CN104336043B - Insecticidal and bactericidal composition containing alkene oxime amine and application thereof - Google Patents
Insecticidal and bactericidal composition containing alkene oxime amine and application thereof Download PDFInfo
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- CN104336043B CN104336043B CN201310316688.XA CN201310316688A CN104336043B CN 104336043 B CN104336043 B CN 104336043B CN 201310316688 A CN201310316688 A CN 201310316688A CN 104336043 B CN104336043 B CN 104336043B
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- China
- Prior art keywords
- seed treatment
- difenoconazole
- oxime amine
- alkene oxime
- pesticide
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- 230000001717 pathogenic effect Effects 0.000 description 1
- 235000021017 pears Nutrition 0.000 description 1
- 239000008194 pharmaceutical composition Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- LROWVYNUWKVTCU-STWYSWDKSA-M sodium sorbate Chemical compound [Na+].C\C=C\C=C\C([O-])=O LROWVYNUWKVTCU-STWYSWDKSA-M 0.000 description 1
- 235000019250 sodium sorbate Nutrition 0.000 description 1
- JHJUUEHSAZXEEO-UHFFFAOYSA-M sodium;4-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=C(S([O-])(=O)=O)C=C1 JHJUUEHSAZXEEO-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100000820 toxicity test Toxicity 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to technical field of pesticide, relate to a kind of insecticidal and bactericidal composition containing alkene oxime amine and application thereof.Insecticidal and bactericidal composition is antibacterial and insecticide, and specially alkene oxime amine (A), Difenoconazole (B) and Diacloden (C) are the ternary built of effective ingredient.Wherein antibacterial is 1:100 100:1 with the weight ratio of insecticide, and wherein antibacterial alkene oxime amine is 1:10 10:1 with the weight ratio of Difenoconazole.The seed treatment that the present invention relates to is mainly used in preventing and treating Semen Tritici aestivi, Oryza sativa L., the pest and disease damage of corn crop.Disease that Rhizoctonia cerealis is caused by the pesticide-germicide mixture of the present invention and aphid, subterranean pest-insect have excellent prevention effect, facilitate peasant household to use, reduce cost.This mixture is prepared as seed treatment, the preventing and treating of pest and disease damage can be carried out from crop seed period, improve pesticide utilization rate, thus the growth to crop plays a good protection.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of insecticidal and bactericidal composition containing alkene oxime amine and application thereof.
Background technology
Alkene oxime amine
Alkene oxime amine is the methoxy acrylic new type bactericide of Shenyang Chemical Engineering Inst's independent research
(CN1309897A).Its structural formula is (I):
Alkene oxime amine has the advantages that fungicidal spectrum is wide, bactericidal activity is high, consumption is few, and has treatment and protective effect.Suitable
Most of fungal diseases are prevented and treated in various crop.As prevented and treated rice banded sclerotial blight, rice blast, false smut, wheat rust, Fructus Cucumidis sativi white lead
Disease, sigatoka, banana freckle and the powdery mildew of other melon and fruit classes, rust etc..
Difenoconazole
Difenoconazole is the triazole bactericidal agent of a kind of broad-spectrum high efficacy, and its structural formula is (II):
Difenoconazole mainly suppresses the biosynthesis of pathogenic bacteria cell ergosterol, thus destroys membrane structure and merit
Can, multiple fungal disease is had well protection and therapeutical effect.Its fungicidal spectrum is wide, and foliar treatment or seed treatment can carry
The yield of high crop and guaranteed quality.
Diacloden
Diacloden is a kind of wide spectrum, efficient, the bio-mimetic syntheses insecticide of low toxicity, is second filial generation anabasine insecticide, with
The mechanism of action of the first generation anabasine insecticides such as imidacloprid is similar, but has higher biological activity, has insect tactile
Kill, stomach toxicity, systemic action, the feature such as speed of action is fast, lasting period length.To sucking pest such as aphid, plant hopper, leafhopper, aleyrodid
Preferable etc. preventive effect.Its structural formula is (III):
Diacloden is with conventional pesticides such as pyrethroid, chlorinated hydrocarbons, organic phosphates and carbamates etc. very
Less or no interactions resistance, this insecticides is made that significant contribution for preventing and treating some worldwide Severe pests.
At present, the preparation containing alkene oxime amine, it mostly is suspending agent, cream and oil-suspending agent, mainly prevents and treats with foliar spray
Be main, rarely seen applied in seed treatment, and without alkene oxime amine and Difenoconazole mixture in terms of seed treatment should
With.For by the seed-borne disease caused by seed dispersal and in soil propagate soil-borne disease, most economical effectively preventing
Means then should be set about from the seed of crop, is i.e. prepared as seed treatment, carries out the preventing and treating of pest and disease damage.
The method of existing controlling crop diseases and insect pests, is to need insecticide and antibacterial individually to buy mostly, and insect pest occurs
Carry out insect-prevention treatment, there is carrying out diseases prevention process in disease, and this method easily misses control approach, and peasant household is not easy to grasp
Insecticidal bactericide mixture optimum proportioning or its whether can mixture, thus affect the preventive effect of pest and disease damage, even produce poisoning etc. bad
Consequence.This pesticide-germicide mixture for seed treatment advantage gradually by field of pesticide preparation personnel it is realized that such as Switzerland
Thiophene worm suspension seed-coating agent coughed up by the product 313g/L phenylate of Syngenta Co., Ltd's exploitation, and its controlling disease is that Semen Tritici aestivi dissipates dust-brand and gold
Pin worm.Prior art there is not yet the mixture relating to the present composition for preventing and treating the diseases such as banded sclerotial blight, aphid and subterranean pest-insect
The seed treatment of insect pest.
Based on above-mentioned insecticide, the feature of antibacterial, inventor carries out compound screening at the good characteristic applying each medicament
In, find to compound alkene oxime amine with Difenoconazole, for preventing and treating the banded sclerotial blight that Rhizoctonia cerealis causes, have the most anti-
Effect.Difenoconazole is to prevent and treat the antibacterial that banded sclerotial blight is excellent, and the present invention is by after itself and alkene oxime amine mixture, for banded sclerotial blight
Preventing and treating, relatively alkene oxime amine single dose, Difenoconazole single dose all have the most excellent fungistatic effect.By this bactericidal composition and parasite killing
Agent Diacloden phase mixture, in seed treatment, all has excellent preventive effect to aphid, subterranean pest-insect, to bacteriostasis without shadow
Ringing, it is to crop safety, environmentally friendly simultaneously.
