CN104351186A - Compounded fungicide with allicin and pyrimethanil as effective ingredients - Google Patents

Compounded fungicide with allicin and pyrimethanil as effective ingredients Download PDF

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Publication number
CN104351186A
CN104351186A CN201410630370.3A CN201410630370A CN104351186A CN 104351186 A CN104351186 A CN 104351186A CN 201410630370 A CN201410630370 A CN 201410630370A CN 104351186 A CN104351186 A CN 104351186A
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China
Prior art keywords
allicin
compound disinfectant
mould amine
phonetic mould
attapulgite
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Application number
CN201410630370.3A
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Chinese (zh)
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CN104351186B (en
Inventor
孙波
孙倩
穆柯晓
郝爱华
王蒙蒙
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Shuangliu Vegetable Planting Cooperative in Rongchang District of Chongqing
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Jinan Xinqidian Medical Technology Co Ltd
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Abstract

The invention relates to a compounded fungicide with allicin and pyrimethanil as effective ingredients. The compounded fungicide has the dosage form of water-dispersible granules, effective ingredients are allicin and pyrimethanil, auxiliaries are arylphenol polyoxyethylene succinate sulfonate, sodium dodecylbenzene sulfonate and urea, and attapulgite serves as a carrier. The compounded fungicide has very good preventing and treating effects on cucumber gray mold; by using the preventing and treating actions of allicin and pyrimethanil on the cucumber gray mold, the compounded fungicide is high in effect taking speed and long in lasting period and does not affect non-target crops.

