CN1043505C - Chinese herbal medicine anti-mould anthelmintic - Google Patents
Chinese herbal medicine anti-mould anthelmintic Download PDFInfo
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- CN1043505C CN1043505C CN93105059A CN93105059A CN1043505C CN 1043505 C CN1043505 C CN 1043505C CN 93105059 A CN93105059 A CN 93105059A CN 93105059 A CN93105059 A CN 93105059A CN 1043505 C CN1043505 C CN 1043505C
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- oil
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- geraniol
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Abstract
The present invention relates to an anti-mildew insect repellent which is made from Chinese herbal medicines and is especially suitable for books and files. The insect repellent is made from Fructus Litseae oil, clove oil, wrinkled gianthyssop herb oil, heartleaf houttuynia herb oil and geraniol in the percentage by weight of 50, 20, 10, 10, 10 in turn through the following steps: firstly mixing the clove oil, the wrinkled gianthyssop herb oil and the heartleaf houttuynia herb oil; adding the geraniol later; adding the Fructus Litseae oil, and then mixing. The insect repellent has the characteristics of good anti-mildew and insect repelling effect, particularly good eliminating effect on mildew and pest in file data, safe use and no pollution, and is suitable for the file data, grain storage facilities, cultural relics, family clothes and leather.
Description
The present invention relates to the Chinese herbal medicine mould resistant that a kind of article preservation is used.Especially for the anti-mildew of book and file etc., also can be used as the mould resistant of grain depot, historical relic and family's clothing, leather.
At present, the medicine to book and file mildew-resistant expelling parasite is mainly chemosynthesis medicine both at home and abroad, and as copper system, organotin system, chlorophenol system, quaternary ammonium salt system, thiazole system, isothiazole system and organic bromine system etc., but they all exist in various degree pollution and toxicity problem.Anti-mould anthelmintic is made with geraniol by units such as China's archives preservation once joint research and development; Chinese patent CN1062267A provides a kind of natural fungicidal agent, makes with cinnamomum septentrionale hand. mazz. leaf or broad-leaved camphor leaf, can be antibacterial and sterilization, but the employed active ingredient of above preparation is dull, easily forms biotic resistance.In recent years, Japan is developed into the volatility mould inhibitor, and main blending has the special public clear 55-2403 of the P-dichloro-benzenes＜Japan Patent of P-chloro-M-dimethylbenzene phenols 〉, can produce harm in vivo, sterilize, but easily cause the fine crystalline muddiness of human eye, use is restricted.
The object of the invention is mould resistant main component, that be applicable to purposes such as books preservation with the Chinese herbal medicine for adopting China's plant resources peculiar, raised growth to be prepared into a kind of, its existing antifungi function, and produce the said preparation three-waste free pollution, during use to the person poultry safety, thereby the mould resistant that a kind of raw material can be supplied in a large number, anti-mildew is effective, production cost is low is provided.
Content of the present invention can be achieved through the following technical solutions: is 50,20,10,10,10 with Litsea cubeba oil, caryophyllus oil, palchouli oil, Herba Houttuyniae oil and geraniol in order with percentage by weight, after caryophyllus oil, palchouli oil, Herba Houttuyniae oil mixing, add geraniol again, add Litsea cubeba oil then, regulate its pH value to neutral, in closed container, connect, enter the preparation machine, promptly can be made into mould resistant with the carrier bag.The formulation of preparation of the present invention can be liquid, and also the available packages junctor is made solid, and carrier can be molecular sieve, dextrin etc.
Various components can obtain as follows:
The extraction of Litsea cubeba oil.[Litsea Cubeba (Lour)] is raw material with cubeb litsen tree, keeps carpopodium when gathering as far as possible, and the fresh fruit of gathering is layered on the distillation screen, piles 2/3rds height to the steamer bucket.Add water to below the screen in the pot, water and steam distillation is carried out in heating.Distillate is separated the Litsea cubeba oil of light specific gravity by condenser and oil water separator.The cubeb litsen tree main body of oil is a citral, and its boiling point is 228 ℃, also has methyl heptenone and rhodinal etc. in addition.
The extraction of caryophyllus oil.With cloves [Eugenia Caryophyllate Thunb] bud is raw material, and the bud of gathering when calyx changes aubergine into dries, and is placed on after fragmentation in the water of boiler, carries out the poach distillation, first slow fire heating, and when steam comes out, heating continuously.Steam is through being condensed into liquid, separated and collected proportion than water big＜1.044～1.057 caryophyllus oil.Caryophyllus oil contains eugenol 70～90%, and 254 ℃ of its boiling points in addition, also have Acetyl eugenol.
