CN104336057B - Composition pesticide containing Flupyrazofos-containpesticide Yu chrysanthemum lactone component - Google Patents
Composition pesticide containing Flupyrazofos-containpesticide Yu chrysanthemum lactone component Download PDFInfo
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- CN104336057B CN104336057B CN201410618088.3A CN201410618088A CN104336057B CN 104336057 B CN104336057 B CN 104336057B CN 201410618088 A CN201410618088 A CN 201410618088A CN 104336057 B CN104336057 B CN 104336057B
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- 239000000203 mixture Substances 0.000 title claims abstract description 61
- 239000000575 pesticide Substances 0.000 title claims abstract description 15
- 235000007516 Chrysanthemum Nutrition 0.000 title abstract description 3
- 244000189548 Chrysanthemum x morifolium Species 0.000 title abstract description 3
- 150000002596 lactones Chemical class 0.000 title abstract description 3
- 241000238631 Hexapoda Species 0.000 claims abstract description 14
- 241000244206 Nematoda Species 0.000 claims abstract description 8
- 239000005946 Cypermethrin Substances 0.000 claims abstract description 5
- 241000196324 Embryophyta Species 0.000 claims abstract description 5
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229960005424 cypermethrin Drugs 0.000 claims abstract description 5
- 230000003405 preventing effect Effects 0.000 claims abstract description 5
- ZXQYGBMAQZUVMI-UNOMPAQXSA-N cyhalothrin Chemical compound CC1(C)C(\C=C(/Cl)C(F)(F)F)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-UNOMPAQXSA-N 0.000 claims abstract description 4
- 238000010413 gardening Methods 0.000 claims abstract description 4
- ZFHGXWPMULPQSE-SZGBIDFHSA-N (Z)-(1S)-cis-tefluthrin Chemical compound FC1=C(F)C(C)=C(F)C(F)=C1COC(=O)[C@@H]1C(C)(C)[C@@H]1\C=C(/Cl)C(F)(F)F ZFHGXWPMULPQSE-SZGBIDFHSA-N 0.000 claims abstract description 3
- 239000005939 Tefluthrin Substances 0.000 claims abstract description 3
- QQODLKZGRKWIFG-QSFXBCCZSA-N cyfluthrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@@H](C#N)C1=CC=C(F)C(OC=2C=CC=CC=2)=C1 QQODLKZGRKWIFG-QSFXBCCZSA-N 0.000 claims abstract description 3
- 229960001591 cyfluthrin Drugs 0.000 claims abstract description 3
- 241000256247 Spodoptera exigua Species 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 8
- 241000344246 Tetranychus cinnabarinus Species 0.000 claims description 7
- 241000607479 Yersinia pestis Species 0.000 claims description 7
- 241000234295 Musa Species 0.000 claims description 6
- 235000018290 Musa x paradisiaca Nutrition 0.000 claims description 6
- 241000255777 Lepidoptera Species 0.000 claims description 2
- 239000003595 mist Substances 0.000 claims 1
- 239000007921 spray Substances 0.000 claims 1
- 238000005507 spraying Methods 0.000 abstract description 4
- 239000003814 drug Substances 0.000 description 18
- 230000000694 effects Effects 0.000 description 13
- 230000002195 synergetic effect Effects 0.000 description 9
- 238000012360 testing method Methods 0.000 description 7
- 241000243785 Meloidogyne javanica Species 0.000 description 6
- 230000003449 preventive effect Effects 0.000 description 5
- 239000007788 liquid Substances 0.000 description 4
- AZSNMRSAGSSBNP-UHFFFAOYSA-N 22,23-dihydroavermectin B1a Natural products C1CC(C)C(C(C)CC)OC21OC(CC=C(C)C(OC1OC(C)C(OC3OC(C)C(O)C(OC)C3)C(OC)C1)C(C)C=CC=C1C3(C(C(=O)O4)C=C(C)C(O)C3OC1)O)CC4C2 AZSNMRSAGSSBNP-UHFFFAOYSA-N 0.000 description 3
