CN107057821A - A kind of hydraulic support oil emulsion and preparation method thereof - Google Patents

A kind of hydraulic support oil emulsion and preparation method thereof Download PDF

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Publication number
CN107057821A
CN107057821A CN201710370936.7A CN201710370936A CN107057821A CN 107057821 A CN107057821 A CN 107057821A CN 201710370936 A CN201710370936 A CN 201710370936A CN 107057821 A CN107057821 A CN 107057821A
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China
Prior art keywords
antirust
complexing agent
hydraulic support
water
oil emulsion
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CN201710370936.7A
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Inventor
杨侠
刘著著
刘高强
张霄
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Yulin Jinshiyuan Mining Oil Products Co Ltd
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Yulin Jinshiyuan Mining Oil Products Co Ltd
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Priority to CN201710370936.7A priority Critical patent/CN107057821A/en
Publication of CN107057821A publication Critical patent/CN107057821A/en
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M177/00—Special methods of preparation of lubricating compositions; Chemical modification by after-treatment of components or of the whole of a lubricating composition, not covered by other classes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08—Inorganic acids or salts thereof
    • C10M2201/082—Inorganic acids or salts thereof containing nitrogen
    • C10M2201/083—Inorganic acids or salts thereof containing nitrogen nitrites
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/087—Boron oxides, acids or salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/123—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms polycarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/141—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/10—Amides of carbonic or haloformic acids
    • C10M2215/102—Ureas; Semicarbazides; Allophanates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/12—Partial amides of polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/042—Sulfate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/02—Pour-point; Viscosity index
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/08—Resistance to extreme temperature
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/16—Antiseptic; (micro) biocidal or bactericidal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/18—Anti-foaming property

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention discloses a kind of hydraulic support environment protective emulsive oil and preparation method thereof, wherein each key component and the glycerine that weight/mass percentage composition is 5% ~ 10%, 4% ~ 6% antirust agent, 10% ~ 20% lubrication complexing agent, 5% ~ 10% emulsification complexing agent, 15% ~ 25% antirust, anti-corrosive water, and sodium hydroxide, EDTA 2Na, sodium citrate, antioxidant, bactericide, defoamer, pigment and water composition.The oily crude oil concentration of environment protective emulsive of the present invention is high, consumption is small, resistance to hard water is strong, applied widely, condensation point is low, and condensate oil, graining phenomenon are not produced in equipment operation, separated out in dispensing box without floating object, the greasy filth of non-cohesive difficult cleaning on column, such a concentrate itself is soluble in cold water, and with preferable cold water wash.