With the compounding fungicide in mixture of alkene oxime amine and Difenoconazole disclosed in CN1596644, this patent is protected
The microbicide compositions protected, is applied in emulsion, suspending agent, aqueous emulsion, wettable powder or water dispersible granules, this group not mentioned
Compound can be applicable in seed treatment.Both bactericidal compositions are compounded by the present invention just, and by itself and insecticide thiophene worm
Piperazine mixture becomes the brand-new ternary mixture of a kind of insecticidal bactericide, is more applied to but is not limited in seed treatment, passes through
Biological activity test is verified, its fungistatic effect is excellent, and can preferably pest control.One aspect of the present invention provides a kind of brand-new
Combination of active principles, on the other hand expand the range of application of this insecticidal bactericide combination.And it is being currently used for pesticide seed
In the pesticide-germicide mixture of inorganic agent, have no and be applied to the ternary composition of the present invention prevent and treat banded sclerotial blight, aphid and underground evil
The report of the seed treatment of worm.
Summary of the invention
It is an object of the invention to provide a kind of insecticidal and bactericidal composition containing alkene oxime amine and application thereof.
For achieving the above object, the technical solution used in the present invention is:
The present invention is antibacterial alkene oxime amine and Difenoconazole and parasite killing containing the insecticidal and bactericidal composition of alkene oxime amine
Agent Diacloden ternary built mixture, antibacterial is 1:100-100:1, preferably 1:50-10:1 with the weight ratio of insecticide, wherein
Antibacterial alkene oxime amine is 1:10-10:1, preferably 1:5-5:1 with the weight ratio of Difenoconazole.
A kind of insecticidal and bactericidal composition containing alkene oxime amine is for preventing and treating the application in plant disease pest/pathogenic bacteria evil.
Further, said composition has significantly excellent prevention effect, to aphid, to banded sclerotial blight to Rhizoctonia cerealis
Preferable insecticidal activity is had with subterranean pest-insect, and to crop safety.
A kind of insecticidal and bactericidal composition containing alkene oxime amine is as pesticide seed treatment, involved seed treatment master
It is applied to prevent and treat Semen Tritici aestivi, Oryza sativa L., the pest and disease damage of corn crop.Rhizoctonia cerealis is caused by the pesticide-germicide mixture of the present invention
Disease and aphid, subterranean pest-insect have an excellent prevention effect, convenient guide peasant household to start to enter pest and disease damage from crop seed simultaneously
Row prevention, the pesticide-germicide mixture related in the present invention use the preventing and treating that can ensure pest and disease damage in best period.Through associating
In vitro toxicity test, mixture recipe determination and field efficacy checking, the compositions in the present invention is excellent to the prevention effect of pest and disease damage
Good, especially notable to the prevention effect of banded sclerotial blight, the enforcement of the present invention simultaneously can reduce cost accounting.
The seed treatment of the present invention, including effective ingredient, auxiliary agent and carrier, described effective ingredient is by alkene oxime amine, benzene
Ether methyl cyclic-azole and Diacloden composition, described auxiliary agent includes wetting dispersing agent, film former, polymerization monomer, thickening agent and alert toner.
Above-mentioned each component be can be prepared by according to the Conventional processing methods of pesticide seed treatment the seed treatment of the present invention.
Seed treatment of the present invention is 0.9%-as the total weight percent in insecticidal and bactericidal composition effective ingredient
90%, preferably 21%-70%.
The range of application of the compositions of the present invention can be used for but is not limited in pesticide seed treatment, as said composition also may be used
It is applied to the pesticide such as suspending agent, aqueous emulsion, microemulsion, cream, wettable powder, water dispersible granules, suspension emulsion, microcapsule suspending agent
In dosage form.
The seed treatment containing alkene oxime amine of the present invention, the most each component and weight percentage are as follows: alkene oxime amine
0.2-20%, Difenoconazole 0.2-20%, Diacloden 0.5-50%, auxiliary agent 3-40%, carrier or disperse medium 20-90%.
The present invention more preferably technical scheme is, in the seed treatment containing alkene oxime amine, and each component and weight percent
Content is as follows: alkene oxime amine 0.5-10%, Difenoconazole 0.5-10%, Diacloden 20-50%, auxiliary agent 5-25%, carrier or dispersion
Medium 30-70%.
Described seed treatment is prepared as seed treatment dry powder doses (DS), seed treatment dispersibles powder (WS), seed
Process suspending agent (FS), suspension seed-coating agent (FSC) and seed treatment microcapsule suspending agent (CF).Wherein according to national standard
Specifying in the GB19378-2003 formulations of pesticide and code, the difference of FS with FSC is, FS is direct or after dilution, for seed
The stable suspersion liquid formulation processed, and FSC is containing film former, with water as medium, directly or is used for seed pelleting after diluting
Stable suspension seed treatment formulations.
Described auxiliary agent be the one in wetting dispersing agent, emulsifying agent, polymerization monomer, film former, thickening agent, warning coloration or
Several.
Described wetting dispersing agent is selected from lignosulfonates, polymeric carboxylic salt, naphthalene sulfonate, naphthalene sulphonate formaldehyde contracting
Compound, alkylphenol-polyethenoxy base ether formaldehyde condensate sulfonate, dodecylbenzene sodium sulfonate, sodium lauryl sulphate, high score
One or more in sub-parental type anionic and nonionic compound surfactant；Wherein lignosulfonates such as can selected from but not
It is limited to Ultrazine NA or Borresperse NA；Polymeric carboxylic salt such as can be selected from, but not limited to,
Tersperse2700, GY-W10 or GY-D07；Naphthalenesulfonate such as can be selected from, but not limited to, NNO, Morwet D425 or
Morwet EFW；Alkylphenol-polyethenoxy base ether formaldehyde condensate sulfonate such as can be selected from, but not limited to, YUS-FS3000；
Macromolecule parental type anionic and nonionic compound surfactant such as can be selected from, but not limited to, macromolecule dispersing agent SP-SC3.
Described emulsifying agent compounds surface selected from anion surfactant, nonionic surfactant and anionic and nonionic and lives
One or more in property agent；Wherein anion surfactant is mainly calcium dodecyl benzene sulfonate and sodium polyacrylate；Non-
Ionic surface active agent is mainly castor oil polyoxyethylene ether class, alkylphenol polyoxyethylene class, phenethyl phenol polyethenoxy ether
Class, alkylphenol polyoxyethylene formaldehyde condensation species, fatty alcohol polyethenoxy ether class, sorbitan fatty acid ester, dehydration mountain
Pears alcohol fatty acid ester polyoxyethylene ether, styrene maleic anhydride copolymer, phenethyl phenol polyethenoxy polyethenoxy ether and
Formaldehyde condensation species.Wherein said castor oil polyoxyethylene ether class is selected from agriculture breast BY series such as but not limited to BY-125；Castor
Oleum Sesami polyethenoxy ether class is further selected from EL series such as but not limited to EL-80；Alkylphenol polyoxyethylene class is selected from TX system
Row are such as but not limited to TX-10；Alkylphenol polyoxyethylene class is serial such as but not limited to OP-7, OP-10 also selected from OP；Alkane
Base phenol polyethenoxy ethers is further selected from NP series such as but not limited to NP-10；Phenethyl phenol polyethenoxy ethers can be selected from
Such as but not limited to agriculture breast 600#；Alkylphenol polyoxyethylene formaldehyde condensation products can be selected from such as but not limited to Nongru-700 #；
Fatty alcohol polyethenoxy ether class is selected from AEO series such as but not limited to AEO-3, AEO-9；Fatty alcohol polyethenoxy ether class also may be used
Selected from peregal series such as but not limited to SA-20；Sorbitan fatty acid ester be selected from Span series such as but not limited to
Span-80；Sorbitan fatty acid ester polyoxyethylene ether is selected from Tween series such as but not limited to Tween-80；Benzene second
Base phenol polyethenoxy polyethenoxy ether and formaldehyde condensation products can be selected from such as but not limited to agriculture breast 1601#, agriculture breast 1602#；Cloudy
Nonionic compound surfactant can be selected from such as but not limited to agriculture breast 0201B.