- SPBDXSGPUHCETR-JFUDTMANSA-N 8883yp2r6d Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O[C@@H]([C@@H](C)CC4)C(C)C)O3)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1C[C@H](C)[C@@H]([C@@H](C)CC)O[C@@]21O[C@H](C\C=C(C)\[C@@H](O[C@@H]1O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C1)[C@@H](C)\C=C\C=C/1[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\1)O)C[C@H]4C2 SPBDXSGPUHCETR-JFUDTMANSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 229940079593 drug Drugs 0.000 description 3
- 230000000857 drug effect Effects 0.000 description 3
- 229960002418 ivermectin Drugs 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 241000488583 Panonychus ulmi Species 0.000 description 2
- ZBXICRCDECBVDN-UHFFFAOYSA-N [P].[S].[F].N1C=CC=C1 Chemical compound [P].[S].[F].N1C=CC=C1 ZBXICRCDECBVDN-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 230000008485 antagonism Effects 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- CXEGAUYXQAKHKJ-NSBHKLITSA-N emamectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](NC)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 CXEGAUYXQAKHKJ-NSBHKLITSA-N 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 230000010534 mechanism of action Effects 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- FNELVJVBIYMIMC-UHFFFAOYSA-N Ethiprole Chemical compound N1=C(C#N)C(S(=O)CC)=C(N)N1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl FNELVJVBIYMIMC-UHFFFAOYSA-N 0.000 description 1
- 240000000905 Nymphoides indica Species 0.000 description 1
- 235000017590 Nymphoides indica Nutrition 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 240000006677 Vicia faba Species 0.000 description 1
- 235000010749 Vicia faba Nutrition 0.000 description 1
- 235000002098 Vicia faba var. major Nutrition 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- RQFQJYYMBWVMQG-IXDPLRRUSA-N chitotriose Chemical compound O[C@@H]1[C@@H](N)[C@H](O)O[C@H](CO)[C@H]1O[C@H]1[C@H](N)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)N)[C@@H](CO)O1 RQFQJYYMBWVMQG-IXDPLRRUSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002361 compost Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- JZUKGAJJLZRHGL-UHFFFAOYSA-N diethoxy-[2-phenyl-5-(trifluoromethyl)pyrazol-3-yl]oxy-sulfanylidene-lambda5-phosphane Chemical compound CCOP(=S)(OCC)OC1=CC(C(F)(F)F)=NN1C1=CC=CC=C1 JZUKGAJJLZRHGL-UHFFFAOYSA-N 0.000 description 1
- -1 emamectin benzoate Compound Chemical class 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- XQUXKZZNEFRCAW-UHFFFAOYSA-N fenpropathrin Chemical group CC1(C)C(C)(C)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 XQUXKZZNEFRCAW-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 238000000386 microscopy Methods 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Abstract
The invention discloses a kind of composition pesticide containing Flupyrazofos-containpesticide Yu chrysanthemum lactone component, said composition includes component A and the B component of effective dose, component A is Flupyrazofos-containpesticide, one or more in effective cypermethrin, Cyhalothrin, Tefluthrin, cyfluthrin of B component, the mass fraction of component A and B component is than for 30:1 1:30, composition is applied to crop or crop part, preventing and treating agricultural, gardening or the insect of forestry plant, evil mite or nematode by spraying, pouring root or seed dressing.
Description
The application is the divisional application of " containing the composition pesticide of Flupyrazofos-containpesticide " application for a patent for invention, original application day:
On November 21st, 2013, application number: 2013105935881
Technical field
The present invention relates to a kind of composition pesticide, be specifically related to a kind of containing Flupyrazofos-containpesticide to agricultural, gardening, forest
Insect, evil mite, nematode have the synergistic composition of excellent results.
Background technology
Flupyrazofos-containpesticide (flupyrazofos) is organic phosphates new pesticides, and the insect of various crop is had excellent preventing
Effect, especially has excellent effect to lepidoptera pest.For Reasonable Protection medicament, delay insect generation drug-fast to new medicament
And improve the prevention effect of medicament, it is necessary to carry out rational composition research.The answering containing Flupyrazofos-containpesticide announced at present
Joining insecticide research less, the present invention has been found through experiments synergistic effect and has significantly contained the composition pesticide of Flupyrazofos-containpesticide.
Summary of the invention
It is an object of the invention to provide a kind of prevent and treat plant insect, evil mite, the agricultural chemicals containing Flupyrazofos-containpesticide of nematode
Composition, it is to be compounded by the composition of two kinds of different structures and mechanism of action, reaches expanding prevention spectrum and improves drug effect, more
It is important to avoid that or delay the insect generation to new composition resistance.
It is an object of the invention to be realized by following measures.
The invention provides a kind of composition pesticide containing Flupyrazofos-containpesticide, it is characterised in that said composition includes effective dose
Component A and B component, component A is Flupyrazofos-containpesticide, B component be selected from AVM, pleocidin, Affirm (Merck Co.) benzene first
Hydrochlorate (calling emamectin benzoate in the following text), ivermectin, effective cypermethrin, Cyhalothrin, Tefluthrin, cyfluthrin, ethiprole,
One or more in chitosan oligosaccharide.
In above-mentioned composition, the mass fraction of component A and B component is than for 30:1-1:30.
In above-mentioned composition of the present invention, the quality sum of component A and B component accounts for the 1-60% of composition gross mass.
Present invention also offers above-mentioned composition for the method preventing and treating crop pest, it is characterised in that passed through by composition
Spraying, pouring root or seed dressing are applied to crop.
Above-mentioned pest, refers to the cause harm insect of agricultural, gardening or forestry plant, evil mite or nematode, it is preferred that insect is squama
Wing mesh insect, evil mite is Tetranychus cinnabarinus, and nematode is root-knot nematode, it is further preferred that insect is lepidopterous beet armyworm, line
Worm is banana root-knot nematode.
The medicine have the advantages that
1, synergistic effect is obvious: composition shows good synergistic effect in certain ratio range, improves composition
Effect.
2, reduction use cost: because of compounding, there is raising preventive effect, preventing and treating spectrum increase, decrease access times, reduce and make
Use cost；
3, the resistance to the action of a drug is delayed: the composition of two kinds of different mechanism of action compounds, and pest is not likely to produce the resistance to the action of a drug, delays insect pair
The drug-fast generation of single dose.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described, but the present invention is never limited to following embodiment.
Embodiment 1 is containing the Flupyrazofos-containpesticide composition pesticide effect to Laphygma exigua Hubner
Test uses the beet armyworm that field gathers, for testing after raising for 2 generations.Concrete grammar is as follows:
Leaf dish prepares: chooses cleaning bud dish, cleans and dry, making into leaf dish with card punch standby.
Medicament is prepared: before test, according to mix proportion scheme, former medicine is configured to different concentration.
Dipping: soak in liquid 5 seconds with tweezers gripping leaf dish, take out and dry in the air on blotting paper, be put in 24 after natural air drying
In orifice plate, 2, every hole.Every concentration processes puts 3 plates altogether.
Connect worm: 1 beet armyworm 3 instar larvae is put in the 24 every holes of orifice plate, put into after building insectary (25 ± 1 DEG C, 12H/
In 12H).
Investigation statistics: check dead borer population after processing 48 hours, calculates synergistic action effect according to below equation.
In theoretical death rate formula, x be concentration be the death rate of medicament A during a, y be concentration be the dead of medicament B during b
Die rate, relatively the theoretical death rate and actual, evaluate the synergy of composition.When actual is dead more than theoretical
Being synergistic effect during rate, be antagonism during less than the theoretical death rate, test result is shown in Table 1.
