CN1594518A - Lubricating oil composition and use thereof - Google Patents
Lubricating oil composition and use thereof Download PDFInfo
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- CN1594518A CN1594518A CN 200410010389 CN200410010389A CN1594518A CN 1594518 A CN1594518 A CN 1594518A CN 200410010389 CN200410010389 CN 200410010389 CN 200410010389 A CN200410010389 A CN 200410010389A CN 1594518 A CN1594518 A CN 1594518A
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Abstract
The invention discloses a lubricating oil composition and use thereof, wherein the lubricating oil composition comprises 40-80 wt% of mineral oil, 10-50 wt% of oily agent, 4-10 wt% of emulsifying agent, 1-5 wt% of inhibitor, 2-5 wt% of antiwearing agent, 0.1-1.0 wt% of solubility promoter, 0.1-2.0 wt% of anti-oxidizing agent, and 0-0.5 wt% of metallic deactivator.
Description
Technical field
The invention belongs to lubricant and Application Areas thereof, particularly a kind of lubricating oil composition and application thereof that is used for rolling copper and alloy thereof.
Background technology
The rolling of copper and alloy thereof carries out under two kinds of lubricating systems usually, a kind of is that full oil is rolling, the rolling general use light mineral oil of full oil adds additives such as a certain amount of oiliness improver, sanitas, oxidation inhibitor as lubricated and heat-eliminating medium, is usually used in the finish rolling of copper and alloy thereof; Another kind is that emulsion is rolling, because bigger deflection produces bigger distortion heat, need take away a large amount of heats as lubricated and heat-eliminating medium with emulsion in the work in-process operation of rolling, is beneficial to template control.Because copper is a kind of very active metal; very easily variable color behind the chance water; therefore except that requiring emulsion to have preferably the lubricity and cooling performance; also require emulsion to have splendid antiseptic power; in addition for saving cost and protection environment, also require emulsion to have that nontoxic odorless is difficult for characteristics such as putrid and deteriorated in long service life, the use.
The emulsification ROLLING OIL of traditional copper and alloy thereof is made base oil with mineral oil, add additives such as oiliness improver, emulsifying agent, extreme pressure anti-wear additives, sanitas, oxidation inhibitor, sterilant and form, during use according to the rolling emulsion that requires water to be made into 5～20 weight %.The oiliness improver that uses is mainly lipid acid, Fatty Alcohol(C12-C14 and C12-C18) and natural oil lipid at present, does not even add oiliness improver under the less demanding situation to oilness.Used emulsifying agent mainly is anionic emulsifier and nonionic emulsifier, and these emulsifying agents have negative impact to preventing the copper coin variable color, and emulsion is to the requirements in water quality height.China copper processing producer is numerous, but does not have suitable emulsion to use.That domestic present use is more is the porsol 67 of MOBIL company, but this kind lubricant is the hot rolling oil that is used for aluminium, be not to develop for rolling copper and alloy thereof, when therefore being used for rolling copper and alloy thereof, its anti-copper coin colour change function a little less than.The domestic homemade ROLLING OIL of rolling copper and alloy thereof that is used for is as 1
#Emulsion, antiseptic property is relatively poor, and the copper strip corrosion after rolling is comparatively serious.
Summary of the invention
The present invention is for the antiseptic property difference that solves the emulsification ROLLING OIL existence that is used for copper and alloy rolling thereof in the prior art and the defective a little less than preventing the copper discoloration ability, and provide a kind of rolling copper and alloy thereof lubricating oil composition, be used for the rolling of copper and alloy sheets thereof, band, tubing and bar, said composition has good rolling lubrication, cooling property, antiseptic property, has the copper discoloration of preventing ability.The present invention also provides said composition to be used for the application method of copper when rolling.
Lubricating oil composition of the present invention contains following component:
(a) mineral oil of 40.0～80.0 weight %;
(b) oiliness improver of 10.0～50.0 weight %;
(c) emulsifying agent of 4.0～10.0 weight %;
(d) 1.0～5.0 weight % prevent the inhibiter of copper discoloration;
(e) extreme pressure anti-wear additives of 1.0～6.0 weight %;
(f) solubility promoter of 0.1～1.0 weight %;
(g) 0.1～2.0 weight % oxidation inhibitor;
(h) metal passivator of 0～0.5 weight %.
