CN104312358A - 一种功能型内墙涂料 - Google Patents

一种功能型内墙涂料 Download PDF

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CN104312358A
CN104312358A CN201410521557.XA CN201410521557A CN104312358A CN 104312358 A CN104312358 A CN 104312358A CN 201410521557 A CN201410521557 A CN 201410521557A CN 104312358 A CN104312358 A CN 104312358A
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吴真信
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ANHUI ZHENXIN PAINT Co Ltd
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Abstract

本发明公开了一种功能型内墙涂料，它是由下述重量份的原料组成的：聚碳化二亚胺1-2、十二烷基硫醇1-2、3-吡咯啉0.6-1、十溴联苯醚2-3、偏硼酸钡1-2、亚磷酸三壬基苯酯2-3、海螺壳粉2-3、2.4-二氯过氧化苯甲酰0.6-1、异噻唑啉酮1-2、亚磷酸三壬基苯酯2-3、海泡石粉10-13、六甲基环三硅氧烷80-100、甲基丙烯酸丁酯120-160、丙烯酸己酯130-200、去离子水500-600、过硫酸钾2-4、op-103-4、亚硫酸氢铵0.4-1、粘结助剂3-6，本发明的涂料耐洗刷性高达5000次以上，表面抗性高，具有很好的杀菌防腐功效，使用本发明的涂料作为内墙涂料可营造冬季干爽、温暖，夏季清新的环境。

Description

一种功能型内墙涂料
技术领域
    本发明主要涉及涂料领域，尤其涉及一种功能型内墙涂料。
背景技术
    涂于物体表面能形成具有保护、装饰或特殊性能(如绝缘、防腐、标志等)的固态涂膜的一类液体或固体材料的总称，包括油(性)漆、水性漆、粉末涂料。漆是可流动的液体涂料，包括油(性)漆及水性漆。油漆是以有机溶剂为介质或高固体、无溶剂的油性漆。水性漆是可用水溶解或用水分散的涂料。涂料作为家庭装修的主材之一，在装饰装修中占的比例较大，购买涂料的合格与否直接影响到整体装修效果和居室的环境，有时甚至会对人体的健康产生极大的危害。目前随着各种各样涂料的产生，对涂料的品质要求也不断提高，而不断提高涂料质量对于建筑、生活都可以起到很大的帮助作用。
发明内容
本发明目的就是提供一种功能型内墙涂料。
本发明是通过以下技术方案实现的：
一种功能型内墙涂料，其特征在于它是由下述重量份的原料组成的：
聚碳化二亚胺1-2、十二烷基硫醇1-2、3-吡咯啉0.6-1、十溴联苯醚2-3、偏硼酸钡1-2、亚磷酸三壬基苯酯2-3、海螺壳粉2-3、2.4-二氯过氧化苯甲酰0.6-1、异噻唑啉酮1-2、亚磷酸三壬基苯酯2-3、海泡石粉10-13、六甲基环三硅氧烷80-100、甲基丙烯酸丁酯120-160、丙烯酸己酯130-200、去离子水500-600、过硫酸钾2-4、op-10 3-4、亚硫酸氢铵0.4-1、粘结助剂3-6；
所述的粘结助剂是由下述重量份的各原料组成的：
甲基丙烯酸甲酯5-10、醋丙乳液20-25、铝酸酯偶联剂2-3、香樟木微粉1-2、异冰片甲基丙烯酸酯2-3、过硫酸钾1-2、十二烷基苯磺酸钠0.6-1、去离子水13-20；
将上述甲基丙烯酸甲酯与铝酸酯偶联剂混合，搅拌均匀后加入十二烷基苯磺酸钠、异冰片甲基丙烯酸酯，50-60℃下保温搅拌3-5分钟；
将香樟木微粉加入到去离子水中，搅拌均匀后加入过硫酸钾，搅拌均匀；
将上述处理后的各原料混合，加入到醋丙乳液中，300-400转/分搅拌分散15-20分钟，即得所述粘结助剂。
一种如权利要求1所述的功能型内墙涂料的制备方法，其特征在于包括以下步骤：
（1）取上述甲基丙烯酸丁酯重量的50-60%、丙烯酸己酯重量的50-60%混合，得单体a；
（2）将剩余的甲基丙烯酸丁酯、丙烯酸己酯与六甲基环三硅氧烷混合，在60-70℃下保温搅拌3-5分钟，加入异噻唑啉酮，搅拌均匀，冷却至常温，得单体b；
（3）将过硫酸钾、亚硫酸氢铵混合，加入上述去离子水重量的10-20%，搅拌均匀，得引发剂溶液；
（4）取op-10与剩余去离子水重量的10-20%混合，加入引发剂溶液，升高至温度为60-70℃，保温搅拌20-30分钟，滴加上述单体a，在2-4 小时内滴完，滴加完毕后在上述温度下保温20-30分钟，得种子乳液；
（5）在上述种子乳液中滴加单体b，滴加时间为100-120分钟，滴加完毕后，在70-80℃下保温1-2小时，冷却，用200-250目筛网过滤出料；
（6）将上述步骤（5）得到的物料与剩余各原料混合，800-1200转/分搅拌分散20-30分钟，即得所述功能型内墙涂料。
本发明的优点是：
    本发明的涂料耐洗刷性高达5000 次以上，表面抗性高，具有很好的杀菌防腐功效，使用本发明的涂料作为内墙涂料可营造冬季干爽、温暖，夏季清新的环境。本发明的粘结助剂加入的甲基丙烯酸甲酯在水中可以形成胶态，与异冰片甲基丙烯酸酯、过硫酸钾、醋丙乳液等混合改性，具有很强的粘结效果，可以提高涂膜表面粘结性和稳定性。
具体实施方式
实施例1
一种功能型内墙涂料，其特征在于它是由下述重量份的原料组成的：
聚碳化二亚胺2、十二烷基硫醇1、3-吡咯啉0.6、十溴联苯醚3、偏硼酸钡1、亚磷酸三壬基苯酯2、海螺壳粉3、2.4-二氯过氧化苯甲酰0.6、异噻唑啉酮2、亚磷酸三壬基苯酯2、海泡石粉13、六甲基环三硅氧烷100、甲基丙烯酸丁酯160、丙烯酸己酯200、去离子水600、过硫酸钾4、op-10 3、亚硫酸氢铵0.4、粘结助剂3；
所述的粘结助剂是由下述重量份的各原料组成的：
甲基丙烯酸甲酯10、醋丙乳液25、铝酸酯偶联剂3、香樟木微粉2、异冰片甲基丙烯酸酯3、过硫酸钾2、十二烷基苯磺酸钠0.6、去离子水20；
将上述甲基丙烯酸甲酯与铝酸酯偶联剂混合，搅拌均匀后加入十二烷基苯磺酸钠、异冰片甲基丙烯酸酯，60℃下保温搅拌5分钟；
将香樟木微粉加入到去离子水中，搅拌均匀后加入过硫酸钾，搅拌均匀；
将上述处理后的各原料混合，加入到醋丙乳液中，400转/分搅拌分散20分钟，即得所述粘结助剂。
一种功能型内墙涂料的制备方法，其特征在于包括以下步骤：
（1）取上述甲基丙烯酸丁酯重量的50-60%、丙烯酸己酯重量的60%混合，得单体a；
（2）将剩余的甲基丙烯酸丁酯、丙烯酸己酯与六甲基环三硅氧烷混合，在70℃下保温搅拌5分钟，加入异噻唑啉酮，搅拌均匀，冷却至常温，得单体b；
（3）将过硫酸钾、亚硫酸氢铵混合，加入上述去离子水重量的20%，搅拌均匀，得引发剂溶液；
（4）取op-10与剩余去离子水重量的20%混合，加入引发剂溶液，升高至温度为70℃，保温搅拌30分钟，滴加上述单体a，在4 小时内滴完，滴加完毕后在上述温度下保温30分钟，得种子乳液；
（5）在上述种子乳液中滴加单体b，滴加时间为120分钟，滴加完毕后，在80℃下保温1小时，冷却，用250目筛网过滤出料；
（6）将上述步骤（5）得到的物料与剩余各原料混合，1200转/分搅拌分散30分钟，即得所述功能型内墙涂料。
性能测试：
延伸率：≥300％ ；
不透水性：0.3MPa( 一个小时不透水)。

Claims (2)

1.一种功能型内墙涂料，其特征在于它是由下述重量份的原料组成的：
聚碳化二亚胺1-2、十二烷基硫醇1-2、3-吡咯啉0.6-1、十溴联苯醚2-3、偏硼酸钡1-2、亚磷酸三壬基苯酯2-3、海螺壳粉2-3、2.4-二氯过氧化苯甲酰0.6-1、异噻唑啉酮1-2、亚磷酸三壬基苯酯2-3、海泡石粉10-13、六甲基环三硅氧烷80-100、甲基丙烯酸丁酯120-160、丙烯酸己酯130-200、去离子水500-600、过硫酸钾2-4、op-10 3-4、亚硫酸氢铵0.4-1、粘结助剂3-6；
所述的粘结助剂是由下述重量份的各原料组成的：
甲基丙烯酸甲酯5-10、醋丙乳液20-25、铝酸酯偶联剂2-3、香樟木微粉1-2、异冰片甲基丙烯酸酯2-3、过硫酸钾1-2、十二烷基苯磺酸钠0.6-1、去离子水13-20；
将上述甲基丙烯酸甲酯与铝酸酯偶联剂混合，搅拌均匀后加入十二烷基苯磺酸钠、异冰片甲基丙烯酸酯，50-60℃下保温搅拌3-5分钟；
将香樟木微粉加入到去离子水中，搅拌均匀后加入过硫酸钾，搅拌均匀；
将上述处理后的各原料混合，加入到醋丙乳液中，300-400转/分搅拌分散15-20分钟，即得所述粘结助剂。
2.一种如权利要求1所述的功能型内墙涂料的制备方法，其特征在于包括以下步骤：
（1）取上述甲基丙烯酸丁酯重量的50-60%、丙烯酸己酯重量的50-60%混合，得单体a；
（2）将剩余的甲基丙烯酸丁酯、丙烯酸己酯与六甲基环三硅氧烷混合，在60-70℃下保温搅拌3-5分钟，加入异噻唑啉酮，搅拌均匀，冷却至常温，得单体b；
（3）将过硫酸钾、亚硫酸氢铵混合，加入上述去离子水重量的10-20%，搅拌均匀，得引发剂溶液；
（4）取op-10与剩余去离子水重量的10-20%混合，加入引发剂溶液，升高至温度为60-70℃，保温搅拌20-30分钟，滴加上述单体a，在2-4 小时内滴完，滴加完毕后在上述温度下保温20-30分钟，得种子乳液；
（5）在上述种子乳液中滴加单体b，滴加时间为100-120分钟，滴加完毕后，在70-80℃下保温1-2小时，冷却，用200-250目筛网过滤出料；
（6）将上述步骤（5）得到的物料与剩余各原料混合，800-1200转/分搅拌分散20-30分钟，即得所述功能型内墙涂料。
CN201410521557.XA 2014-10-08 2014-10-08 一种功能型内墙涂料 Pending CN104312358A (zh)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5374687A (en) * 1991-11-04 1994-12-20 Rheox, Inc. Anti-settling agents for aqueous coating compositions
CN101704656A (zh) * 2009-06-23 2010-05-12 深圳市龙富华节能技术有限公司 一种内墙涂料组合物
CN103725141A (zh) * 2013-12-17 2014-04-16 江苏苏博特新材料股份有限公司 一种用于建筑外墙防护的水性乳液及其制备方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5374687A (en) * 1991-11-04 1994-12-20 Rheox, Inc. Anti-settling agents for aqueous coating compositions
CN101704656A (zh) * 2009-06-23 2010-05-12 深圳市龙富华节能技术有限公司 一种内墙涂料组合物
CN103725141A (zh) * 2013-12-17 2014-04-16 江苏苏博特新材料股份有限公司 一种用于建筑外墙防护的水性乳液及其制备方法

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Application publication date: 20150128