Table 1 composition effect to Laphygma exigua Hubner
The effect of Laphygma exigua Hubner is shown in Table 1 by composition, it can be seen that relative to single dose, composition is effectively
When composition proportion is 30:1-1:30, composition is above the theoretical preventive effect of composition to the actual preventive effect of Laphygma exigua Hubner；Institute
With, Flupyrazofos-containpesticide and the group of the composition of AVM, Flupyrazofos-containpesticide and the composition of pleocidin, Flupyrazofos-containpesticide and emamectin benzoate
Compound, Flupyrazofos-containpesticide and the composition of ivermectin, Flupyrazofos-containpesticide and the composition of effective cypermethrin, Flupyrazofos-containpesticide and trifluoro
The composition of cypermethrin is synergy to the synergy of Laphygma exigua Hubner, can reach to improve drug effect, reduces times for spraying, profit
In increasing economic efficiency and environmental ecology.
The embodiment 2 composition pesticide containing the Flupyrazofos-containpesticide effect to red spider
Examination worm: indoor broad bean seedling raises Tetranychus cinnabarinus throughout the year, before test, two-sided tape is attached to one end of slide,
Select with writing brush and expand that consistent one-tenth mite of numerous age is counter to be posted on adhesive tape, about 50, every slide note, it is put in and is covered with filter paper and protects
In wet 9cm culture dish.Microscopy after 2 hours, discards dead polypide.
Medicament is prepared: before test, according to mix proportion scheme, former medicine is configured to different concentration.
Dipping: from the beginning of low concentration, pick up slide with tweezers, immerses concentration series to be measured by the one end being stained with mite molten
In liquid, take out after being shaken gently for 3 seconds, filter off liquid and suck unnecessary liquid with blotting paper, being put in culture dish.Every concentration 3
Individual slide.
Investigation statistics: check red spider death toll after processing 48 hours, calculate synergistic action effect according to below equation.
In theoretical death rate formula, x be concentration be the death rate of medicament A during a, y be concentration be the dead of medicament B during b
Die rate, relatively the theoretical death rate and actual, evaluate the synergy of composition.When actual is dead more than theoretical
Being synergistic effect during rate, be antagonism during less than the theoretical death rate, test result is shown in Table 2.
Table 2 composition effect to Tetranychus cinnabarinus
The effect of Tetranychus cinnabarinus is shown in Table 2 by composition, it can be seen that relative to single dose, composition is in active ingredient
Proportioning is under 30:1-1:30, and composition is above the theoretical preventive effect of composition to the actual preventive effect of Tetranychus cinnabarinus；So, pyrrole fluorine
Sulphur phosphorus and the composition of AVM, Flupyrazofos-containpesticide and the composition of pleocidin, Flupyrazofos-containpesticide and the composition of emamectin benzoate, pyrrole
Fluorine sulphur phosphorus and the composition of ivermectin, Flupyrazofos-containpesticide and the composition of Fenpropathrin, Flupyrazofos-containpesticide and Cyhalothrin
Composition is synergy to the synergy of Tetranychus cinnabarinus, can reach to improve drug effect, reduce times for spraying, be beneficial to increase economic efficiency
And environmental ecology.
The embodiment 3 composition pesticide containing the Flupyrazofos-containpesticide effect to banana root-knot nematode
It is mixed into compost with sterilized soil and sterilizing river sand, fully after mixing, is mixed into medicament.Drug concentration is with every kilogram of soil
Earth contains the milligram number meter of the active ingredient of this medicament, directly mixes soil with corresponding dosage formulation, adds clear water after fully mixing thoroughly
Make water content 30%, then mix rear quantitatively loading basin alms bowl thoroughly, the banana seedlings of growth 20d is transplanted in basin, transplants latter 7 days, every basin
Access root-knot nematode 2 instar larvae 500, be placed in greenhouse, Routine Management.Every chemicals treatment 6 basin, and it is set to blank.After 40d
Investigate the root knot number of every basin plant, and carry out classification by Liu Weizhi (1995): 0 grade, without root knot；1 grade, 1-2 root knot；2 grades, 3-
10 root knots；3 grades, 11-30 root knot；4 grades, 31-100 root knot；5 grades, more than 100 root knots.Banana plant is tiled, system
Meter root knot number, the effect of different disposal is shown in Table 3.
As seen from Table 3, after 40d, under same medicine concentration, the root of the banana that the different components containing Flupyrazofos-containpesticide processes
Knot mean is considerably less than the root knot number that corresponding single dose processes, it is seen then that containing Flupyrazofos-containpesticide composition pesticide to root-knot nematode higher than single
Agent, composition has synergistic effect.
The table 3 composition pesticide containing the Flupyrazofos-containpesticide effect to banana root-knot nematode
Claims (6)
1. the composition pesticide containing Flupyrazofos-containpesticide, it is characterised in that said composition includes component A and the B group of effective dose
Point, component A is Flupyrazofos-containpesticide, and B component is selected from effective cypermethrin, Cyhalothrin, Tefluthrin, cyfluthrin
Kind or multiple, the mass fraction of component A and B component ratio is for 10:1-1:20.
Composition pesticide the most according to claim 1, it is characterised in that the quality sum of component A and B component accounts for the total matter of composition
The 1-60% of amount.
3. the composition pesticide of claim 1 or 2 is for the method preventing and treating crop pest, it is characterised in that by composition by spray
Mist, pouring root or seed dressing are applied to crop.
Method the most according to claim 3, it is characterised in that pest refers to the cause harm insect of agricultural, gardening or forestry plant, evil mite
Or nematode.
Method the most according to claim 4, it is characterised in that insect is lepidoptera pest, evil mite is Tetranychus cinnabarinus, and nematode is root
Tie lines worm.
Method the most according to claim 5, it is characterised in that insect is lepidopterous beet armyworm, nematode is Banana Root tie lines
Worm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410618088.3A CN104336057B (en) | 2013-11-21 | 2013-11-21 | Composition pesticide containing Flupyrazofos-containpesticide Yu chrysanthemum lactone component |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310593588.1A CN103651553B (en) | 2013-11-21 | 2013-11-21 | Flupyrazofos-containing pesticide composition |
| CN201410618088.3A CN104336057B (en) | 2013-11-21 | 2013-11-21 | Composition pesticide containing Flupyrazofos-containpesticide Yu chrysanthemum lactone component |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310593588.1A Division CN103651553B (en) | 2013-11-21 | 2013-11-21 | Flupyrazofos-containing pesticide composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104336057A CN104336057A (en) | 2015-02-11 |
| CN104336057B true CN104336057B (en) | 2016-09-07 |
Family
ID=52493139
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410618088.3A Active CN104336057B (en) | 2013-11-21 | 2013-11-21 | Composition pesticide containing Flupyrazofos-containpesticide Yu chrysanthemum lactone component |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104336057B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1052590A (en) * | 1989-12-20 | 1991-07-03 | 中国人民解放军北京军区军医学校 | A kind of processing method of compound insecticide |
| KR20020005213A (en) * | 2000-06-27 | 2002-01-17 | 김충섭 | A improved process for preparing 3-trifluoromethyl-5- hydroxypyrazole phosphonic acid ester derivatives in water solvent |
| CN1463602A (en) * | 2002-06-12 | 2003-12-31 | 毕光耀 | Highly effective alphamethrin-phoxim wettable powder |
-
2013
- 2013-11-21 CN CN201410618088.3A patent/CN104336057B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1052590A (en) * | 1989-12-20 | 1991-07-03 | 中国人民解放军北京军区军医学校 | A kind of processing method of compound insecticide |
| KR20020005213A (en) * | 2000-06-27 | 2002-01-17 | 김충섭 | A improved process for preparing 3-trifluoromethyl-5- hydroxypyrazole phosphonic acid ester derivatives in water solvent |
| CN1463602A (en) * | 2002-06-12 | 2003-12-31 | 毕光耀 | Highly effective alphamethrin-phoxim wettable powder |
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| Publication number | Publication date |
|---|---|
| CN104336057A (en) | 2015-02-11 |
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