Description

Active ingredient is the compound disinfectant of allicin and phonetic mould amine
Technical field
The present invention relates to the compound disinfectant that active ingredient is allicin and phonetic mould amine, be specifically related to active ingredient be the compound disinfectant of allicin and phonetic mould amine for preventing and treating gray mold of cucumber, belong to technical field of pesticide.
Background technology
Phonetic mould amine has another name called Shi Jiale, and chemical name is N-(4,6-dimethyl pyrimidine-2-base) aniline, belong to anilino-pyrimidine new type bactericide, by suppressing the generation of infection process enzyme thus stoping infecting and killing germ of germ.There is Inner and inhale conduction and fumigation action, reach rapidly the spraying such as the flower of plant, the young fruit position that is beyond one's reach after dispenser and kill germ, drug effect sooner, more stable.The ash arrhizus bacteria effect particularly developed immunity to drugs to benzimidazole and carbamate fungicide is better, but phonetic mould amine uses some crop as on eggplant, easily occurs poisoning, and when concentration is high or consumption is large, poisoning can be more serious.
Allicin (Allicin) is a kind of organosulfur compound extracted from the bulb (garlic) of Liliaceae allium garlic (Allium Sativum), is also present in onion and other alliums.Formal name used at school GIUCOSinoate.Pale yellow oily liquid body.Boiling point 80-85 DEG C (0.2kPa), relative density 1.112(20/4 DEG C), index of refraction 1.561.Be dissolved in ethanol, chloroform or ether.Solvability 2.5% (quality) (10 DEG C) in water, its pH value of water solution is 6.5, has grease sediment to be formed time standing.With ethanol, ether and benzene can dissolve each other.Unstable to thermokalite, acid is stablized.By being present in the bulb of liliaceous plant garlic, under large allinase effect, transform generation by the garlic aminoacid existed.Also be present in the bulb of green onion.Have strong large garlic odour, taste is peppery.
Summary of the invention
The invention provides the compound disinfectant that a kind of active ingredient is allicin and phonetic mould amine, be specifically related to active ingredient be the compound disinfectant of allicin and phonetic mould amine for preventing and treating gray mold of cucumber, field efficacy of the present invention is high, can reduce poisoning, and the lasting period is long.
Technical scheme of the present invention is as follows:
A kind of active ingredient is the compound disinfectant of allicin and phonetic mould amine, the formulation of described compound disinfectant is water dispersible granules, active ingredient is allicin and phonetic mould amine, and auxiliary agent aryl phenol polyoxyethylene succinate sulfonate, neopelex, urea, carrier is attapulgite.
Further, each raw material components of the present invention is by mass percentage:
Allicin 0.1%-1%, phonetic mould amine 1%-50%, aryl phenol polyoxyethylene succinate sulfonate 3%-10%, neopelex 3%-9%, urea 1%-5%, attapulgite are supplied.
Further, each raw material components of the present invention is by mass percentage:
Allicin 0.15%-0.8%, phonetic mould amine 5%-40%, aryl phenol polyoxyethylene succinate sulfonate 4%-9%, neopelex 4%-8%, urea 1.5%-4%, attapulgite are supplied.
Further, each raw material components of the present invention is by mass percentage:
Allicin 0.3%-0.5%, phonetic mould amine 10%-30%, aryl phenol polyoxyethylene succinate sulfonate 5%-8%, neopelex 4.5%-7%, urea 2%-3.5%, attapulgite are supplied.
Further, each raw material components of the present invention is by mass percentage:
Allicin 0.4%, phonetic mould amine 19.6%, aryl phenol polyoxyethylene succinate sulfonate 7%, neopelex 6%, urea 3%, attapulgite are supplied.
Compound disinfectant of the present invention for preventing and treating gray mold of cucumber, morbidity early stage dispenser; Annual spraying times is 1 or 2 time; Active ingredient dosage is 5 grams/ha-15 grams/ha, and preferably, dosage is 6.67 grams/ha.
The present invention has extraordinary control efficiency to gray mold of cucumber, and the present invention utilizes allicin and phonetic mould amine to the effect of the prevention and therapy of gray mold of cucumber, and instant effect, the lasting period is long, on non-Target crops without impact.
Embodiment
Further describe the present invention below in conjunction with specific embodiment, advantage and disadvantage of the present invention will be more clear along with description.But embodiment is only exemplary, does not form any restriction to scope of the present invention.It will be understood by those skilled in the art that and can modify to the details of technical solution of the present invention and form or replace down without departing from the spirit and scope of the present invention, but these amendments and replacement all fall within the scope of protection of the present invention.
Embodiment 1 one kinds of active ingredients are the compound disinfectant of allicin and phonetic mould amine
Each raw material components is by mass percentage:
Allicin 0.4%, phonetic mould amine 19.6%, aryl phenol polyoxyethylene succinate sulfonate 7%, neopelex 6%, urea 3%, attapulgite are supplied.
By above-mentioned each composition application conventional pesticide process technology, the water dispersible granules goods being applicable to agriculturally using made.In the present embodiment, the co-toxicity coefficient of allicin and phonetic mould amine is 326.14.
