A kind of drilling fluid temperature resistance Wear-resistant drag reducer
Technical field
The invention belongs to petroleum drilling technology fields, more specifically, it relates to a kind of wear-resistant drag reduction of drilling fluid temperature resistance
Agent.
Background technique
Currently, the complex situations faced in drilling engineering become increasingly conspicuous as petroleum exploration and development continues to develop, orientation
The highly difficult well such as well, horizontal well, extended reach well constantly increases in drilling well ratio.In drilling process, due to drilling tool and casing
Caused energy loss and drilling speed loss cause a large amount of economic loss.In order to reduce the friction of drilling tool and casing, need
A certain amount of antiwear additive is added in drilling fluid to reduce drilling rod torque.Further, when drilling arrives layer deeper, face is needed
Challenge to the complex geological conditions such as high temperature, with high salt, high density solid phase, this is also just to the temperature resistance of the antiwear additive in drilling fluid
More stringent requirements are proposed for performance.
Currently, the technical solution for having some high temperature resistant lubricants or antiwear additive discloses.As patent publication No. is
A kind of high temperature resistant drilling fluids lubricant is disclosed in the patent of invention of CN102863946A, using the benzene second for containing wear-resistant elementary sulfur
Alkene thiocarbamide or phosphorous 1-isobutyl-3,5-dimethylhexylphosphoric acid sodium salt are as antiwear additive;CN 109439294A discloses a kind of high density brill
Well liquid heat and salinity tolerance extreme-pressure lubricant, using EP agent sulfide aliphatic acid methyl esters, vulcanization triglyceride, olefine sulfide
Or organic-molybdenum is as antiwear additive, using di-2-ethylhexylphosphine oxide Keywords dibutyl dithiocarbamate or antimony dialkyl-dithiocarbamate
One or both of mixture as surface modifier;CN108690576A discloses a kind of drilling fluid lubrication resistant to high temperatures
Agent and preparation method thereof, using silane coupling agent to the production after zinc dialkyl dithiophosphate and nitridation boron modification, mixed calcining
Object is as antiwear additive;CN101157850A discloses a kind of preparation of high temperature resistant lubricant for drilling liquid by animal plant oil, using ester
Waste grease is as antiwear additive after changing, vulcanizing;CN104893688A discloses a kind of lubricant for drilling fluids resistant to high temperatures, mainly
Using synthetic Lubricating grease as lubricating additive, but added without antiwear additive.
Technology disclosed above mostly uses the substance of sulfur-bearing as antiwear additive, under the effect of high temperature extreme pressure, sulphur and metal
It chemically reacts, generates metal sulfide protective film to reduce frictional resistance and play lubricating action;But then, it passes through
Many experiments and application discovery are crossed, in circulation of drilling fluid use process, sulfur-bearing antifriction lubricant can generate under high temperature action
Hydrogen sulfide, causing corrosion to drilling rod, casing, there are major safety risks;Circulating fluid can also have the effluvium of hydrogen sulfide
Taste brings strong influence to the personal safety of wellbore construction personnel.
Summary of the invention
In view of the deficiencies of the prior art, the present invention intends to provide a kind of wear-resistant drag reduction of drilling fluid temperature resistance
Agent has the advantages that safety and environmental protection by using inorganic nano metallic compound as antiwear additive.
To achieve the above object, the present invention provides the following technical scheme that a kind of drilling fluid temperature resistance Wear-resistant drag reducer,
By include following parts by weight raw material be made: 5~50 parts of base oil, 1~5 part of surfactant, 20~70 parts of antiwear additive,
0.5~3 part of dispersion stabilizer, 2~10 parts of preservatives with high temperature tolerance, the antiwear additive are inorganic nano metallic compound.
By using above-mentioned technical proposal, since the antiwear additive in drilling fluid temperature resistance Wear-resistant drag reducer is inorganic receives
Rice metallic compound will not generate while torque caused by drilling rod and sleeve friction increases in drilling process is effectively reduced
Harmful substance, safety and environmental protection.