Described polymerization monomer is polyureas performed polymer.
Described film former, without particular determination, is generally used for the film former of seed treatment product, such as polyvinyl alcohol.
One or more in xanthan gum, aluminium-magnesium silicate of described thickening agent.
One or more in dyestuff, pigment (including toner and mill base) of described alert toner.
Described carrier is one or more in white carbon, kieselguhr, Kaolin, bentonite, dimethylbenzene or water.
If seed treatment in the present invention uses or is stored in the torrid areas that temperature is higher, also can add appropriate steady
Determine one or more in agent such as epoxy soybean oil, sodium benzoate, sodium sorbate, epoxychloropropane, hydroquinone；If use or
It is stored in the cold district that temperature is relatively low, it is also possible to add in appropriate antifreezing agent such as ethylene glycol, propylene glycol, glycerol, carbamide
One or more.This point is that the those of ordinary skill in pesticide processing field is familiar with.
Seed treatment in the present invention can use sodium hydroxide and/or hydrochloric acid to carry out the pH value of regulation system, and this point is
The those of ordinary skill in pesticide processing field is familiar with.
Advantage for present invention:
The insecticidal and bactericidal composition that the present invention provides, by the joint toxicity measuring to Rhizoctonia cerealis, learns the present invention
Compositions alkene oxime amine and Difenoconazole mixture Rhizoctonia cerealis is had good fungistatic effect, its co-toxicity coefficient is long-range
In 120, all show as potentiation, and the bacteriostasis of alkene oxime amine with Difenoconazole mixture is not had by insecticides thiamethoxam
Impact.
Above-mentioned mixture is applied in seed treatment by the present invention, and through indoor biological determination of activity, the present invention's is the most of the same race
Sub-inorganic agent is respectively provided with good biological effect and excellent prevention effect to wheat sharp eyespot, average preventive effect can reach 50% with
On.By the seed treatment of the field control effectiveness test checking present invention to aphid and the prevention effect of subterranean pest-insect and control sample
The prevention effect of (600g/L imidacloprid and the mixing of 30g/L Difenoconazole are used) is close, is better than the preventive effect of wheat sharp eyespot
Control sample.
Alkene oxime amine, Difenoconazole and Diacloden these three effective ingredient are re-dubbed mixture by the present invention, and are applied to
In seed treatment, obtain corresponding seed treatment by the screening of pharmaceutical formulation, and through indoor biological activity, field medicine
Effect verification experimental verification, the disease that the seed treatment of the present invention causes for Rhizoctonia cerealis, such as banded sclerotial blight, there is excellent preventing and treating
Effect, the preventive effect for aphid and subterranean pest-insect is the most excellent.Empirical tests invention formulation is bright to the prevention effect of banded sclerotial blight
Show and be better than the commercially available elegant formulations preventing and treating banded sclerotial blight, and the preparation of the present invention can play the most anti-eliminating aphis and the effect of subterranean pest-insect
Really.Additionally, the seed treatment preparation processing containing alkene oxime amine of the present invention is simple, good drug efficacy, low cost, pesticide profit can be improved
By rate, reduce environmental pollution, and to crop safety, it is possible to effectively prevent and treat multiple pest and disease damage.
Detailed description of the invention
Specific examples below is used for describing in detail the present invention, but the present invention is not limited only to these examples.All formulations
Formula in percentage ratio be all weight percentage.In formula, active component is rolled over hundred post-dised, and alkene oxime amine is purchased from Shenyang section
Wound Chemical Company；Other auxiliary agents and raw material are commercially available conventional variety.
Formulation Example
Seed treatment dry powder doses (DS)
According to recipe requirements, by effective ingredient alkene oxime amine, Difenoconazole and Diacloden, film former, alert toner, carrier
Premixing is uniform, then pulverizes, then mix homogeneously, and Con trolling index detects at any time, qualified rear discharging, and subpackage obtains seed
Process dry powder doses.
Example 1 below-embodiment 4 is all carried out according to technique made above.
Embodiment 1
Alkene oxime amine 0.6%, Difenoconazole 1.8%, Diacloden 50%, pigment toner 3%, polyvinyl alcohol 2%, white carbon 5%,
Calcium lignosulfonate 3%, sodium lauryl sulphate 2%, Kaolin complements to 100%.
Embodiment 2
Alkene oxime amine 0.6%, Difenoconazole 3%, Diacloden 45%, pigment toner 3%, polyvinyl alcohol 2%, white carbon 5%, wood
Quality sodium sulfonate 3%, sodium lauryl sulphate 2%, bentonite complements to 100%.
Embodiment 3
Alkene oxime amine 3%, Difenoconazole 9%, Diacloden 45%, pigment toner 3%, polyvinyl alcohol 2%, white carbon 5%, naphthalene sulphur
Hydrochlorate formaldehyde condensation products 2%, sodium lauryl sulphate 2%, Kaolin complements to 100%.
Embodiment 4
Alkene oxime amine 3%, Difenoconazole 1%, Diacloden 25%, pigment toner 3%, polyvinyl alcohol 2%, white carbon 5%, wooden
Element sulfoacid calcium 2%, sodium lauryl sulphate 2%, Kaolin complements to 100%.
Seed treatment dispersibles powder (WS)
According to recipe requirements, by effective ingredient alkene oxime amine, Difenoconazole and Diacloden, dispersant, alert toner, carrier
Premixing is uniform, then pulverizes, then mix homogeneously, and Con trolling index detects at any time, qualified rear discharging, and subpackage obtains seed
Process dispersibles powder.
Example 5 below-embodiment 9 is all carried out according to technique made above.
Embodiment 5
Alkene oxime amine 0.6%, Difenoconazole 0.6%, Diacloden 50%, NNO5%, pigment toner 3%, white carbon 5%, wooden
Element sodium sulfonate 3%, sodium lauryl sulphate 2%, Kaolin complements to 100%.
Embodiment 6
Alkene oxime amine 1%, Difenoconazole 3%, Diacloden 50%, NNO5%, pigment toner 3%, white carbon 5%, sulfomethylated lignin
Acid calcium 3%, sodium lauryl sulphate 2%, kieselguhr complements to 100%.
Embodiment 7
Alkene oxime amine 1%, Difenoconazole 5%, Diacloden 45%, NNO6%, pigment toner 3%, white carbon 5%, sulfomethylated lignin
Acid sodium 2%, sodium lauryl sulphate 2%, bentonite complements to 100%.
