CN1043261C - Natrual silk fibres and method for refining fabrics made from such fibres - Google Patents
Natrual silk fibres and method for refining fabrics made from such fibres Download PDFInfo
- Publication number
- CN1043261C CN1043261C CN90102144A CN90102144A CN1043261C CN 1043261 C CN1043261 C CN 1043261C CN 90102144 A CN90102144 A CN 90102144A CN 90102144 A CN90102144 A CN 90102144A CN 1043261 C CN1043261 C CN 1043261C
- Authority
- CN
- China
- Prior art keywords
- silk
- concise
- silk gum
- acid
- scouring agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Images
Landscapes
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
To homogeneously degum silk filaments with excellent reproducibility in a short without deteriorating fibroin by utilizing composite effects of an alkaline buffer solution containing an alkali metal salt of a polybasic acid having a specific dissociation constant and a prescribed acid with calcium hydroxide, etc. Silk filaments are degummed utilizing composite effects of an alkaline buffer solution, prepared by adding an alkali metal salt of a polybasic acid (e.g. potassium or sodium borate) having a dissociation constant within the range of 6-10 and an acid, such as boric acid, and having buffering within a suitable pH region with calcium hydroxide, barium hydroxide or a mixture thereof. The above-mentioned buffer solution and one selected from sodium carbonate, sodium bicarbonate, sodium silicate, sodium borate and potassium salts thereof and a cationic surfactant are used in combination for wild silk and colored raw silk, etc., to carry out degumming. Thereby, the homogeneous degumming is performed by suitably controlling the residual amount of sericin according to the use of the silk in a short time with excellent reproducibility without deteriorating fibroin.
Description
The method for refining of relevant silk fiber of the present invention and fabric thereof.
The raw silk of filature gained in being spun by silkworm and wild silkworm (giant silkworm, tussah etc.), close (sth.s made by twisting) silk (below, all be called silk fiber) and silk fabrics thereof, up to now, all be, and be processed to the silk of softness by concise removal silk gum.Figure 1 shows that and put the dog cross section perpendicular to cocoon length filament length degree direction.Cocoon length silk structure is: by the scleroprotein plastid that fibroin is formed, and its topped other kind of protein of forming by silk gum in outside.Remove this silk gum selectively, with the technology of the original characteristic of performance silk, promptly concise technology.At this moment, preferably keep the innermost layer silk gum that contacts with fibroin and exist.
As not having innermost layer silk gum, fibroin directly is subjected to the influence of the concise liquid of thermokalite, then not only in the fibre structure of fibroin tangible deterioration part can take place, its intensity, elongation lowers, and has filoplume to generate on the silk, elasticity disappears, and is obviously reduced by promptly visible its grade of outward appearance.
In the present concise technology, used with textile soap, sodium bicarbonate, sodium carbonate, sodium metasilicate etc. are the concise medicament of host.These are strong basicity with agent, concise liquid pH10.5～11.5.That is, in this pH codomain, it is irreversible participating in the basic ion of reaction and the reaction of coming unstuck between the silk gum, and silk gum is removed more up hill and dale, and then also makes the reaction of fibroin deterioration simultaneously.
Its result causes tangible grade to reduce, and creasing easily, and is not wear-resisting, and the evaluation that should not carry out machine-washing etc. is considered to the characteristics of silk.
In existing concise technology, concise raw silk is given birth to the fabric required time, and the difference of criticizing according to its place of production and cocoon then differs more than two times sometimes.Therefore, at concise scene, be always by rule of thumb, the concise condition of sensation control.In addition, at concise raw silk, when giving birth to fabric, for preventing finish, come unstuck and remove the adhesion once again of thing, and suitably use fatty acid soaps (anion surfactant), anion surfactant, non-ionic surface active agent.
Because these surfactants without exception, have all shown the effect that promotion is come unstuck, and give the character of silk surface with close ACID DYES, therefore, can't catch silk with the pigment of the ejusdem generis coloured raw silk of basic-dyeable fibre tool.But, to be processed into white silk for need but be necessary function to this not dying property.
In the silkworm, have and can make Huang, red, the green silkworm of waiting colored cocoon.From this type of look cocoon, can obtain the beautiful raw silk of tool natural colouring matter.But in the former concise operation, pigment will lose jointly with silk gum, thereby, can't utilize natural colouring matter.Especially, exploitation can keep the method for refining of giant silkworm raw silk fresh green, is relevant person's hope for a long time always.
