CN104309185B - The preparation method of red mud-expanded perlite multiaspect illuminated light wall material - Google Patents

The preparation method of red mud-expanded perlite multiaspect illuminated light wall material Download PDF

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Publication number
CN104309185B
CN104309185B CN201410535330.0A CN201410535330A CN104309185B CN 104309185 B CN104309185 B CN 104309185B CN 201410535330 A CN201410535330 A CN 201410535330A CN 104309185 B CN104309185 B CN 104309185B
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China
Prior art keywords
raw material
red mud
preparation
expanded perlite
light wall
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Expired - Fee Related
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CN201410535330.0A
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Chinese (zh)
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CN104309185A (en
Inventor
唐竹兴
刘坤
刘敏
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Shandong University of Technology
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Shandong University of Technology
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/24—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B30/00—Compositions for artificial stone, not containing binders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
    • B32B2264/10—Inorganic particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/10—Properties of the layers or laminate having particular acoustical properties
    • B32B2307/102—Insulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/304—Insulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/56—Damping, energy absorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2607/00—Walls, panels

Abstract

The preparation method of red mud expanded perlite multiaspect illuminated light wall material, it is characterised in that: red mud expanded perlite multiaspect illuminated light wall material is made up of color coat (1), transition zone (2), heat-insulation layer (3) three part.Red mud expanded perlite multiaspect illuminated light wall material prepared by the present invention have employed once-firing, transition zone is added in the middle of color coat with heat-insulation layer, efficiently solve color coat excessive with the hole diameter that insulation interlayer causes owing to material melting point is inconsistent, the shortcoming that bond strength and thermal shock resistance reduce, it is prepared as monochrome by adding pottery toner, the colors such as tertiary colour and the interior and exterior decoration material of pattern, without additional decoration, production technology is simple, low cost, building heat preservation is effective, energy-conservation, environmental protection, the red mud expanded perlite multiaspect illuminated light wall material collection decoration produced, insulation, heat insulation, sound insulation and shockproof etc. multi-functional.