Description

A kind of hydraulic support oil emulsion and preparation method thereof
Technical field
The present invention relates to a kind of preparation method of the super oil emulsion of hydraulic support environmental protection.
Background technology
Hydraulic support is a kind of using fluid pressure generation support force and to realize automatic mobile device and carry out roof timbering It is the indispensable corollary equipment of comprehensive mechanical coal mining with a kind of hydraulic power unit of management.Hydraulic support oil emulsion It is hydraulic bracket system " blood ", the lifting of hydraulic support, mobile and overload protection etc. are required for using hydraulic support breast Carburetion.Hydraulic support oil emulsion driving medium is the important component of hydraulic system, and the Effec-tive Function of hydraulic test is not from Early sucking carburetion driving medium, it directly influences the service life and security of equipment.
According to coal industry standard MT76-2011《Hydraulic support（Post）With oil emulsion, concentrate and High water cut hydraulic fluid》 Classification, hydraulic support（Post）Include two classes, i.e. emulsifying with High water cut hydraulic fluid（HFAE）And concentrated type（HFAS）, it is corresponding Hydraulic fluid stoste is respectively hydraulic support oil emulsion and hydraulic support concentrate.
The oil emulsion that colliery is used at present is oily sintetics based on mineral oil, because the products material is mainly Non-renewable petroleum resources, price is influenceed very big by international petroleum product, and petroleum resources are fewer and fewer, price progressively on Rise, while also bringing problem of environmental pollution.With the continuous improvement of popular environmental consciousness, regulation constantly improve, especially to mine Bottom water pollution proposes higher requirement, therefore, and research and development Environment-friendlyhydraulic hydraulic support is significant with oil emulsion.
The content of the invention
Present invention aims at providing, a kind of synthesis technique is simple, performance indications are complete, Environment-friendlyhydraulic hydraulic support emulsification Oil and preparation method thereof.
Implementation process of the present invention is as follows：
A kind of hydraulic support oil emulsion, each component and weight/mass percentage composition are：
Glycerine 5% ~ 10%
Antirust agent 4% ~ 6%
Lubricate complexing agent 10% ~ 20%
Emulsify complexing agent 5% ~ 10%
Antirust, anti-corrosive water 15% ~ 25%
Sodium hydroxide 0.5% ~ 2%
EDTA-2Na 2% ~ 4%
Sodium citrate 3% ~ 5%
Antioxidant 1% ~ 3%
Bactericide 1% ~ 3%
Defoamer 0.05% ~ 0.2%
Pigment 0.01% ~ 0.05%
Water 20% ~ 40%
The antirust agent is the glycerine saturated solution of borax；
The lubrication complexing agent is triethanolamine, ricinoleic acid sulfuric ester sodium salt, modified phosphate and glycerine according to mass ratio 1 ~ 3：1 ~3：1~3：2 ~ 5 compound obtain；
The emulsification complexing agent is condensation compound of alkyl phenol and epoxy ethane, polyoxyethylene sorbitan fatty acid ester and fatty alcohol APEO is according to mass ratio 1 ~ 3：1~3：1 ~ 3 compound obtains.
Above-mentioned antirust, anti-corrosive water is that natrium nitrosum, sodium benzoate and urea quality ratio are 1 ~ 3：1~3：1 ~ 3 aqueous solution.
The preparation method of above-mentioned hydraulic support oil emulsion, be specifically by sodium hydroxide, EDTA-2Na, sodium citrate according to It is secondary to be added to the water, stir to transparent clear, then add antirust, anti-corrosive water thereto and stir to transparent clear, then sequentially add Antirust agent, lubrication complexing agent, glycerine, emulsification complexing agent, antioxidant, bactericide, defoamer and pigment, whole system temperature control System reconciles at 0 DEG C ~ 30 DEG C, until system is homogeneous, pH is 7.5~10.
The super oil emulsion of hydraulic support environmental protection of the present invention（Code name HFAE-JSY25-5）Outward appearance is yellow green clear oil Liquid, it is adaptable to the driving medium used in coal mine hydraulic supporting, must be in strict accordance with national MT76-2011 standards, i.e., when using By 95% running water（Or mine water）：5% this product oil emulsion part by weight is prepared, stirring can be used.Its crude oil concentration Height, consumption is small, and resistance to hard water is strong, and applied widely, condensation point is low, does not produce condensate oil, graining phenomenon in equipment operation, matches somebody with somebody Separated out in liquid case without floating object, the greasy filth of non-cohesive difficult cleaning on column, such a concentrate itself is soluble in cold water, and has Preferable cold water wash.Sediment is not produced in operation, and support can fall on bottom entirely, extend rubber seal service life, Without the system phenomenon of leakage during normal operation, no bacterium, fungi are grown, and rotten change is not produced, unusual odor is not produced.Cost is low, carries High coal mine production efficiency, effectively protection hydraulic support equipment normally runs, increased the service life.
Embodiment
Embodiment 1
A kind of hydraulic support oil emulsion, each component and weight/mass percentage composition are：Glycerine 6%, antirust agent 4% lubricates complexing agent 14%, complexing agent 8% is emulsified, antirust, anti-corrosive water 20%, sodium hydroxide 0.8%, EDTA-2Na 3%, sodium citrate 4% is anti-oxidant Agent 1%, bactericide 1%, defoamer 0.1%, pigment 0.01%, water polishing 100%.