The objective of the invention is: by making concise progress homogenising, and when shortening the operation required time, strengthen coming unstuck function selectively, can reproduce required product preferably to provide, and the more large-duty method of tool; And then provide the method for refining of the pigment that keeps giant silkworm and coloured raw silk etc.
The present invention relates to the complex effect of utilizing scouring agent and calcium ion, barium ions and hybrid ionic thereof, silk fiber and fabric thereof are made the method for refining processing.Above-mentioned scouring agent is by containing the alkali metal salt that dissociation constant (pka) is about the polyacid in the 6-10 scope, and institute decides sour alkaline buffer and forms.
In addition, the present invention also provides the complex effect of utilizing scouring agent and calcium ion, barium ions and hybrid ionic thereof, carries out mixing cationic surfactant simultaneously when concise, with the method for refining of the pigment of the silk fiber that keeps giant silkworm and coloured silkworm and fabric thereof.Above-mentioned scouring agent is by containing the alkali metal salt that dissociation constant (pka) is about the polyacid in 6～10 scopes, and institute decides sour alkaline buffer and forms.
Below, the action effect of concise host is described in detail in detail.
Fig. 2 is the amplification diagram of two kinds of representational different silk kinds A portions in Fig. 1.Generally, on the long filament outer surface, there are 4 kinds of silk gum to exist with stratiform.1. they be called (from the outside) silk gum, silk gum 2., 4. 3. silk gum reach silk gum.In addition, silk gum 1. and silk gum have between 2. this mixed layer of two layers to exist.1. and the mixed layer 2. in concise, what must remove fully is exactly that 1. layer and silk gum for silk gum.
As using above-mentioned scouring agent of the present invention (alkaline buffer), the chemical reaction in coming unstuck is just no longer as before for irreversible, and at as shown in Figure 2 silk gum layer 2., or root a tree name needs, at the silk gum layer 4., reversible chemical balance takes place selectively, so, the stopping of reaction of coming unstuck.That is, at the silk gum layer 2., 3. the silk gum layer reaches the silk gum layer and 4. goes up, and can suitably control the silk gum residual quantity according to the purposes of silk.
Used scouring agent is the basic ion supply source with binary or the ternary acid of the about 6-10 of dissociation constant (pka) among the present invention.As one of dissociation constant is near the sylvite (dipotassium tetraborate) of the boric acid of 9.2 (pka), or sodium salt (sodium tetraborate) etc., and by adding regulation acid thereon, make it in suitable pH value is regional (in other words, make the specific pH corresponding to concise purpose, tool resiliency) carry out purifying reaction.At this moment, again calcium ion, barium ions or its hybrid ionic and silk gum layer 2. or the silk gum layer 3., or the silk gum layer forms complex between 4., improves the hot water resistance of silk greatly, and it can selectively be come unstuck more accurately.
Below, the alkaline buffer that is used as scouring agent among the present invention is described in detail in detail.Mixing ratio as dipotassium tetraborate and boric acid is 10: 3.At this moment, 1. reach 1. and mixed layer 2. for the silk gum layer, concise being carried out, but to the silk gum layer 2., 4. 3. the silk gum layer reach the silk gum layer, then produces chemical balance instead would not be taken place by coming unstuck of participating in of basic ion.1. and the mixed layer 2. its result is concise to remove the silk gum layer and 1. reaches the silk gum layer, and the silk gum layer 2., and 3. the silk gum layer reaches the silk gum layer and 4. can stay.When using sodium tetraborate, the mixing ratio of sodium tetraborate and boric acid is 10: 12, can get same scouring result.
Equally, the mixing ratio of sodium tetraborate and boric acid is 10: 12 o'clock, from the silk gum layer 1. to the reaction of can coming unstuck till 2. of silk gum layer, and to the silk gum layer 3. with the silk gum layer 4., as sylvite reacting field unification sample chemical balance can take place, and can not carry out the reaction of coming unstuck by the basic ion participation.Therefore, this occasion can keep the silk gum layer and 3. reach 4. concise of silk gum.
Silicic acid and boric acid are similar, and the one dissociation constant remains near 9.7 (pka), can make it to become and the similar scouring agent of boric acid.Disodium hydrogen phosphate also can be used as the basic ion supply source, is used for of the present invention concise.
Summarize spendable scouring agent among the present invention, can exemplify as follows:
No. 1, scouring agent:
BK type: sodium tetraborate 10: the mixture of boric acid 3 (weight ratio: together following).
