CN104263125A - 一种多聚物外墙涂料 - Google Patents

一种多聚物外墙涂料 Download PDF

Info

Publication number
CN104263125A
CN104263125A CN201410448342.XA CN201410448342A CN104263125A CN 104263125 A CN104263125 A CN 104263125A CN 201410448342 A CN201410448342 A CN 201410448342A CN 104263125 A CN104263125 A CN 104263125A
Authority
CN
China
Prior art keywords
parts
minute
add
deionized water
emulsion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410448342.XA
Other languages
English (en)
Inventor
孙立新
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
QINGYANG SHUANGLONG COATING Co Ltd
Original Assignee
QINGYANG SHUANGLONG COATING Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by QINGYANG SHUANGLONG COATING Co Ltd filed Critical QINGYANG SHUANGLONG COATING Co Ltd
Priority to CN201410448342.XA priority Critical patent/CN104263125A/zh
Publication of CN104263125A publication Critical patent/CN104263125A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
    • C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
    • C09D131/04—Homopolymers or copolymers of vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02—Esters of monocarboxylic acids
    • C08F218/04—Vinyl esters
    • C08F218/08—Vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F263/00—Macromolecular compounds obtained by polymerising monomers on to polymers of esters of unsaturated alcohols with saturated acids as defined in group C08F18/00
    • C08F263/02—Macromolecular compounds obtained by polymerising monomers on to polymers of esters of unsaturated alcohols with saturated acids as defined in group C08F18/00 on to polymers of vinyl esters with monocarboxylic acids
    • C08F263/04—Macromolecular compounds obtained by polymerising monomers on to polymers of esters of unsaturated alcohols with saturated acids as defined in group C08F18/00 on to polymers of vinyl esters with monocarboxylic acids on to polymers of vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C08F220/281—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing only one oxygen, e.g. furfuryl (meth)acrylate or 2-methoxyethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Paints Or Removers (AREA)

Abstract

本发明公开了一种多聚物外墙涂料，它是由下述重量份的原料组成的：丙烯酸十三氟辛酯2-4、2，2-二溴-3-氰基丙酰胺1-2、聚乙烯醇缩丁醛0.6-1、聚乳酸1-2、聚丙烯酸甲酯2-3、1,4-环己烷二甲醇1-3、钛酸钾1-2、二硫化二苯并噻唑0.6-1、方解石粉10-14、纳米碳粉2-3、过硫酸钠0.7-2、丙烯酸戊酯120-160、醋酸乙烯酯140-200、乳化剂OP-102-3、去离子水500-700、粘结助剂4-6，本发明的涂料耐水性能好，可长时间浸泡在水中，室内墙壁有污垢可用水冲刷，漆膜无损，无有害物质挥发，各原料复配，粘结性强，附着力强，漆膜坚固，经久耐用。