The extraction of palchouli oil.[Pogostemon Cablin (Blanco) Bench] is raw material with Pogostemon cablin, before plant blossom is extremely fallen leaves, select sunny weather to uproop, the excision root, be exposed to the sun daytime, the fermentation of banking up evening, about 1.5～2.0 meters of the height of banking up, stack fermentation after three days, scatter and dry, the leaf look becomes golden yellow or isabelline; After perhaps having dug plant, excision root and backbone wash, and promptly place under the sun and shine two days, dry in the shade three days.To grind with travel fatigue through above-mentioned ready Pogostemon cablin, and use the way of distillation waterborne, difference is near the bottom of a pan live (open) steam inlet duct to be housed, with 1～1.5 * 10
5P
aPressure live (open) steam distillation, about 14～15 hours of distillation time directly cools off steam, collecting the palchouli oil＜proportion lighter than water is 0.95～0.98 〉.Palchouli oil contains Patchoulicalcohol 52～57%, and boiling point is 56 ℃, also has patchoulene etc. in addition.
The extraction of Herba Houttuyniae oil.[Houttuynia Corclata Thunb] is raw material with cordate houttuynia, in summer, autumn herb is uprooped, clean and dry in the shade, be cut into about one centimetre segment, put into digester, according to the ratio lixiviate with 3 liters of digestion agents of 1 kilogram of cordate houttuynia, digestion agent can be ethanol, carbon tetrachloride, propane diols etc.After the hydraulic fluid, the pressure reducing and steaming digestion agent promptly gets medicinal extract, and then from medicinal extract distillation extraction Herba Houttuyniae oil, main component is decanoy acetaldehyde, methyl n nonyl ketone, laurene, capraldehyde etc.
Geraniol is manufactured goods, can buy on market.
The anti-mildew of preparation of the present invention is respond well.Especially the mould in the archives material there is bigger killing action, with the similar products at home and abroad ratio, can not only mildew-resistant, and can kill mycotic spore, effect is obvious, referring to subordinate list one, two.Table one is the fungistatic effect comparison sheet of this preparation and other mould inhibitor, as can be seen, with behind this preparation, the not growth rate of various moulds is identical with certain foreign mould inhibitor and the brilliant G of homemade camphor, be absolutely, and homemade mould inhibitor N, J, Z all do not reach hundred-percent not growth rate.Table two is this preparation and the bactericidal assay of the brilliant G of homemade camphor and certain foreign mould inhibitor R comparison sheet as a result, from table two as can be seen, after handling with preparation of the present invention, listed various moulds fail to regenerate in the table, and other mould inhibitor then can not guarantee not have the regeneration mould.This preparation is a natural extract, and through acute, conventional and special toxicological test, toxicity is less, and long-term use can not make human body produce ANOMALOUS VARIATIONS.This preparation physicochemical property is stable, observes through different temperatures, and except that reducing because of volatilization, it is slower to lose efficacy.
Chinese herbal medicine anti-mould anthelmintic through the inventive method preparation, belong to Chinese herbal medicine extract, used raw material such as cubeb litsen tree, cloves, Pogostemon cablin and cordate houttuynia are China and spread all over southern each province growing plants, this anti-mildew preparation manufacturing process is simple, and cost is low, and it is strong to have a mold resistance, safe in utilization, pollution-free, characteristics such as the term of validity is long have remarkable result to the anti-mildew of archives material, grain depot, historical relic and family's clothing, leather; Need can also be used to the others of anti-mildew.
Subordinate list one preparation of the present invention and part commodity mould inhibitor fungistatic effect comparison sheet
The bactericidal assay of subordinate list two preparations of the present invention and camphor crystalline substance, certain outer homemade mould inhibitor is comparison sheet as a result
Subordinate list one: preparation of the present invention and part commodity mould inhibitor fungistatic effect comparison sheet
Subordinate list two: this shows the bactericidal assay of preparation of the present invention and camphor crystalline substance, certain outer homemade mould inhibitor as a result
Annotate: numeral is a colony diameter in the subordinate list one, two, and unit is mm
| Handle | Handling the back fate observes | Aspergillus niger | Aspergillus japonicus | Aspergillus flavus | Aspergillus versicolor | Penicillium chrysogenum | Withered grey mould | Penicillium oxalicum | Portugal's wine and women-sensual pursuits mould | The branch spore is mould | Cupreum | Wood is composed sickle-like bacteria | The spore that intersects is mould | Curved spore is mould |
| Camphor G crystalline substance | One day | 0 | ?7 | ?10 | ?4 | ?2 | ?6 | ?7 | ?2 | ?4 | ?4 | ?9 | ?4 | ?10 |
| Two days | 21 | ?21 | ?19 | ?6 | ?7 | ?12 | ?14 | ?4 | ?10 | ?8 | ?20 | ?11 | ?22 | |
| Certain produces the anti-mould R of state of agent outward | One day | 6 | ?8 | ?8 | ?3 | ?2 | ?4 | ?5 | ?4 | ?2 | ?6 | ?8 | ?5 | ?11 |
| Two days | 23 | ?27 | ?17 | ?5 | ?6 | ?10 | ?14 | ?8 | ?4 | ?19 | ?17 | ?10 | ?23 | |
| This system invention agent | One day | 0 | ?0 | ?0 | ?0 | ?0 | ?0 | ?0 | ?0 | ?0 | ?0 | ?0 | ?0 | ?0 |
| Two days | 0 | ?0 | ?0 | ?0 | ?0 | ?0 | ?0 | ?0 | ?0 | ?0 | ?0 | ?0 | ?0 |
Claims (2)
1. Chinese herbal medicine mould resistant is characterized in that it is made up of Litsea cubeba oil, caryophyllus oil, palchouli oil, Herba Houttuyniae oil and geraniol, and its percentage by weight is 50,20,10,10,10 in order.