Antirust agent is the glycerine saturated solution of borax, is specifically dissolved in borax in glycerine at 60 DEG C ~ 70 DEG C, obtains transparent clear Bright liquid.
Lubrication complexing agent is triethanolamine, ricinoleic acid sulfuric ester sodium salt, modified phosphate and glycerine according to mass ratio 1：2： 3：3 compound obtain；
Emulsification complexing agent is condensation compound of alkyl phenol and epoxy ethane, polyoxyethylene sorbitan fatty acid ester and fatty alcohol polyoxy Vinethene is according to mass ratio 1：1：1 compound obtains.
Antirust, anti-corrosive water is that natrium nitrosum, sodium benzoate and urea quality ratio are 1：1：1 20% aqueous solution.
Embodiment 2
A kind of hydraulic support oil emulsion, each component and weight/mass percentage composition are：Glycerine 7%, antirust agent 5% lubricates complexing agent 17%, emulsify complexing agent 8%, antirust, anti-corrosive water 21%, sodium hydroxide 1%, EDTA-2Na 3%, sodium citrate 4%, antioxidant 2%, bactericide 2%, defoamer 0.1%, pigment 0.02%, water polishing 100%.
Antirust agent is the glycerine saturated solution of borax, is specifically dissolved in borax in glycerine at 60 DEG C ~ 70 DEG C, obtains transparent clear Bright liquid.
Lubrication complexing agent is triethanolamine, ricinoleic acid sulfuric ester sodium salt, modified phosphate and glycerine according to mass ratio 1：1： 3：5 compound obtain；
Emulsification complexing agent is condensation compound of alkyl phenol and epoxy ethane, polyoxyethylene sorbitan fatty acid ester and fatty alcohol polyoxy Vinethene is according to mass ratio 2：1：1 compound obtains.
Antirust, anti-corrosive water is that natrium nitrosum, sodium benzoate and urea quality ratio are 1：2：3 20% aqueous solution.
Embodiment 3
A kind of hydraulic support oil emulsion, each component and weight/mass percentage composition are：Glycerine 10%, antirust agent 6% lubricates complexing agent 18%, complexing agent 10% is emulsified, antirust, anti-corrosive water 20%, sodium hydroxide 1%, EDTA-2Na 3%, sodium citrate 3% is anti-oxidant Agent 2%, bactericide 1%, defoamer 0.1%, pigment 0.02%, water polishing 100%.
Antirust agent is the glycerine saturated solution of borax, is specifically dissolved in borax in glycerine at 60 DEG C ~ 70 DEG C, obtains transparent clear Bright liquid.
Lubrication complexing agent is triethanolamine, ricinoleic acid sulfuric ester sodium salt, modified phosphate and glycerine according to mass ratio 1：2： 3：5 compound obtain；
Emulsification complexing agent is condensation compound of alkyl phenol and epoxy ethane, polyoxyethylene sorbitan fatty acid ester and fatty alcohol polyoxy Vinethene is according to mass ratio 1：1：1 compound obtains.
Antirust, anti-corrosive water is that natrium nitrosum, sodium benzoate and urea quality ratio are 2：1：1 aqueous solution.
Example 1-3 oil emulsions are tested as follows, are as a result seen attached list.
Test specimens 1：The super oil emulsion HFAE-JSY25-5 of this product hydraulic support of embodiment 1 environmental protection by weight than 3% adds Enter into 97% No. 25 hard water, stir and be made into liquid.
Test specimens 2：The super oil emulsion HFAE-JSY25-5 of this product hydraulic support of embodiment 2 environmental protection by weight than 4% adds Enter into 96% No. 25 hard water, stir and be made into liquid.
Test specimens 3：The super oil emulsion HFAE-JSY25-5 of this product hydraulic support of embodiment 3 environmental protection by weight than 5% adds Enter into 95% No. 25 hard water, stir and be made into liquid.
Test specimens 4：Normal hydraulic support of the weight than 3% is added to 97% No. 25 hard water with oil emulsion HFAE25-5 In, stir and be made into liquid.
Test specimens 5：Normal hydraulic support of the weight than 4% is added to 96% No. 25 hard water with oil emulsion HFAE25-5 In, stir and be made into liquid.
Test specimens 6：Normal hydraulic support of the weight than 5% is added to 95% No. 25 hard water with oil emulsion HFAE25-5 In, stir and be made into liquid.
Present invention emulsification complexing agent is selected from condensation compound of alkyl phenol and epoxy ethane, polyoxyethylene sorbitan fatty acid ester It is very important with AEO tri compound, when lacking condensation compound of alkyl phenol and epoxy ethane, with liquid Room temperature stability and heat endurance reach critical value, and liquid level precipitate volume content reaches 0.1%.
In the present invention lubricate complexing agent by triethanolamine, ricinoleic acid sulfuric ester sodium salt, modified phosphate and glycerine configure and Into modified phosphate is selected from the phosphates of Shanghai Dai Le trade Co., Ltds AL 200, adds after modified phosphate, hence it is evident that add Oil emulsion matches somebody with somebody the lubricity of liquid, can reach PBValue >=392N（40kgf）.
In subordinate list hydraulic support crude oil and with liquid contrast test it may be concluded that hydraulic support of the present invention is environmentally friendly Super oil emulsion is when matched proportion density is 3%-4%, and indices are qualified, and now widely used hydraulic support is emulsified Oil, when matched proportion density is 3%-4%, part index number is unqualified.When same matched proportion density is 5%, hydraulic support environmental protection of the present invention is super The part index number of energy oil emulsion is better than widely used hydraulic support oil emulsion.
Economy and effect on environment
The super oil emulsion HFAE-JSY25-5 of hydraulic support environmental protection of the present invention is free of mineral oil, and multiple additives are all by plant It is composited, both saves use cost, saving energy resource consumption is environmentally safe again, is a kind of environmentally friendly machine.