Embodiment 8
Alkene oxime amine 5%, Difenoconazole 5%, Diacloden 40%, NNO6%, pigment toner 3%, white carbon 5%, naphthalene sulfonate
Formaldehyde condensation products 4%, sodium lauryl sulphate 2%, bentonite complements to 100%.
Embodiment 9
Alkene oxime amine 5%, Difenoconazole 1%, Diacloden 45%, NNO5%, pigment toner 3%, white carbon 5%, sulfomethylated lignin
Acid sodium 3%, sodium lauryl sulphate 2%, kieselguhr complements to 100%.
Seed treatment suspending agent (FS)
According to recipe requirements, effective ingredient, wetting dispersing agent, emulsifying agent, thickening agent, alert toner, disperse medium etc. are mixed
Close, carry out high shear pre-dispersed, be subsequently adding in sand milling still, be ground to particle diameter less than 5 μm, can be prepared by seed treatment and hang
Floating agent.
Example 10 below-embodiment 15 is all carried out according to technique made above.
Embodiment 10
Alkene oxime amine 0.6%, Difenoconazole 3%, Diacloden 20%, Polyfon H(virtue Wei Shiweike company, hereafter go out
Now with herein) 2%, MF3%, BX pull open powder 2%, xanthan gum 0.06%, aluminium-magnesium silicate 0.5%, and dispersible pigment color paste 5%, water complements to 100%.
Embodiment 11
Alkene oxime amine 1%, Difenoconazole 5%, Diacloden 20%, Tersperse2700(Huntsman Corporation, appear below same
This chemical company of herein) 2%, YUS-FS3000(bamboo, appears below with the most herein) 2%, BX pulls open powder 2%, xanthan gum 0.02%, silicic acid
Magnalium 0.4%, dispersible pigment color paste 2%, water complements to 100%.
Embodiment 12
Alkene oxime amine 5%, Difenoconazole 1%, Diacloden 20%, GY-W10(Guang Yuanyi agriculture company, appear below with the most herein)
2%, YUS-FS3000 1%, NNO2%, xanthan gum 0.05%, aluminium-magnesium silicate 0.1%, dispersible pigment color paste 2%, water complements to 100%.
Embodiment 13
Alkene oxime amine 5%, Difenoconazole 1%, Diacloden 45%, Tersperse2700 2%, Morwet EFW(Aksu
Nobel company, appears below with the most herein) 1%, Morwet D425(Akzo Nobel N.V., appear below with the most herein) 1%,
Xanthan gum 0.04%, aluminium-magnesium silicate 0.09%, dispersible pigment color paste 4%, water complements to 100%.
Embodiment 14
Alkene oxime amine 9%, Difenoconazole 3%, Diacloden 20%, MF2%, SC209(Nanjing Ke Hong company, appear below same
Herein) 2%, SA-202%, xanthan gum 0.05%, aluminium-magnesium silicate 0.1%, dispersible pigment color paste 3%, water complements to 100%.
Embodiment 15
Alkene oxime amine 9%, Difenoconazole 3%, Diacloden 45%, Borresperse NA(Bao Lige company, appear below
With herein) 2%, BY125 2%, EL-80 2%, xanthan gum 0.03%, aluminium-magnesium silicate 0.07%, dispersible pigment color paste 3%, water complements to
100%。
Suspension seed-coating agent (FSC)
According to recipe requirements, effective ingredient, wetting dispersing agent, emulsifying agent, thickening agent, alert toner, film former, dispersion are situated between
Matter etc. mix, and carry out high shear pre-dispersed, are subsequently adding in sand milling still, are ground to particle diameter less than 5 μm, can be prepared by suspending
Seed coat agent.
Example 1 below 6-embodiment 39 is all carried out according to technique made above.
Embodiment 16
Alkene oxime amine 0.6%, Difenoconazole 0.6%, Diacloden 20%, (virtue Wei Shiweike company, hereafter goes out dispersant A
Now with herein) 1%, Morwet EFW1%, Morwet D4251%, 600#1%, xanthan gum 0.2%, aluminium-magnesium silicate 2%, pigment toner
2%, polyvinyl alcohol 2%, water complements to 100%.
Embodiment 17
Alkene oxime amine 0.6%, Difenoconazole 0.6%, Diacloden 40%, dispersant N3%, NNO2%, YUS-TXC(this change of bamboo
Work company, appears below with herein) 3%, AEO-9 2%, xanthan gum 0.1%, aluminium-magnesium silicate 1%, dispersible pigment color paste 4%, polyvinyl alcohol
3%, water complements to 100%.
Embodiment 18
Alkene oxime amine 0.6%, Difenoconazole 1.8%, Diacloden 20%, Borresperse NA2%, YUS-FS3000 3%,
OP-10 3%, xanthan gum 0.2%, aluminium-magnesium silicate 1%, pigment toner 2%, polyvinyl alcohol 2%, water complements to 100%.
Embodiment 19
Alkene oxime amine 0.6%, Difenoconazole 1.8%, Diacloden 42.6%, Ultrazine NA(Bao Lige company, hereafter
Occur with herein) 2%, YUS-FS3000 4%, 0201B2%, xanthan gum 0.05%, aluminium-magnesium silicate 0.5%, pigment toner 2%, poly-second
Enol 3%, water complements to 100%.
Embodiment 20
Alkene oxime amine 0.6%, Difenoconazole 1.8%, Diacloden 35%, Ultrazine NA2%, YUS-FS3000 3%,
1602# 2%, xanthan gum 0.1%, aluminium-magnesium silicate 1%, pigment toner 2%, polyvinyl alcohol 2%, water complements to 100%.
Embodiment 21
Alkene oxime amine 0.6%, Difenoconazole 1.8%, Diacloden 42.6%, Tersperse2700 2%, YUS-FS3000
2%, 1601# 2%, xanthan gum 0.05%, aluminium-magnesium silicate 0.5%, dispersible pigment color paste 4%, polyvinyl alcohol 2%, water complements to 100%.
Embodiment 22
Alkene oxime amine 0.6%, Difenoconazole 1.8%, Diacloden 25%, Morwet EFW2%, Morwet D425 1%,
YUS-FS3000 3%, 1602#2%, xanthan gum 0.05%, aluminium-magnesium silicate 0.5%, pigment toner 2%, polyvinyl alcohol 3%, water complements to
100%。
Embodiment 23
Alkene oxime amine 0.6%, Difenoconazole 1.8%, Diacloden 42.6%, Ultrazine NA2%, YUS-FS3000 2%,
EL-80 2%, xanthan gum 0.2%, aluminium-magnesium silicate 1%, dispersible pigment color paste 4%, polyvinyl alcohol 2%, water complements to 100%.