Preferably, the parts by weight of drilling fluid temperature resistance Wear-resistant drag reducer raw material are as follows: 15~35 parts of base oil, surfactant
0.5~3 part, 42~58 parts of antiwear additive, 1~2.4 part of dispersion stabilizer, 3~5 parts of preservatives with high temperature tolerance.
Further, the base oil is that white oil, diesel oil, biodiesel, synthetic oil, plant squeeze oil, animal tallow oil
It is one or more.
White oil is mainly the cycloalkane and alkane mixture being saturated, and is by crude oil atmospheric and vacuum fractionation, solvent extraction
And dewaxing, hydrofinishing and obtain;Diesel oil is oils, complicated hydro carbons (carbon atom number about 10~22) mixture, is bavin
Oil machine fuel, mainly by crude distillation, catalytic cracking, thermal cracking, be hydrocracked, the diesel oil distillate of the processes production such as petroleum coking
It deploys, can also be processed by shale oil and coal liquefaction is produced;Biodiesel refers to vegetable oil (such as rapeseed oil, soybean oil, peanut
Oil, corn oil, cottonseed oil etc.), animal oil (such as fish oil, lard, butter, sheep oil), waste grease or microbial oil and first
Alcohol or ethyl alcohol are converted through ester and the fatty acid methyl ester or ethyl ester of formation;Synthetic oil is formed with the compound of polyalkenes or esters
Base oil, this maximum feature of base oil is that oxidation resistance is strong, and has natural detersive, so it will ensure that profit
Using for a long time, performance is all not easy to fail lubricating oil.
Further, the surfactant includes aliphatic acid polyethenoxy ether, alkyl phenol polyoxyethylene ether, sorbitol anhydride
Monostearate, glycine betaine it is one or more.
By using above-mentioned technical proposal, fatty alcohol polyoxyethylene ether is most important a kind of nonionic surfactant,
Ehter bond in molecule is not easy to be destroyed by acid, alkali, so high stability, water-soluble preferable, electrolyte-resistant;Sorbitol anhydride list is stearic
Acid esters is suitable as water-in-oil emulsifier, and easily biological-degradable, nontoxic odorless.
Further, the surfactant is aliphatic acid polyethenoxy ether EL-12 and aliphatic acid polyethenoxy ether EL-
100, the weight ratio of the two is 7:3~5:5.
Further, the antiwear additive uses TiO2、ZrO2、Zn(OH)2、Ni(OH)2、La(OH)3、LaAlO3、Mg
(OH)2、Sb2O5、ZnO、CuO、MgO、SiO2、Fe3O4、Fe2O3、Mg2B2O5、B4CaO7、CeO2、CePO4、Ti3(BO3)4、
Ce0.25NiFeO3It is one or more.
Further, the dispersion stabilizer uses hyper-dispersant.
By using above-mentioned technical proposal, the nonpolar wetting dispersing agent containing amine anchoring group has multiple absorption points,
Other material surfaces can be securely adsorbed in, the viscosity of dispersion is reduced, prevent from flocculating;Collaborative dispersant is anchored with containing amine
The nonpolar wetting dispersing agent of group is used cooperatively, and reaches best use effect.
Further, the preservatives with high temperature tolerance is selected from polystyrene, polymethyl methacrylate, polyacrylonitrile, poly- carbon
Acid esters it is one or more.
In conclusion the invention has the following advantages:
1, drilling fluid of the invention is inorganic nano metallic compound with the antiwear additive of temperature resistance Wear-resistant drag reducer, is effectively being dropped
While torque caused by drilling rod and sleeve friction increases in low drilling process, harmful substance, safety and environmental protection will not be generated;
2, drilling fluid of the invention makes drag reducer can be resistant to height with temperature resistance Wear-resistant drag reducer by the preservatives with high temperature tolerance of addition
Temperature.
Specific embodiment
Invention is further described in detail with reference to embodiments.
