CN104342267B - Electronics aluminum processes special aqueous cutting fluid without silicon - Google Patents
Electronics aluminum processes special aqueous cutting fluid without silicon Download PDFInfo
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- CN104342267B CN104342267B CN201410519526.0A CN201410519526A CN104342267B CN 104342267 B CN104342267 B CN 104342267B CN 201410519526 A CN201410519526 A CN 201410519526A CN 104342267 B CN104342267 B CN 104342267B
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- Prior art keywords
- cutting fluid
- silicon
- aluminum
- electronics
- aqueous cutting
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- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 21
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 21
- 239000002173 cutting fluid Substances 0.000 title claims abstract description 16
- 229910052710 silicon Inorganic materials 0.000 title claims abstract description 10
- 239000010703 silicon Substances 0.000 title claims abstract description 10
- 238000000034 method Methods 0.000 title claims abstract description 9
- -1 syntholube Substances 0.000 abstract description 7
- 239000013556 antirust agent Substances 0.000 abstract description 5
- 239000002199 base oil Substances 0.000 abstract description 5
- 230000005764 inhibitory process Effects 0.000 abstract description 5
- 239000004094 surface-active agent Substances 0.000 abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 description 6
- 230000007797 corrosion Effects 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000007788 liquid Substances 0.000 description 5
- 239000002480 mineral oil Substances 0.000 description 5
- 235000010446 mineral oil Nutrition 0.000 description 5
- 239000004721 Polyphenylene oxide Substances 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- BTFJIXJJCSYFAL-UHFFFAOYSA-N arachidyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCO BTFJIXJJCSYFAL-UHFFFAOYSA-N 0.000 description 4
- 229920000570 polyether Polymers 0.000 description 4
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 4
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 3
- 239000004327 boric acid Substances 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- GIAFURWZWWWBQT-UHFFFAOYSA-N 2-(2-aminoethoxy)ethanol Chemical compound NCCOCCO GIAFURWZWWWBQT-UHFFFAOYSA-N 0.000 description 2
- QIDCRGDFWRMBJC-UHFFFAOYSA-N 2-aminoethanol;boric acid Chemical compound NCCO.OB(O)O QIDCRGDFWRMBJC-UHFFFAOYSA-N 0.000 description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 2
- 229910001018 Cast iron Inorganic materials 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 239000008118 PEG 6000 Substances 0.000 description 2
- 229920001030 Polyethylene Glycol 4000 Polymers 0.000 description 2
- 229920002584 Polyethylene Glycol 6000 Polymers 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 150000008052 alkyl sulfonates Chemical class 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- 239000013530 defoamer Substances 0.000 description 2
- 150000005690 diesters Chemical class 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 125000001664 diethylamino group Chemical group [H]C([H])([H])C([H])([H])N(*)C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 125000005313 fatty acid group Chemical group 0.000 description 2
- 231100000636 lethal dose Toxicity 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- 235000010288 sodium nitrite Nutrition 0.000 description 2
- 231100000611 venom Toxicity 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- CSDREXVUYHZDNP-UHFFFAOYSA-N alumanylidynesilicon Chemical compound [Al].[Si] CSDREXVUYHZDNP-UHFFFAOYSA-N 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000012136 culture method Methods 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000010808 liquid waste Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- 210000001533 respiratory mucosa Anatomy 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229950004959 sorbitan oleate Drugs 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000012224 working solution Substances 0.000 description 1
Abstract
The invention discloses a kind of electronics aluminum and process special aqueous cutting fluid without silicon, be made up of base oil, antirust agent, syntholube, surfactant, water.Product of the present invention is the most siliceous, and defoaming, aluminum rust inhibition, resistance to corruptibility are excellent.
Description
Technical field
The present invention relates to a kind of electronics aluminum and process special aqueous cutting fluid without silicon.
Background technology
Current domestic commercially available electronics aluminum Cutting fluid for processing, commonly uses siliceous aluminum corrosion inhibiter and froth breaking in formula
Agent.Although siliceous electronics aluminum Cutting fluid for processing has excellent aluminum corrosion inhibition and antifoam performance, but there is also one and dash forward
Go out drawback: add be difficult to man-hour to meet the follow-up performance quality requirements of electronic product (siliceous electronic product easily cause short circuit,
Disk read-write is bad；Under high temperature, the silicon of volatilization adsorbs on electronic devices and components surface, causes resistance change or resistance to puncture；Siliceous
The existence of material also can affect the surface adsorption effect of CPU heat-conducting medium, makes heat eliminating medium be difficult to play a role, and affects CPU and dissipates
Heat), it is impossible to adapt to the requirement of high-end market customers.In addition, commercially available electronics aluminum Cutting fluid for processing also has 2 problems also
Need to put forth effort to solve.One is anti-corrupt poor performance, and service life cycle is short (although also added with antibacterial in working solution, but typically making
Take less than 10 months, begin to long bacterium smelly, putrid and deteriorated, need to change in time liquid.This not only can have a strong impact on the production of enterprise
Working environment, and too increase the cost changing liquid and liquid waste processing)；Two is containing venomous injurants such as sodium nitrite in formula
Matter, affects Environmental security, jeopardizes health.
Summary of the invention
It is an object of the invention to provide a kind of electronics aluminum with excellent aluminum inhibition, defoaming and resistance to corrupt performance to process
Special aqueous cutting fluid without silicon.
The technical solution of the present invention is:
A kind of electronics aluminum processes special aqueous cutting fluid without silicon, it is characterized in that: comprise the following components in percentage by weight:
Base oil 50～70%
Antirust agent 10～20%
Syntholube 10～15%
Surfactant 5～10%
Water surplus.
Base oil is naphthenic mineral oil or paraffin base mineral oil.
Antirust agent is fatty acid, alkylsulfonate, amine, amide boric acid monoethanolamine, sulfonic acid ammonia salt, boric acid, borate, oil
The mixture of one or more compositions in acid.
Syntholube refers to one or more in synthetic ester such as polyester, binary acid diester or polyol ester.
Surfactant is diethylamine block polyether, Ge Erte eicosanol PEG-6000 succinate, Ge Erte
One or more in eicosanol PEG-4000 succinate.
Product of the present invention is the most siliceous, and defoaming, aluminum rust inhibition, resistance to corruptibility are excellent；
1. formula constituent uses the most siliceous aluminum corrosion inhibiter and defoamer (to substitute the silicon-aluminum containing that commercially available prod commonly uses
Corrosion inhibiter and defoamer).Test through laboratory aluminum corrosion experiment and defoaming: ACD12 aluminum is under 50 DEG C of environment, 5% concentration dilution
Still invariant color after putting 4 hours in liquid；After 5 points of kinds of 5% concentration dilution liquid high-speed stirred (10000 revs/min), foam in 1 minute
It is highly 0.Its aluminum corrosion inhibition and antifoam performance can compare favourably with siliceous cutting fluid completely.
2. formula constituent uses and is difficult to be bacterially decomposed, have additive (the example macromole chain amine of special molecular structure
The 2-aminoethoxyethanol of structure, the at a high ph ph stability of guarantee system, substitute what commercially available prod commonly used
Antibacterial), improve the anti-corrupt performance of product, the service life cycle of diluent is extended to more than 2 years (more commercially available siliceous products
Product extend 1 times).Test through the anti-corruptibility of laboratory: 180 grams of cast-iron scraps and 36 grams of lubricating oil, add the antibacterial of 107 numbers
Corrupt liquid, use froth culture method test proceed to 28 days, each item data of cutting fluid is in normally, wherein cutting fluid outward appearance
Being still milky, concentration >=5%, pH >=9.0, cast-iron scrap does not becomes rusty, and bacterial population is 103, but cutting fluid will not be corrupt smelly.
3. formula constituent does not use sodium nitrite, heavy metal etc. to jeopardize the venomous injurant of Environmental security and health
Matter (selects the alternative material that biodegradable properties are excellent, friendly to human and environment), biological half lethal dose LD50 of product
>=5000mg/kg, half lethal concentration LC50 >=5000mg/m3, respiratory mucosa stimulates≤1 grade.
Below in conjunction with embodiment, the invention will be further described.
Detailed description of the invention
Embodiment 1:
A kind of electronics aluminum processes special aqueous cutting fluid without silicon, is the product obtained by weight components mix and blend:
Naphthenic mineral oil 52%
2-aminoethoxyethanol 8%
Boric acid 2%
Polyether ester 11%
Diethylamine block polyether 5%
Polyethylene glycol (PEG) oleate 7%
Sorbitan oleate 3%
Oleic acid 4%
Water 8%.
Embodiment 2:
A kind of electronics aluminum processes special aqueous cutting fluid without silicon, comprises the following components in percentage by weight:
Base oil 50～70%(example 50%, 60%, 70%)
Antirust agent 10～20%(example 10%, 15%, 20%)
Syntholube 10～15%(example 10%, 12%, 15%)
Surfactant 5～10%(example 5%, 8%, 10%)
Water surplus.
Base oil is naphthenic mineral oil or paraffin base mineral oil.
Antirust agent is fatty acid, alkylsulfonate, amine, amide boric acid monoethanolamine, sulfonic acid ammonia salt, boric acid, borate, oil
The mixture of one or more compositions in acid.
Syntholube refers to one or more in synthetic ester such as polyester, binary acid diester or polyol ester.
Surfactant is diethylamine block polyether, Ge Erte eicosanol PEG-6000 succinate, Ge Erte
One or more in eicosanol PEG-4000 succinate.
Claims (1)
1. an electronics aluminum processes special aqueous cutting fluid without silicon, it is characterized in that: comprise the following components in percentage by weight:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410519526.0A CN104342267B (en) | 2014-09-30 | 2014-09-30 | Electronics aluminum processes special aqueous cutting fluid without silicon |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410519526.0A CN104342267B (en) | 2014-09-30 | 2014-09-30 | Electronics aluminum processes special aqueous cutting fluid without silicon |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104342267A CN104342267A (en) | 2015-02-11 |
| CN104342267B true CN104342267B (en) | 2016-08-24 |
Family
ID=52498732
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410519526.0A Active CN104342267B (en) | 2014-09-30 | 2014-09-30 | Electronics aluminum processes special aqueous cutting fluid without silicon |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104342267B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104818100A (en) * | 2015-03-18 | 2015-08-05 | 启东尤希路化学工业有限公司 | Environment-friendly and low-cost special grinding fluid for steel ball hard grinding |
| CN115746944A (en) * | 2022-11-30 | 2023-03-07 | 上海尤希路化学工业有限公司 | Alcohol-free amine total-synthesis water-based cutting fluid and preparation method and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101104831A (en) * | 2007-08-10 | 2008-01-16 | 中国石油化工集团公司 | Micro-emulsification stainless steel cutting liquid |
| CN102925269A (en) * | 2012-11-09 | 2013-02-13 | 上海应用技术学院 | Aluminum alloy semisynthesis cutting liquid and preparation method thereof |
| CN103031195A (en) * | 2011-10-10 | 2013-04-10 | 洛科斯润滑油（上海）有限公司 | Microemulsion cutting fluid |
| CN103468382A (en) * | 2013-08-30 | 2013-12-25 | 广州机械科学研究院有限公司 | Boron-free chlorine-free formaldehyde-free microemulsified cutting fluid and application thereof |
-
2014
- 2014-09-30 CN CN201410519526.0A patent/CN104342267B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101104831A (en) * | 2007-08-10 | 2008-01-16 | 中国石油化工集团公司 | Micro-emulsification stainless steel cutting liquid |
| CN103031195A (en) * | 2011-10-10 | 2013-04-10 | 洛科斯润滑油（上海）有限公司 | Microemulsion cutting fluid |
| CN102925269A (en) * | 2012-11-09 | 2013-02-13 | 上海应用技术学院 | Aluminum alloy semisynthesis cutting liquid and preparation method thereof |
| CN103468382A (en) * | 2013-08-30 | 2013-12-25 | 广州机械科学研究院有限公司 | Boron-free chlorine-free formaldehyde-free microemulsified cutting fluid and application thereof |
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| Publication number | Publication date |
|---|---|
| CN104342267A (en) | 2015-02-11 |
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