Embodiment 24
Alkene oxime amine 1%, Difenoconazole 1%, Diacloden 35%, Morwet EFW3%, Morwet D425 3%, YUS-
FS3000 5%, xanthan gum 0.05%, aluminium-magnesium silicate 0.5%, dyestuff 1%, polyvinyl alcohol 2%, water complements to 100%.
Embodiment 25
Alkene oxime amine 1%, Difenoconazole 1%, Diacloden 45%, Ultrazine NA2%, NNO2%, SC209 6%, 1601#
3%, xanthan gum 0.02%, aluminium-magnesium silicate 0.5%, dispersible pigment color paste 4%, polyvinyl alcohol 2%, water complements to 100%.
Embodiment 26
Alkene oxime amine 1%, Difenoconazole 3%, Diacloden 40%, Tersperse2700 2%, SP-SC3(hold up space in Nanjing
Work company, appears below with herein) 2%, EL-80 2%, xanthan gum 0.02%, aluminium-magnesium silicate 0.3%, pigment toner 2%, polyethylene
Alcohol 2%, water complements to 100%.
Embodiment 27
Alkene oxime amine 3%, Difenoconazole 9%, Diacloden 30%, GY-D07(Guang Yuanyi agriculture company, appear below with the most herein)
2%, YUS-FS3000 2%, OP-10 2%, xanthan gum 0.05%, aluminium-magnesium silicate 0.6%, pigment toner 2%, polyvinyl alcohol 3%, water is mended
Foot is to 100%.
Embodiment 28
Alkene oxime amine 3%, Difenoconazole 9%, Diacloden 35%, Ultrazine NA4%, YUS-FS3000 3%, AEO-3
1%, xanthan gum 0.05%, aluminium-magnesium silicate 0.4%, pigment toner 2%, polyvinyl alcohol 2%, water complements to 100%.
Embodiment 29
Alkene oxime amine 5%, Difenoconazole 5%, Diacloden 20%, Borresperse NA2%, Tersperse2700 2%,
700#1%, xanthan gum 0.1%, aluminium-magnesium silicate 0.5%, dispersible pigment color paste 5%, polyvinyl alcohol 2%, water complements to 100%.
Embodiment 30
Alkene oxime amine 5%, Difenoconazole 5%, Diacloden 30%, GY-D07 4%, Morwet EFW2%, Morwet D425
2%, BY125 1%, xanthan gum 0.12%, aluminium-magnesium silicate 0.4%, dyestuff 2%, polyvinyl alcohol 2%, water complements to 100%.
Embodiment 31
Alkene oxime amine 2%, Difenoconazole 10%, Diacloden 20%, Ultrazine NA2%, YUS-FS3000 2%, NP-10
1%, xanthan gum 0.05%, aluminium-magnesium silicate 0.8%, dispersible pigment color paste 6%, polyvinyl alcohol 2%, water complements to 100%.
Embodiment 32
Alkene oxime amine 10%, Difenoconazole 10%, Diacloden 35%, dispersant N(virtue Wei Shiweike company, appear below
With herein) 2%, Polyfon H2%, Span80 2%, xanthan gum 0.06%, aluminium-magnesium silicate 1%, pigment toner 2%, polyvinyl alcohol 3%,
Water complements to 100%.
Embodiment 33
Alkene oxime amine 5%, Difenoconazole 1%, Diacloden 20%, NNO2%, YUS-TXC3%, TX-10 1%, Tween80
2%, xanthan gum 0.04%, aluminium-magnesium silicate 0.5%, dispersible pigment color paste 4%, polyvinyl alcohol 3%, water complements to 100%.
Embodiment 34
Alkene oxime amine 5%, Difenoconazole 1%, Diacloden 35%, Tersperse2700 2%, SP-SC3 4%, 0201B
2%, xanthan gum 0.03%, aluminium-magnesium silicate 0.5%, pigment toner 2%, polyvinyl alcohol 2%, water complements to 100%.
Embodiment 35
Alkene oxime amine 1%, Difenoconazole 5%, Diacloden 35%, Ultrazine NA3%, YUS-FS3000 2%, 1601#
2%, xanthan gum 0.02%, aluminium-magnesium silicate 0.4%, pigment toner 3%, polyvinyl alcohol 2%, water complements to 100%.
Embodiment 36
Alkene oxime amine 3%, Difenoconazole 1%, Diacloden 45%, Ultrazine NA3%, YUS-FS3000 2%,
0201B1%, xanthan gum 0.03%, aluminium-magnesium silicate 0.5%, dyestuff 3%, polyvinyl alcohol 2%, water complements to 100%.
Embodiment 37
Alkene oxime amine 1.8%, Difenoconazole 0.6%, Diacloden 20%, Morwet EFW2%, Morwet D425 1%, SP-
SC3 2%, 0201B2%, xanthan gum 0.05%, aluminium-magnesium silicate 0.2%, dispersible pigment color paste 3%, polyvinyl alcohol 2%, water complements to 100%.
Embodiment 38
Alkene oxime amine 1.8%, Difenoconazole 0.6%, Diacloden 35%, Ultrazine NA2%, BX pull open powder 2%, SP-
SC3 1%, NP-10 1%, xanthan gum 0.04%, aluminium-magnesium silicate 0.3%, pigment toner 2%, polyvinyl alcohol 2%, water complements to 100%.
Embodiment 39
Alkene oxime amine 1.8%, Difenoconazole 0.6%, Diacloden 50%, NNO1%, Morwet EFW1%, Morwet D425
2%, YUS-TXC2%, xanthan gum 0.03%, aluminium-magnesium silicate 0.2%, dyestuff 2%, polyvinyl alcohol 3%, water complements to 100%.
Seed treatment microcapsule suspending agent (CF)
Effective ingredient is dissolved in xylene solvent, obtains homogeneous oil-phase solution；It is added thereto to containing emulsifying dispersant
Aqueous solution, with being stirred vigorously, make with the former medicine of solid, dimethylbenzene as oil phase, with the aqueous solution containing emulsifying dispersant be
Emulsion stablized by the O/W type of aqueous phase.The urea-formaldehyde prepolymer prepared in advance is added in emulsion, uses low content hydrochloric acid to adjust
, under acid catalysed conditions, there is polyreaction, make oil phase substance be wrapped, form microcapsule suspending agent in joint system pH value.To
This microcapsule suspending agent adds thickening agent, antifreeze, film former, alert toner, stirs, both obtained seed treatment microcapsule suspension
Agent.
Example 4 below 0-embodiment 42 is all carried out according to technique made above.
Embodiment 40
Alkene oxime amine 0.6%, Difenoconazole 0.6%, Diacloden 30%, Ultrazine NA1%, sodium polyacrylate 2%, poly-
Urea performed polymer 10%, styrene maleic anhydride copolymer 1%, dimethylbenzene 15%, hydrochloric acid 3%, sodium hydroxide 0.01%, xanthan gum
0.01%, dispersible pigment color paste 3%, polyvinyl alcohol 2%, water complements to 100%.
