CN105623811A - Stainless steel calendaring plate dripping oil - Google Patents
Stainless steel calendaring plate dripping oil Download PDFInfo
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- CN105623811A CN105623811A CN201610015545.9A CN201610015545A CN105623811A CN 105623811 A CN105623811 A CN 105623811A CN 201610015545 A CN201610015545 A CN 201610015545A CN 105623811 A CN105623811 A CN 105623811A
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- rustless steel
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- leaf fat
- oil
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
- C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
- C10M133/04—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M133/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
- C10M145/18—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M145/24—Polyethers
- C10M145/26—Polyoxyalkylenes
- C10M145/34—Polyoxyalkylenes of two or more specified different types
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M161/00—Lubricating compositions characterised by the additive being a mixture of a macromolecular compound and a non-macromolecular compound, each of these compounds being essential
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/22—Acids obtained from polymerised unsaturated acids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/286—Esters of polymerised unsaturated acids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
- C10M2207/401—Fatty vegetable or animal oils used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/01—Physico-chemical properties
- C10N2020/055—Particles related characteristics
- C10N2020/06—Particles of special shape or size
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/01—Physico-chemical properties
- C10N2020/081—Biodegradable compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/64—Environmental friendly compositions
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/247—Stainless steel
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The invention relates to the technical field of lubricating oil, in particular to stainless steel calendaring plate dripping oil, containing following components in percent by weight: 70-78percent of basic oil, 10-20 percent of lubricant, 0.1-0.6 percent of surfactant, 5-8 percent of emulsifier, and 0.1-16 percent of functional additive. The lubricating material is particularly suitable for a 850mm inclined eight roll reversible stainless steel calendaring unit with high lubricating requirement, and a unique self-emulsifying formula design realizes recycle use of the plate dripping oil and obviously improves a cooling recycle system integral environment; an excellent cleaning performance reduces or even solves the problem of residue of traditional plate dripping oil on a finished product plate and annealing oil spots, and a comprehensive plate quality of the finished product is greatly enhanced.
Description
Technical field
The present invention relates to lubricating oil field, drip leaf fat particularly to a kind of rustless steel calendering.
Background technology
Along with constantly advancing of modern society, the living standard of people especially material conditions there occurs earth-shaking change, stainless steel products is because of superperformances such as corrosion-resistant, high temperature resistance, high, the surface finenesses of intensity, being applied to the fields such as kitchen appliance, transportation, medical treatment, building industry more and more widely, stainless steel products becomes one of primary article indispensable in people's daily life already. China's rustless steel industry, than European and American developed countries, starts to walk all relative later with development; After reform and opening-up, along with the fast development of national economy, stainless steel products is just from the daily life of original defence and military industry entry ordinary people. Last century, the nineties started, and China's rustless steel industry presents the trend of fast development, and integrated demand is far above whole world average level.
According to statistics, within 2014, China's rustless steel crude steel yield increases by 14.27% to 2169.2 ten thousand ton on a year-on-year basis, accounts for whole world yield 50%. Huge market capacity and the actual demand quickly increased so that new stainless-steel cold-rolling enterprise constantly goes into operation, and large quantities of medium-sized and small enterprises are existed and develop. These corporate bosses are reversible based on 450mm tetra-roller, 750mm tetra-roller is reversible, 850 4 rollers or the reversible type of unit such as inclined eight rollers are reversible, 900mm tetra-roller is reversible, and rolled material is mainly based on 201,304; Wherein the inclined eight reversible unit speeds of roller of 850mm are fast, drafts big, and processing characteristics is excellent, but also that lubricating requirement is higher. The medium and small re-entrant trough profiled steel sheeting of domestic below 1000mm is widely present in the private enterprise that scale is relatively small, and its rapidoprint upstream source relative complex is with extensively, and quality is uneven, and overall processing difficulty is bigger. At present, the mode of domestic rustless steel calendering processing still commonly used dropping machinery oil or pure oil product carries out technological lubrication, machinery oil can not recycle and cleaning difference is easily attached on plate face, finished products detergency is poor, easily produce macula lutea, while causing that stainless steel enterprises product overall market competitiveness is on the low side, also create substantial amounts of waste oil, run in the opposite direction with the policy of national energy-saving environmental protection.