Be used for preventing and treating gray mold of cucumber by the water dispersible granules that the embodiment of the present invention 1 obtains, the dispenser of gray mold of cucumber their early stage, active ingredient dosage is 6.67 grams/ha, and spray 2 times, after secondary medicine, the control efficiency of 7 days, 14 days is respectively 90.1%, 96.2%.40% phonetic mould amine wetting powder active ingredient presses 20 grams/ha of spray pesticides 2 times, and after secondary medicine, the control efficiency of 7 days, 14 days is respectively 73.5%, 71.6%.2.5% allicin missible oil presses 2000 times of spray pesticides 2 times, and after secondary medicine, the control efficiency of 7 days, 14 days is respectively 31.5%, 34.6%.
Embodiment 2 one kinds of active ingredients are the compound disinfectant of allicin and phonetic mould amine
Each raw material components is by mass percentage:
Allicin 0.1%, phonetic mould amine 39.9%, aryl phenol polyoxyethylene succinate sulfonate 4%, neopelex 5%, urea 1.5%, attapulgite are supplied.
By above-mentioned each composition application conventional pesticide process technology, the water dispersible granules goods being applicable to agriculturally using made.In the present embodiment, the co-toxicity coefficient of allicin and phonetic mould amine is 295.36.
Be used for preventing and treating gray mold of cucumber by the water dispersible granules that the embodiment of the present invention 2 obtains, the dispenser of gray mold of cucumber their early stage, active ingredient dosage is 5 grams/ha, and spray 2 times, after secondary medicine, the control efficiency of 7 days, 14 days is respectively 88.5%, 93.1%.40% phonetic mould amine wetting powder active ingredient presses 20 grams/ha of spray pesticides 2 times, and after secondary medicine, the control efficiency of 7 days, 14 days is respectively 73.5%, 71.6%.2.5% allicin missible oil presses 2000 times of spray pesticides 2 times, and after secondary medicine, the control efficiency of 7 days, 14 days is respectively 31.5%, 34.6%.
Embodiment 3 one kinds of active ingredients are the compound disinfectant of allicin and phonetic mould amine
Each raw material components is by mass percentage:
Allicin 1%, phonetic mould amine 19%, aryl phenol polyoxyethylene succinate sulfonate 5%, neopelex 6%, urea 3%, attapulgite are supplied.
By above-mentioned each composition application conventional pesticide process technology, the water dispersible granules goods being applicable to agriculturally using made.In the present embodiment, the co-toxicity coefficient of allicin and phonetic mould amine is 264.15.
Be used for preventing and treating gray mold of cucumber by the water dispersible granules that the embodiment of the present invention 3 obtains, the dispenser of gray mold of cucumber their early stage, active ingredient dosage is 8.5 grams/ha, and spray 2 times, after secondary medicine, the control efficiency of 7 days, 14 days is respectively 86.7%, 90.6%.40% phonetic mould amine wetting powder active ingredient presses 20 grams/ha of spray pesticides 2 times, and after secondary medicine, the control efficiency of 7 days, 14 days is respectively 73.5%, 71.6%.2.5% allicin missible oil presses 2000 times of spray pesticides 2 times, and after secondary medicine, the control efficiency of 7 days, 14 days is respectively 31.5%, 34.6%.
Embodiment 4 one kinds of active ingredients are the compound disinfectant of allicin and phonetic mould amine
Each raw material components is by mass percentage:
Allicin 0.5%, phonetic mould amine 14.5%, aryl phenol polyoxyethylene succinate sulfonate 8%, neopelex 3%, urea 2%, attapulgite are supplied.
By above-mentioned each composition application conventional pesticide process technology, the water dispersible granules goods being applicable to agriculturally using made.In the present embodiment, the co-toxicity coefficient of allicin and phonetic mould amine is 245.32.
Be used for preventing and treating gray mold of cucumber by the water dispersible granules that the embodiment of the present invention 4 obtains, the dispenser of gray mold of cucumber their early stage, active ingredient dosage is 6 grams/ha, and spray 2 times, after secondary medicine, the control efficiency of 7 days, 14 days is respectively 83.6%, 89.9%.40% phonetic mould amine wetting powder active ingredient presses 20 grams/ha of spray pesticides 2 times, and after secondary medicine, the control efficiency of 7 days, 14 days is respectively 73.5%, 71.6%.2.5% allicin missible oil presses 2000 times of spray pesticides 2 times, and after secondary medicine, the control efficiency of 7 days, 14 days is respectively 31.5%, 34.6%.
Embodiment 5 one kinds of active ingredients are the compound disinfectant of allicin and phonetic mould amine
Each raw material components is by mass percentage:
Allicin 0.9%, phonetic mould amine 40.1%, aryl phenol polyoxyethylene succinate sulfonate 3%, neopelex 7%, urea 3%, attapulgite are supplied.
By above-mentioned each composition application conventional pesticide process technology, the water dispersible granules goods being applicable to agriculturally using made.In the present embodiment, the co-toxicity coefficient of allicin and phonetic mould amine is 255.21.
Be used for preventing and treating gray mold of cucumber by the water dispersible granules that the embodiment of the present invention 5 obtains, the dispenser of gray mold of cucumber their early stage, active ingredient dosage is 5.5 grams/ha, and spray 2 times, after secondary medicine, the control efficiency of 7 days, 14 days is respectively 88.4%, 91.1%.40% phonetic mould amine wetting powder active ingredient presses 20 grams/ha of spray pesticides 2 times, and after secondary medicine, the control efficiency of 7 days, 14 days is respectively 73.5%, 71.6%.2.5% allicin missible oil presses 2000 times of spray pesticides 2 times, and after secondary medicine, the control efficiency of 7 days, 14 days is respectively 31.5%, 34.6%.
Known by above-described embodiment, compound disinfectant of the present invention not only significantly improves preventive effect, and reduces the dosage of active ingredient, decreases residue of pesticide, alleviates to use due to agricultural chemicals the harm caused ecotope.