Embodiment 41
Alkene oxime amine 1%, Difenoconazole 1%, Diacloden 20%, Ultrazine NA2%, sodium polyacrylate 2.5%, polyureas
Performed polymer 8%, styrene maleic anhydride copolymer 1%, dimethylbenzene 10%, hydrochloric acid 3%, sodium hydroxide 0.01%, xanthan gum
0.01%, dispersible pigment color paste 3%, polyvinyl alcohol 2%, water complements to 100%.
Embodiment 42
Alkene oxime amine 1%, Difenoconazole 3%, Diacloden 25%, Ultrazine NA2%, sodium polyacrylate 3%, polyureas is pre-
Aggressiveness 10%, styrene maleic anhydride copolymer 2%, dimethylbenzene 12%, hydrochloric acid 3%, sodium hydroxide 0.01%, xanthan gum
0.01%, dispersible pigment color paste 3%, polyvinyl alcohol 2%, water complements to 100%.
Biological activity test embodiment
The comparison medicament mentioned in following biological activity test has:
30 grams per liter difenoconazole suspending seed-dressing agents, are purchased from Xian Zhengda crop science company limited；
600 grams per liter imidacloprid suspension seed-coating agents, are purchased from Bayer Cropscience (Chinese) company limited.
Embodiment 43 joint toxicity measuring
Contrast alkene oxime amine single dose, Difenoconazole single dose and the mixture co-toxicity effect to Rhizoctonia cerealis thereof.Root
Need to weigh medicament sample according to test, with acetone solution, make medicament mother solution；Aseptically preparation graded series medicinal liquid.
According to alkene oxime amine and Difenoconazole mixed synergies measurement result, different ratio selects two dosage, adds respectively
Enter Diacloden and be added without Diacloden and measure its fungistatic effect.
Use mycelial growth rate method.Whole operating process is carried out at aseptic condition, the culture medium cooling first will melted
To 60-70 DEG C, add quantitative graded series medicinal liquid, pour culture dish into, make the toxic culture medium containing different doses, treat that it fills
That inoculates diameter 0.5cm after dividing cooling supplies examination pathogen bacterium cake, cultivates (25 DEG C ± 1 DEG C) in placement incubator.
48h " Invest, Then Investigate " result of the test, measures colony diameter, is calculated as follows fungistatic effect.
The synergy type of two medicament difference mixed ratios is evaluated: calculate the different blended proportioning of mixture according to the abundant method of Sun Yun
The co-toxicity coefficient (CTC) of example, CTC<80 is antagonism, and 80≤CTC≤120 are summation action, and CTC>120 is potentiation.
Co-toxicity coefficient (CTC) is calculated as follows.
Wherein: ATI represents that mixture surveys toxicity index, and TTI represents mixture theory toxicity index.
Wherein: S represents the EC of standard agent50Theoretical value, M represents the EC of mixture50Theoretical value.
TTI=TIA×PA+TIB×PB
Wherein: TIARepresent A medicament actual measurement toxicity index, PARepresenting A medicament mass percent in mixture, unit is hundred
Divide rate (%), TIBRepresent B medicament actual measurement toxicity index, PBRepresenting B medicament mass percent in mixture, unit is percentage rate
(%).
Test result is shown in Tables 1 and 2.
Table 1 alkene oxime amine and the Difenoconazole mixture co-toxicity effect measurement result to Rhizoctonia cerealis
The impact on alkene oxime amine Yu Difenoconazole mixture bacteriostasis of table 2 Diacloden
Note: "+" represent that "-" represents without Diacloden containing Diacloden.
As can be seen from Table 1, alkene oxime amine, Difenoconazole mixture have significant fungistatic effect to Rhizoctonia cerealis,
Especially compared with Difenoconazole single dose, there is more excellent fungistatic effect.When alkene oxime amine and Difenoconazole mixture are 5:1
Time, its EC50Value (0.1088mg/L) and the EC of Difenoconazole single dose50Value (0.0925mg/L) is close；When alkene oxime amine and benzene
When ether methyl cyclic-azole mixture is 3:1, its EC50Value (0.0631mg/L) is less than the EC of Difenoconazole single dose50Value (0.0925mg/
L)；When alkene oxime amine and Difenoconazole mixture are 1:5, its EC50Value (0.0441mg/L) is significantly less than Difenoconazole list
The EC of agent50Value (0.0925mg/L)；When alkene oxime amine and Difenoconazole mixture are 1:1, its EC50Value (0.0286mg/L)
It is far smaller than the EC of Difenoconazole single dose50Value (0.0925mg/L)；When alkene oxime amine and Difenoconazole mixture are 1:3,
Its EC50Value (0.0242mg/L) is far smaller than the EC of Difenoconazole single dose50Value (0.0925mg/L)；Alkene oxime amine and phenylate
The co-toxicity coefficient of five proportioning mixtures (5:1,3:1,1:1,1:3,1:5) of methyl cyclic-azole is respectively 403.09,505.60,614.51,
501.42,249.06, all show as excellent potentiation.
As can be seen from Table 2, the bacteriostasis to alkene oxime amine Yu Difenoconazole mixture that adds of Diacloden does not has shadow
Ring.
Embodiment 44 prevents and treats the indoor biological preventive effect of wheat sharp eyespot
Seed-coating method
45% alkene benzene thiophene FSC-1#(embodiment 19), 2#(embodiment 21) with 3#(embodiment 23) with alkene oxime amine with
The total active ingredient of Difenoconazole calculates, and 1.8% Difenoconazole FSC and 0.9% alkene oxime amine FSC is respectively in terms of its active ingredient
Calculating, all medicaments are all provided with four dosage, respectively 180mg/kg, 90mg/kg, 75mg/kg, 60mg/kg；Need to claim according to test
Take in proper amount of medication addition wheat seed and be coated, dry standby.
Germination percentage assay method
Wheat seed and blank (not being coated process) the directly sowing of different seed coat agent Cotton seeds are being trained
Supporting in alms bowl, every alms bowl 12 seeds of sowing, often process 4 alms bowls, every alms bowl is a repetition, and the repeating of different disposal is divided into four district's groups,
Routine Management in greenhouse, emerges number respectively at 7 days " Invest, Then Investigate "s, is calculated as follows germination percentage, and carries out the Deng Kenshi significance of difference
Statistical analysis, the results are shown in Table 3.
The different alkene benzene thiophene FSC germination percentage measurement result to wheat seed treatment of table 3
As can be seen from Table 3, the alkene oxime amine of per kilogram seed and the effective content of Difenoconazole are at 60mg to 180mg
Between time, germination percentage is all more than 93%, and after coating, the germination percentage of seed has a certain degree of decline compared with blank, is
General knowledge known to this professional field personnel.The capsuled seed of the present invention difference compared with blank germination percentage within 5%, and
Average germination percentage, more than 90%, can normally be germinateed after all this seed pelleting can being described.Therefore, data above three kinds of samples are known
To wheat seed safety after product coating.
