CN104327554A - Electric heating paint - Google Patents

Electric heating paint Download PDF

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Publication number
CN104327554A
CN104327554A CN201410664921.8A CN201410664921A CN104327554A CN 104327554 A CN104327554 A CN 104327554A CN 201410664921 A CN201410664921 A CN 201410664921A CN 104327554 A CN104327554 A CN 104327554A
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China
Prior art keywords
oxide
kilograms
raw material
percentage
weight
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Pending
Application number
CN201410664921.8A
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Chinese (zh)
Inventor
李元杰
谭立春
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WEIHAI EAST RED NEW MATERIAL CO Ltd
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WEIHAI EAST RED NEW MATERIAL CO Ltd
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Priority to CN201410664921.8A priority Critical patent/CN104327554A/en
Publication of CN104327554A publication Critical patent/CN104327554A/en
Pending legal-status Critical Current

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Abstract

The invention relates to the field of paint compositions and particularly relates to electric heating paint. The electric heating paint is prepared from the following raw materials in percentage by weight: 40-60% of metal oxides, 5-2% of nonmetal oxides, 5-20% of organic semiconductor materials and 5-20% of high-molecular polymer; the metal oxides consist of the following raw materials in percentage by weight: 20-40% of tin dioxide, 5-20% of antimony pentoxide, 5-10% of cobaltosic oxide, 5-35% of aluminium oxide, 5-15% of zinc oxide, 5-10% of barium oxide, 5-10% of yttrium oxide, 0-20% of zirconium oxide and 5-10% of lithium oxide; the nonmetal oxides consist of the following raw materials in percentage by weight: 10-30% of boron oxide, 30-50% of silicon dioxide and 20-40% of tellurium dioxide; the organic semiconductor materials consist of the following raw materials in percentage by weight: 10-90% of polyaniline and 10-90% of polypyrrole; and the high-molecular polymer consists of the following raw materials in percentage by weight: 10-90% of poly(propionitrile) and 10-90% of polyamide.

Description

Electric-heating coatings
Technical field
The present invention relates to coating composition field, specifically the electric-heating coatings that combines of a kind of metal oxide and nonmetal oxide and organic semiconductor and high molecular polymer.
 
Background technology
As everyone knows, existing Electric radiant Heating Film, it is mainly by the semi-conductor conductive powder of Graphite Powder 99 and plumbous oxide, silicon oxide, gasification magnesium, silicon oxide, the inorganic membrane-forming agent of boron oxide many oxide and metal powder and water-miscible organic solvent mutual blend composition one electrically conducting coating, by semi-conductor electrically conducting coating appropriate for modulation, with spraying or printing treatment, directly electrically conducting coating is sprayed to through cleaning, drying wellhandled dielectric surface, baking again through high temperature is dried, and through high temperature around knot process, Electric radiant Heating Film raw material is made to form the microcosmic energising network of overlap joint in the surface of medium, for consistent heat generation.Though the electrothermal film technology of prior art has the effect of heating, the shortcoming that its tool is following: 1, the electrothermal film technology of prior art, it is the Electric radiant Heating Film that a thickness is very thick, and therefore, its thermal source produces the similar linear conduction of heat, therefore its heating efficiency is not good.2, the electrothermal film technology of prior art only can be used in non-conductive class and resistant to elevated temperatures medium as pottery and glass, therefore, its use range is restricted and cannot be used in the surface of the high high conduction metal species medium of heat conduction efficiency.3, the electrothermal film technology of prior art uses 220v power supply, and heating exists potential safety hazard.4, the electrothermal film technology power of prior art has decay, affects work-ing life.
 