Description

The preparation method of red mud-expanded perlite multiaspect illuminated light wall material
Technical field
The present invention relates to the preparation method of red mud-expanded perlite multiaspect illuminated light wall material, belong to ceramic standby Technical field.
Background technology
Red mud-expanded perlite multiaspect illuminated light wall material collection decoration, heat insulation integrated Novel light wall body material Material, is to use colored microcrystalline glass decorating wall material, is that one has decoration, insulation, waterproof, sound insulation and the function such as shockproof The novel wall material of integration.Construction material typically uses structural clay tile, cement hollow building blocks and air entrained concrete at present Building blocks etc., these construction material heat-insulating properties and decoration poor-performing, be applied to during inner, external wall need additionally to add tiling or wall Paper, is the building and ornament materials that manufacturing cost is high.
Summary of the invention
It is an object of the invention to provide red mud-expanded perlite multiaspect that a kind of serviceability is excellent, production cost is low color The preparation method of decorations light wall material, its technical scheme is:
The preparation method of red mud-expanded perlite multiaspect illuminated light wall material, red mud-expanded perlite multiaspect illuminated Light wall material is made up of color coat (1), transition zone (2), heat-insulation layer (3) three part, and concrete grammar includes following step Rapid:
A. the preparation of color coat (1) raw material: by long to clay, quartz sand, Borax, zircon sand, zinc oxide, albite, potassium The Ceramic Materials such as stone, lithium Anhydrite, stannum oxide, brium carbonate, by chemical composition be: SiO2It is 12 ~ 32%, B2O3It is 10 ~ 25%, Al2O3 It is 3 ~ 6%, K2O is 6 ~ 11%, Li2O is 1 ~ 6%, Na2O is 12 ~ 1%, and ZnO is 11 ~ 21%, and BaO is 6 ~ 11%, TiO2It is 4 ~ 11%, SnO is 0 ~ 5%, ZrO2Be 0 ~ 6% dispensing and frit raw material made in fine grinding, then by frit raw material with weight ratio be 50 ~ 95% with pottery Pigment weight ratio is the ratio uniform mixing of 5 ~ 50%, makes, 850 ~ 1000 DEG C of melt process, the colour that granularity is 1 ~ 3mm and melts Block granule；
B. the preparation of transition zone (2) raw material: be 50 ~ 95% and clay with weight ratio by the frit raw material of preparation in step (a) 5 ~ 50% are uniformly mixed and made into transition zone raw material；
C. the preparation of heat-insulation layer (3) raw material: red mud is added water and the waterglass of 5 ~ 20% that weight ratio is 30 ~ 60% Make red mud mud, then be 10 ~ 40% uniformly to mix red mud mud and expanded perlite granule with volume ratio, make after drying Heat-insulation layer raw material；
D. the preparation of red mud-expanded perlite multiaspect illuminated light wall material: left and right initially with load bearing board (4), Forward and backward and bottom surface surrounds upper opening of cube and holds burning mould, and coats releasing agent, then by the coloured silk of preparation in step (a) Color frit granule (1) uniformly plain cloth is in holding the bottom burning mould, and separates with external partition (5) and be evenly distributed in the inner side holding burning mould Face, thickness is 1 ~ 10mm, and profile height is 25 ~ 35mm, then with internal partition (6) by the transition zone raw material of preparation in step (b) Being evenly distributed in the inner side of colored frit granule, thickness is 1 ~ 5mm, the uniform plain cloth of heat-insulation layer raw material then step (c) prepared Inside transition zone raw material, make the gross thickness vertically holding the inner plane direction, bottom burning mould reach 25 ~ 35mm, then take out four The external partition (5) in week, internal partition (6), be incubated 1 ~ 5 hour at a temperature of 800 ~ 1100 DEG C, brilliant at a temperature of 400 ~ 750 DEG C Change, annealing 5 ~ 15 hours, cooled, come out of the stove, cut and surface grinding makes red mud-expanded perlite multiaspect illuminated light weight wall Body material.
Compared with prior art, its advantage is the present invention:
1, technique is simple, and the red mud of production-expanded perlite multiaspect illuminated light wall material has stronger decoration, anti- Water, insulation, heat insulation, sound insulation and antiknock quality；
2, red mud-expanded perlite multiaspect illuminated light wall material can by add pottery toner be prepared as monochrome, The colors such as tertiary colour and the interior and exterior decoration material of pattern；
3, in the middle of color coat with heat-insulation layer, add transition zone, efficiently solve color coat with insulation interlayer owing to material melts The shortcoming that the inconsistent hole diameter caused is excessive for point, bond strength and thermal shock resistance reduce；
4, due to the fact that and have employed once-firing, and without additional decoration, cost, Er Qiejian are greatly reduced Build high insulating effect, energy-saving and environmental protection.
Accompanying drawing explanation
Fig. 1 is holding burning mould and assembling structural representation of red mud-expanded perlite multiaspect illuminated light wall material；
1, color coat；2, transition zone；3, heat-insulation layer；4, burning version is held；5, external partition；6, internal partition.
Detailed description of the invention
Embodiment 1
A. the preparation of color coat (1) raw material: by clay, quartz sand, Borax, zircon sand, zinc oxide, albite, potassium feldspar, The Ceramic Materials such as lithium Anhydrite, stannum oxide, brium carbonate, by chemical composition be: SiO2It is 32%, B2O3It is 25%, Al2O3It is 3%, K2O It is 6%, Li2O is 1%, Na2O is 12%, and ZnO is 11%, and BaO is 6%, TiO2It is 4% dispensing and frit raw material is made in fine grinding, then will be molten Block raw material is 50% to mix with the ratio uniform that ceramic pigment weight ratio is 50%, at 850 DEG C of melt process corning with weight ratio Degree is the colored frit granule of 1mm；
B. the preparation of transition zone (2) raw material: by the frit raw material of preparation in step (a) with weight ratio be 50% with clay 50% Uniformly it is mixed and made into transition zone raw material；
C. the preparation of heat-insulation layer (3) raw material: red mud is added water that weight ratio is 30% and 20% waterglass make Red mud mud, then be 10% uniformly to mix red mud mud and expanded perlite granule with volume ratio, make heat-insulation layer after drying former Material；