To wheat sharp eyespot efficiency test
Use greenhouse pot culture method.Soil is mixed homogeneously with the part by weight of 10:1 with rhizoctonia cerealis, sows,
7 days " Invest, Then Investigate "s manage germination percentage, every alms bowl 15 seeds of sowing everywhere, calculate sickness rate and prevention effect according to following formula, and carry out Duncan
Family name's significance of difference statistical analysis, the results are shown in Table 4.
Sickness rate (%)=100-germination percentage
The different alkene benzene thiophene FSC of table 4 is to wheat sharp eyespot prevention effect
As can be seen from Table 4, different alkene benzene thiophene suspension seed-coating agents carry out seed pelleting to wheat sharp eyespot to Semen Tritici aestivi
Having good prevention effect, its prevention effect is superior to alkene oxime amine single dose and Difenoconazole single dose.
Embodiment 45 indoor insecticidal activity test
The germination impact of capsuled seed
Processing method
45% alkene benzene thiophene FSC-1#(embodiment 19), 2#(embodiment 21) with Diacloden active ingredient calculate, compare medicine
Agent is 600 grams per liter imidacloprid suspension seed-coating agents, calculates with its imidacloprid active ingredient (being approximately equivalent to the mass percent of 50%),
All medicaments are all provided with four dosage, respectively 14.2g/kg, 7.1g/kg, 5.3g/kg, 3.5g/kg, weigh little with electronic balance
Wheat Seeds, 100 grams every part, then reagent agent is accurately weighed with electronic analytical balance, it is coated by above-mentioned dosage, after process
Seed dries in the shade naturally.Four dosage choose the wheat seed 30 of coating respectively, and embryo is placed in the culture dish being placed with filter paper upward
In, if three times are repeated, separately set blank.In illumination box, moisturizing is cultivated.
Investigation computational methods
1-5 days routine observations after wheat seed process, record chitting piece number, within 5 days, calculate germination percentage.
Subnumber × 100 are planted experimentally in the chitting piece number/confession of germination percentage (%)=in test fixed date in latter stage
The capsuled seed impact on plant shoots quality
Processing method
Choose the wheat seed 30 that Cotton seeds is good, potted plant sowing, if three times are repeated, separately set blank, put
It is placed in greenhouse cultivation.
Investigation computational methods
Wheat seed after planting 6 days, calculates emergence rate, the results are shown in Table 5.
Subnumber × 100 are planted experimentally in the chitting piece number/confession of emergence rate (%)=in test fixed date at initial stage
Table 5 capsuled seed germinates and the measurement result of plant shoots quality influence
As can be seen from Table 5, reagent agent is under four dosage, and after coating, seed is to germinating energy, germination percentage and emergence rate
All without impact.
Insecticidal activity is tested
Processing method
45% alkene benzene thiophene FSC-1#(embodiment 19), 2#(embodiment 21) with Diacloden active ingredient calculate, compare medicine
Agent is 600 grams per liter imidacloprid suspension seed-coating agents, calculates with imidacloprid active ingredient (being approximately equivalent to the mass percent of 50%), institute
There is medicament to be all provided with four dosage, respectively 4.26g/kg, 2.84g/kg, 2.13g/kg, 1.06g/kg, weigh with electronic balance little
Wheat Seeds, 100 grams every part, then reagent agent is accurately weighed with electronic analytical balance, it is coated by above-mentioned dosage, after process
Seed dries in the shade naturally.
Choose the wheat seed 60 that Cotton seeds is good, potted plant sowing, be positioned in greenhouse cultivation.Emerge plant
Within latter 4 days and 8 days, carry out the test of pesticide effectiveness.Concrete processing method is as follows, cotten aphid, black bean aphid: by different disposal, switching examination on seedling
Worm about 40, investigates radix；Beet armyworm, mythimna separata: by different disposal, seedling leaves cut, be positioned in culture dish, turns
Connect 3 instar larvae 10, if three times are repeated.
Investigation and statistical method
Cotten aphid, black bean aphid: the seedling after processing, be positioned over greenhouse and continue to cultivate, reinvestigate borer population alive after connecing worm 2 days,
And calculate mortality rate；Beet armyworm, mythimna separata: be positioned in the observation ward of certain condition by culture dish, connect 3 days dead worms of " Invest, Then Investigate " of worm
Number, and calculate mortality rate, the results are shown in Table 6.
Table 6 insecticidal activity assay result
As can be seen from Table 6, two groups of reagent agents, the parasite killing under four dosage, to cotten aphid, beet armyworm and mythimna separata
Activity is superior to compare medicament, and the insecticidal activity of black bean aphid slightly below compares medicament, but with compare under medicament Isodose,
Insecticidal activity is basic with to compare medicament fair, illustrates that two groups of reagent agents are excellent to cotten aphid, beet armyworm and mythimna separata insecticidal activity
Good, black bean aphid is had preferable insecticidal activity.
Embodiment 46 field control effectiveness test
The pest and disease damage test of preventing and treating Semen Tritici aestivi field
Processing method
45% alkene benzene thiophene FSC-1#(embodiment 19) divide with insecticide active ingredient with antibacterial when carrying out seed pelleting
Not calculating, wherein antibacterial calculates with alkene oxime amine, Difenoconazole effective ingredient sum, and insecticide is with Diacloden effective ingredient
Calculate.Comparison medicament is respectively 30 grams per liter difenoconazole suspending seed-dressing agents and 600 grams per liter imidacloprid suspension seed-coating agents, for examination
Medicament sets two dosage, be respectively with antibacterial Rapid Dose Calculation as 196mg/kg, 98mg/kg, with insecticide Rapid Dose Calculation be
3.49g/kg、1.75g/kg.Being coated by above-mentioned dosage, the seed after process dries in the shade naturally.
Test site selects at two:
Test site one: carry out in great Gong building, Kong Zhuan township, Xiayi County, Shangqiu, the Henan flat wheat paddock of village Lu Wei；
Test site two: carry out in great Gong building, Kong Zhuan township, Xiayi County, Shangqiu, the Henan flat wheat paddock of village Lu Wei.
It is experimental field sandy loam, stubble after Semen arachidis hypogaeae, use compound fertilizer's 50kg/ mu.During sowing, soil moisture content is slightly worse, every mu of anticipated sowing
30kg, line-spacing 20cm.
The preventive effect of wheat sharp eyespot is investigated
Investigate each process community diseased plant quantity mid-term in grouting, and calculate diseased plant rate and preventive effect, the results are shown in Table 7.
Table 7 alkene benzene thiophene suspension seed-coating agent anti-banded sclerotial blight result of the test statistical analysis table
As can be seen from Table 7, reagent agent is excellent to the preventive effect of wheat sharp eyespot, with to compare dosing close
Under 196.8mg/kg dosage, the preventive effect in two places is superior to compare medicament, when low dosage 98.4mg/kg, to banded sclerotial blight also
There is certain preventive and therapeutic effect.