(pH=9.2 of 0.1% aqueous solution)
BN type: sodium tetraborate 10: the mixture of boric acid 12,
(pH=8.3 of 0.1% aqueous solution)
KK type: potassium silicate 10: the mixture of malic acid 2 (0.1% aqueous solution pH=9.2)
KN type: sodium metasilicate 10: the mixture of malic acid 4 (0.1% aqueous solution pH=8.3)
No. 2, scouring agent:
BK type: dipotassium tetraborate 10: the mixture of boric acid 1 (0.1% aqueous solution pH=9.3)
BN type: sodium tetraborate 10: the mixture of boric acid 2
(0.1% aqueous solution pH=8.8)
KN type: sodium metasilicate 10: the mixture of malic acid 2 (0.1% aqueous solution pH=8.8)
When using No. 1, scouring agent, remain with silk gum 2. on the silk, silk gum 3., silk gum 4., thereby, can make the long-pending thing of stiffening silk, and when using No. 2, scouring agent, can keep silk gum 3., 4. silk gum can obtain soft fabric.
Below, from being that the complex of dentate forms with silk gum, and select concise viewpoint to set out, describe in detail and the effect during with calcium ion and barium ions.
1. and the main cause of the resistance that comes unstuck of the mixed layer 2. (timeliness changes except the resistance that comes unstuck cause) 1. reach the silk gum layer as changing the silk gum layer greatly, have polyvalent metal ion silk gum to be easy to the influence of desorb.Usually can consider extensively to be present in calcium ion and the magnesium ion that reaches on the ground in the water and be counted as the representative of the harmful metal ion in the filature water as these metal ions.These metal ions are by feed, or by in the filature water, are easy to form coordinate bond on silk gum and change its solubility greatly.Because silk gum is the cause of structural characteristics (the molecule gap is minimum) of layer 1., it is generally acknowledged ionic radius the calcium ion of big (0.99 ) be difficult to enter 1. layer of silk gum, and can only 1. form coordinate bond near the laminar surface at silk gum.On the other hand, can inference: less (0.66 ) magnesium ion of ionic radius enters silk gum 1. in the layer, because of the feature of polyvalent metal, in the bridged bond structure of the intermolecular formation coordinate bond of silk gum, improved greatly than calcium ion bigger for silk gum 1. the layer the resistance that comes unstuck.
During concise beginning, as additive, as use than magnesium ion more can form complex and, the calcium ion that ionic radius is bigger, it is played a role, then calcium ion promptly easily by silk gum 1. near the complex bound magnesium ion of molecule intercropping the laminar surface replace.At this moment, the calcium ion of sufficient amount is in silk gum molecule intercropping coordination combination 1., and gets intramolecular coordination, and the intermolecular three-dimensional structure of magnesium ion is eliminated, and the reaction of coming unstuck is from 1. near surface of silk gum, in proper order, easily carry out.
In a single day the complex of calcium-silk gum and the complex of barium-silk gum form, and the resistance that comes unstuck increases, and the pH value of concise liquid can design high, thereby can shorten concise required time.
Along with concise carrying out, the pH value of concise liquid reduces, and can automatically become near the concise liquid that keeps buffering pH value 5～9.In this pH value scope, the reaction of coming unstuck takes place 1. for silk gum, for silk gum 2., does not then take place.2. complex of the calcium ion-silk gum of Sheng Chenging because of having improved hot water resistance, can be realized selecting accurately to come unstuck simultaneously.
In addition, when use is dissolved with the scouring agent of barium ions, (barium ions have than calcium ion bigger with the ability silk gum complexing, and the bigger ionic radius of tool), even it is then concise in same pH codomain, generally can't see calcium ion has the effect that strengthens the silk gum resistance that comes unstuck 2., come unstuck then with the 1. identical principle of structure occasion that forms of layer of magnesium ion and silk gum layer, proceed to silk gum 4. till the surface of layer.Also provable thus, the action principle of calcium ion and barium ions.
Above-mentioned demonstration, metal ion such as magnesium, calcium, barium and silk gum with the stability order that dentate participates in the complex that complexing forms are: magnesium＜calcium＜barium.And show, this purifying reaction, be based in the electropositivity metal of alkaline-earth metal the effect of displacement reaction of common representative property.