Claims (10)

1. active ingredient is the compound disinfectant of allicin and phonetic mould amine, it is characterized in that, the formulation of described compound disinfectant is water dispersible granules, active ingredient is allicin and phonetic mould amine, auxiliary agent aryl phenol polyoxyethylene succinate sulfonate, neopelex, urea, carrier is attapulgite.
2. compound disinfectant according to claim 1, is characterized in that, in described compound disinfectant, each raw material components is by mass percentage:
Allicin 0.1%-1%, phonetic mould amine 1%-50%, aryl phenol polyoxyethylene succinate sulfonate 3%-10%, neopelex 3%-9%, urea 1%-5%, attapulgite are supplied.
3. compound disinfectant according to claim 2, is characterized in that, in described compound disinfectant, each raw material components is by mass percentage:
Allicin 0.15%-0.8%, phonetic mould amine 5%-40%, aryl phenol polyoxyethylene succinate sulfonate 4%-9%, neopelex 4%-8%, urea 1.5%-4%, attapulgite are supplied.
4. compound disinfectant according to claim 3, is characterized in that, in described compound disinfectant, each raw material components is by mass percentage:
Allicin 0.3%-0.5%, phonetic mould amine 10%-30%, aryl phenol polyoxyethylene succinate sulfonate 5%-8%, neopelex 4.5%-7%, urea 2%-3.5%, attapulgite are supplied.
5. compound disinfectant according to claim 4, is characterized in that, in described compound disinfectant, each raw material components is by mass percentage:
Allicin 0.4%, phonetic mould amine 19.6%, aryl phenol polyoxyethylene succinate sulfonate 7%, neopelex 6%, urea 3%, attapulgite are supplied.
6. the compound disinfectant according to any one of claim 1-5, is characterized in that, described compound disinfectant is for preventing and treating gray mold of cucumber.
7. compound disinfectant according to claim 6, is characterized in that, described compound disinfectant is in morbidity dispenser in early stage.
8. compound disinfectant according to claim 7, is characterized in that, the annual spraying times of described compound disinfectant is 1 or 2 time.
9. compound disinfectant according to claim 8, is characterized in that, described compound disinfectant active ingredient dosage is 5 grams/ha-15 grams/ha.
10. compound disinfectant according to claim 9, is characterized in that, described compound disinfectant dosage is 6.67 grams/ha.
CN201410630370.3A 2014-11-11 2014-11-11 Effective ingredient is the compound disinfectant of garlicin and pyrimethanil Expired - Fee Related CN104351186B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105613602A (en) * 2016-03-22 2016-06-01 侯仰运 Biological insectofungicide containing both sowthistle tasselflower herb and garlicin and production process of insectofungicide

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4318372B4 (en) * 1992-06-10 2010-10-28 BASF Agro B.V., Arnhem (NL)-Wädenswil-Branch Fungicidal mixtures
JP3634409B2 (en) * 1993-09-13 2005-03-30 ビーエーエスエフ アクチェンゲゼルシャフト Disinfectant mixture
CN1461590A (en) * 2002-05-26 2003-12-17 汪建利 Sterilizing composition contg. ethylicin

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105613602A (en) * 2016-03-22 2016-06-01 侯仰运 Biological insectofungicide containing both sowthistle tasselflower herb and garlicin and production process of insectofungicide

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Effective date of registration: 20160621

Address after: 266109, No. 111, sunny road, Chengyang District, Shandong, Qingdao

Applicant after: JINAN CAVIN BIOTECHNOLOGY CO., LTD.

Address before: 250001 Shandong Province, Ji'nan City District Court building 2303 No. 288

Applicant before: JINAN XINQIDIAN MEDICINE SCIENCE & TECHNOLOGY CO., LTD.

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Effective date of registration: 20181127

Address after: 402473 Three Groups of Shuangliu Village, Wujia Town, Rongchang District, Chongqing

Patentee after: Shuangliu Vegetable Planting Cooperative in Rongchang District of Chongqing

Address before: 266109 Yan Yang Road, Chengyang District, Qingdao, Shandong Province, No. 111

Patentee before: Qingdao Qingzhi Enterprise Management Consulting Co., Ltd.

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CF01 Termination of patent right due to non-payment of annual fee