The preventive effect of wheat aphid and subterranean pest-insect is investigated
Aphid is investigated: carrying out 1 field investigation in after planting 200 days, investigation content is each process community Aphed population, and
Calculate hundred strains or hundred fringe aphid amount and preventive effects；
Subterranean pest-insect was investigated: carried out 1 investigation in after planting 145 days, digs Seedling at random by 5, each treatment region " Z " type and adjusts
Looking into, each point shoveling 50cm × 50cm × 30cm, investigation wheat soil pest is caused harm wheat strain quantity, and calculates the attacked trees rate of Semen Tritici aestivi
And preventive effect, the results are shown in Table 8.
Table 8 alkene benzene thiophene suspension seed-coating agent is to aphid and subterranean pest-insect preventive effect result statistical analysis table
As can be seen from Table 8, under the 3.49g/kg dosage close with compareing dosing, right with place two in place one
The preventive effect of aphid with to compare medicament suitable, a pair subterranean pest-insect in place preventive effect with compare medicament quite, in place two over the ground
The preventive effect of lower insect slightly below compares medicament；Under relatively low-dose 1.75g/kg, in place one and the place two preventive effect to aphid
All more than 90%, to the preventive effect of subterranean pest-insect all more than 80%.Data above explanation invention formulation when big Tanaka applies,
Aphid is had preferable preventive effect, subterranean pest-insect is had certain preventive effect.
Claims (9)
1. a pesticide seed treatment, it is characterised in that: the effective ingredient in this pesticide seed treatment is containing alkene oxime amine
Insecticidal and bactericidal composition, insecticidal and bactericidal composition is antibacterial and insecticide, specially alkene oxime amine (A), Difenoconazole
(B) and Diacloden (C) is the ternary built of effective ingredient, the weight percentage of its effective ingredient is 0.9%～90%；
Described antibacterial and insecticide are calculated as 1:100～100:1 by weight；Described alkene oxime amine (A) and Difenoconazole (B)
It is calculated as 1:10～10:1 by weight.
Pesticide seed treatment the most according to claim 1, it is characterised in that described antibacterial and insecticide are by weight
It is calculated as 1:50～10:1；Described alkene oxime amine (A) and Difenoconazole (B) are calculated as 1:5～5:1 by weight.
Pesticide seed treatment the most according to claim 1, it is characterised in that: the effective one-tenth in this pesticide seed treatment
The weight percentage divided is 21%～70%.
Pesticide seed treatment the most according to claim 1, it is characterised in that: each component of pesticide seed treatment and weight
Percentage composition is as follows: alkene oxime amine 0.2～20%, Difenoconazole 0.2～20%, Diacloden 0.5～50%, auxiliary agent 3～
40%, carrier or disperse medium 20～90%.
Pesticide seed treatment the most according to claim 4, it is characterised in that: each composition weight of pesticide seed treatment hundred
Point content is alkene oxime amine 0.5～10%, Difenoconazole 0.5～10%, Diacloden 20～50%, auxiliary agent 5～25%, carrier
Or disperse medium 30～70%.
Pesticide seed treatment the most according to claim 1, it is characterised in that: the dosage form of described pesticide seed treatment can
Be prepared as seed treatment dry powder doses, seed treatment dispersibles powder, seed treatment suspending agent, suspension seed-coating agent or seed treatment micro-
Capsule suspending agent.
7. according to the pesticide seed treatment described in claim 4 or 5, it is characterised in that: described auxiliary agent be wetting dispersing agent,
One or more in emulsifying agent, polymerization monomer, film former, thickening agent, alert toner.
8. the pesticide seed treatment described in a claim 1 is for preventing and treating the application in plant disease pest/pathogenic bacteria evil.
Pesticide seed treatment the most according to claim 8 is for preventing and treating the application in plant disease pest/pathogenic bacteria evil, its feature
Being, the weight percentage of insecticidal and bactericidal composition is 21%～70%.
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| CN109601538A (en) * | 2018-12-10 | 2019-04-12 | 沈阳化工大学 | A kind of pesticide seed treatment containing alkene oxime amine |
| CN112823629B (en) * | 2019-11-21 | 2022-08-02 | 沈阳中化农药化工研发有限公司 | Seed treatment agent containing bisamide compounds and application thereof |
| CN112823628B (en) * | 2019-11-21 | 2022-06-07 | 沈阳中化农药化工研发有限公司 | Seed treatment agent containing active component of alkene oxime amine and application thereof |
| CN114847298A (en) * | 2022-05-19 | 2022-08-05 | 江苏艾津作物科技集团有限公司 | Seed treatment suspending agent containing thiamethoxam |
| CN116391718B (en) * | 2023-03-31 | 2024-06-11 | 沈阳中化农药化工研发有限公司 | Liquid sterilization preparation containing enestroburin and application thereof |
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| CN1596644A (en) * | 2003-09-19 | 2005-03-23 | 沈阳化工研究院 | Bacteridal composition containing alkene oxime amine and triazole kind compound |
| CN102197818A (en) * | 2010-03-22 | 2011-09-28 | 中国中化股份有限公司 | Bactericidal composition |
| CN102204542A (en) * | 2011-04-14 | 2011-10-05 | 陕西汤普森生物科技有限公司 | Bactericidal composition containing enostroburin and triazole compound |
| CN102308838A (en) * | 2011-09-28 | 2012-01-11 | 联保作物科技有限公司 | Flowable concentrate for seed coating for insecticidal purpose and disease prevention |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1596644A (en) * | 2003-09-19 | 2005-03-23 | 沈阳化工研究院 | Bacteridal composition containing alkene oxime amine and triazole kind compound |
| CN102197818A (en) * | 2010-03-22 | 2011-09-28 | 中国中化股份有限公司 | Bactericidal composition |
| CN102204542A (en) * | 2011-04-14 | 2011-10-05 | 陕西汤普森生物科技有限公司 | Bactericidal composition containing enostroburin and triazole compound |
| CN102308838A (en) * | 2011-09-28 | 2012-01-11 | 联保作物科技有限公司 | Flowable concentrate for seed coating for insecticidal purpose and disease prevention |
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Effective date of registration: 20160115 Address after: 110021 Liaodong Road, Tiexi District, Liaoning, No. 8-1, No. Applicant after: SHENYANG SINOCHEM AGROCHEMICALS R&D Co.,Ltd. Address before: 100031 Beijing, Xicheng District, the door of the revitalization of the main street, No. 28 Applicant before: SINOCHEM Corp. Applicant before: SHENYANG RESEARCH INSTITUTE OF CHEMICAL INDUSTRY Co.,Ltd. |
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Effective date of registration: 20240715 Address after: 110021 Shenyang Liaodong Road, Tiexi District, Shenyang, Liaoning 8-1 Patentee after: SHENYANG SINOCHEM AGROCHEMICALS R&D Co.,Ltd. Country or region after: China Patentee after: JIANGSU YANGNONG CHEMICAL Co.,Ltd. Address before: 110021 Shenyang Liaodong Road, Tiexi District, Shenyang, Liaoning 8-1 Patentee before: SHENYANG SINOCHEM AGROCHEMICALS R&D Co.,Ltd. Country or region before: China |
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