Dispersion stabilizer is all made of dimension Persian new material Co., Ltd hyper-dispersant series WinSperse in following embodiment
3030, one of WinSperse 3050, WinSperse 3090, WinSperse 2010, WinSperse 2050 or more
Kind;White oil uses industrial grade white oil;Diesel oil uses 0# diesel oil;Plant squeezes oil using rapeseed oil;Animal tallow oil selects lard;
Synthetic oil selects Holland shell CSL 5W-30;Glycine betaine uses dodecyl dimethyl sulphur third class glycine betaine;Alkyl phenol polyoxy second
Alkene ether uses nonylphenol polyoxyethylene ether.
Embodiment 1
A kind of drilling fluid temperature resistance Wear-resistant drag reducer, each component and its corresponding parts by weight are as follows: white oil 15g, diesel oil 15g, close
Oily 5g, aliphatic acid polyethenoxy ether (EL-12) 3.5g, aliphatic acid polyethenoxy ether (EL-100) are squeezed at oily 15g, plant
1.5g、TiO2 5g、ZnO 5g、SiO2 5g、Fe3O4 5g、WinSperse 3030 0.3g、WinSperse 2010 0.2g、
Polystyrene 5g, polymethyl methacrylate 5g.
A kind of preparation method of drilling fluid temperature resistance Wear-resistant drag reducer of embodiment 1 is prepared, method includes the following steps:
Step 1: 15g white oil, 15g diesel oil, 15g synthetic oil and 5g plant are squeezed into oil and stir 20min extremely mixing at 70 DEG C
It is even;
Step 2: 5g TiO is sequentially added into the mixture that step 1 obtains2、5g ZnO、5g SiO2、5g Fe3O4, 5g it is poly-
Styrene, 5g polymethyl methacrylate, at 90 DEG C stir 30min to be uniformly mixed;
Step 3: 3.5g aliphatic acid polyethenoxy ether (EL-12), 1.5g fat are sequentially added into the mixture that step 2 obtains
Sour polyoxyethylene ether (EL-100), 0.3g WinSperse 3030,0.2g WinSperse 2010, stir evenly, are cooled to
Room temperature obtains drilling fluid temperature resistance Wear-resistant drag reducer.
Embodiment 2
A kind of drilling fluid temperature resistance Wear-resistant drag reducer, each component and its corresponding parts by weight are as follows: white oil 10g, diesel oil 10g, close
Oily 5g, aliphatic acid polyethenoxy ether (EL-12) 2.1g, aliphatic acid polyethenoxy ether (EL-100) are squeezed at oily 10g, plant
0.9g、TiO2 10g、ZnO 8g、SiO2 6g、Fe3O4 6g、WinSperse 3030 0.5g、WinSperse 2010 0.5g、
Polystyrene 5g, polymethyl methacrylate 3g.
Embodiment 3
A kind of drilling fluid temperature resistance Wear-resistant drag reducer, each component and its corresponding parts by weight are as follows: white oil 10g, diesel oil 5g, synthesis
Oily 5g, plant squeeze oily 5g, aliphatic acid polyethenoxy ether (EL-12) 1.75g, aliphatic acid polyethenoxy ether (EL-100) 0.75g,
TiO2 15g、ZnO 12g、SiO2 10g、Fe3O43,030 2010 0.8g of 1g, WinSperse of 5g, WinSperse, polyphenyl
Ethylene 3g, polymethyl methacrylate 2g.
Embodiment 4
A kind of drilling fluid temperature resistance Wear-resistant drag reducer, each component and its corresponding parts by weight are as follows: white oil 4g, diesel oil 4g, synthesis
Oily 4g, plant squeeze oily 3g, aliphatic acid polyethenoxy ether (EL-12) 0.9g, aliphatic acid polyethenoxy ether (EL-100) 0.6g,
TiO2 16g、ZnO 15g、SiO2 15g、Fe3O43,030 2010 1g of 1.4g, WinSperse of 12g, WinSperse, polyphenyl
Ethylene 1.5g, polymethyl methacrylate 1.5g.
Embodiment 5
A kind of drilling fluid temperature resistance Wear-resistant drag reducer, each component and its corresponding parts by weight are as follows: white oil 2g, diesel oil 1g, synthesis
Oily 1g, plant squeeze oily 1g, aliphatic acid polyethenoxy ether (EL-12) 0.5g, aliphatic acid polyethenoxy ether (EL-100) 0.5g,
TiO2 10g、ZnO 8g、SiO2 8g、Fe3O4 8g、ZrO26g、La(OH)3 6g、Mg(OH)2 6g、B4CaO7 6g、CePO4
6g、Ni(OH)23,030 2010 1g of 2g, WinSperse of 6g, WinSperse, polystyrene 1g, polymethyl methacrylate
1g。
Embodiment 6
A kind of drilling fluid temperature resistance Wear-resistant drag reducer, each component and its corresponding parts by weight are as follows: biodiesel 20g, plant are squeezed
Take oily 15g, animal tallow oil 15g, nonylphenol polyoxyethylene ether 2.5g, sorbitan monostearate 1.5g, dodecyl two
Methyl sulphur third class glycine betaine 1g, Zn (OH)2 5g、CuO 5g、MgO 5g、Fe2O3 5g、WinSperse 3050 0.2g、
3,090 2050 0.2g of 0.1g, WinSperse of WinSperse, polyacrylonitrile 5g, polycarbonate 5g.
Embodiment 7
A kind of drilling fluid temperature resistance Wear-resistant drag reducer, each component and its corresponding parts by weight are as follows: biodiesel 15g, plant are squeezed
Take oily 10g, animal tallow oil 10g, nonylphenol polyoxyethylene ether 1.5g, sorbitan monostearate 1g, dimethyl
Base sulphur third class glycine betaine 0.5g, Zn (OH)2 10g、CuO 8g、MgO 6g、Fe2O3 6g、WinSperse 3050 0.4g、
3,090 2050 0.3g of 0.3g, WinSperse of WinSperse, polyacrylonitrile 5g, polycarbonate 3g.
Embodiment 8
A kind of drilling fluid temperature resistance Wear-resistant drag reducer, each component and its corresponding parts by weight are as follows: biodiesel 12g, plant are squeezed
Take oily 8g, animal tallow oil 5g, nonylphenol polyoxyethylene ether 1g, sorbitan monostearate 1g, dodecyl dimethyl sulphur
Third class glycine betaine 0.5g, Zn (OH)2 15g、CuO 12g、MgO 10g、Fe2O3 5g、WinSperse 3050 1g、
WinSperse3090 0.5g, 2050 WinSperse 0.3g, polyacrylonitrile 3g, polycarbonate 2g.
Embodiment 9
A kind of drilling fluid temperature resistance Wear-resistant drag reducer, each component and its corresponding parts by weight are as follows: biodiesel 5g, plant are squeezed
Oily 5g, animal tallow oil 5g, nonylphenol polyoxyethylene ether 0.5g, sorbitan monostearate 0.5g, dodecyl dimethyl
Sulphur third class glycine betaine 0.5g, Zn (OH)2 16g、CuO 15g、MgO 15g、Fe2O3 12g、WinSperse 3050 1g、
3,090 2050 0.6g of 0.8g, WinSperse of WinSperse, polyacrylonitrile 1.5g, polycarbonate 1.5g.
Embodiment 10
A kind of drilling fluid temperature resistance Wear-resistant drag reducer, each component and its corresponding parts by weight are as follows: biodiesel 3g, plant are squeezed
Oily 1g, animal tallow oil 1g, nonylphenol polyoxyethylene ether 0.5g, sorbitan monostearate 0.23g, dodecyl dimethyl
Sulphur third class glycine betaine 0.2g, Zn (OH)2 10g、CuO 8g、MgO 8g、Fe2O3 8g、CeO2 6g、Ti3(BO3)4 6g、
Ce0.25NiFeO3 6g、LaAlO3 6g、Sb2O5 6g、Mg2B2O5 6g、WinSperse 3050 1.2g、WinSperse
2050 0.8g of 30901g, WinSperse, polyacrylonitrile 1g, polycarbonate 1g.
The preparation method of drag reducer in embodiment 2-10 is identical as 1 method of embodiment, exists with the difference of embodiment 1
In: each component and its corresponding mass fraction are different from embodiment 1.
Comparative example 1
A kind of drilling fluid temperature resistance Wear-resistant drag reducer, each component and its corresponding parts by weight are as follows: white oil 15g, diesel oil 15g, close
Oily 5g, aliphatic acid polyethenoxy ether (EL-12) 3.5g, aliphatic acid polyethenoxy ether (EL-100) are squeezed at oily 15g, plant
3,030 2010 0.2g of 0.3g, WinSperse of 1.5g, WinSperse, polystyrene 5g, polymethyl methacrylate 5g.
Comparative example 2
A kind of drilling fluid temperature resistance Wear-resistant drag reducer, each component and its corresponding parts by weight are as follows: white oil 15g, diesel oil 15g, close
Oily 5g, aliphatic acid polyethenoxy ether (EL-12) 3.5g, aliphatic acid polyethenoxy ether (EL-100) are squeezed at oily 15g, plant
1.5g、TiO2 5g、ZnO 5g、SiO2 5g、Fe3O4 5g、WinSperse 3030 0.3g、WinSperse 2010 0.2g。
Comparative example 3
The emulsion-type polyacrylamide drag reducer of the selection source Henan Kai Bi water-purifying material Co., Ltd compares.
Base slurry formula
A kind of base slurry, each component and its corresponding parts by weight are as follows: water 40g, sodium soil 2g, natrium carbonicum calcinatum 0.1g, blanc fixe
0.1g。
Performance detection test
Benchmark test is carried out with the drag reducer of temperature resistance Wear-resistant drag reducer and comparative example to the drilling fluid that each embodiment obtains, is commented
Its greasy property and extreme pressure property, test result in base slurry of valence is shown in Table 1.
Test method is as follows:
1, lubricity is tested
Usually test the fluid resistance of different lubricating additives.The lubricating coefficient test of standard is that two hardening steel surfaces mention
For 150lb, rotated at 60RPM.Coefficient of friction calculation method are as follows:
F --- coefficient of friction;
l0--- hydralic pressure gauge readings (lb);
lWater--- the table readings (lb) of water
2, extreme pressure (EP) performance test
By toggle, test force is provided to torque bearing to test the extreme pressure film-strength of liquid, EP is tested generally in high shear
It is carried out under rate 1000RPM, extreme pressure film-strength is calculated by the scratch between observation test wrapper and the surface of test block, counted
Calculation method are as follows:
P --- film-strength (PSI);
T --- torque meter readings (lb);
W --- scratch width (in);
L --- scratch length (in)
Table 1: performance test data of the drilling fluid of each embodiment with temperature resistance Wear-resistant drag reducer in base slurry
Note: test temperature: 220 DEG C, density 2.2g/cm3, antiwear additive dosage is the 1.5% of base slurry product;
Test equipment: OFIE.P.&Lubricity Tester, model: 112-00-1-C.
It can be seen that drilling fluid of the invention with temperature resistance Wear-resistant drag reducer anti-from the data of the embodiment 1-10 in upper table
Significant effect in terms of high-temperature behavior, can keep its performance under 220 DEG C of high temperature;From the point of view of coefficient of friction reduced rate data, turn round
Square reduced rate is not less than 70%, can effectively reduce the increase of the torque due to caused by drilling rod and sleeve friction;Embodiment 1-10's is anti-
Performance is ground compared with comparative example 1 and 2, preferably, illustrates antiwear additive used in the present invention and preservatives with high temperature tolerance significant effect;
For embodiment 1-10 compared with comparative example 3, effect is preferable, illustrates that drag reducer of the invention is more excellent than properties of product of the same trade
It is good.
Above-mentioned specific embodiment is only explanation of the invention, is not limitation of the present invention, art technology
Personnel can according to need the modification that not creative contribution is made to the present embodiment after reading this specification, but as long as
All by the protection of Patent Law in scope of the presently claimed invention.