Along with the surplus of recent year stainless steel industry production capacity, exacerbating the competition between stainless steel enterprises, production board shape, surface quality are proposed increasingly higher requirement by market. Simultaneously, the constantly ripe of technology and development is rolled due to rustless steel, the importance of calendering lubriation material increasingly obtains the consistent accreditation of industry personnel, for farthest improving product quality, the strategy that the comprehensive market competitiveness of further enterprise and quickening Promoting Enterprise cleaning produce, mostly proposes new expectation to the lubriation material suitable in domestic rustless steel calendering technology.
Summary of the invention
The technical problem to be solved is to provide a kind of rustless steel calendering and drips leaf fat.
The technical problem to be solved is achieved by the following technical programs:
Leaf fat is dripped in a kind of rustless steel calendering, containing, for example the component of lower percentage by weight:
Base oil 70 ~ 78%, lubricant 10 ~ 20%, surfactant 0.1 ~ 0.6%, emulsifying agent 5 ~ 8%, function additive 0.1 ~ 16%, wherein said surfactant is the mixture of expoxy propane/ethylene oxide copolymer, dodecyldimethylammonium hydroxide inner salt and cationic surfactant.
Further, described cationic surfactant is at least one in Dodecyl trimethyl ammonium chloride and octadecyl trimethyl ammonium chloride. The present invention, in order to effectively control size, adopts special surface activator composition, and the synergism by 3 effectively controls particle size.
Further, described emulsifying agent is at least one in isopropanol, Macrogol 600 monoleate, sorbitan monooleate, Sucker plucker polyoxyethylene ether, sorbitan oleate polyoxyethylene ether, condensation compound of alkyl phenol and epoxy ethane, castor oil polyoxyethylene ester and castor oil polyoxyethylene ether.
Further, described base oil is at least one in Oleum Cocois, Petiolus Trachycarpi oil and Oleum Brassicae campestris.
Further, described lubricant is at least one in Adeps Sus domestica, 12/tetradecyl alchohol oleate, sulfuration triglyceride, sulfuration succinate, oleic acid diethyl alcohol ester, dimeric dibasic acid and dimeric dibasic acid glycol ester.
Further, described function additive is at least one in antirust agent, antiwear additive, antioxidant.
Further, described antirust agent is at least one in diakylaminomethylene benzotriazole, heterocycle sulfur-nitrogen compound, zinc naphthenate, oxidized petrolatum barium soap, SA sodium, alkenyl succinic acid half ester and fatty diglycollic amide.
Further, described antiwear additive is at least one in fatty alcohol modified phosphate ester, many alkyl benzyl sulfide, sulfide isobutene, dialkyl dithiophosphate and butyl triphenyl thiophosphate.
Further, described brightener is at least one in polyisobutylene, succinate, overbased calcium alkyl-salicylate and sulfur phosphorization polyisobutylene titanate salt.
Wherein, described antioxidant is that the antioxidant that the art is commonly used all can realize the present invention, at least one in SULFURIZED CALCIUM ALKYL PHENATE WITH HIGH BASE NUMBER, 2,6-di-tert-butyl-hydroxy phenyl propionic esters, octyl group substituted diphenylamine, thiocarbamic acid copper and butyl octyl diphenylamines.
Further, the calendering of described rustless steel drips leaf fat by the component of following percentage by weight:
Base oil 70 ~ 78%, lubricant 10 ~ 20%, expoxy propane/ethylene oxide copolymer 0.1%, dodecyldimethylammonium hydroxide inner salt 0.1%, cationic surfactant 0.1%, emulsifying agent 5 ~ 8%, antirust agent 0.5 ~ 2%, antiwear additive 3 ~ 10%, brightener 1 ~ 3%, antioxidant 0.1 ~ 0.5%
There is advantages that
The currently preferred optimized combination of each additive, the calendering obtained has the combination property of excellence with dripping leaf fat, inventive formulation system combines the process characteristic of the inclined eight reversible rustless steel re-entrant trough profiled steel sheeting of roller of 850mm, and adopts special surface activator composition to control size and technological lubrication for meeting multiple medium and small rustless steel re-entrant trough profiled steel sheeting requires emulsifying size controlling at 7.50 ~ 8.50 ��m. By preferred emulsifier, base oil, lubricant to set up suitable emulsifying and lubricating system, while reaching to ensure rustless steel calendering technology lubricating requirement, all adopt eco-friendly biodegradable vegetable base oil. The present invention is the logical composite use to additives such as antiwear additive, brightener and antioxidant also, while draught pressure when reducing rustless steel calendering pressure greatly, excellent cleaning performance minimizing even solves tradition and drips the leaf fat residual in production board face and Annealing oil stain problem, is greatly improved the comprehensive board surface quality of finished product.
Accompanying drawing explanation
Fig. 1 is the granularmetric analysis figure that leaf fat is dripped in the rustless steel calendering that embodiments of the invention 1 prepare.
Fig. 2 is the granularmetric analysis figure that leaf fat is dripped in the rustless steel calendering that embodiments of the invention 2 prepare.
Fig. 3 is the granularmetric analysis figure that leaf fat is dripped in the rustless steel calendering that embodiments of the invention 3 prepare.
Fig. 4 is the granularmetric analysis figure that leaf fat is dripped in the rustless steel calendering that embodiments of the invention 4 prepare.
Detailed description of the invention
The preparation method of the present invention is conventional configuration and hybrid technology, does not elaborate at this.
Below in conjunction with drawings and Examples, the present invention will be described in detail.
Embodiment 1:
Leaf fat is dripped in a kind of rustless steel calendering, raw material including following percentage by weight: Oleum Cocois 70%, zinc naphthenate 0.4%, SA sodium 0.2%, sulfuration triglyceride 19%, dimeric dibasic acid glycol ester 1%, fatty alcohol modified phosphate ester 1%, many alkyl benzyl sulfide 2%, Macrogol 600 monoleate 1.5%, Sucker plucker polyoxyethylene ether 2%, castor oil polyoxyethylene ether 1.3%, sulfenyl phenolate 0.2%, octyl group substituted diphenylamine 0.1%, succinate 1%, expoxy propane/ethylene oxide copolymer 0.1%, , dodecyldimethylammonium hydroxide inner salt 0.1%, octadecyl trimethyl ammonium chloride 0.1%.
Embodiment 2:
Leaf fat is dripped in a kind of rustless steel calendering, raw material including following percentage by weight: Petiolus Trachycarpi oil 71.3%, diakylaminomethylene benzotriazole 0.2%, oxidized petrolatum barium soap 0.3%, Adeps Sus domestica 9%, dimeric dibasic acid 1%, sulfide isobutene 6%, dialkyl dithiophosphate 2%, isopropanol 1.5%, sorbitan monooleate 4%, castor oil polyoxyethylene ester 2.8%, 2, 6-di-tert-butyl-hydroxy phenyl propionic ester 0.1%, overbased calcium alkyl-salicylate 1.5%, expoxy propane/ethylene oxide copolymer 0.1%, dodecyldimethylammonium hydroxide inner salt 0.1%, Dodecyl trimethyl ammonium chloride 0.1%.
Embodiment 3:
Leaf fat is dripped in a kind of rustless steel calendering, raw material including following percentage by weight: Oleum Brassicae campestris 70%, heterocycle sulfur-nitrogen compound 0.4%, fatty diglycollic amide 0.8%, 12/tetradecyl alchohol oleate 10%, many alkyl benzyl sulfide 5%, butyl triphenyl thiophosphate 5%, sorbitan oleate polyoxyethylene ether 1.5%, castor oil polyoxyethylene ether 3.5%, butyl octyl diphenylamines 0.3%, sulfenyl phenolate 0.2%, overbased calcium alkyl-salicylate 2%, polyisobutylene 1%, expoxy propane/ethylene oxide copolymer 0.1%, dodecyldimethylammonium hydroxide inner salt 0.1%, Dodecyl trimethyl ammonium chloride 0.1%.
Embodiment 4:
Leaf fat is dripped in a kind of rustless steel calendering, raw material including following percentage by weight: Oleum Brassicae campestris 38%, Petiolus Trachycarpi oil 40%, alkenyl succinic acid half ester 0.7%, fatty diglycollic amide 1.3%, oleic acid diethyl alcohol ester 9%, sulfuration triglyceride 1%, fatty alcohol modified phosphate ester 3%, condensation compound of alkyl phenol and epoxy ethane 1.5%, Macrogol 600 monoleate 1.5%, sorbitan oleate polyoxyethylene ether 2.5%, thiocarbamic acid copper 0.2%, sulfur phosphorization polyisobutylene titanate salt 1%, expoxy propane/ethylene oxide copolymer 0.1%, dodecyldimethylammonium hydroxide inner salt 0.1%, Dodecyl trimethyl ammonium chloride 0.1%.