D. the preparation of red mud-expanded perlite multiaspect illuminated light wall material: left and right initially with load bearing board (4), Forward and backward and bottom surface surrounds upper opening of cube and holds burning mould, and coats releasing agent, then by the coloured silk of preparation in step (a) Color frit granule (1) uniformly plain cloth is in holding the bottom burning mould, and separates with external partition (5) and be evenly distributed in the inner side holding burning mould Face, thickness is 1mm, and profile height is 25mm, then with internal partition (6) by the uniform cloth of transition zone raw material of preparation in step (b) In the inner side of colored frit granule, thickness is 1mm, and the uniform plain cloth of heat-insulation layer raw material then step (c) prepared is in transition zone Inside raw material, make the gross thickness vertically holding the inner plane direction, bottom burning mould reach 25mm, then take out the external partition of surrounding (5), internal partition (6), at a temperature of 800 DEG C be incubated 1 hour, at a temperature of 400 DEG C crystallization, annealing 5 hours, cooled, Come out of the stove, cut and surface grinding makes red mud-expanded perlite multiaspect illuminated light wall material.
The purity of the proportion material used by experiment is technical pure.
Embodiment 2
A. the preparation of color coat (1) raw material: by long to clay, quartz sand, Borax, zircon sand, zinc oxide, albite, potassium The Ceramic Materials such as stone, lithium Anhydrite, stannum oxide, brium carbonate, by chemical composition be: SiO2It is 22%, B2O3It is 17.5%, Al2O3For 4.5%, K2O is 8.5%, Li2O is 3.5%, Na2O is 6.5%, and ZnO is 16%, and BaO is 8.5%, TiO2Being 7.5%, SnO is 2.5%, ZrO2Be 3% dispensing and frit raw material made in fine grinding, then by frit raw material with weight ratio be 72% with ceramic pigment weight ratio for 28% Ratio uniform mixing, make, 920 DEG C of melt process, the colored frit granule that granularity is 2mm；
B. the preparation of transition zone (2) raw material: by the frit raw material of preparation in step (a) with weight ratio be 75% with clay 25% Uniformly it is mixed and made into transition zone raw material；
C. the preparation of heat-insulation layer (3) raw material: red mud is added water that weight ratio is 45% and 13% waterglass make Red mud mud, then be 25% uniformly to mix red mud mud and expanded perlite granule with volume ratio, make heat-insulation layer after drying former Material；
D. the preparation of red mud-expanded perlite multiaspect illuminated light wall material: left and right initially with load bearing board (4), Forward and backward and bottom surface surrounds upper opening of cube and holds burning mould, and coats releasing agent, then by the coloured silk of preparation in step (a) Color frit granule (1) uniformly plain cloth is in holding the bottom burning mould, and separates with external partition (5) and be evenly distributed in the inner side holding burning mould Face, thickness is 5mm, and profile height is 30mm, then with internal partition (6) by the uniform cloth of transition zone raw material of preparation in step (b) In the inner side of colored frit granule, thickness is 3mm, and the uniform plain cloth of heat-insulation layer raw material then step (c) prepared is in transition zone Inside raw material, make the gross thickness vertically holding the inner plane direction, bottom burning mould reach 30mm, then take out the external partition of surrounding (5), internal partition (6), at a temperature of 950 DEG C be incubated 3 hours, at a temperature of 600 DEG C crystallization, annealing 10 hours, cooled, Come out of the stove, cut and surface grinding makes red mud-expanded perlite multiaspect illuminated light wall material.
The purity of the proportion material used by experiment is technical pure.
Embodiment 3
A. the preparation of color coat (1) raw material: by long to clay, quartz sand, Borax, zircon sand, zinc oxide, albite, potassium The Ceramic Materials such as stone, lithium Anhydrite, stannum oxide, brium carbonate, by chemical composition be: SiO2It is 12%, B2O3It is 10%, Al2O3It is 6%, K2O is 11%, Li2O is 6%, Na2O is 1%, and ZnO is 21%, and BaO is 11%, TiO2Being 11%, SnO is 5%, ZrO2It is that 6% dispensing is the thinnest It is milled into frit raw material, then is 95% to mix frit raw material with the ratio uniform that ceramic pigment weight ratio is 5% with weight ratio, 1000 DEG C of melt process make the colored frit granule that granularity is 3mm；
B. the preparation of transition zone (2) raw material: by the frit raw material of preparation in step (a) with weight ratio be 95% with clay 5% Uniformly it is mixed and made into transition zone raw material；
C. the preparation of heat-insulation layer (3) raw material: red mud is added water that weight ratio is 60% and 5% waterglass make red Mud mud, then be 40% uniformly to mix red mud mud and expanded perlite granule with volume ratio, make heat-insulation layer after drying former Material；
D. the preparation of red mud-expanded perlite multiaspect illuminated light wall material: left and right initially with load bearing board (4), Forward and backward and bottom surface surrounds upper opening of cube and holds burning mould, and coats releasing agent, then by the coloured silk of preparation in step (a) Color frit granule (1) uniformly plain cloth is in holding the bottom burning mould, and separates with external partition (5) and be evenly distributed in the inner side holding burning mould Face, thickness is 10mm, and profile height is 35mm, then with internal partition (6) by the uniform cloth of transition zone raw material of preparation in step (b) In the inner side of colored frit granule, thickness is 5mm, and the uniform plain cloth of heat-insulation layer raw material then step (c) prepared is in transition zone Inside raw material, make the gross thickness vertically holding the inner plane direction, bottom burning mould reach 35mm, then take out the external partition of surrounding (5), internal partition (6), at a temperature of 1100 DEG C be incubated 5 hours, at a temperature of 750 DEG C crystallization, annealing 15 hours, through cold But, come out of the stove, cut and surface grinding makes red mud-expanded perlite multiaspect illuminated light wall material.
The purity of the proportion material used by experiment is technical pure.