Summary of the invention
Object of the present invention is exactly that provide a kind of electric-heating coatings, electric heating conversion efficiency is high in order to overcome above-mentioned the deficiencies in the prior art, and rate of heating is fast, long service life.
The technical scheme that the present invention solves the problems of the technologies described above employing is: a kind of electric-heating coatings, it is characterized in that being made up of the raw material of following weight percent, metal oxide 40-60%, nonmetal oxide 5-2%, organic semiconductor material 5-20%, high molecular polymer 5-20%; Described metal oxide is made up of the raw material of following weight percent, tindioxide 20 ~ 40%, antimony peroxide 5 ~ 20%, tricobalt tetroxide 5 ~ 10%, aluminium sesquioxide 5 ~ 35%, zinc oxide 5 ~ 15%, barium oxide 5 ~ 10%, yttrium oxide 5 ~ 10%, zirconium white 0 ~ 20%, Lithium Oxide 98min 5 ~ 10%; Described nonmetal oxide is made up of the raw material of following weight percent, boron oxide 10 ~ 30%, silicon-dioxide 30 ~ 50%, tellurium dioxide 20 ~ 40%; Described organic semiconductor material is made up of the raw material of following weight percent, polyaniline 10 ~ 90%, polypyrrole 10 ~ 90%; Described high molecular polymer is made up of the raw material of following weight percent, poly-third cyanogen 10 ~ 90%, polymeric amide 10 ~ 90%.Above raw material is stirred 10-30 minute in agitator, and temperature controls, at 80-180 DEG C, to obtain this product.
The invention has the beneficial effects as follows, electro-thermal coatings is very thin, and electric heating conversion efficiency is high, and rate of heating is fast, reaches the effect of saving the energy.Conduction bands place is not oxidized, and do not burn during heating oxygen.Radiation infrared energy.Use 6-380v power supply, available below 36v voltage of warming oneself, safety performance is high.Electric radiant Heating Film can reach 30-600 DEG C of temperature.Nanometer plane is generated heat, undamped, long service life.
 
Embodiment
Below in conjunction with embodiment, the invention will be further described:
Embodiment one:
The present embodiment raw material gross weight is 1000 kilograms, wherein tindioxide 150 kilograms, antimony peroxide 60 kilograms, tricobalt tetroxide 30 kilograms, aluminium sesquioxide 30 kilograms, 40 kilograms, zinc oxide, 40 kilograms, barium oxide, yttrium oxide 50 kilograms, zirconium dioxide 60 kilograms, Lithium Oxide 98min 40 kilograms; Boron oxide 50 kilograms, silica 1 00 kilogram, tellurium dioxide 50 kilograms; Polyaniline 75 kilograms, polypyrrole 75 kilograms, poly-75 kilograms, third cyanogen, polymeric amide 75 kilograms.First addition polymerization third cyanogen in agitator, polymeric amide, be warming up to 80-180 DEG C of solubilizing reaction, add polyaniline again, polypyrrole, tindioxide, antimony peroxide, tricobalt tetroxide, aluminium sesquioxide, zinc oxide, barium oxide, yttrium oxide, zirconium dioxide, Lithium Oxide 98min, boron oxide, silicon-dioxide, tellurium dioxide, stirs 10 ~ 30 minutes to obtain product.
Embodiment two:
The present embodiment raw material gross weight is 1000 kilograms, wherein tindioxide 200 kilograms, antimony peroxide double centner, tricobalt tetroxide 50 kilograms, aluminium sesquioxide 50 kilograms, 40 kilograms, zinc oxide, 40 kilograms, barium oxide, yttrium oxide 20 kilograms, Lithium Oxide 98min 50 kilograms; Boron oxide 40 kilograms, silica 1 00 kilogram, tellurium dioxide 60 kilograms; Polyaniline 50 kilograms, polypyrrole 50 kilograms, poly-75 kilograms, third cyanogen, polymeric amide 75 kilograms.First addition polymerization third cyanogen in agitator, polymeric amide, is warming up to 80-180 DEG C of solubilizing reaction, then adds polyaniline, polypyrrole, tindioxide, antimony peroxide, tricobalt tetroxide, aluminium sesquioxide, zinc oxide, barium oxide, yttrium oxide, Lithium Oxide 98min; Boron oxide, silicon-dioxide, tellurium dioxide, stirs 10 ~ 30 minutes to obtain product.