2. by the mould resistant described in the claim 1, feature is: after caryophyllus oil, palchouli oil, Herba Houttuyniae oil are mixed, add geraniol again, add Litsea cubeba oil then, regulate its pH value to neutral, in closed container, connect with the carrier bag, enter the preparation machine, make mould resistant, wherein: fresh cubeb litsen tree fruit is layered on the distillation screen, carry out water and steam distillation, and obtain Litsea cubeba oil through condensation, separation; Cloves bud after the fragmentation is placed on poach distillation in the water of boiler,, obtains caryophyllus oil steam condensation, separation; The Pogostemon cablin that dries and fermented is ground with travel fatigue, adopt described water and steam distillation method distillation, and then by 1～1.5 * 10
5P
aThe steam of pressure directly distilled about 14～15 hours, steam was directly cooled off obtain palchouli oil; Put into the digester lixiviate in 1 kilogram of ratio with 3 liters of digestion agents of cordate houttuynia, the pressure reducing and steaming digestion agent gets medicinal extract, again distillation extraction Herba Houttuyniae oil from medicinal extract.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN93105059A CN1043505C (en) | 1993-05-19 | 1993-05-19 | Chinese herbal medicine anti-mould anthelmintic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN93105059A CN1043505C (en) | 1993-05-19 | 1993-05-19 | Chinese herbal medicine anti-mould anthelmintic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1095217A CN1095217A (en) | 1994-11-23 |
| CN1043505C true CN1043505C (en) | 1999-06-02 |
Family
ID=4985515
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN93105059A Expired - Fee Related CN1043505C (en) | 1993-05-19 | 1993-05-19 | Chinese herbal medicine anti-mould anthelmintic |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1043505C (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101537200B (en) * | 2009-04-27 | 2013-02-27 | 广东工业大学 | Mildewproof sterilized method for ancient books |
| CN102428852A (en) * | 2011-09-01 | 2012-05-02 | 中国农业科学院麻类研究所 | Degradable agricultural natural insect-repelling mulching film and preparation method thereof |
| CN104170954A (en) * | 2013-05-27 | 2014-12-03 | 王鹏 | Efficient non-toxic foodstuff insect repellent |
| CN105532754B (en) * | 2016-02-03 | 2018-08-07 | 中南林业科技大学 | A kind of infested natural plants combined extracts to go mouldy of prevention grain |
| CN107019004A (en) * | 2017-04-21 | 2017-08-08 | 安徽家壹味食品有限公司 | The method for preparing oil meal Vermins-proof mildew-proof agent using Zanthoxylum essential oil processing byproduct pricklyash hull |
| CN110623008A (en) * | 2019-09-24 | 2019-12-31 | 徐云 | Green quality guaranteeing agent and preparation method thereof |
-
1993
- 1993-05-19 CN CN93105059A patent/CN1043505C/en not_active Expired - Fee Related
Non-Patent Citations (4)
| Title |
|---|
| 《中药大辞典》第一版 1986.6.1 江苏新医学院编 * |
| 《化工辞典》第二版 1979.12.1 化工出版社 * |
| 《化工辞典》第二版 1979.12.1 化工出版社;《土农药及生物防治》第一版 1979.10.1 化工出版社;《中药大辞典》第一版 1986.6.1 江苏新医学院编 * |
| 《土农药及生物防治》第一版 1979.10.1 化工出版社 * |
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| Publication number | Publication date |
|---|---|
| CN1095217A (en) | 1994-11-23 |
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