In addition, the place that calcium ion, barium ions react considers it is carboxyl from structure of coordination compound.Therefore, free carboxyl crested has been lived, the silk gum on silk surface and the silk gum that dissociates because of coming unstuck, and the two all only is with (+) positive charge.For this reason, the two produces electricity each other repels, and eliminates absorption once more.Why this promptly can shorten the concise time, and can not take place because of polluting the reason that the whiteness that causes reduces phenomenon again.
Above-mentioned theory can directly apply to the concise method of tussah raw silk.The tussah raw silk is by topped in conjunction with the silk gum institute that forms bridged bond by the coordination of calcium ion.Therefore, for the above reasons, with sodium ion, potassium ion during as the host of scouring agent, remove fully must concise removal outer silk gum (can regard as and be equivalent to 1. layer of silkworm silk gum, the chromophore that forms based on structure is arranged) be very difficult.And owing to have the color reversion phenomenon of brown pigment to produce, and can not reach bleaching completely.Therefore, utilized the strong basicity scouring agent or the concise enzyme of using at high price that can cause the silk quality deterioration in the past always.But, in scouring agent of the present invention, as long as the fusion barium ions, can provide with domestic silkworm silk concise there is not what different high efficiency scouring agent.
The selectivity of the silk gum that can automatically the work interaction energy that comes unstuck makes internal layer silk gum (this layer silk gum can be thought and is equivalent to silkworm silk gum 2., 3. reaching 4. layer) repeatability remains well, this internal layer silk gum is handled because of not hindering bleaching, can carry out the not bleaching of color reversion.In addition, also shown the function that to improve the silk various characteristics.This specific character is common in the occasion of domestic silkworm silk.
Calcium ion, barium ions is made by the hydroxide or the salt of calcium metal, barium metal.
On scouring agent of the present invention is formed, can use boric acid, silicic acid, carbonic acid, malic acid, phosphoric acid etc. as the polyacid that forms alkali metal salt.In addition, alkali metal except that potassium, sodium etc., also available lithium etc.
Also have, about with this alkali metal salt use simultaneously fixed acid, because of the suitable fusion of crystalloid acid, transport conveniently, preferably boric acid, malic acid etc., other, acetic acid, hydrochloric acid, phosphoric acid etc. form the acid of water miscible buffer solution in this way, also can use.
On mixing ratio, the ratio of the acid of above-mentioned alkali metal salt and afore mentioned rules, for No. 1, scouring agent, weight ratio 10: (0.5-15) for well, as 10: (1-12) then better.This mixed proportion is also different because of kind.Alkali metal salt is sylvite in this way, and then aforementioned proportion is with 10: (0.5-12) better, and 10: (1-10) better.Sodium salt in this way, 10: (1-15) better, 10: (2-12) better.
Again, for No. 2, scouring agent, aforementioned proportion then wishes to be 10: (0.2-6), and 10: (0.3-4) better.At this moment, alkali metal salt is sylvite then 10 in this way: (0.2-5) better, and 10: (0.3-3) better.Sodium salt then 10: (0.5-6) better, 10: (0.6-4) better.
Have again, used above-mentioned polyacid among the present invention, its dissociation constant (pka) is about this point of 6-10, and the above-mentioned explanation of root a tree name is absolutely necessary.Also promptly, less than 6, the reaction itself of coming unstuck can't produce as (pka), and crosses 10, and then alkalescence is strong excessively, uncontrollable degumming degree.This (pka) is advisable with 8.5-9.8.Corresponding therewith, the pH value of used above-mentioned alkaline buffer among the present invention, about 6-10, but 9.5-8.0 is better, and 9.2-8.3 is better.
The concentration of this alkaline buffer in concise liquid is advisable with 0.03%-0.5%, 0.03-0.3% in No. 1, scouring agent, and 0.05-0.5% is advisable in No. 2, scouring agent.
The scouring agent of above-mentioned alkaline buffer and generate the compound of calcium ion, barium ions-be: weight ratio best 10 as the mixing ratio of calcium acetate or barium acetate: (0.5-40), 10: (1-30) better.
In addition, the past carries out when concise the coloured silk of band natural colouring matter, does not dye silk on pigment is not understood and runs off, thereby can't utilize pigment.But we recognize the character of remaining pigment, similar to alkaline synthetic dyestuffs.Thereby the present inventor is using sodium carbonate, sodium bicarbonate, sodium metasilicate, the basic solvent of sodium tetraborate and sylvite thereof etc. is when above-mentioned scouring agent, simultaneously, also in scouring agent, added cationic surfactant,, pigment has been dyed on silk with the stain that increases as basic-dyeable fibre.Used cationic surface active agent among the present invention and since its character relation can make concise carry out slow, thereby, never be used as scouring agent and used.Yet, because of this surfactant has shown the silk surface alkaline natural colouring matter is absorbed in modifying function in the degummed silk, so original impossibility may have been accomplished now.We can say that this concise method is an organic growth direction of having complied with natural goods, successfully makes the beautiful silk of the natural colouring matter that has utilized cocoon.