Claims (1)

1. an electric-heating coatings, is characterized in that being made up of the raw material of following weight percent, metal oxide 40-60%, nonmetal oxide 5-2%, organic semiconductor material 5-20%, high molecular polymer 5-20%; Described metal oxide is made up of the raw material of following weight percent, tindioxide 20 ~ 40%, antimony peroxide 5 ~ 20%, tricobalt tetroxide 5 ~ 10%, aluminium sesquioxide 5 ~ 35%, zinc oxide 5 ~ 15%, barium oxide 5 ~ 10%, yttrium oxide 5 ~ 10%, zirconium white 0 ~ 20%, Lithium Oxide 98min 5 ~ 10%; Described nonmetal oxide is made up of the raw material of following weight percent, boron oxide 10 ~ 30%, silicon-dioxide 30 ~ 50%, tellurium dioxide 20 ~ 40%; Described organic semiconductor material is made up of the raw material of following weight percent, polyaniline 10 ~ 90%, polypyrrole 10 ~ 90%; Described high molecular polymer is made up of the raw material of following weight percent, poly-third cyanogen 10 ~ 90%, polymeric amide 10 ~ 90%.
CN201410664921.8A 2014-11-20 2014-11-20 Electric heating paint Pending CN104327554A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410664921.8A CN104327554A (en) 2014-11-20 2014-11-20 Electric heating paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410664921.8A CN104327554A (en) 2014-11-20 2014-11-20 Electric heating paint

Publications (1)

Publication Number Publication Date
CN104327554A true CN104327554A (en) 2015-02-04

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410664921.8A Pending CN104327554A (en) 2014-11-20 2014-11-20 Electric heating paint

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CN (1) CN104327554A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106085211A (en) * 2016-06-16 2016-11-09 汤海涛 A kind of Graphene electric-heating coatings
CN107382087A (en) * 2017-07-24 2017-11-24 太仓市双凤镇薄彩工艺品厂 A kind of electrically conductive coloured glaze
CN107641846A (en) * 2016-07-20 2018-01-30 深圳东睦科技发展有限公司 A kind of nano superconductive fiber
CN108003701A (en) * 2017-12-16 2018-05-08 深圳埃法智能科技有限公司 A kind of far infrared heat conduction slurry and its preparation method and application
CN109913075A (en) * 2019-03-29 2019-06-21 秾源科技(北京)有限公司 A kind of electric-heating coatings and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1069384A (en) * 1991-08-03 1993-02-24 尹维平 A kind of novel thick film electric heating body and preparation method
CN1136263A (en) * 1996-03-12 1996-11-20 尹维平 Inorganic oxide electric heating film and the manufacture thereof
US6176918B1 (en) * 1996-09-27 2001-01-23 Merck Patent Gesellschaft Mit Beschrankter Haftung And Huels Ag Modified nacreous luster pigments for water paint systems
CN1402766A (en) * 1999-12-04 2003-03-12 纳幕尔杜邦公司 Antistatic powder coating compositions and their use
CN103533681A (en) * 2013-10-25 2014-01-22 天津市旺东新材料研发有限公司 Electrothermal film and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1069384A (en) * 1991-08-03 1993-02-24 尹维平 A kind of novel thick film electric heating body and preparation method
CN1136263A (en) * 1996-03-12 1996-11-20 尹维平 Inorganic oxide electric heating film and the manufacture thereof
US6176918B1 (en) * 1996-09-27 2001-01-23 Merck Patent Gesellschaft Mit Beschrankter Haftung And Huels Ag Modified nacreous luster pigments for water paint systems
CN1402766A (en) * 1999-12-04 2003-03-12 纳幕尔杜邦公司 Antistatic powder coating compositions and their use
CN103533681A (en) * 2013-10-25 2014-01-22 天津市旺东新材料研发有限公司 Electrothermal film and preparation method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106085211A (en) * 2016-06-16 2016-11-09 汤海涛 A kind of Graphene electric-heating coatings
CN107641846A (en) * 2016-07-20 2018-01-30 深圳东睦科技发展有限公司 A kind of nano superconductive fiber
CN107382087A (en) * 2017-07-24 2017-11-24 太仓市双凤镇薄彩工艺品厂 A kind of electrically conductive coloured glaze
CN108003701A (en) * 2017-12-16 2018-05-08 深圳埃法智能科技有限公司 A kind of far infrared heat conduction slurry and its preparation method and application
CN109913075A (en) * 2019-03-29 2019-06-21 秾源科技(北京)有限公司 A kind of electric-heating coatings and preparation method thereof

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