Component (a) is that 40 ℃ of following kinematic viscosity are 30～80mm
2The paraffin base mineral oil of/s.Preferred 55.0～70.0 weight % of the add-on of this component.
Component (b) is a kind of or more than one a mixture in Fatty Alcohol(C12-C14 and C12-C18) and the fatty acid ester, and wherein Fatty Alcohol(C12-C14 and C12-C18) is C
1～C
30Be preferably C
12-C
18Fatty Alcohol(C12-C14 and C12-C18), as decyl alcohol, lauryl alcohol, tetradecyl alcohol, hexadecanol, oleyl alcohol, stearyl alcohol, eicosanol or triacontanol etc.; Fatty acid ester is a natural animal-plant grease or by C
1～C
30Fatty Alcohol(C12-C14 and C12-C18) and C
1～C
54Be preferably C
8～C
36Lipid acid synthetic ester, natural animal-plant grease such as butter, soya-bean oil or peanut wet goods, fatty acid ester recommends to use oleic pentaerythritol ester, oleic trihydroxymethylpropanyl ester, the pentaerythritol ester of coco-nut oil fatty acid or the trihydroxymethylpropanyl ester of palm oil fatty acid etc., synthesis condition and method adopt known technology, and (meticulous organic chemical industry prepares handbook, scientific and technical literature press, Beijing in 1994, P
483-487).Preferred 15.0～30.0 weight % of the content of component (b) in composition.
Component (c) can be the combination that is selected from least two kinds of single agent in anion surfactant, cats product and the nonionogenic tenside.Anion surfactant comprises: soap, sulfonated petro-leum or phosphates; Cats product comprises: amine salt type or quaternary amine type, wherein amine salt type such as Marlamid, fatty acid chain alkanolamine ester or fatty amide etc.; Nonionogenic tenside can be the polyvalent alcohol type, as sorbitan fatty(acid)ester or sorbitan fatty(acid)ester Soxylat A 25-7 etc.Preferred 6.0～8.0 weight % of the add-on of component (c).
Component (d) is the inhibiter that prevents copper discoloration, can be T703 (17 alkenyl imidazoline succinate), T704 (zinc naphthenate), T705 (dinonyl naphthalene barium mahogany sulfonate), T706 (benzotriazole), T708 (alkyl phosphate imidazoline salt), methyl benzotriazazole, N, the mixture of one or more in the derivative of two (benzotriazole methylene radical) lauryl amines of N-, 2-mercaptobenzothiazole, N-oleoyl sarcosine stearylamine salt, benzotriazole soap, benzotriazole and the sorbitan fatty(acid)ester etc.The add-on of component (d) is preferably 2.0～4.0 weight %.
Component (e) is C
4～C
12Fatty Alcohol(C12-C14 and C12-C18), carbonatoms is 1～12 alkylphenol in the alkyl, carbonatoms is 1～12 the alkylphenol polyoxyethylene or the phosphoric acid ester of fatty alcohol-polyoxyethylene ether in the alkyl, phosphorous acid ester or acid phosphate amine salt, or its mixture, tributyl phosphate preferably, Tritolyl Phosphate, the di (isooctyl) phosphate triethanolamine salt, 17 alkenyl imidazoline di (isooctyl) phosphate salt, di-n-butyl phosphite, the mixture of one or more in alkylphenol polyoxyethylene phosphate amine salt and the aliphatic alcohol polyoxyvinethene phosphate amine salt, the carbonatoms of Fatty Alcohol(C12-C14 and C12-C18) is 8～18 in the wherein said fatty alcohol-polyoxyethylene ether, preferred 2.0～4.0 weight % of the add-on of component (e).
Component (f) is a kind of solubility promoter, selects C for use
1～C
10Fatty Alcohol(C12-C14 and C12-C18), preferred C
4～C
8Fatty Alcohol(C12-C14 and C12-C18), preferred 0.3～0.8 weight % of add-on.