The silk cocoon pigment mainly be present in silk gum 1. with silk gum 2. the layer, so pigment and silk gum are simultaneously from the raw silk stripping.Because this pigment has shown the character of basic-dyeable fibre, thereby be not easy directly by the fibroin fiber absorption of tool parent ACID DYES character.But, by allowing fibroin fiber absorption cationic surfactant in advance, or make cationic surfactant coexist as the fibroin fiber surface, thereby make the fibroin surface be pro-alkaline, get final product adsorpting pigment, and with suitable mordant fixed pigment.
Concise method about the green pigment that keeps wild silk yarn, as doing detailed slightly explanation, following requirement is arranged: remove tool adhesiveness, the dry silk gum that hard sense is arranged afterwards selectively, simultaneously, removal invests the oxalates on the raw silk, the oil of twisting thread, paste, various medicament, stain etc., can obtain to keep fresh green, is rich in gloss, soft wild silk yarn.
At this moment, should be controlled at existing commonly in concise as far as possible, select to remove for the nothing of silk gum, so as to stay be equivalent to silk gum 2., silk gum 3., silk gum silk gum layer 4. is with the protection fibroin, improves the wild silk yarn ABRASION RESISTANCE.The anti-wear performance difference was the shortcoming of wild silk yarn originally.Again, for stablizing of dye compound, calcium ion also is a desirable metal ion, can be used as calcium acetate and adds.
In the method for the invention,, can enumerate as above-mentioned cationic surfactant: the Fixanol of irreducibility, alkylammonium salt, and alkyl dimethyl benzyl ammonium salt etc.
The use amount of above-mentioned cationic surfactant, for well, 8-12% is better with the 5-15% of silk or silk fabric weight.
E, embodiment
Below, the present invention will be described in more detail with embodiment.
(intend keep silk gum 2. time)
Embodiment 1 (raw silk and thin living fabric)
Scouring agent consist of following mixing:
32 parts of calcium acetates
18 parts of carbonated soda
20 parts in tetraboric acid soda
5 parts of boric acid
20 parts of powder stabilizing agents
Use is 3% scouring agent to the raw silk or the weight ratio (hereinafter to be referred as owf) of giving birth to fabric, adds suitable neutral lotion and an amount of chelating agent, makes bath raio and be 40 times concise liquid (pH value 9.3),, comes unstuck 40-60 minute under 94 ℃ with this scouring agent.
Finish precontract 10 minutes in the processing of coming unstuck, add the sodium dithionite of owf1.5%,, after the rinsing, handle dehydration again, drying through draining with used usually finishing agent.
Suitable neutral lotion refers to neutral surface active agent or the neutral surface active agent of nonionic and their mixture of anionic.An amount of chelating agent is, for covering filature water and raw silk etc. by poisonous metal institute expenses such as institute's iron content, copper in the concise material.Again, the powder stabilizing agent is, is the additive that adds of the bonding of medicament that prevented fusion.
Embodiment 2 (wrinkle silk fabric and thick and heavy living fabric concise)
A is concise in advance
Scouring agent consist of following mixing:
32 parts of calcium acetates
18 parts in sodium carbonate
20 parts of sodium tetraborates
5 parts of boric acid
20 parts of powder stabilizing agents
The scouring agent of owf (silk or silk fabrics weight) 3% with suitable neutral lotion, chelating agent, is made bath raio and be 40 times concise liquid (pH value 9.0), after coming unstuck 120-200 minute under 98-100 ℃, wash.
B is concise
The composition of scouring agent
50 parts of dipotassium tetraborates
50 parts of boric acid
The scouring agent of owf (silk and silk fabrics weight) 3% with an amount of textile soap (owf5%), chelating agent, is made bath raio and be 40 times concise liquid (pH value 9.3), after coming unstuck 40-60 minute under 98-100 ℃, wash.Corresponding to required processing whiteness, in preceding 15 minutes of the end of coming unstuck, add sodium dithionite,, after the rinsing, handle dehydration again, drying through draining with finishing agent commonly used.