Claims (1)

1. the preparation method of red mud-expanded perlite multiaspect illuminated light wall material, it is characterised in that: red mud-expanded pearlite Rock multiaspect illuminated light wall material is made up of color coat (1), transition zone (2), heat-insulation layer (3) three part, concrete grammar Comprise the following steps:
(a). the preparation of color coat (1) raw material: by clay, quartz sand, Borax, zircon sand, zinc oxide, albite, potassium feldspar, Lithium Anhydrite, stannum oxide, brium carbonate, by chemical composition be: SiO2It is 12 ~ 32%, B2O3It is 10 ~ 25%, Al2O3It is 3 ~ 6%, K2O is 6 ~ 11%, Li2O is 1 ~ 6%, Na2O is 1 ~ 12%, and ZnO is 11 ~ 21%, and BaO is 6 ~ 11%, TiO2Being 4 ~ 11%, SnO is 0 ~ 5%, ZrO2 Be 0 ~ 6% dispensing and frit raw material made in fine grinding, then by frit raw material with percentage by weight be 50 ~ 95% with ceramic pigment weight hundred Proportion by subtraction is the ratio uniform mixing of 5 ~ 50%, makes, 850 ~ 1000 DEG C of melt process, the colored frit granule that granularity is 1 ~ 3mm；
(b). the preparation of transition zone (2) raw material: be 50 ~ 95% with viscous with percentage by weight by the frit raw material of preparation in step (a) Soil 5 ~ 50% is uniformly mixed and made into transition zone raw material；
(c). the preparation of heat-insulation layer (3) raw material: red mud is added water and the water glass of 5 ~ 20% that percentage by weight is 30 ~ 60% Glass makes red mud mud, then is 10 ~ 40% uniformly to mix red mud mud and expanded perlite granule with percent by volume, dries After make heat-insulation layer raw material；
(d). the preparation of red mud-expanded perlite multiaspect illuminated light wall material: left and right, front initially with load bearing board (4), Rear and bottom surface surrounds upper opening of cube and holds burning mould, and coats releasing agent, is then melted by the colour of preparation in step (a) The uniform plain cloth of block granule in hold burn mould bottom, and separate with external partition (5) be evenly distributed in hold burning mould medial surface, thickness Being 1 ~ 10mm, profile height is 25 ~ 35mm, then is evenly distributed in by the transition zone raw material of preparation in step (b) with internal partition (6) The inner side of colored frit granule, thickness is 1 ~ 5mm, and the uniform plain cloth of heat-insulation layer raw material then step (c) prepared is in transition zone Inside raw material, the gross thickness making vertically to hold the inner plane direction, bottom burning mould reaches 25 ~ 35mm, then take out surrounding outer every Plate (5), internal partition (6), be incubated 1 ~ 5 hour at a temperature of 800 ~ 1100 DEG C, crystallization, annealing 5 at a temperature of 400 ~ 750 DEG C ~ 15 hours, cooled, come out of the stove, cut and surface grinding makes red mud-expanded perlite multiaspect illuminated light wall material.
CN201410535330.0A 2014-10-13 2014-10-13 The preparation method of red mud-expanded perlite multiaspect illuminated light wall material Expired - Fee Related CN104309185B (en)

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CN105967654A (en) * 2016-05-17 2016-09-28 岑溪市新建球陶瓷有限公司 Preparation method of thermal-insulation external tile

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DE20302119U1 (en) * 2003-02-11 2003-07-03 Saint Gobain Isover G & H Ag Double-skin partition with a mineral wool filling
CN102875112A (en) * 2012-09-15 2013-01-16 汉寿县永兴砖厂 Sludge poured colorful building board
CN103669773B (en) * 2013-11-22 2016-03-02 青岛文创科技有限公司 A kind of heat preservation energy-saving composite material outer wall decorative wallboard
CN103641437A (en) * 2013-11-25 2014-03-19 大连创达技术交易市场有限公司 Preparation method of composite heat insulation material

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