Component (g) is an oxidation inhibitor, be selected from shield phenol type and the arylamine type antioxidant one or more, as: home-made T501 (2, the 6-ditertbutylparacresol), T502 (2, mixed phenols such as 6-di-tert-butylphenol), T511 (4,4 '-methylene radical-2,6-di-tert-butylphenol), T521 (2,6-di-t-butyl α dimethylamino p-cresol) and T531 (phenyl αNai An) etc.
Component (h) is a metal passivator, is selected from the nitrogen-containing heterocycle compound based metal deactivators one or more, as: T551 (124 Triazole-aldehyde-amine condenses) and T561 (2,5-dialkyl group curing-thiadiazoles) etc.
Except that above component, also can in above-mentioned composition, add other additive of 0～2.0 weight %, as sterilant or defoamer etc. as required.The available sterilant has phenols sterilant, formaldehyde to discharge series bactericidal agent etc., as six hydrogen-1,3, and 5-three (2-hydroxyethyl)-(all) triazine etc.; The available defoamer has polyethers and silicone based defoamer.But the most effective method for disinfection is to add sterilant in emulsion, and the most effective debubbling method is to add defoamer in emulsion.
The preparation method of lubricating oil composition of the present invention is as follows:
With oiliness improver, emulsifying agent, prevent that the inhibiter of copper discoloration from joining in the blending kettle, be heated to 45～55 ℃, constant temperature stirred 30～50 minutes, after stirring other additives such as mineral oil, extreme pressure anti-wear additives, oxidation inhibitor are joined in the blending kettle, be heated to 55～65 ℃, insulated and stirred 40～50 minutes stirs after check discharging.
Lubricating oil composition of the present invention is used in rolling copper and alloy sheet strip, tubing and bar, and its using method is as follows:
The present composition is made into oil-in-water emulsion with softening water in use and uses, and the preferred deionized water of softening water is heated to 35～40 ℃ with softening water, under agitation adds the emulsion that a certain amount of present composition is made into desired concn.The concentration of emulsion is generally 1～15 weight %, preferred 2～10 weight %, and working concentration can be regulated according to the particular case of every milling train, and the use temperature of emulsion is usually at 30～60 ℃.
The present composition has good rolling lubrication, cooling property, antiseptic property, particularly has the copper discoloration of preventing ability.Its component (a) is a paraffin base mineral oil, has oxidation stability and oilness preferably, can guarantee to roll the clean annealing of back copper coin.The effect of each component is not single in the said composition in addition, as when selecting for use sorbitan fatty(acid)ester, fatty acid chain alkanolamine salt, Marlamid or fatty acid chain alkanolamine ester to be emulsifying agent, it also is an inhibiter simultaneously; Select the alkylphenol polyoxyethylene phosphate amine salt for use, when the aliphatic alcohol polyoxyvinethene phosphate amine salt is extreme pressure anti-wear additives, it also is emulsifying agent and inhibiter simultaneously.Therefore use rolling copper of the present composition and alloy thereof can obtain the good product of surface quality.
Embodiment
Describe the present invention in detail with specific embodiment below, but do not limit the scope of the invention.
Embodiment 1
With TriMethylolPropane(TMP) coco-nut oil fatty acid ester 19.0kg, lauryl alcohol 2.0kg, triethanol amine oleate 4.0kg, triethanolamine oleate ester 2.0kg, Si Ben-80 2.0kg, benzotriazole 0.6kg, N, two (benzotriazole methylene radical) the lauryl amine 1.0kg of N-, propyl carbinol 0.6kg joins in the blending kettle, is heated to 50 ℃, constant temperature stirred 30 minutes, after stirring with mineral oil (46mm
2S
-1/ 40 ℃) 65.9kg, tritolyl phosphate 2.0kg, 2,6-ditertbutylparacresol 0.5kg, T531 (phenyl αNai An) 0.3kg, T551 (124 Triazole-aldehyde-amine condenses) 0.1kg joins in the blending kettle, is heated to 55 ℃, insulated and stirred 40 minutes, the stir emulsified state of back inspection group compound reaches discharging after the requirement.
