CN104263121A - 一种聚醋酸乙烯乳胶漆 - Google Patents

一种聚醋酸乙烯乳胶漆 Download PDF

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CN104263121A
CN104263121A CN201410445384.8A CN201410445384A CN104263121A CN 104263121 A CN104263121 A CN 104263121A CN 201410445384 A CN201410445384 A CN 201410445384A CN 104263121 A CN104263121 A CN 104263121A
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王和山
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Tianchang Kailin Chemical Co Ltd
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Abstract

本发明公开了一种聚醋酸乙烯乳胶漆，它是由下述重量份的原料组成的：醋酸乙烯乳液52-60、烟酸乙酯0.4-1、甲基丙烯酰胺1-2、乙二胺四亚甲基叉膦酸钠1-2、轻质碳酸钙30-37、硅灰石粉20-26、钼酸铵0.2-1、尿素1-2、羧乙基纤维素2-3、成膜助剂6-7、去离子水45-50；本发明的乳胶漆毒性小，不易燃，耐洗刷、耐水性、耐碱性好，使用安全且原料易得，遮盖力强，特别适用于室内墙面的涂装。

Description

一种聚醋酸乙烯乳胶漆
 
技术领域
    本发明主要涉及涂料领域，尤其涉及一种聚醋酸乙烯乳胶漆。
背景技术
以丙烯酸酯共聚乳液为代表的一大类合成树脂乳液涂料。乳胶漆是水分散性涂料，它是以合成树脂乳液为基料，填料经过研磨分散后加入各种助剂精制而成的涂料。乳胶漆具备了与传统墙面涂料不同的众多优点，如易于涂刷、干燥迅速、漆膜耐水、耐擦洗性好等；水溶性内墙乳胶漆无污染、无毒、无火灾隐患，易于涂刷、干燥迅速，漆膜耐水、耐擦洗性好，色彩柔和。水溶性内墙乳胶漆，以水作为分散介质，无有机溶剂性毒气体带来的环境污染问题，透气性好，避免了因涂膜内外温度压力差而导致的涂膜起泡弊病，适合未干透的新墙面涂装。
发明内容
本发明目的就是提供一种聚醋酸乙烯乳胶漆。
本发明是通过以下技术方案实现的：
一种聚醋酸乙烯乳胶漆，它是由下述重量份的原料组成的：
醋酸乙烯乳液52-60、烟酸乙酯0.4-1、甲基丙烯酰胺1-2、乙二胺四亚甲基叉膦酸钠1-2、轻质碳酸钙30-37、硅灰石粉20-26、钼酸铵0.2-1、尿素1-2、羧乙基纤维素2-3、成膜助剂6-7、去离子水45-50；
所述的成膜助剂是由下述重量份的原料组成的：
硅丙乳液20-30、醋酸乙烯酯3-5、乙氧基化烷基硫酸铵1-2、磷酸二氢铝2-3、过硫酸铵0.5-2、去离子水10-20；
将乙氧基化烷基硫酸铵加入到上述去离子水中，搅拌得预混液；
将醋酸乙烯酯加热到40-50℃，加入磷酸二氢铝，保温搅拌混合20-30分钟，加入到上述预混液中，200-300转/分搅拌分散3-5分钟，得分散液；
将过硫酸铵加入到硅丙乳液中，搅拌混合均匀后与上述分散液混合，充分球磨，即得所述成膜助剂。
一种聚醋酸乙烯乳胶漆的制备方法，包括以下步骤：
（1）将上述烟酸乙酯加入到尿素，在40-60℃下搅拌混合2-4分钟，搅拌均匀后加入甲基丙烯酰胺，搅拌至常温；
（2）将轻质碳酸钙、硅灰石粉与钼酸铵混合，加入到去离子水中，搅拌混合3-5分钟，加入羧乙基纤维素、乙二胺四亚甲基叉膦酸钠，300-400转/分搅拌分散4-6分钟；
（3）将上述处理后的各原料与剩余各原料混合，1500-1600转/分搅拌分散30-40分钟，即得所述乳胶漆。
本发明的优点是：
    本发明的乳胶漆毒性小，不易燃，耐洗刷、耐水性、耐碱性好，使用安全且原料易得，遮盖力强，特别适用于室内墙面的涂装。
具体实施方式
实施例1
一种聚醋酸乙烯乳胶漆，它是由下述重量份（公斤）的原料组成的：
醋酸乙烯乳液60、烟酸乙酯0.4、甲基丙烯酰胺1、乙二胺四亚甲基叉膦酸钠1、轻质碳酸钙37、硅灰石粉26、钼酸铵0.2、尿素2、羧乙基纤维素3、成膜助剂6、去离子水50；
所述的成膜助剂是由下述重量份的原料组成的：
硅丙乳液30、醋酸乙烯酯3、乙氧基化烷基硫酸铵1、磷酸二氢铝3、过硫酸铵0.5、去离子水20；
将乙氧基化烷基硫酸铵加入到上述去离子水中，搅拌得预混液；
将醋酸乙烯酯加热到50℃，加入磷酸二氢铝，保温搅拌混合30分钟，加入到上述预混液中，300转/分搅拌分散3分钟，得分散液；
将过硫酸铵加入到硅丙乳液中，搅拌混合均匀后与上述分散液混合，充分球磨，即得所述成膜助剂。
一种聚醋酸乙烯乳胶漆的制备方法，包括以下步骤：
（1）将上述烟酸乙酯加入到尿素，在60℃下搅拌混合2分钟，搅拌均匀后加入甲基丙烯酰胺，搅拌至常温；
（2）将轻质碳酸钙、硅灰石粉与钼酸铵混合，加入到去离子水中，搅拌混合3分钟，加入羧乙基纤维素、乙二胺四亚甲基叉膦酸钠，400转/分搅拌分散4分钟；
（3）将上述处理后的各原料与剩余各原料混合，1600转/分搅拌分散40分钟，即得所述乳胶漆。
性能测试：
漆膜外观平整、无硬块、手感好、光泽度好；
耐洗刷性试验：5000 次通过，漆膜无破损；
耐人工老化性试验：2000小时不起泡、不剥落、无裂纹；
耐水性：140h漆膜无破损；
耐碱性：120h漆膜无破损。