Comparative example 1:
Leaf fat is dripped in a kind of rustless steel calendering, including the raw material of following percentage by weight: Oleum Cocois 70%, and zinc naphthenate 0.4%, SA sodium 0.2%, vulcanizes triglyceride 19%, dimeric dibasic acid glycol ester 1%, fatty alcohol modified phosphate ester 1%, many alkyl benzyl sulfide 2%, Macrogol 600 monoleate 1.5%, Sucker plucker polyoxyethylene ether 2%, castor oil polyoxyethylene ether 1.3%, sulfenyl phenolate 0.2%, octyl group substituted diphenylamine 0.1%, succinate 1%, octadecyl trimethyl ammonium chloride 0.3%.
Comparative example 2:
Leaf fat is dripped in a kind of rustless steel calendering, including the raw material of following percentage by weight: Oleum Cocois 70%, and zinc naphthenate 0.4%, SA sodium 0.2%, vulcanizes triglyceride 19%, dimeric dibasic acid glycol ester 1%, fatty alcohol modified phosphate ester 1%, many alkyl benzyl sulfide 2%, Macrogol 600 monoleate 1.5%, Sucker plucker polyoxyethylene ether 2%, castor oil polyoxyethylene ether 1.3%, sulfenyl phenolate 0.2%, octyl group substituted diphenylamine 0.1%, succinate 1%, market Common surface activating agent 0.3%.
Then rustless steel calendering droplet leaf fat deionized water embodiment prepared is diluted to the diluent that mass concentration is 3% and carries out droplet measurement. Wherein, the mean diameter of embodiment 1 is 8.131 ��m; Shown in particle size distribution Fig. 1; The mean diameter of embodiment 2 is 7.700 ��m; Shown in particle size distribution Fig. 2; The mean diameter of embodiment 3 is 7.935 ��m; Shown in particle size distribution Fig. 3; The mean diameter of embodiment 4 is 8.306 ��m; Shown in particle size distribution Fig. 4.
Then above-described embodiment, comparative example and market like product are carried out correlated performance test, specifically as shown in table 1.
Table 1 impact of performance table
Remarks:Maximum sting load P without clickB(representing lubricity) and sintering load PD(representing extreme pressure property) adopts country testing standard GB/T3142 to test, and emulsion particle diameter adopts Britain's Malvern laser particle analyzer (MS2000).
From the above, the performance detection of comparative example and market like product can be seen that, the rustless steel calendering of the present invention is dripped a leaf fat extreme pressure and antiwear behavior and is superior to comparative example and market like product, simultaneously average particle size distribution all 7.50 ~ 8.50 ��m and be evenly distributed, stable. Illustrate that the rustless steel calendering of the present invention is dripped leaf fat and had good extreme pressure and antiwear behavior and excellent greasy property, it is possible to meet the lubricating requirement of rustless steel calendering technology. The leaf fat self emulsifying speciality of dripping of the present invention makes it have better cleaning performance, will effectively reduce production board face residual, thus improving rustless steel bright annealing efficiency, improves plate face comprehensive quality.
Embodiment described above only have expressed embodiments of the present invention; it describes comparatively concrete and detailed; but therefore can not be interpreted as the restriction to the scope of the claims of the present invention; in every case the technical scheme adopting the form of equivalent replacement or equivalent transformation to obtain, all should drop within protection scope of the present invention.
Claims (10)
1. leaf fat is dripped in a rustless steel calendering, it is characterised in that containing, for example the component of lower percentage by weight:
Base oil 70 ~ 78%, lubricant 10 ~ 20%, surfactant 0.1 ~ 0.6%, emulsifying agent 5 ~ 8%, function additive 0.1 ~ 16%, wherein said surfactant is the mixture of expoxy propane/ethylene oxide copolymer, dodecyldimethylammonium hydroxide inner salt and cationic surfactant.
2. leaf fat is dripped in a kind of rustless steel calendering according to claim 1, it is characterised in that described cationic surfactant is at least one in Dodecyl trimethyl ammonium chloride and octadecyl trimethyl ammonium chloride.
3. leaf fat is dripped in a kind of rustless steel calendering according to claim 1, it is characterized in that, described emulsifying agent is at least one in isopropanol, Macrogol 600 monoleate, sorbitan monooleate, Sucker plucker polyoxyethylene ether, sorbitan oleate polyoxyethylene ether, condensation compound of alkyl phenol and epoxy ethane, castor oil polyoxyethylene ester and castor oil polyoxyethylene ether.
4. leaf fat is dripped in a kind of rustless steel calendering according to claim 1, it is characterised in that described base oil is at least one in Oleum Cocois, Petiolus Trachycarpi oil and Oleum Brassicae campestris.
5. leaf fat is dripped in a kind of rustless steel calendering according to claim 1, it is characterized in that, described lubricant is at least one in Adeps Sus domestica, 12/tetradecyl alchohol oleate, sulfuration triglyceride, sulfuration succinate, oleic acid diethyl alcohol ester, dimeric dibasic acid and dimeric dibasic acid glycol ester.
6. leaf fat is dripped in a kind of rustless steel calendering according to claim 1, it is characterised in that described function additive is at least one in antirust agent, antiwear additive, antioxidant.
7. leaf fat is dripped in a kind of rustless steel calendering according to claim 6, it is characterized in that, described antirust agent is at least one in diakylaminomethylene benzotriazole, heterocycle sulfur-nitrogen compound, zinc naphthenate, oxidized petrolatum barium soap, SA sodium, alkenyl succinic acid half ester and fatty diglycollic amide.
8. leaf fat is dripped in a kind of rustless steel calendering according to claim 6, it is characterized in that, described antiwear additive is at least one in fatty alcohol modified phosphate ester, many alkyl benzyl sulfide, sulfide isobutene, dialkyl dithiophosphate and butyl triphenyl thiophosphate.
9. leaf fat is dripped in a kind of rustless steel calendering according to claim 6, it is characterised in that described brightener is at least one in polyisobutylene, succinate, overbased calcium alkyl-salicylate and sulfur phosphorization polyisobutylene titanate salt.
10. leaf fat is dripped in a kind of rustless steel calendering according to claim 1 ~ 9 any one, it is characterised in that by the component of following percentage by weight:
Base oil 70 ~ 78%, lubricant 10 ~ 20%, expoxy propane/ethylene oxide copolymer 0.1%, dodecyldimethylammonium hydroxide inner salt 0.1%, cationic surfactant 0.1%, emulsifying agent 5 ~ 8%, antirust agent 0.5 ~ 2%, antiwear additive 3 ~ 10%, brightener 1 ~ 3%, antioxidant 0.1 ~ 0.5%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610015545.9A CN105623811B (en) | 2016-01-11 | 2016-01-11 | Stainless steel calendering dropping board oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610015545.9A CN105623811B (en) | 2016-01-11 | 2016-01-11 | Stainless steel calendering dropping board oil |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105623811A true CN105623811A (en) | 2016-06-01 |
| CN105623811B CN105623811B (en) | 2020-01-14 |
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| CN201610015545.9A Active CN105623811B (en) | 2016-01-11 | 2016-01-11 | Stainless steel calendering dropping board oil |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106987300A (en) * | 2017-04-17 | 2017-07-28 | 奎克化学（中国）有限公司 | It is a kind of non-maintaining to contain the metal rolled liquid of polymerizing cationically and preparation method |
| CN107057821A (en) * | 2017-05-24 | 2017-08-18 | 榆林市金世源矿用油品有限公司 | A kind of hydraulic support oil emulsion and preparation method thereof |
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| CN1594518A (en) * | 2004-07-06 | 2005-03-16 | 中国石油化工集团公司 | Lubricating oil composition and use thereof |
| US7435707B2 (en) * | 2002-05-23 | 2008-10-14 | The Lubrizol Corporation | Oil-in-water emulsions and a method of producing |
| CN103589491A (en) * | 2013-11-29 | 2014-02-19 | 广州机械科学研究院有限公司 | Lubricating material for cold rolling and its preparation method and use |
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| US7435707B2 (en) * | 2002-05-23 | 2008-10-14 | The Lubrizol Corporation | Oil-in-water emulsions and a method of producing |
| CN1594518A (en) * | 2004-07-06 | 2005-03-16 | 中国石油化工集团公司 | Lubricating oil composition and use thereof |
| CN103589491A (en) * | 2013-11-29 | 2014-02-19 | 广州机械科学研究院有限公司 | Lubricating material for cold rolling and its preparation method and use |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106987300A (en) * | 2017-04-17 | 2017-07-28 | 奎克化学（中国）有限公司 | It is a kind of non-maintaining to contain the metal rolled liquid of polymerizing cationically and preparation method |
| CN106987300B (en) * | 2017-04-17 | 2019-12-13 | 奎克化学（中国）有限公司 | Maintenance-free metal rolling liquid containing polymeric cations and preparation method thereof |
| CN107057821A (en) * | 2017-05-24 | 2017-08-18 | 榆林市金世源矿用油品有限公司 | A kind of hydraulic support oil emulsion and preparation method thereof |
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| CN105623811B (en) | 2020-01-14 |
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