Embodiment 2
With PETO 15.0kg, triethanol amine oleate 4.0kg, triethanolamine oleate ester 2.0kg, cocoanut fatty acid diethanolamide 2.0kg, benzotriazole 0.6kg, benzotriazole soap 1.0kg, n-hexyl alcohol 0.6kg joins in the blending kettle, is heated to 55 ℃, insulated and stirred 25 minutes, after stirring with mineral oil (46mm
2S
-1/ 40 ℃) 70.9kg, di (isooctyl) phosphate 3.0kg, 2,6-ditertbutylparacresol 0.5kg, T531 (phenyl αNai An) 0.3kg, T551 (124 Triazole-aldehyde-amine condenses) 0.1kg joins in the blending kettle, be heated to 60 ℃, insulated and stirred 40 minutes stirs after check discharging.
Embodiment 3
With tricarboxymethyl propane oleate 18.0kg, the alcohol mixture 2.0kg of lauryl alcohol and tetradecyl alcohol, triethanol amine oleate 3.0kg, fatty acid amide 4.0kg, benzotriazole 0.6kg, benzotriazole soap 1.0kg, propyl carbinol 0.4kg joins in the blending kettle, is heated to 55 ℃, insulated and stirred 30 minutes, after stirring with mineral oil (46mm
2S
-1/ 40 ℃) 67.5kg, di (isooctyl) phosphate triethanolamine salt 3.0kg, 2,6 ditertiary butyl p cresol 0.5kg joins in the blending kettle, is heated to 55 ℃, insulated and stirred 40 minutes, the emulsified state of the back inspection group compound that stirs reaches discharging after the requirement.
Embodiment 4
With tetramethylolmethane coco-nut oil fatty acid ester 20.0kg, triethanolamine oleate ester 3.0kg, fatty acid amide 5.0kg, 17 alkenyl imidazoline succinate 2.0kg, benzotriazole 0.6kg, N, two (benzotriazole methylene radical) the lauryl amine 1.0kg of N-, propyl carbinol 0.4kg, join in the blending kettle, be heated to 55 ℃, insulated and stirred 30 minutes, after stirring with mineral oil (46mm
2S
-1/ 40 ℃) 64.4kg, Nonyl pheno (4) ether phosphate triethanolamine salt 3.0kg, 2,6 ditertiary butyl p cresol 0.6kg, join in the blending kettle, be heated to 55 ℃, insulated and stirred 40 minutes, the stir emulsified state of back inspection group compound reaches discharging after the requirement.
Embodiment 5
With PETO 19.0kg, triethanol amine oleate 3.0kg, fatty acid amide 4.0kg, T708 2.0kg, benzotriazole 0.6kg, benzotriazole soap 1.0kg, n-hexyl alcohol 0.4kg joins in the blending kettle, is heated to 55 ℃, insulated and stirred 30 minutes, after stirring with mineral oil (46mm
2S
-1/ 40 ℃) 66.2kg, tritolyl phosphate 3.0kg, 2,6 ditertiary butyl p cresol 0.8kg joins in the blending kettle, is heated to 55 ℃, insulated and stirred 40 minutes, the emulsified state of the back inspection group compound that stirs reaches discharging after the requirement.
Embodiment 6
With PETO 15.0kg, neopentyl glycol oleic acid ester 12kg, the alcohol mixture 2.0kg of lauryl alcohol and tetradecyl alcohol, triethanol amine oleate 3.0kg, triethanolamine oleate ester 2.0kg, fatty acid amide 3.0kg, benzotriazole 0.6kg, N, two (benzotriazole methylene radical) the lauryl amine 1.0kg of N-, n-Octanol 0.5kg, join in the blending kettle, be heated to 55 ℃, insulated and stirred 30 minutes, after stirring with mineral oil (46mm
2S
-1/ 40 ℃) 57.1kg, phosphoric acid lauryl alcohol dibasic acid esters 3.0kg, 2,6 ditertiary butyl p cresol 0.8kg joins in the blending kettle, is heated to 55 ℃, insulated and stirred 40 minutes, the emulsified state of the back inspection group compound that stirs reaches discharging after the requirement.