In above-mentioned example 1, example 2 in gained silk and the silk, because of utilized the silk gum layer that originally do not utilize 2. with the silk gum layer 3., so, have following feature.
1, (a) concise yield rate improves 3-5%.(b) because fibroin is protected by the silk gum layer, can not come unstuck and handle caused fibroin degradation phenomena.Its intensity, elongation all improve about 30%.(see figure 3)
(c) same reason, the silk ABRASION RESISTANCE also significantly improves.Not wear-resisting this shortcoming of silk becomes the past.(see figure 3)
(d) owing to kept the silk gum layer 2., unusual fine fibre (lousiness fiber) is embedded in the silk gum layer, can control the generation (except the cellulose silk) of lousiness fiber.
(e) shrinkage factor is little, and ABRASION RESISTANCE increases, and wash durability also is improved.
2, quality significantly improves, and drapability is good, springiness, suitable especially suit facing material.
3, to mixed yarn (the compound silk that mixes other fiber) when carrying out refining processing, used scouring agent can reduce mixed polyester, vinegar ester, the deterioration of other fiber such as wool because of the such strong basicity not as using in the past.
4, because of fibroin is the cladding of amorphous silk gum, its dyeability is also good than former.
5, concise required time and without the situation of calcium ion by comparison, will reduce more than 1/2nd sometimes.
6, the deviation of being criticized the concise time that causes by the raw material cocoon is very little, thereby can control because raw material mixes the generation of the specking that forms, and reduces defective product.
7, owing to before concise end, add a spot of reductant (for example sodium dithionite), the trifling silk surface (joining the value combination) that sticks to securely of calcium salt, so because its ultraviolet reflection effect, the anti-yellowish-brown sex change of the silk after coming unstuck also improves a lot.In addition, thus, the reduction of quality does not take place.As former anti-yellowish-brown became processing, this function can not go down because of washing face yet in addition.This point also can be understood by its effect function.(see figure 3)
(intend to remove glue to silk gum layer 3. the time)
Embodiment 3
Scouring agent consists of following mixing:
25 parts of barium acetates
20 parts in sodium carbonate
50 parts of sodium tetraborates
5 parts of boric acid
With the scouring agent of owf (silk and silk fabrics weight) 3% and suitable neutral lotion, chelating agent together, making bath raio and be 40 times concise liquid (p10.5) came unstuck under 94 ℃ 40-60 minute.Finished precontract 10 minutes coming unstuck, add the sodium dithionite of owf (silk and fabric weight thereof) 0.5%, draining after the rinsing, is handled with finishing agent commonly used, dehydration, oven dry.
(tussah raw silk, fabric concise)
Scouring agent consist of following mixing:
75 parts of barium hydroxides
20 parts of dipotassium tetraborates
5 parts of boric acid
Get the scouring agent of owf3%, with suitable neutral surface active agent and chelating agent, the concise liquid (pH11.3) that makes bath raio and be 40 times after coming unstuck 60 minutes, adds the sodium dithionite that accounts for owf5% at 94 ℃, after continuing again to come unstuck 15 minutes, and reducing bleach.Draining, after the rinsing, dehydration, and after the oxidation bleaching operation via hydrogen peroxide commonly used, washing, dehydration, drying.
(giant silkworm raw silk green concise)
Concise liquid is formed:
Cationic surfactant (alkyl dimethyl benzyl ammonium salt): account for owf 10%
Scouring agent: account for owf 3%
Scouring agent consists of following mixing:
45 parts of dipotassium tetraborates
32 parts of boric acid
15 parts of calcium acetates
8 parts in potash
Make the concise liquid (pH8.8-9.0) of 40 times of bath raioes, under 94 ℃, begin to come unstuck, after 10 minutes, add potash, make the pH value get back to 8.8-9.0, after continuing again to come unstuck 70-80 minute, draining, rinsing.After, as required, clean after washing, drying with non-ionic surface active agent.
(keeping the concise of the coloured raw silk pigment of silkworm)
Cationic surfactant (alkyl dimethyl benzyl ammonium salt): account for owf 10%
Scouring agent: account for owf 3%
Scouring agent consists of following mixing:
50 parts of dipotassium tetraborates
10 parts of boric acid
25 parts of calcium acetates
15 parts in sodium carbonate
Make the concise liquid (pH10.0) of 40 times of bath raioes, add an amount of chelating agent, begin to come unstuck at 94 ℃, after 10 minutes, it is 9.5 that adding potash makes pH, proceeds to come unstuck 90-120 minute again.Afterwards, add mordant (as stannous chloride owf 0.2%), after special its dissolving, draining, rinsing.Then, as required, after cleaning with non-ionic surface active agent, or rinsing
And after carrying out conventional arrangement processing, dry coal.
