1%-1%, pyrimethanil 1%-50%, aryl phenol polyoxyethylene succinate sulfonate 3%-10%, dodecylbenzene sodium sulfonate 3%-9%, carbamide 1%-5%, attapulgite are supplied.
Further, each raw material components of the present invention is by mass percentage:
Garlicin 0.15%-0.8%, pyrimethanil 5%-40%, aryl phenol polyoxyethylene succinate sulfonate 4%-9%, dodecylbenzene sodium sulfonate 4%-8%, carbamide 1.5%-4%, attapulgite are supplied.
Further, each raw material components of the present invention is by mass percentage:
Garlicin 0.3%-0.5%, pyrimethanil 10%-30%, aryl phenol polyoxyethylene succinate sulfonate 5%-8%, dodecylbenzene sodium sulfonate 4.5%-7%, carbamide 2%-3.5%, attapulgite are supplied.
Further, each raw material components of the present invention is by mass percentage:
Garlicin 0.4%, pyrimethanil 19.6%, aryl phenol polyoxyethylene succinate sulfonate 7%, dodecylbenzene sodium sulfonate 6%, carbamide 3%, attapulgite are supplied.
Compound disinfectant of the present invention is used for preventing and treating gray mold of cucumber, early stage dispenser of falling ill;Annual spraying times is 1 or 2 time;Effective ingredient dosage is 5 grams/ha-15 grams/ha, it is preferred that dosage is 6.67 grams/ha.
The present invention has extraordinary prevention effect to gray mold of cucumber, and the present invention utilizes the prevention to gray mold of cucumber of garlicin and pyrimethanil and the effect for the treatment of, instant effect, and the lasting period is long, on non-Target crops without impact.
Detailed description of the invention
Below in conjunction with specific embodiment further describe the present invention, advantages of the present invention and feature will be with describe and apparent.But embodiment is only exemplary, the scope of the present invention is not constituted any restriction.It will be understood by those skilled in the art that and the details of technical solution of the present invention and form can be modified or replace lower without departing from the spirit and scope of the present invention, but these amendments and replacement each fall within protection scope of the present invention.
1 one kinds of effective ingredient of embodiment are the compound disinfectant of garlicin and pyrimethanil
Each raw material components is by mass percentage:
Garlicin 0.4%, pyrimethanil 19.6%, aryl phenol polyoxyethylene succinate sulfonate 7%, dodecylbenzene sodium sulfonate 6%, carbamide 3%, attapulgite are supplied.
By above-mentioned each composition application conventional pesticide process technology, the water dispersible granules goods being suitable for agriculturally using made.In the present embodiment, the co-toxicity coefficient of garlicin and pyrimethanil is 326.14.
The water dispersible granules that the embodiment of the present invention 1 obtains is used for preventing and treating gray mold of cucumber, gray mold of cucumber their early stage dispenser, and effective ingredient dosage is 6.67 grams/ha, sprays 2 times, after secondary medicine 7 days, the prevention effect of 14 days be respectively 90.1%, 96.2%.40% pyrimethanil wettable powder effective ingredient by 20 grams/ha of spray pesticides 2 times, after secondary medicine 7 days, the prevention effect of 14 days be respectively 73.5%, 71.6%.2.5% garlicin cream by 2000 times of spray pesticides 2 times, after secondary medicine 7 days, the prevention effect of 14 days be respectively 31.5%, 34.6%.
2 one kinds of effective ingredient of embodiment are the compound disinfectant of garlicin and pyrimethanil
Each raw material components is by mass percentage:
Garlicin 0.1%, pyrimethanil 39.9%, aryl phenol polyoxyethylene succinate sulfonate 4%, dodecylbenzene sodium sulfonate 5%, carbamide 1.5%, attapulgite are supplied.
By above-mentioned each composition application conventional pesticide process technology, the water dispersible granules goods being suitable for agriculturally using made.In the present embodiment, the co-toxicity coefficient of garlicin and pyrimethanil is 295.36.
The water dispersible granules that the embodiment of the present invention 2 obtains is used for preventing and treating gray mold of cucumber, gray mold of cucumber their early stage dispenser, and effective ingredient dosage is 5 grams/ha, sprays 2 times, after secondary medicine 7 days, the prevention effect of 14 days be respectively 88.5%, 93.1%.40% pyrimethanil wettable powder effective ingredient by 20 grams/ha of spray pesticides 2 times, after secondary medicine 7 days, the prevention effect of 14 days be respectively 73.5%, 71.6%.2.5% garlicin cream by 2000 times of spray pesticides 2 times, after secondary medicine 7 days, the prevention effect of 14 days be respectively 31.5%, 34.6%.
3 one kinds of effective ingredient of embodiment are the compound disinfectant of garlicin and pyrimethanil
Each raw material components is by mass percentage:
Garlicin 1%, pyrimethanil 19%, aryl phenol polyoxyethylene succinate sulfonate 5%, dodecylbenzene sodium sulfonate 6%, carbamide 3%, attapulgite are supplied.
By above-mentioned each composition application conventional pesticide process technology, the water dispersible granules goods being suitable for agriculturally using made.In the present embodiment, the co-toxicity coefficient of garlicin and pyrimethanil is 264.15.
The water dispersible granules that the embodiment of the present invention 3 obtains is used for preventing and treating gray mold of cucumber, gray mold of cucumber their early stage dispenser, and effective ingredient dosage is 8.5 grams/ha, sprays 2 times, after secondary medicine 7 days, the prevention effect of 14 days be respectively 86.7%, 90.6%.40% pyrimethanil wettable powder effective ingredient by 20 grams/ha of spray pesticides 2 times, after secondary medicine 7 days, the prevention effect of 14 days be respectively 73.5%, 71.6%.2.5% garlicin cream by 2000 times of spray pesticides 2 times, after secondary medicine 7 days, the prevention effect of 14 days be respectively 31.5%, 34.6%.
4 one kinds of effective ingredient of embodiment are the compound disinfectant of garlicin and pyrimethanil
Each raw material components is by mass percentage:
Garlicin 0.5%, pyrimethanil 14.5%, aryl phenol polyoxyethylene succinate sulfonate 8%, dodecylbenzene sodium sulfonate 3%, carbamide 2%, attapulgite are supplied.
By above-mentioned each composition application conventional pesticide process technology, the water dispersible granules goods being suitable for agriculturally using made.In the present embodiment, the co-toxicity coefficient of garlicin and pyrimethanil is 245.32.
The water dispersible granules that the embodiment of the present invention 4 obtains is used for preventing and treating gray mold of cucumber, gray mold of cucumber their early stage dispenser, and effective ingredient dosage is 6 grams/ha, sprays 2 times, after secondary medicine 7 days, the prevention effect of 14 days be respectively 83.6%, 89.9%.40% pyrimethanil wettable powder effective ingredient by 20 grams/ha of spray pesticides 2 times, after secondary medicine 7 days, the prevention effect of 14 days be respectively 73.5%, 71.6%.2.5% garlicin cream by 2000 times of spray pesticides 2 times, after secondary medicine 7 days, the prevention effect of 14 days be respectively 31.5%, 34.6%.
5 one kinds of effective ingredient of embodiment are the compound disinfectant of garlicin and pyrimethanil
Each raw material components is by mass percentage:
Garlicin 0.9%, pyrimethanil 40.1%, aryl phenol polyoxyethylene succinate sulfonate 3%, dodecylbenzene sodium sulfonate 7%, carbamide 3%, attapulgite are supplied.
By above-mentioned each composition application conventional pesticide process technology, the water dispersible granules goods being suitable for agriculturally using made.In the present embodiment, the co-toxicity coefficient of garlicin and pyrimethanil is 255.21.
The water dispersible granules that the embodiment of the present invention 5 obtains is used for preventing and treating gray mold of cucumber, gray mold of cucumber their early stage dispenser, and effective ingredient dosage is 5.5 grams/ha, sprays 2 times, after secondary medicine 7 days, the prevention effect of 14 days be respectively 88.4%, 91.1%.40% pyrimethanil wettable powder effective ingredient by 20 grams/ha of spray pesticides 2 times, after secondary medicine 7 days, the prevention effect of 14 days be respectively 73.5%, 71.6%.2.5% garlicin cream by 2000 times of spray pesticides 2 times, after secondary medicine 7 days, the prevention effect of 14 days be respectively 31.5%, 34.6%.
By above-described embodiment, compound disinfectant of the present invention not only significantly improves preventive effect, and reduces the dosage of effective ingredient, decreases pesticide residues, alleviates and uses, due to pesticide, the harm causing ecological environment.