Embodiment 7
With PETO 15.0kg, butyl stearate 12kg, the alcohol mixture 2.0kg of lauryl alcohol and tetradecyl alcohol, triethanol amine oleate 3.0kg, triethanolamine oleate ester 2.0kg, fatty acid amide 3.0kg, benzotriazole 0.6kg, benzotriazole soap 1.0kg, n-Octanol 0.5kg joins in the blending kettle, is heated to 55 ℃, insulated and stirred 30 minutes, after stirring with mineral oil (46mm
2S
-1/ 40 ℃) 57.1kg, tritolyl phosphate 3.0kg, 2,6-ditertbutylparacresol 0.5kg, T531 (phenyl αNai An) 0.3kg joins in the blending kettle, is heated to 55 ℃, insulated and stirred 40 minutes, the emulsified state of the back inspection group compound that stirs reaches discharging after the requirement.
Embodiment 8
With PETO 23.0kg, triethanol amine oleate 3.0kg, triethanolamine oleate ester 2.0kg, fatty acid amide 3.0kg, benzotriazole 0.6kg, N, two (benzotriazole methylene radical) the lauryl amine 1kg of N-, propyl carbinol 0.5kg, join in the blending kettle, be heated to 55 ℃, insulated and stirred 30 minutes, after stirring with mineral oil (46mm
2S
-1/ 40 ℃) 63.1kg, tritolyl phosphate 3.0kg, 2,6 ditertiary butyl p cresol 0.5kg, T531 (phenyl αNai An) 0.3kg joins in the blending kettle, is heated to 55 ℃, insulated and stirred 40 minutes, the emulsified state of the back inspection group compound that stirs reaches discharging after the requirement.
Embodiment 9
With butyl stearate 10.0kg, tetramethylolmethane coco-nut oil fatty acid ester 10.0kg, the alcohol mixture 2.0kg of lauryl alcohol and tetradecyl alcohol, triethanol amine oleate 3.0kg, triethanolamine oleate ester 2.0kg, fatty acid amide 4.0kg, benzotriazole 0.6kg, N, two (benzotriazole methylene radical) the lauryl amine 1.0kg of N-, propyl carbinol 0.6kg, join in the blending kettle, be heated to 55 ℃, insulated and stirred 30 minutes, after stirring with mineral oil (68mm
2S
-1/ 40 ℃) 63.3kg, phosphoric acid lauryl alcohol dibasic acid esters diethanolamine salt 3.0kg, 2,6 ditertiary butyl p cresol 0.5kg joins in the blending kettle, is heated to 55 ℃, insulated and stirred 40 minutes, the emulsified state of the back inspection group compound that stirs reaches discharging after the requirement.
Embodiment 10
With neopentyl glycol oleic acid ester 20.0kg, triethanol amine oleate 3.0kg, fatty acid amide 4.0kg, N-oleoyl sarcosine stearylamine salt 2.0kg, benzotriazole 0.6kg, benzotriazole soap 1.0kg, propyl carbinol 0.6kg joins in the blending kettle, is heated to 55 ℃, insulated and stirred 30 minutes, after stirring with mineral oil (46mm
2S
-1/ 40 ℃) 66.3kg, tritolyl phosphate 2.0kg, 2,6-ditertbutylparacresol 0.5 kg, six hydrogen-1,3,5-three (2-hydroxyethyl)-(all) triazine 0.05kg, methyl-silicone oil 0.03kg joins in the blending kettle, is heated to 55 ℃, insulated and stirred 40 minutes, the stir emulsified state of back inspection group compound reaches discharging after the requirement.
The physical and chemical index of embodiment 1-10 is as shown in table 1.