The gained nett silk is in above-mentioned example 5, the example 6, and softness is rich in gloss, with former raw silk look same boiled-off silk.
As above, the present invention has not only solved the major part of a silk industry difficult technologies difficult problem of a specified duration and unsettled, and, nett silk and silk thereof based on gained of the present invention, also because its silk performance newly developed, and the open range of application of silk fabrics, expectation can make the expanded demand of people to silk fabrics.
Four, the accompanying drawing simple declaration
Accompanying drawing is in order to explanation the present invention
Fig. 1 is the long filament sectional view that has amplified;
Fig. 2 is the further amplification schematic cross-section at the main position of two kinds of different representative silk kinds.
Fig. 3 is that the physical property of nett silk silk compares schematic diagram.
As follows about the yellowness experimental details:
(very complicated because of this test, as only to do one relatively) in the Y I
-with existing methods concise the silk 1.
■-to have the concise silk of method 2.
The silk that △-with the invention that becomes basis of the present invention is concise
● the silk that-the present invention handles
As can be seen, the anti-yellowish-brown sex change of silk that the present invention handles has obvious characteristic, shines after 5 hours, and yellowish-brown speed change degree of initial stage is the about 70% of control sample, and the control case of shining between 15-30 hour is similar therewith.The physical property test table of nett silk silk (sample: the friction test test method crepe of refining): 100 times back pressure 2 kilograms/1/5 sample calicos: the moistening previous method as a result of nylon: the whole white severe the present invention of wiping: lose and wipe white strength and elongation: shrinkage test
Crease recovery rate
| Longitudinal direction | Transverse direction |
| Intensity (kilogram) degree of stretching (%) shrinkage factor (%) previous method 61.1 ± 9.6 34.0 ± 1.7 14.1 the present invention 83.7 ± 3.2 41.4 ± 2.2 11.1 | Intensity (kilogram) degree of stretching (%) shrinkage factor (%) 61.2 ± 3.9 31.2 ± 5.2 1.4 83.2 ± 6.8 44.6 ± 3.5 0.7 |
Claims (2)
1. method of silk fiber and fabric thereof being made refining processing, it is characterized in that said method utilized the complex effect of scouring agent and calcium ion, barium ions or its hybrid ionic, scouring agent by contain dissociation constant be about the polyacid in the 6-10 scope alkali metal salt and decide acid alkaline buffer formed; It is 10: 0.5～10: 12 that the alkali metal salt of described polyacid and institute decide the sour weight ratio that contains.
2. one kind when the silk fiber of giant silkworm and coloured silkworm and fabric thereof made refining processing, the method that keeps its pigment, it is characterized in that, said method is in the complex effect of having utilized scouring agent and calcium ion, barium ions or its hybrid ionic, carry out when concise, the surfactant of being mixed has used cationic surfactant, described scouring agent by contain dissociation constant be about the polyacid in the 6-10 scope alkali metal salt and decide acid alkaline buffer formed; It is 10: 0.5～10: 12 that the alkali metal salt of described polyacid and institute decide the sour weight ratio that contains.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP90960 | 1989-04-10 | ||
| JP9096089A JPH064933B2 (en) | 1989-04-10 | 1989-04-10 | Method for refining silk fiber or its fabric |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1047123A CN1047123A (en) | 1990-11-21 |
| CN1043261C true CN1043261C (en) | 1999-05-05 |
Family
ID=14013064
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN90102144A Expired - Fee Related CN1043261C (en) | 1989-04-10 | 1990-04-10 | Natrual silk fibres and method for refining fabrics made from such fibres |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JPH064933B2 (en) |
| CN (1) | CN1043261C (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102965867A (en) * | 2012-10-09 | 2013-03-13 | 浙江理工大学 | Degumming process of natural yellow silk fabrics |
| CN101757374B (en) * | 2008-12-25 | 2013-10-16 | 朱小放 | Medicine for curing burns and scalds and preparation method thereof |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20040022903A (en) * | 2002-09-10 | 2004-03-18 | 에스케이케미칼주식회사 | Procedure of scouring for silk textiles |