Claims (6)

1. effective ingredient is the compound disinfectant of garlicin and pyrimethanil, it is characterised in that in described compound disinfectant, each raw material components is by mass percentage:
Garlicin 0.4%, pyrimethanil 19.6%, aryl phenol polyoxyethylene succinate sulfonate 7%, dodecylbenzene sodium sulfonate 6%, carbamide 3%, attapulgite are supplied.
Compound disinfectant the most according to claim 1, it is characterised in that described compound disinfectant is used for preventing and treating gray mold of cucumber.
Compound disinfectant the most according to claim 2, it is characterised in that described compound disinfectant is in morbidity early stage dispenser.
Compound disinfectant the most according to claim 3, it is characterised in that the annual spraying times of described compound disinfectant is 1 or 2 time.
Compound disinfectant the most according to claim 4, it is characterised in that described compound disinfectant effective ingredient dosage is 5 grams/ha-15 grams/ha.
Compound disinfectant the most according to claim 5, it is characterised in that described compound disinfectant dosage is 6.67 grams/ha.
CN201410630370.3A 2014-11-11 2014-11-11 Effective ingredient is the compound disinfectant of garlicin and pyrimethanil Expired - Fee Related CN104351186B (en)

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* Cited by examiner, † Cited by third party
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CN105613602A (en) * 2016-03-22 2016-06-01 侯仰运 Biological insectofungicide containing both sowthistle tasselflower herb and garlicin and production process of insectofungicide

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU4009993A (en) * 1992-06-10 1993-12-23 Schering Aktiengesellschaft Fungicidal mixtures
CN1111933A (en) * 1993-09-13 1995-11-22 Basf公司 Fungicidal mixtures
CN1461590A (en) * 2002-05-26 2003-12-17 汪建利 Sterilizing composition contg. ethylicin

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU4009993A (en) * 1992-06-10 1993-12-23 Schering Aktiengesellschaft Fungicidal mixtures
CN1111933A (en) * 1993-09-13 1995-11-22 Basf公司 Fungicidal mixtures
CN1461590A (en) * 2002-05-26 2003-12-17 汪建利 Sterilizing composition contg. ethylicin

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
勉县早春黄瓜—秋冬蒜苗一年两茬设施高效栽培技术;肖慧;《现代农业科技》;20121231(第23期);87,89 *

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Patentee after: Shuangliu Vegetable Planting Cooperative in Rongchang District of Chongqing

Address before: 266109 Yan Yang Road, Chengyang District, Qingdao, Shandong Province, No. 111

Patentee before: Qingdao Qingzhi Enterprise Management Consulting Co., Ltd.

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