The physical and chemical index of table 1 embodiment 1-10
| 40 ℃ of kinematic viscosity mm 2·s -1 | 50 ℃ of 3h of copper corrosion | The lamination test grade | Oil film strength N | Frictional coefficient | |
| Embodiment 1 | ??46.3 | ??1a | ??1 | ????647 | ????0.068 |
| Embodiment 2 | ??66.5 | ??1a | ??1 | ????647 | ????0.068 |
| Embodiment 3 | ??61.6 | ??1a | ??1 | ????647 | ????0.068 |
| Embodiment 4 | ??71.6 | ??1a | ??1 | ????696 | ????0.067 |
| Embodiment 5 | ??63.1 | ??1a | ??1 | ????696 | ????0.067 |
| Embodiment 6 | ??47.3 | ??1a | ??1 | ????696 | ????0.067 |
| Embodiment 7 | ??42.1 | ??1a | ??1 | ????696 | ????0.065 |
| Embodiment 8 | ??57.9 | ??1a | ??1 | ????745 | ????0.068 |
| Embodiment 9 | ??51.0 | ??1a | ??1 | ????746 | ????0.066 |
| Embodiment 10 | ??50.4 | ??1a | ??1 | ????696 | ????0.067 |
| Porsol?67 | ??52.13 | ??1a | ??2 | ????470 | ????0.079 |
| The method of inspection | ??GB/T265 | ??GB/T5096 | As follows | ????GB/T3142-82 | ????SH/T0190-92 |
Lamination test method: the emulsion that testing combination is mixed with 5 weight % with distilled water.With the 180# sand papering of 30 * 30mm latten(-tin), after sherwood oil, dehydrated alcohol clean, a slice is kept flat, evenly drip 1ml 5 weight % emulsion to be measured, another sheet is stacked on it, placed 50 ℃ of climatic chambers 24 hours.Take out the back and dip in the sherwood oil wiped clean, observe copper sheet surface corrosion situation with absorbent cotton.For ease of quantification, regulation: surface-brightening is 0 grade as before, and it is 1 grade that slight evidence of corrosion is arranged, and evidence of corrosion is evident as 2 grades, and surperficial serious discoloration is more than 3 grades.
The porsol 67 and 1 of embodiment 1 and embodiment 2 and MOBIL company in the industrial application of reality
#Emulsion is compared good lubricating property and cooling performance and the excellent anti-copper discoloration ability of showing, smooth operation in the embodiment 1 and embodiment 2 operations of rolling, plate shape is easy to control, roll that back plate shape is good, surface-brightening, residue be few, roll the back band and place the long period nondiscoloration, clean up the annealing light in the postprocessing working procedures.
Claims (9)
1. lubricating oil composition, it is characterized in that: said composition contains following component:
(a) mineral oil of 40.0～80.0 weight %;
(b) oiliness improver of 10.0～50.0 weight %;
(c) emulsifying agent of 4.0～10.0 weight %;
(d) 1.0～5.0 weight % prevent the inhibiter of copper discoloration;
(e) extreme pressure anti-wear additives of 1.0～6.0 weight %;
(f) solubility promoter of 0.1～1.0 weight %;
(g) 0.1～2.0 weight % oxidation inhibitor;
(h) metal passivator of 0～0.5 weight %;
Described component (a) is that 40 ℃ of following kinematic viscosity are 30～80mm
2The paraffin base mineral oil of/s;
Component (b) is a kind of or more than one a mixture in Fatty Alcohol(C12-C14 and C12-C18) and the fatty acid ester, and wherein Fatty Alcohol(C12-C14 and C12-C18) is C
1～C
30Fatty Alcohol(C12-C14 and C12-C18), fatty acid ester is a natural animal-plant grease or by C
1～C
30Fatty Alcohol(C12-C14 and C12-C18) and C
1～C
54Lipid acid synthetic ester;
Component (c) is the combination of at least two kinds of single agent in anion surfactant, cats product and the nonionogenic tenside;
Component (e) is C
4～C
12Fatty Alcohol(C12-C14 and C12-C18), alkyl in carbonatoms be that carbonatoms is 1～12 the alkylphenol polyoxyethylene or phosphoric acid ester, phosphorous acid ester or the acid phosphate amine salt of fatty alcohol-polyoxyethylene ether in 1～12 alkylphenol, the alkyl, or its mixture, wherein the carbonatoms of Fatty Alcohol(C12-C14 and C12-C18) is 8～18 in the fatty alcohol-polyoxyethylene ether;
Component (f) is C
1～C
10Fatty Alcohol(C12-C14 and C12-C18);
Component (g) is one or more in shield phenol type and the arylamine type antioxidant;
Component (h) is one or more in the nitrogen-containing heterocycle compound based metal deactivators.