Claims (3)

1. a kind of hydraulic support oil emulsion, it is characterised in that comprising following component, each component and weight/mass percentage composition are：
Glycerine 5% ~ 10%
Antirust agent 4% ~ 6%
Lubricate complexing agent 10% ~ 20%
Emulsify complexing agent 5% ~ 10%
Antirust, anti-corrosive water 15% ~ 25%
Sodium hydroxide 0.5% ~ 2%
EDTA-2Na 2% ~ 4%
Sodium citrate 3% ~ 5%
Antioxidant 1% ~ 3%
Bactericide 1% ~ 3%
Defoamer 0.05% ~ 0.2%
Pigment 0.01% ~ 0.05%
Water 20% ~ 40%
The antirust agent is the glycerine saturated solution of borax；
The lubrication complexing agent is triethanolamine, ricinoleic acid sulfuric ester sodium salt, modified phosphate and glycerine according to mass ratio 1 ~ 3：1 ~3：1~3：2 ~ 5 compound obtain；
The emulsification complexing agent is condensation compound of alkyl phenol and epoxy ethane, polyoxyethylene sorbitan fatty acid ester and fatty alcohol APEO is according to mass ratio 1 ~ 3：1~3：1 ~ 3 compound obtains.
2. hydraulic support oil emulsion according to claim 1, it is characterised in that：The antirust, anti-corrosive water is nitrous acid Sodium, sodium benzoate and urea quality ratio are 1 ~ 3：1~3：1 ~ 3 aqueous solution.
3. the preparation method of the hydraulic support oil emulsion described in claim 1, it is characterised in that：By sodium hydroxide, EDTA- 2Na, sodium citrate are added sequentially in water, are stirred to transparent clear, then addition antirust, anti-corrosive water is stirred to transparent clear thereto It is bright, then sequentially add antirust agent, lubrication complexing agent, glycerine, emulsification complexing agent, antioxidant, bactericide, defoamer and color Element, whole system temperature control reconciles at 0 DEG C ~ 30 DEG C, until system is homogeneous, pH is 7.5~10.
CN201710370936.7A 2017-05-24 2017-05-24 A kind of hydraulic support oil emulsion and preparation method thereof Pending CN107057821A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110499146A (en) * 2019-09-02 2019-11-26 淄博爱科工矿机械有限公司 A kind of high-performance environmentally-friendly type hydraulic support anti-icing fluid and preparation method
CN111718784A (en) * 2020-07-25 2020-09-29 淮北金岭石化有限公司 Preparation process of emulsified oil complexing agent for hydraulic support
CN116574551A (en) * 2023-03-17 2023-08-11 榆林市金世源矿用油品有限公司 Concentrated hydraulic fluid and preparation method thereof
CN116590084A (en) * 2023-05-09 2023-08-15 福斯润滑油(中国)有限公司 Rapidly biodegradable emulsified oil for hydraulic support and preparation method thereof

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CN105623811A (en) * 2016-01-11 2016-06-01 广州科卢斯流体科技有限公司 Stainless steel calendaring plate dripping oil
CN105838494A (en) * 2016-04-29 2016-08-10 榆林市金世源矿用油品有限公司 Environment-friendly concentrated solution for hydraulic support and preparation method of environment-friendly concentrated solution
CN106381208A (en) * 2016-08-31 2017-02-08 湖南宏旺环保科技有限公司 Preparation method of concentrate for hydraulic support

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CN105623811A (en) * 2016-01-11 2016-06-01 广州科卢斯流体科技有限公司 Stainless steel calendaring plate dripping oil
CN105838494A (en) * 2016-04-29 2016-08-10 榆林市金世源矿用油品有限公司 Environment-friendly concentrated solution for hydraulic support and preparation method of environment-friendly concentrated solution
CN106381208A (en) * 2016-08-31 2017-02-08 湖南宏旺环保科技有限公司 Preparation method of concentrate for hydraulic support

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110499146A (en) * 2019-09-02 2019-11-26 淄博爱科工矿机械有限公司 A kind of high-performance environmentally-friendly type hydraulic support anti-icing fluid and preparation method
CN110499146B (en) * 2019-09-02 2021-05-11 淄博爱科工矿机械有限公司 High-performance environment-friendly anti-freezing solution for hydraulic support and preparation method thereof
CN111718784A (en) * 2020-07-25 2020-09-29 淮北金岭石化有限公司 Preparation process of emulsified oil complexing agent for hydraulic support
CN116574551A (en) * 2023-03-17 2023-08-11 榆林市金世源矿用油品有限公司 Concentrated hydraulic fluid and preparation method thereof
CN116590084A (en) * 2023-05-09 2023-08-15 福斯润滑油(中国)有限公司 Rapidly biodegradable emulsified oil for hydraulic support and preparation method thereof

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