Description

一种多聚物外墙涂料
 
技术领域
    本发明主要涉及涂料领域，尤其涉及一种多聚物外墙涂料。
背景技术
    涂于物体表面能形成具有保护、装饰或特殊性能(如绝缘、防腐、标志等)的固态涂膜的一类液体或固体材料的总称，包括油(性)漆、水性漆、粉末涂料。漆是可流动的液体涂料，包括油(性)漆及水性漆。油漆是以有机溶剂为介质或高固体、无溶剂的油性漆。水性漆是可用水溶解或用水分散的涂料。涂料作为家庭装修的主材之一，在装饰装修中占的比例较大，购买涂料的合格与否直接影响到整体装修效果和居室的环境，有时甚至会对人体的健康产生极大的危害。目前随着各种各样涂料的产生，对涂料的品质要求也不断提高，而不断提高涂料质量对于建筑、生活都可以起到很大的帮助作用。
发明内容
本发明目的就是提供一种多聚物外墙涂料。
本发明是通过以下技术方案实现的：
一种多聚物外墙涂料，其特征在于它是由下述重量份的原料组成的：
丙烯酸十三氟辛酯2-4、2，2-二溴-3-氰基丙酰胺1-2、聚乙烯醇缩丁醛0.6-1、聚乳酸1-2、聚丙烯酸甲酯2-3、1,4-环己烷二甲醇1-3、钛酸钾1-2、二硫化二苯并噻唑0.6-1、方解石粉10-14、纳米碳粉2-3、过硫酸钠0.7-2、丙烯酸戊酯120-160、醋酸乙烯酯140-200、乳化剂OP-10 2-3、去离子水500-700、粘结助剂4-6；
所述的粘结助剂是由下述重量份的各原料组成的：
醋丙乳液30-37、紫檀木微粉1-2、甲基丙烯酸羟乙酯2-3、壬基酚聚氧乙烯醚2-3、偏硅酸钠1-2、硅胶1-2、脂肪醇聚氧乙烯醚硫酸铵0.8-1、去离子水10-15；
将硅胶、壬基酚聚氧乙烯醚混合，搅拌均匀后加入甲基丙烯酸羟乙酯，在60-70℃下搅拌混合3-5分钟，加入到醋丙乳液中，搅拌均匀；
将偏硅酸钠与紫檀木微粉混合加入到去离子水中，升高温度为50-60℃，加入脂肪醇聚氧乙烯醚硫酸铵，搅拌均匀；
将上述处理后的各原料与剩余各原料混合，300-400转/分搅拌分散10-20分钟，即得所述粘结助剂。
一种多聚物外墙涂料的制备方法，其特征在于包括以下步骤：
（1）取过硫酸钠加入上述去离子水重量的10-15%，搅拌溶解，得引发剂溶液；
（2）取乳化剂op-10，加入剩余去离子水重量的70-80%，在50-60℃下保温搅拌10-20分钟，冷却至常温，得预乳液；
（3）取上述丙烯酸戊酯重量的30-40%、醋酸乙烯酯重量的40-50%、丙烯酸十三氟辛酯混合，加入上述预乳液，在60-65℃下搅拌混合30-35分钟，升高温度为70-75℃，加入上述引发剂溶液，待乳液呈蓝相，保温60-70分钟，得种子乳液；
（4）将剩余的丙烯酸戊酯、醋酸乙烯酯混合，在65-70℃下保温搅拌20-30分钟，得混合单体；
（5）取钛酸钾，加入剩余去离子水重量的20-30%，搅拌均匀，加入1,4-环己烷二甲醇，在50-60℃下保温搅拌3-10分钟，冷却至常温，得液a；
（6）在上述种子乳液中加滴加混合单体，滴加时间为90-120分钟，滴加完毕后，加入上述液a，搅拌均匀，在80-90℃下保温50-60分钟，冷却，用200-250目筛网过滤出料；
（7）将上述步骤（6）得到的物料与剩余各原料混合，800-1200转/分搅拌分散20-30分钟，即得所述多聚物外墙涂料。
本发明的优点是：
    本发明的涂料耐水性能好，可长时间浸泡在水中，室内墙壁有污垢可用水冲刷，漆膜无损，无有害物质挥发，各原料复配，粘结性强，附着力强，漆膜坚固，经久耐用。本发明的粘结助剂中加入的壬基酚聚氧乙烯醚具有保温隔热效果，醋丙乳液与紫檀木微粉、甲基丙烯酸羟乙酯、偏硅酸钠、硅胶混合改性可以有效提高粘结强度，增强涂层表面抗性和稳定性。
具体实施方式
实施例1
一种多聚物外墙涂料，其特征在于它是由下述重量份的原料组成的：
丙烯酸十三氟辛酯2、2，2-二溴-3-氰基丙酰胺2、聚乙烯醇缩丁醛0.6、聚乳酸2、聚丙烯酸甲酯2、1,4-环己烷二甲醇3、钛酸钾2、二硫化二苯并噻唑0.6、方解石粉14、纳米碳粉2-3、过硫酸钠0.7、丙烯酸戊酯160、醋酸乙烯酯200、乳化剂OP-10 2-3、去离子水700、粘结助剂4；
所述的粘结助剂是由下述重量份的各原料组成的：
醋丙乳液37、紫檀木微粉1、甲基丙烯酸羟乙酯2、壬基酚聚氧乙烯醚3、偏硅酸钠1、硅胶2、脂肪醇聚氧乙烯醚硫酸铵0.8、去离子水15；
将硅胶、壬基酚聚氧乙烯醚混合，搅拌均匀后加入甲基丙烯酸羟乙酯，在70℃下搅拌混合5分钟，加入到醋丙乳液中，搅拌均匀；
将偏硅酸钠与紫檀木微粉混合加入到去离子水中，升高温度为50℃，加入脂肪醇聚氧乙烯醚硫酸铵，搅拌均匀；
将上述处理后的各原料与剩余各原料混合，400转/分搅拌分散20分钟，即得所述粘结助剂。
一种如权利要求1所述的多聚物外墙涂料的制备方法，其特征在于包括以下步骤：
（1）取过硫酸钠加入上述去离子水重量的15%，搅拌溶解，得引发剂溶液；
（2）取乳化剂op-10，加入剩余去离子水重量的80%，在60℃下保温搅拌20分钟，冷却至常温，得预乳液；
（3）取上述丙烯酸戊酯重量的40%、醋酸乙烯酯重量的50%、丙烯酸十三氟辛酯混合，加入上述预乳液，在65℃下搅拌混合35分钟，升高温度为75℃，加入上述引发剂溶液，待乳液呈蓝相，保温70分钟，得种子乳液；
（4）将剩余的丙烯酸戊酯、醋酸乙烯酯混合，在70℃下保温搅拌30分钟，得混合单体；
（5）取钛酸钾，加入剩余去离子水重量的30%，搅拌均匀，加入1,4-环己烷二甲醇，在60℃下保温搅拌10分钟，冷却至常温，得液a；
（6）在上述种子乳液中加滴加混合单体，滴加时间为120分钟，滴加完毕后，加入上述液a，搅拌均匀，在90℃下保温60分钟，冷却，用250目筛网过滤出料；
（7）将上述步骤（6）得到的物料与剩余各原料混合，1200转/分搅拌分散30分钟，即得所述多聚物外墙涂料。
性能测试：
延伸率：≥300％ ；
不透水性：0.3MPa( 一个小时不透水)。

Claims (2)

1.一种多聚物外墙涂料，其特征在于它是由下述重量份的原料组成的：
丙烯酸十三氟辛酯2-4、2，2-二溴-3-氰基丙酰胺1-2、聚乙烯醇缩丁醛0.6-1、聚乳酸1-2、聚丙烯酸甲酯2-3、1,4-环己烷二甲醇1-3、钛酸钾1-2、二硫化二苯并噻唑0.6-1、方解石粉10-14、纳米碳粉2-3、过硫酸钠0.7-2、丙烯酸戊酯120-160、醋酸乙烯酯140-200、乳化剂OP-10 2-3、去离子水500-700、粘结助剂4-6；
所述的粘结助剂是由下述重量份的各原料组成的：
醋丙乳液30-37、紫檀木微粉1-2、甲基丙烯酸羟乙酯2-3、壬基酚聚氧乙烯醚2-3、偏硅酸钠1-2、硅胶1-2、脂肪醇聚氧乙烯醚硫酸铵0.8-1、去离子水10-15；
将硅胶、壬基酚聚氧乙烯醚混合，搅拌均匀后加入甲基丙烯酸羟乙酯，在60-70℃下搅拌混合3-5分钟，加入到醋丙乳液中，搅拌均匀；
将偏硅酸钠与紫檀木微粉混合加入到去离子水中，升高温度为50-60℃，加入脂肪醇聚氧乙烯醚硫酸铵，搅拌均匀；
将上述处理后的各原料与剩余各原料混合，300-400转/分搅拌分散10-20分钟，即得所述粘结助剂。
2.一种如权利要求1所述的多聚物外墙涂料的制备方法，其特征在于包括以下步骤：
（1）取过硫酸钠加入上述去离子水重量的10-15%，搅拌溶解，得引发剂溶液；
（2）取乳化剂op-10，加入剩余去离子水重量的70-80%，在50-60℃下保温搅拌10-20分钟，冷却至常温，得预乳液；
（3）取上述丙烯酸戊酯重量的30-40%、醋酸乙烯酯重量的40-50%、丙烯酸十三氟辛酯混合，加入上述预乳液，在60-65℃下搅拌混合30-35分钟，升高温度为70-75℃，加入上述引发剂溶液，待乳液呈蓝相，保温60-70分钟，得种子乳液；
（4）将剩余的丙烯酸戊酯、醋酸乙烯酯混合，在65-70℃下保温搅拌20-30分钟，得混合单体；
（5）取钛酸钾，加入剩余去离子水重量的20-30%，搅拌均匀，加入1,4-环己烷二甲醇，在50-60℃下保温搅拌3-10分钟，冷却至常温，得液a；
（6）在上述种子乳液中加滴加混合单体，滴加时间为90-120分钟，滴加完毕后，加入上述液a，搅拌均匀，在80-90℃下保温50-60分钟，冷却，用200-250目筛网过滤出料；
（7）将上述步骤（6）得到的物料与剩余各原料混合，800-1200转/分搅拌分散20-30分钟，即得所述多聚物外墙涂料。
CN201410448342.XA 2014-09-04 2014-09-04 一种多聚物外墙涂料 Pending CN104263125A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410448342.XA CN104263125A (zh) 2014-09-04 2014-09-04 一种多聚物外墙涂料

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410448342.XA CN104263125A (zh) 2014-09-04 2014-09-04 一种多聚物外墙涂料

Publications (1)

Publication Number Publication Date
CN104263125A true CN104263125A (zh) 2015-01-07

Family

ID=52154716

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410448342.XA Pending CN104263125A (zh) 2014-09-04 2014-09-04 一种多聚物外墙涂料

Country Status (1)

Country Link
CN (1) CN104263125A (zh)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105733378A (zh) * 2016-04-23 2016-07-06 陈斌 一种醋丙共聚乳胶漆及其制备方法
CN106280730A (zh) * 2016-08-14 2017-01-04 安庆市沁之源电器有限公司 一种燃气灶抗菌涂料及其制备方法
EP3156222A1 (en) * 2015-10-16 2017-04-19 Tarkett GDL Decorative multi-layer surface covering comprising polyvinyl butyral
WO2017064260A1 (en) * 2015-10-16 2017-04-20 Tarkett Gdl Decorative multi-layer surface covering comprising polyvinyl butyral

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103896536A (zh) * 2012-12-25 2014-07-02 深圳市嘉达高科产业发展有限公司 一种建筑外墙保温隔热粉末涂料及其制备方法

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103896536A (zh) * 2012-12-25 2014-07-02 深圳市嘉达高科产业发展有限公司 一种建筑外墙保温隔热粉末涂料及其制备方法

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3156222A1 (en) * 2015-10-16 2017-04-19 Tarkett GDL Decorative multi-layer surface covering comprising polyvinyl butyral
WO2017064260A1 (en) * 2015-10-16 2017-04-20 Tarkett Gdl Decorative multi-layer surface covering comprising polyvinyl butyral
CN108367535A (zh) * 2015-10-16 2018-08-03 塔吉特Gdl公司 包含聚乙烯醇缩丁醛的装饰性多层表面覆盖物
CN105733378A (zh) * 2016-04-23 2016-07-06 陈斌 一种醋丙共聚乳胶漆及其制备方法
CN106280730A (zh) * 2016-08-14 2017-01-04 安庆市沁之源电器有限公司 一种燃气灶抗菌涂料及其制备方法

Similar Documents

Publication Publication Date Title
CN104263125A (zh) 一种多聚物外墙涂料
CN104263122A (zh) 一种稳定涂料
CN104231695A (zh) 一种绿色抗菌内墙涂料
CN104263127A (zh) 一种外墙保温抗裂涂料
CN104277620A (zh) 一种环保墙面涂料
CN104263036A (zh) 一种杀菌型有机硅涂料
CN104277619A (zh) 一种憎水自洁涂料
CN104277621A (zh) 一种建筑防水涂料
CN104231692A (zh) 一种复合有机硅涂料
CN104231766A (zh) 一种吸音隔热涂料
CN104263139A (zh) 一种纤维增强涂料
CN104263138A (zh) 一种柔软性抗菌涂料
CN104263121A (zh) 一种聚醋酸乙烯乳胶漆
CN104263029A (zh) 一种墙体抗裂防水涂料
CN104312356A (zh) 一种耐高温抗老化涂料
CN104263031A (zh) 一种平整无气泡装饰涂料
CN104231770A (zh) 一种防火涂料
CN104356838A (zh) 一种高温型保温涂料
CN104231771A (zh) 一种轻质涂料
CN104263128A (zh) 一种树脂基涂料
CN104231828A (zh) 一种绿色天然抗菌涂料
CN104449122A (zh) 一种适用于湿度环境下的外墙涂料
CN104277507A (zh) 一种保温隔热涂料
CN104312358A (zh) 一种功能型内墙涂料
CN104356835A (zh) 一种高分子乳液涂料

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20150107