2. lubricating oil composition according to claim 1, it is characterized in that: component (a) content in composition is 55.0～70.0 weight %, component (b) content in composition is 15.0～30.0 weight %, component (c) content in composition is 6.0～8.0 weight %, component (d) content in composition is 2.0～4.0 weight %, component (e) content in composition is 2.0～4.0 weight %, and component (f) content in composition is 0.3～0.8 weight %.
3. lubricating oil composition according to claim 1 is characterized in that: the Fatty Alcohol(C12-C14 and C12-C18) in the described component (b) is decyl alcohol, lauryl alcohol, tetradecyl alcohol, hexadecanol, oleyl alcohol, stearyl alcohol, eicosanol or triacontanol; Anion surfactant in the component (c) is soap, sulfonated petro-leum or phosphates, and cats product is amine salt type or quaternary amine type, and nonionogenic tenside is the polyvalent alcohol type.
4. lubricating oil composition according to claim 1 is characterized in that: the fatty acid ester in the described component (b) is the pentaerythritol ester of oleic pentaerythritol ester, oleic trihydroxymethylpropanyl ester, coco-nut oil fatty acid or the trihydroxymethylpropanyl ester of palm oil fatty acid.
5. lubricating oil composition according to claim 3 is characterized in that: the amine salt type in the described cats product is Marlamid, fatty acid chain alkanolamine ester or fatty amide; Nonionogenic tenside is sorbitan fatty(acid)ester or sorbitan fatty(acid)ester Soxylat A 25-7.
6. lubricating oil composition according to claim 1, it is characterized in that: component (d) is T703, T704, T705, T706, T708, methyl benzotriazazole, N, the derivative of two (benzotriazole methylene radical) lauryl amines of N-, 2-mercaptobenzothiazole, N-oleoyl sarcosine stearylamine salt, benzotriazole soap, benzotriazole and one or more the mixture in the sorbitan fatty(acid)ester.
7. lubricating oil composition according to claim 1 is characterized in that: component (e) is one or more a mixture in tributyl phosphate, Tritolyl Phosphate, di (isooctyl) phosphate triethanolamine salt, 17 alkenyl imidazoline di (isooctyl) phosphate salt, di-n-butyl phosphite, alkylphenol polyoxyethylene phosphate amine salt and the aliphatic alcohol polyoxyvinethene phosphate amine salt; Component (g) is one or more a mixture among T501, T502, T511, T521 and the T531; Component (h) is one or more a mixture among T551 and the T561.
8. lubricating oil composition according to claim 1 is characterized in that: the sterilant or the defoamer that also contain 0～2.0 weight % in the said composition.
9. the application of the described lubricating oil composition of claim 1, said composition can be used for the rolling of copper and alloy sheets, band, tubing and bar, it is characterized in that: softening water is heated to 35～40 ℃, under agitation add a certain amount of said composition and be made into the emulsion that concentration is 1～15 weight %, be 30～60 ℃ in temperature and use down.
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| CNB2004100103894A CN1309812C (en) | 2004-07-06 | 2004-07-06 | Lubricating oil composition and use thereof |
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|---|---|---|---|
| CNB2004100103894A CN1309812C (en) | 2004-07-06 | 2004-07-06 | Lubricating oil composition and use thereof |
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| CN1309812C CN1309812C (en) | 2007-04-11 |
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| CN101307270B (en) * | 2008-07-04 | 2011-02-16 | 北京科技大学 | Cold rolling emulsified oil for copper and copper alloy and method for manufacturing same |
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Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ZA934846B (en) * | 1992-07-08 | 1994-02-03 | Henkel Corp | Aqueous lubrication and surface conditioning for formed metal surfaces |
| US5583100A (en) * | 1993-10-08 | 1996-12-10 | Kabushiki Kaisha Kobe Seiko Sho | Oil compositions for hot rolling aluminum and aluminum alloys |
| JPH08243605A (en) * | 1995-03-14 | 1996-09-24 | Nisshin Steel Co Ltd | Method and device for cold rolling and rolling agent |
| CN1173021C (en) * | 2001-08-24 | 2004-10-27 | 中国石油天然气股份有限公司 | Rolling oil composition for cold-rolled steel sheet |
-
2004
- 2004-07-06 CN CNB2004100103894A patent/CN1309812C/en not_active Expired - Fee Related
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