Claims (2)

1.一种聚醋酸乙烯乳胶漆，其特征在于它是由下述重量份的原料组成的：
醋酸乙烯乳液52-60、烟酸乙酯0.4-1、甲基丙烯酰胺1-2、乙二胺四亚甲基叉膦酸钠1-2、轻质碳酸钙30-37、硅灰石粉20-26、钼酸铵0.2-1、尿素1-2、羧乙基纤维素2-3、成膜助剂6-7、去离子水45-50；
所述的成膜助剂是由下述重量份的原料组成的：
硅丙乳液20-30、醋酸乙烯酯3-5、乙氧基化烷基硫酸铵1-2、磷酸二氢铝2-3、过硫酸铵0.5-2、去离子水10-20；
将乙氧基化烷基硫酸铵加入到上述去离子水中，搅拌得预混液；
将醋酸乙烯酯加热到40-50℃，加入磷酸二氢铝，保温搅拌混合20-30分钟，加入到上述预混液中，200-300转/分搅拌分散3-5分钟，得分散液；
将过硫酸铵加入到硅丙乳液中，搅拌混合均匀后与上述分散液混合，充分球磨，即得所述成膜助剂。
2.一种如权利要求1所述的聚醋酸乙烯乳胶漆的制备方法，其特征在于包括以下步骤：
（1）将上述烟酸乙酯加入到尿素，在40-60℃下搅拌混合2-4分钟，搅拌均匀后加入甲基丙烯酰胺，搅拌至常温；
（2）将轻质碳酸钙、硅灰石粉与钼酸铵混合，加入到去离子水中，搅拌混合3-5分钟，加入羧乙基纤维素、乙二胺四亚甲基叉膦酸钠，300-400转/分搅拌分散4-6分钟；
（3）将上述处理后的各原料与剩余各原料混合，1500-1600转/分搅拌分散30-40分钟，即得所述乳胶漆。
CN201410445384.8A 2014-09-03 2014-09-03 一种聚醋酸乙烯乳胶漆 Withdrawn CN104263121A (zh)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105936755A (zh) * 2016-05-26 2016-09-14 广西梧州龙鱼漆业有限公司 防潮乳胶漆
CN105968920A (zh) * 2016-05-26 2016-09-28 广西梧州龙鱼漆业有限公司 防潮乳胶漆制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101955856A (zh) * 2010-09-19 2011-01-26 张家港市塘桥镇春禾农业生产专业合作社 一种花卉清洗剂及其制备方法
CN102533032A (zh) * 2010-12-10 2012-07-04 深圳市嘉达高科产业发展有限公司 一种室内湿度自动调节涂料
CN102690568A (zh) * 2012-06-20 2012-09-26 海安县国力化工有限公司 一种聚醋酸乙烯乳胶漆
CN103031551A (zh) * 2012-12-18 2013-04-10 安徽六方重联机械股份有限公司 一种含有乙二胺四亚甲基叉膦酸钠的金属表面硅烷处理剂及其制备方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101955856A (zh) * 2010-09-19 2011-01-26 张家港市塘桥镇春禾农业生产专业合作社 一种花卉清洗剂及其制备方法
CN102533032A (zh) * 2010-12-10 2012-07-04 深圳市嘉达高科产业发展有限公司 一种室内湿度自动调节涂料
CN102690568A (zh) * 2012-06-20 2012-09-26 海安县国力化工有限公司 一种聚醋酸乙烯乳胶漆
CN103031551A (zh) * 2012-12-18 2013-04-10 安徽六方重联机械股份有限公司 一种含有乙二胺四亚甲基叉膦酸钠的金属表面硅烷处理剂及其制备方法

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105936755A (zh) * 2016-05-26 2016-09-14 广西梧州龙鱼漆业有限公司 防潮乳胶漆
CN105968920A (zh) * 2016-05-26 2016-09-28 广西梧州龙鱼漆业有限公司 防潮乳胶漆制备方法

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Application publication date: 20150107