| EP2712947A1 (en) * | 2012-09-27 | 2014-04-02 | Ludwig Boltzmann Gesellschaft GmbH | Product made of native silk fibres |
| CN103911855B (en) * | 2013-12-28 | 2016-04-06 | 苏州华策纺织科技有限公司 | A kind of silk fabric refining agent |
| CN104195777B (en) * | 2014-09-16 | 2016-07-20 | 南通那芙尔服饰有限公司 | A kind of improve the method for color depth after natural colorful mulberry silk fabric degumming |
| CN105155247A (en) * | 2015-08-12 | 2015-12-16 | 融水苗族自治县宇隆茧丝有限责任公司 | Degumming and bleaching processing technology for cocoon silk |
| KR101866476B1 (en) * | 2018-05-03 | 2018-06-11 | (주)지유텍스 | Doll Fabric Manufacturing Method |
| KR102211739B1 (en) * | 2018-08-23 | 2021-02-03 | 주식회사 엘지생활건강 | Cosmetic of sheet comprising color silk produced by a part refining method and maskpack thereof |
| CN110029401A (en) * | 2019-04-12 | 2019-07-19 | 苏州丝之源纺织科技有限公司 | A kind of low temperature degumming agent and its Degumming method for natural colorful silk |
| CN112831858B (en) * | 2021-01-20 | 2022-09-02 | 季华实验室 | Bioactive reagent and method for silk fibrosis |
-
1989
- 1989-04-10 JP JP9096089A patent/JPH064933B2/en not_active Expired - Lifetime
-
1990
- 1990-04-10 CN CN90102144A patent/CN1043261C/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101757374B (en) * | 2008-12-25 | 2013-10-16 | 朱小放 | Medicine for curing burns and scalds and preparation method thereof |
| CN102965867A (en) * | 2012-10-09 | 2013-03-13 | 浙江理工大学 | Degumming process of natural yellow silk fabrics |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1047123A (en) | 1990-11-21 |
| JPH02269870A (en) | 1990-11-05 |
| JPH064933B2 (en) | 1994-01-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1043261C (en) | Natrual silk fibres and method for refining fabrics made from such fibres | |
| CN1224751C (en) | Method for the one step preparation of textiles | |
| CN1036148C (en) | Dyeing and printing of cellulosic fibre materials with vat dyes | |
| CN1494622A (en) | Method for use of hydrophobic bleaching systems in cold batch textile preparation | |
| CN1840777A (en) | Method for hand-painted coloration and dyeing of textile | |
| CN103451972A (en) | Low-temperature dyeing auxiliary and application thereof | |
| CN106939515B (en) | The preparation of ball warp mercerization and efficient silkete penetrating agent in a kind of production of denim fabric | |
| CN103541081A (en) | Producing method of heterochromatic polyester cotton melange yarn | |
| CN102797146A (en) | Scouring enzyme, and preparation method, application and application method thereof | |
| CN110453510A (en) | A kind of complex reducing agent and reduction stain method | |
| CN105862477B (en) | A kind of textile auxiliary and preparation method thereof improving colour fixation | |
| TWI689648B (en) | Dyeing auxiliary, its manufacturing method and applied dyeing process | |
| FR2565266A1 (en) | PROCESS FOR DYEING EXHAUST CELLULOSIC FIBERS WITH REACTIVE DYES | |
| CN104294590B (en) | Raw cotton fiber dyeing and finishing auxiliaries and application for colour-spun yarns processing | |
| CN1205378C (en) | Method for the use of hydrophobic bleadching systems in textile preparation | |
| JP2006176888A (en) | Twisted union yarn and method for dyeing the same | |
| CN1289748C (en) | Mediator systems based on mixed metal complexes, used for reducing dyes | |
| TWI428488B (en) | A method for improving colorness of feather and down | |
| CN110438826A (en) | The technique that a kind of auxiliary agent and its preparation method and application bathes method dyeing in fabric entirely | |
| CN109667133A (en) | A kind of bleaching and dyeing process of polyester thread | |
| CN1038607C (en) | Post treatment technology for drawnwork fabric | |
| CN102808232A (en) | Production process of colored viscose filament yarn | |
| CN106049109B (en) | A kind of silk dyeing technique | |
| JP2004534163A5 (en) | ||
| MX2007005607A (en) | Textile products dyed by means of cationic dyes, and process for the manufacture thereof. |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C15 | Extension of patent right duration from 15 to 20 years for appl. with date before 31.12.1992 and still valid on 11.12.2001 (patent law change 1993) | ||
| OR01 | Other related matters | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |