CN111234958A - Efficient environment-friendly water-diversion hydrocarbon cleaning agent and production method thereof - Google Patents

Efficient environment-friendly water-diversion hydrocarbon cleaning agent and production method thereof Download PDF

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Publication number
CN111234958A
CN111234958A CN202010189722.1A CN202010189722A CN111234958A CN 111234958 A CN111234958 A CN 111234958A CN 202010189722 A CN202010189722 A CN 202010189722A CN 111234958 A CN111234958 A CN 111234958A
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Prior art keywords
cleaning agent
diversion
hydrocarbon cleaning
water
friendly water
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CN202010189722.1A
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吴爱平
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Rema Environmental Protection Technology Jiangsu Co ltd
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Rema Environmental Protection Technology Jiangsu Co ltd
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Priority to CN202010189722.1A priority Critical patent/CN111234958A/en
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/265Carboxylic acids or salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/24Hydrocarbons
    • C11D7/241Hydrocarbons linear
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/263Ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/32Organic compounds containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/50Solvents
    • C11D7/5004Organic solvents
    • C11D7/5027Hydrocarbons

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a high-efficiency environment-friendly water-diversion hydrocarbon cleaning agent and a production method thereof, which comprises the following components in percentage by weight; higher saturated fatty acids: 1.75-3.75%; higher aliphatic amine: 2.63-5.63%; a stabilizer: 3% -5%; high-purity straight-chain alkane solvent oil: the balance; the cleaning agent compounded by different high-purity straight-chain alkane solvent oil, high-grade saturated fatty acid, high-grade fatty amine and a stabilizing agent can cut a water washing process into environment-friendly hydrocarbon cleaning, reduces the generation of sewage, effectively solves the rusting phenomenon of iron pieces in a water processing link and a water-based cleaning process, has the action mechanism that an aqueous medium in the water processing link is peeled off and settled from the surface of a product, can be recycled and reused by a settlement and drainage method based on the principle of water-oil incompatibility, reduces the pollution caused by water washing, has stable performance, and is a safe, strong and efficient functional hydrocarbon cleaning agent by matching with a vacuum circulation cleaning machine.

Description

Efficient environment-friendly water-diversion hydrocarbon cleaning agent and production method thereof
Technical Field
The invention relates to the field of hydrocarbon cleaning agents, in particular to a high-efficiency environment-friendly water-diversion hydrocarbon cleaning agent and a production method thereof.
Background
In the field of industrial cleaners, halogenated hydrocarbon cleaners such as freon 113, carbon tetrachloride, trichloroethane, chloroform, methyl bromoform and other ODS (ozone depleting substances) have been widely used for a long time, and these cleaners bring convenience to people and also cause great damage to human health and environment due to their toxicity, volatility, corrosiveness and/or non-degradability. The ODS cleaning agent can damage the earth ozone layer, and further causes long-term harm to human beings and other various organisms on the earth.
With the elimination of ODS and the increasing perfection of environmental regulations, the environmental-friendly hydrocarbon cleaning agent is increasingly becoming a substitute of the ODS cleaning agent due to good decontamination, safety and environmental protection, but the current hydrocarbon cleaning agent is polluted when in use, cannot be recycled and reused, and does not conform to the current environmental protection concept.
Disclosure of Invention
The invention aims to provide a high-efficiency environment-friendly water-diversion hydrocarbon cleaning agent with stable performance and high efficiency.
The technical scheme adopted by the invention for solving the technical problems is as follows: an efficient environment-friendly water-diversion hydrocarbon cleaning agent comprises the following components in percentage by weight;
Figure BDA0002415436710000013
further, the method comprises the following steps: the high-purity straight-chain alkane solvent oil is synthesized straight-chain hydrocarbon.
The invention also discloses a production method of the efficient environment-friendly water-diversion hydrocarbon cleaning agent, which comprises the following steps: injecting high-purity straight-chain alkane solvent oil into a reaction kettle, stirring and heating to 65-70 ℃, adding pasty high-grade fatty amine for 30 minutes under stirring until the high-purity straight-chain alkane solvent oil is completely dissolved, slowly adding high-grade saturated fatty acid, fully stirring for 30 minutes, stopping heating, adding a stabilizer, fully stirring for 1 hour, standing the obtained turbid solution for 6 hours, and taking supernatant to obtain the high-efficiency environment-friendly water-diversion hydrocarbon cleaning agent after fully precipitating suspended matters.
Figure BDA0002415436710000014
The invention has the beneficial effects that: the cleaning agent compounded by different high-purity straight-chain alkane solvent oil, high-grade saturated fatty acid, high-grade fatty amine and a stabilizing agent can cut a water washing process into environment-friendly hydrocarbon cleaning, reduces the generation of sewage, effectively solves the rusting phenomenon of iron pieces in a water processing link and a water-based cleaning process, has the action mechanism that an aqueous medium in the water processing link is peeled off and settled from the surface of a product, can be recycled and reused by a settlement and drainage method based on the principle of water-oil incompatibility, reduces the pollution caused by water washing, has stable performance, and is a safe, strong and efficient functional hydrocarbon cleaning agent by matching with a vacuum circulation cleaning machine.
Detailed Description
In order to make the aforementioned objects, features and advantages of the present invention more comprehensible, specific embodiments thereof will be described in detail with reference to the following examples. In the following description, numerous specific details are set forth in order to provide a thorough understanding of the present invention. This invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein.
The invention discloses a high-efficiency environment-friendly water-diversion hydrocarbon cleaning agent which comprises the following components in percentage by weight;
Figure BDA0002415436710000021
the high-purity straight-chain alkane solvent oil has a carrier and has the function of serving as a main body of a cleaning agent;
the higher saturated fatty acid has lipophilic function;
the higher fatty amine has the functions of hydrophile and metal hydrophile;
the stabilizer is 2-ethylhexyl vinyl ether, maintains the content of water in the whole system, ensures that the water soluble amount is not more than 5 percent, can quickly coagulate and separate water from the system, and ensures the water diversion effect of a water diversion main body;
specifically, the high-purity straight-chain alkane solvent oil is synthetic straight-chain hydrocarbon, such as n-decane, n-undecane, n-dodecane and the like, the purity is more than 95%, the synthetic straight-chain hydrocarbon has the characteristics of high purity, stable recovery and high efficiency, the water diversion effect is poor after the high-efficiency environment-friendly water diversion hydrocarbon cleaning agent is used for a period of time, the high-purity straight-chain alkane solvent oil can be recovered through vacuum recovery and used as a rinsing liquid for reutilization, the performance is stable, the efficiency is high, the used high-grade saturated fatty acid and the used high-grade fatty amine are both refined substances derived from kitchen waste oil, and therefore the reutilization of the kitchen waste oil is realized while the cost is reduced.
The invention also discloses a production method of the efficient environment-friendly water-separating hydrocarbon cleaning agent, which comprises the steps of injecting high-purity straight-chain alkane solvent oil into a reaction kettle, stirring and heating to 65-70 ℃, adding pasty higher fatty amine for 30 minutes under stirring until the pasty higher fatty amine is completely dissolved, slowly adding higher saturated fatty acid, fully stirring for 30 minutes, stopping heating, adding a stabilizer, fully stirring for 1 hour, standing to obtain a turbid solution for 6 hours, fully precipitating suspended matters, and taking supernatant to obtain the efficient environment-friendly water-separating hydrocarbon cleaning agent, wherein the components are as follows in percentage by weight:
Figure BDA0002415436710000022
Figure BDA0002415436710000031
the following are specific examples:
the first embodiment is as follows:
an efficient environment-friendly water-diversion hydrocarbon cleaning agent comprises the following components in percentage by weight;
Figure BDA0002415436710000032
the specific manufacturing process comprises the following steps: injecting high-purity straight-chain alkane solvent oil into a reaction kettle, stirring and heating to 70 ℃, adding pasty higher aliphatic amine for 30 minutes under stirring until the pasty higher aliphatic amine is completely dissolved, slowly adding higher saturated fatty acid, fully stirring for 30 minutes, stopping heating, adding a stabilizer, fully stirring for 1 hour, standing to obtain a turbid solution for 6 hours, and taking supernatant to obtain the high-efficiency environment-friendly water-diversion hydrocarbon cleaning agent after fully precipitating suspended matters.
Example two:
an efficient environment-friendly water-diversion hydrocarbon cleaning agent comprises the following components in percentage by weight;
Figure BDA0002415436710000033
the specific manufacturing process comprises the following steps: injecting high-purity straight-chain alkane solvent oil into a reaction kettle, stirring and heating to 67 ℃, adding pasty higher fatty amine for 30 minutes under stirring until the pasty higher fatty amine is completely dissolved, slowly adding higher saturated fatty acid, fully stirring for 30 minutes, stopping heating, adding a stabilizer, fully stirring for 1 hour, standing to obtain a turbid solution for 6 hours, and taking supernatant to obtain the high-efficiency environment-friendly water-diversion hydrocarbon cleaning agent after fully precipitating suspended matters.
Example three:
an efficient environment-friendly water-diversion hydrocarbon cleaning agent comprises the following components in percentage by weight;
Figure BDA0002415436710000034
Figure BDA0002415436710000041
the specific manufacturing process comprises the following steps: injecting high-purity straight-chain alkane solvent oil into a reaction kettle, stirring and heating to 70 ℃, adding pasty higher aliphatic amine for 30 minutes under stirring until the pasty higher aliphatic amine is completely dissolved, slowly adding higher saturated fatty acid, fully stirring for 30 minutes, stopping heating, adding a stabilizer, fully stirring for 1 hour, standing to obtain a turbid solution for 6 hours, and taking supernatant to obtain the high-efficiency environment-friendly water-diversion hydrocarbon cleaning agent after fully precipitating suspended matters.
The above-mentioned embodiments are intended to illustrate the objects, technical solutions and advantages of the present invention in further detail, and it should be understood that the above-mentioned embodiments are only exemplary embodiments of the present invention, and are not intended to limit the present invention, and any modifications, equivalents, improvements and the like made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (5)

1. The efficient environment-friendly water-diversion hydrocarbon cleaning agent is characterized by comprising the following components in percentage by weight;
Figure FDA0002415436700000011
2. the efficient environment-friendly water-splitting hydrocarbon cleaning agent as claimed in claim 1, wherein the high-purity straight-chain alkane solvent oil is synthetic straight-chain hydrocarbon.
3. The efficient environment-friendly water-splitting hydrocarbon cleaning agent as claimed in claim 1, wherein the stabilizer is 2-ethylhexyl vinyl ether.
4. A production method of a high-efficiency environment-friendly water-diversion hydrocarbon cleaning agent is characterized by injecting high-purity straight-chain alkane solvent oil into a reaction kettle, stirring and heating to 65-70 ℃, adding pasty higher fatty amine for 30 minutes under stirring until the pasty higher fatty amine is completely dissolved, slowly adding higher saturated fatty acid, fully stirring for 30 minutes, stopping heating, adding a stabilizer, fully stirring for 1 hour, standing to obtain a turbid solution for 6 hours, fully precipitating suspended matters, and taking supernatant to obtain the high-efficiency environment-friendly water-diversion hydrocarbon cleaning agent.
5. The production method of the efficient and environment-friendly water-diversion hydrocarbon cleaning agent as claimed in claim 4,
Figure FDA0002415436700000013
CN202010189722.1A 2020-03-18 2020-03-18 Efficient environment-friendly water-diversion hydrocarbon cleaning agent and production method thereof Pending CN111234958A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113652310A (en) * 2021-08-20 2021-11-16 常州智高化学科技有限公司 Multifunctional hydrocarbon detergent and production method thereof
CN114277382A (en) * 2021-12-29 2022-04-05 泰伦特生物工程股份有限公司 Water-cutting cleaning agent replacing rinsing and drying process and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104164311A (en) * 2014-08-20 2014-11-26 江阴市五洋化工有限公司 Method for preparing environment-friendly hydrocarbon cleaner
CN106367220A (en) * 2016-08-24 2017-02-01 诺而曼环保科技(江苏)有限公司 Water replacement additive used in hydrocarbon cleaning agent, and preparation and use methods of same
CN110306197A (en) * 2019-07-26 2019-10-08 东莞市麦克莱恩新材料有限公司 A kind of rust-proof type agent for carbon hydrogen detergent and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104164311A (en) * 2014-08-20 2014-11-26 江阴市五洋化工有限公司 Method for preparing environment-friendly hydrocarbon cleaner
CN106367220A (en) * 2016-08-24 2017-02-01 诺而曼环保科技(江苏)有限公司 Water replacement additive used in hydrocarbon cleaning agent, and preparation and use methods of same
CN110306197A (en) * 2019-07-26 2019-10-08 东莞市麦克莱恩新材料有限公司 A kind of rust-proof type agent for carbon hydrogen detergent and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113652310A (en) * 2021-08-20 2021-11-16 常州智高化学科技有限公司 Multifunctional hydrocarbon detergent and production method thereof
CN114277382A (en) * 2021-12-29 2022-04-05 泰伦特生物工程股份有限公司 Water-cutting cleaning agent replacing rinsing and drying process and preparation method thereof

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